Search Documents

By Abb Raymond

Finely processed industrial minerals in "powdered" form have long been utilized by the plastics, paint, rubber, paper, ceramics, and adhesives industries as fillers, extenders, coatings and special additives. These minerals, primarily calcium carbonate, talc, kaolin, titanium dioxide, and the like, have provided economic, uniform and consistent base materials which have, in turn, been used by the referenced industries to manufacture quality products. The focus of this paper will be the development of equipment and systems at ABB Raymond for the dry processing of such non-metallic minerals in order to meet what have become increasingly stringent requirements of the producers of these minerals. Changes in these requirements seem to have been accelerating rapidly during the last ten years, and it is expected this process will continue into the 1990's.

Jan 1, 1990

By B. T. Darnton

Gravity concentration at the Pegasus Gold Montana Tunnels Mine was initiated in late June, 1991 with the commissioning of a coarse gold scalping circuit that processes a small portion of the ball mill circulating load. The primary objective for the circuit was to reduce the risk of gold particles advancing to flotation that are too coarse to float. The secondary objective was to enhance overall gold recovery and payable gold ounces in a cost effective manner. The gravity circuit has proven itself to be a major success. The above mentioned goals have been achieved, and they have been maintained at record throughput rates that are 30% higher than when the circuit was commissioned. A number of modifications and improvements were made over the last three years which allowed the gravity circuit to keep pace with the higher tonnage, these are discussed in detail in the body of this paper. The overall approach to gravity concentration at Montana Tunnels has always been to optimize production rather than maximize the gold ounces produced. This philosophy has now yielded a circuit expansion and relocation project which will allow for an estimated 50% increase in gravity gold production, while reducing the overall unit costs of production significantly. This paper will review historical gravity circuit performance, improvements, and the current relocation and expansion project.

Jan 1, 1995

By E. Yigit

Hydrometallurgical production of zinc from concentrates is generally carried out by H2SO4 leaching. For the smooth operation of this process, some harmful components must be removed from the leach solution before the electrolysis stage; MgO is one of these compounds. Zinc concentrate samples from the Mount Isa mines were used in leaching tests. Leaching tests with an aqueous solution of H2SO4 and SO2 gas were carried out at various temperatures, pH levels and leaching durations. While duration and the pH value of the solution were effective parameters in H2SO4 leaching, temperature and pH were more effective in SO2 leaching for the removal of MgCO3 and CaCO3. Removal of MgCO3 and CaCO3 was generally achieved at low pH values. The results show that SO2 gas can be a good alternative to sulfuric acid in the leaching of MgCO3 and CaCO3

Jan 1, 2010

By Dan Eyde

Low levels of thallium were detected in the mine water drainages, and process water discharges of western mining and smelting operations. This required remediation under state regulatory standards, which allow discharges of no more than .0017 ppm thallium in mine water discharges. Influent streams containing thallium can be mitigated to state discharge standards after a single pass through the series of fluidized upflow columns. Test work to determine the optimal flow rates used pilot scale systems at two separate locations treating 5 - 25 gpm of effluent. The test system at the gold mine mimics the full-scale system, which will be based on the existing upflow carbon tanks that have been converted to zeolite columns. The system installed at ASARCO's East Helena smelter has a far more complex influent stream with a high loading of competing cations. Nevertheless the columns filled with CABSORB® are successfully mitigating the thallium contamination. CABSORB® ZS500RW is a product based on the sodium analog of the zeolite mineral chabazite named herschelite.

Jan 1, 1998

By Robert A. Blake

Introduction Sulfide copper, zinc and iron concentrates are recovered in the 5000 ton per day flotation plant operated by Cities Service Company at Copperhill, Tennessee. The heavy-sulphide ore is first ground to 50 pct. minus 200 mesh and a bulk concentrate floated. The bulk concentrate, over 60 pct. of the ore weight, is reground to 72 pct. minus 200 mesh and then treated in a selective flotation circuit to recover copper and zinc concentrates. The tailing of selective float is the iron sulphide material source for the manufacture of sulfuric acid and iron sinter. The valuable minerals in the ore are chalcopyrite, marmatitic sphalerite, pyrite, and pyrrhotite. A typical mineralogical analysis will be found in table 1. A typical material flowsheet will be found in figure 1. Shown in the flowsheet are a scavenger float on the bulk rougher tailing and a copper-talc separation unit. At times a lead-copper separation circuit has been run.

Jan 1, 1971

By C. Zhou, J. Srednicki

Electronic systems have been increasingly used in underground mines to improve mine safety. These electronic systems emit electromagnetic (EM) energy which can adversely impact the performance of other electronic systems nearby and thus should be characterized. Researchers at the National Institute for Occupational Safety and Health (NIOSH) characterized the magnetic fields emitted from devices that can potentially interfere with the performance of proximity detection systems (PDSs) and compared the emission levels of these devices to the susceptibility of PDSs. In this paper, we present our measurement results pertaining to this effort. Particularly, magnetic fields emitted from the different orientations of a powered air purifying respirator (PAPR) and two lite trackers are evaluated based on the RE101 protocol specified in the MIL-STD-461G standard. The results show that both devices emit strong magnetic fields which strongly depend on the orientation of the devices. At some frequencies, the maximum emission levels from the two devices exceed both the emission limit given in MIL-STD-461G and the maximum magnetic fields that a PDS can withstand without a failure. The results and findings in this paper can help the mining industry better understand electromagnetic interference (EMI) underground and provide critical scientific data that support mining-specific recommendations to address EMI-related challenges.

Feb 1, 2023

By Henrique D. G Turrer, Desmond Edifor, Marcello R. Cruz, Josue M. de S Junior, Darius Wonyen

A geometallurgical testing program was developed to anticipate ore behavior in the beneficiation plant and support production planning. Over 100 drill core samples from a major iron ore deposit were tested using bench-scale gravity and magnetic separation methods to assess variability in process responses. Results showed significant differences in key attributes such as iron grade, gangue content, slimes generation, and specific gravity, directly impacting concentrate grade, recoveries, and tailings quality. Correlation analysis and regression models were used to link feed properties to process outcomes, and a mass recovery estimation equation (Wrec) was developed for predictive use. The study proposes the integration of geometallurgical parameters—such as Fe, SiO2, Al2O3, LOI, ore type, size fractions, and slimes content—into the block model to support blending decisions and minimize operational risks. This work establishes a solid foundation for long-term mine-to-plant integration, with future phases aiming to expand testing and build a calibrated geometallurgical model.

Feb 22, 2026

By G. W. Phelps

This discussion deals with the geology o£ the Tennessee-Kentucky ball clay deposits; their mineralogy and chemistry; methods of finding, mining and refining; and makes observations on reserves of and future prospects for these clays. Ball clays appear in ceramic formulas for manufacture of vitreous china sanitary-ware, electrical porcelains, floor and wall tile, dinnerware and artwares(l). This type of clay is used for refractory (2) and abrasive products(3), and as a suspending agent for ceramic glazes(4), engobes(5) and porcelain enamel slips(6). Although some ball clay is imported, probably 85-90 percent of ball clay used in the USA(7) is obtained from deposits in Weakley, Henry and Carroll Counties in Tennessee(8), and in adjacent Graves County, Kentucky(9). The term "ball", as applied to clay, probably derives from former mining practice in England whereby conveniently-sized blocks of clay were cut from moist clay beds by spading(10), The expression "ball" has no other technological significance. ASTM(11) defines ball clay as "a secondary clay, commonly characterized by the presence of organic matter, high plasticity, high dry strength, long vitrification range, and a light color when fired." This, and similar(12) definitions, applies to English ball clays but is not satisfactory for many American ball clays. Geology of the Tennessee-Kentucky Ball Clay Deposits Figure 1 shows that most commercial clay areas of the eastern United States lie near the edge of the Coastal Plain; a skew-shaped configuration of its landward boundary outlines the Mississippi Embayment(13), Near the apex of this basin a broad plain, with a rolling, Bullied topography(14), dips gently westward from the Tennessee River to bluffs at the edge of the Mississippi River flood plain.

Jan 1, 1972

By Ananta L. Yennamani

Blast movement measurement (BMM) transmitters are a practical method to measure three-dimensional (3D) rock movement because of blasting. The BMM transmitters are activated, programmed and installed in specially designed drill holes prior to the blast and the BMM detector locates the transmitters after the blast. The BMM software then calculates and summarizes the 3D movement of each BMM transmitter ball. This information helps to redefine the ore and waste boundaries and enables improved ore and waste selection, resulting in a genuine step change in grade control. The BMM program was carried out at Newmont Mining Corp.?s Phoenix Mine, in northern Nevada near the town of Battle Mountain. The mine is in a historic mining district that contains gold, silver and copper. The geology of the pit consists of different formations made up of sandstone, siltstone, limestone, chert-pebble conglomerate, shale, skarn and quartzite, to name a few. Some of the rock is extremely hard and a powder factor of up to 0.5 kg/t (1 lb/st) is required to get adequate fragmentation to ensure sufficient throughput through the crusher and the mill. The result of using such a high powder factor translates into considerable blast movement and heave. This movement means that the ore/waste digging polygons estimated by the ore control engineer from sampling the initial blast holes will no longer be located in their original posi-tions. The purpose of this project was to test the measurement method and to see if locating the digging polygons in the broken muck pile and excavating to those polygons will improve grade control through the mill. Case studies (Zhang, 1994), (Taylor, 1995), (Gilbride, 1995), (Harris, 1997), (Taylor, 2003), Barrick Goldstrike (Gold-strike Mine, 2008), Ruby Hill Mine (Hilkewich, 2009), (Porcupine Mine, 2005) and (Aguirre, 2010) have shown that, by accounting for the blast movement, there is a potential to increase mineral recovery by as much as 25 percent for individual blasts for only a modest cost increase.

Jan 1, 2011

By P. Somasundaran, S. Venkatachalam, N. K. Khosla, K. Khosla

Froth flotation of alumina particles was studied by employing and hydrogen gas bubbles. The effect of current density was studied over a range of 0.1 to1.6 kA/m2. Compared to hydrogen, the use of oxygen bubbles at any given gas evolution rate resulted in a higher flotation recovery. The existence of an optimum current density, for each given particle size was indicated. Flotation at higher current densities resulted in better flotation kinetics, while flotation at lower current densities resulted in better Spas utilization.

Jan 1, 1996

By E. A. Domínguez

La Espingarda kaolin deposit was formed by ?in situ? alteration of volcaniclastic rhyolitic rocks belonging to Jurassic Marifil Formation. Three volcanic lithofacies were identified: porphyric biotitic ignimbrites (PBI), a coarse lithic ignimbrite (ILG), a fluidal intrusive rhyolite (RFI), all kaolinized in different degrees. The alteration covers an ellipsoidal area of ~20,000 m2, with its alteration decreasing downwards and disappearing at 8-12 m from the surface. The length to thickness ratio of alteration is 60:1. An erratic silicification was found as small zones (<3 m2) of quartz stockwork. The mineralogy is kaolinite + quartz + feldspars + Fe-oxyhydroxides ± halloysite ± illite and interstratified I/S, although the relative proportions change in each rock type. Due to coarse grain size and high quartz content, natural kaolin is unsuitable for slip cast ceramics, unless beneficiated. Washed ILG kaolin has the best rheological properties and behavior in casting and drying for its mineralogy, particle size distribution, thin texture and surface activity, as well as a certain fusibility and firing kinetics. PBI and RFI kaolins, due to finer texture, smaller grain size, lower surface activity, and higher halloysite amount, have worse slip viscosity and thixotropy that are due also to soluble salts. For the same reason, they have good casting and drying properties, but their purity brings about higher softening temperatures and water absorption. Several parameters are used to discriminate between hypogene or supergene kaolinite genesis. The hydrothermal genesis is mainly sustained by fluid inclusion temperature (150-180ºC) in quartz veinlets, while weathering is supported by deposit morphology, simple mineralogy, kaolinite stable isotopes (d18O ? 18, 13; dD ? ?59; ?85) and paleoclimatic record. It is concluded that a weathering process formed the main alteration with some participation of steam-heated meteoric waters. Neither the contents of Au, Ag, As, Sb, Hg, nor drill data support the existence of any epithermal gold mineralization at the kaolinite bottom.

Jan 1, 2010

By A. Opara

The weathering of coal mine waste rock releases iron, calcium, sulfate and associated trace elements like selenium [Se], which are introduced to seepage waters. Nitrogen species, such as nitrate and ammonia, are also found in association with coal-mining drainages mainly due to leaching of residual blasting compounds. Elevated concentrations of Se are a ubiquitous occurrence in coal mining environments in British Columbia, with values ranging from below 50 to over 500 µg/L in site waters. Selenate is the most common form of selenium found in waste rock seepages, and is exceedingly mobile in aerobic freshwaters. A major concern with waterborne Se in British Columbia is the potential for its bioaccumulation in aquatic food chains. Treatment to remove Se from coal-mining wastewaters has proven to be challenging for conventional water treatment technologies. Compounding this challenge, many streams are characterized by high flows and low selenium concentrations. Conventional membrane and ion exchange treatments produce concentrated brine streams that are difficult to treat or require disposal. Conventional biotreatment systems use excess nutrients to provide the required electrons to compensate for inefficient and variable electron availability, as well as to adjust reactor chemistry. The Electro-Biochemical Reactor (EBR) technology provides electrons to the microbes directly at a low voltage potential (1-3 V), supplying a controllable and consistent supply of useable electrons to the system and microbes at low current. In this manner, the EBR technology overcomes the shortcomings found in conventional systems, as it reduces the required nutrient addition and provides a more controllable, efficient, economical, and robust biotreatment system than found in past generations of biological treatment systems. Additionally, the EBR process does not produce excess solids or biomass; therefore, solids management post-treatment is not required. Laboratory EBR bench-scale and on-site pilot-scale systems were used to treat five British Columbia coal mine wastewaters; influent Se concentrations ranged from 35 µg/L to 531 µg/L. Se treatment targets for the tested waters ranged from 5 to 10 µg/L. Mean Se concentrations in EBR effluents ranged from 0.5 µg/L to 1.4 µg/L, while reducing sulfate concentrations. The test data demonstrate that the EBR technology is an effective Se removal option for British Columbia?s coal-mining wastewaters.

Feb 23, 2014

By E. O. Jacobs

A coupled solid and rock fracture mechanics model is used to analyze the blast driven fracture propagation phase, predict propagation rates, and directly measure shockwave and particle velocity. The study incorporates quasi-static pre-stress conditions for different depths below the surface. The scaled experiments include dynamic material properties and quasi-dynamic fracture mechanics which are shown to significantly affect the fracture propagation. The study was performed using three-dimensional cube-type laboratory models fabricated from Polymethylmethacrylate (PMMA). The test cubes are loaded with explosives and resulting fracture networks are studied. The dynamic evaluation of the spatial crack system is monitored using a high speed image camera. An experimental model set-up is designed to indicate the pre-stress effect on deep borehole blasting and is shown that the pre-stress conditions have a decisive influence on fracture profiles and orientation. It is found that shockwaves rapidly exceed the slower dynamic fractures and a majority of cracks occur due to detonation pressure. Experimental testing using different parameters validate that explosive fracturing can predict the outcome of fracture and crack propagation in any rock type with known material properties. This can be accomplished under great stress conditions deep below ground surface. The experimental study results can be applied to a variety of industries such as mining and quarrying, tunneling, oil and gas, and construction.

Feb 23, 2014

By P. Zhang

Phosphate mining in Florida generates approximately 100,000 tons/day of phosphatic clays (slime). This waste slime not only creates one of the most difficult disposal problems in the mining industry, but also causes tremendous loss of P2O5. About 20-30% of the phosphate mined end up in phosphatic clays. Recovering the phosphate from this waste is difficult for two main reasons: 1) the slime is extremely fine in size, and 2) clay minerals account for almost half of the material. A half dozen dispersants were evaluated for keeping the clay minerals suspended for subsequent separation from non-clay minerals by either settling or cycloning. The separation efficiency and economics are discussed.

Jan 1, 1998

By J. Choi

For the first time, the influence of stearyl trimethyl ammonium chloride (STAC) as a collector, on the flotation behavior of lepidolite (Uljin, South Korea) was systematically examined in Denver Sub-A cells. Flotation tests were carried out by varying amount of STAC (50?200 g/ton), feed size (-65, -100, -150, and -200 mesh), and solution pH. The impeller speed of 1000 rpm, flotation time of 10 min and AF-65 (a frother) of 250 mL/ton were invariably applied. In order to complement flotation experiments, zeta potential measurements and XRD analysis were conducted. XRD results showed that the ores were mainly composed of lepidolite, muscovite, quartz, calcite and albite. In addition, zeta potential results showed that isoelectric points were about 2.5, 2.3, and 9.7 for quartz, albite, and calcite, respectively, and lepidolite was determined to be less than 2. Overall, the results of 3-stage flotation showed that Li2O grade and recovery tended to increase with increasing STAC dosage and decreasing feed size. In addition, Li2O grade increased with decreasing pH. The results were explained by the extent of the interaction between STAC and each mineral.

Feb 23, 2014

By A. Opara

The weathering of coal mine waste rock releases iron, calcium, sulfate and associated trace elements like selenium [Se], which are introduced to seepage waters. Nitrogen species, such as nitrate and ammonia, are also found in association with coal-mining drainages mainly due to leaching of residual blasting compounds. Elevated concentrations of Se are a ubiquitous occurrence in coal mining environments in British Columbia, with values ranging from below 50 to over 500 µg/L in site waters. Selenate is the most common form of selenium found in waste rock seepages, and is exceedingly mobile in aerobic freshwaters. A major concern with waterborne Se in British Columbia is the potential for its bioaccumulation in aquatic food chains. Treatment to remove Se from coal-mining wastewaters has proven to be challenging for conventional water treatment technologies. Compounding this challenge, many streams are characterized by high flows and low selenium concentrations. Conventional membrane and ion exchange treatments produce concentrated brine streams that are difficult to treat or require disposal. Conventional biotreatment systems use excess nutrients to provide the required electrons to compensate for inefficient and variable electron availability, as well as to adjust reactor chemistry. The Electro-Biochemical Reactor (EBR) technology provides electrons to the microbes directly at a low voltage potential (1-3 V), supplying a controllable and consistent supply of useable electrons to the system and microbes at low current. In this manner, the EBR technology overcomes the shortcomings found in conventional systems, as it reduces the required nutrient addition and provides a more controllable, efficient, economical, and robust biotreatment system than found in past generations of biological treatment systems. Additionally, the EBR process does not produce excess solids or biomass; therefore, solids management post-treatment is not required. Laboratory EBR bench-scale and on-site pilot-scale systems were used to treat five British Columbia coal mine wastewaters; influent Se concentrations ranged from 35 µg/L to 531 µg/L. Se treatment targets for the tested waters ranged from 5 to 10 µg/L. Mean Se concentrations in EBR effluents ranged from 0.5 µg/L to 1.4 µg/L, while reducing sulfate concentrations. The test data demonstrate that the EBR technology is an effective Se removal option for British Columbia?s coal-mining wastewaters.

Feb 23, 2014

By O. Salami, G. Xu

Fire accident is one of the most classic safety concerns in underground mines both in the USA and abroad. It may occur from pool fires due to leakages in hose or pipes, vehicle fires, or fires in tires and conveyor belts in the underground mines. It may also result from the storage of flammable materials such as gasoline, diesel, and explosives in the underground. When fire occurs in an underground mine, it releases heat, smoke, and other toxic gases such as carbon monoxide, and methane to the surrounding thereby making life unbearable to the miners. Furthermore, smoke greatly impact visibility in the underground which makes evacuation even more onerous and challenging. To this end, a thorough investigation of fire behavior and spread of toxic gases in a practical underground mine is imperative to develop a reliable emergency evacuation plan in an event of fire disaster in the underground mine. The objective of this study is to investigate temperature variation and CO spread along mine airways by conducting full-scale fire experiment in the underground mine. The results presented from this study are crucial to developing evacuation plans in underground mines. In addition, the findings from this study could be used to validate existing evacuation models.

Mar 2, 2022

By E. -R. Niinikoski, M. A. Islam, H. Mischo, G. Barakos, J. Joutsenvaara, G. Meissner

European Union's transition to a low-carbon and digital economy highly depends on securing the strategic autonomy of the Critical Raw Materials (CRMs) supply chain. This paper introduces a European Commission-funded research and innovation action, AGEMERA, which aims to create detailed geological and people's concerns maps to unlock the CRMs potential in Europe. Furthermore, the project will develop educational packages for schools and universities, publish online CRM-related games and news flashes, and arrange public events to ensure a basis for socially accepted and sustainable exploration and mining of CRMs in Europe. 1. IntroductionCritical Raw Materials (CRMs), crucial for shifting to a low-carbon and digital economy, should focus on maintaining Europe's overall supply-demand balance (Birol, 2022). Therefore, to proactively address the surge in demand and ensure the strategic autonomy of European industrial supply chains, the exploration and extraction of CRMs must be scaled out across the continent. Moreover, mobilizing Europe's domestic potential is vital for the EU to become more resilient and to establish open strategic autonomy as the demand for CRMs continues to increase quickly on a global scale (European Commission, 2021). Base metal extraction and mining have a long history in Europe. Nevertheless, CRMs mining projects have shown less success, although these have a lot of potential (Guzik et al., 2021). The main barriers are a lack of investment in mining and exploration, complicated and drawn-out national permitting processes, and low levels of public support (European Commission, 2020). It is necessary to have a vast amount of knowledge and intelligence about CRM's potential and market impact. Novel non-invasive geophysical survey techniques that enable sustainable exploration must be created and used to enhance mineral system models of ore deposits incorporating CRMs. The minerals policy framework significantly influences the mining industry's performance, stability, and sustainability. However, the EU Member States' mineral policy frameworks differ significantly (MINLEX, 2017). In addition, the Fraser Institute Annual Survey of Mining Companies offers concrete information on how managers and executives of mining companies view key policy areas that impact mining activities in the jurisdiction in which they operate or are familiar (Jackson & Green, 2015).

Feb 1, 2023

By U. Schoepf

Economic and at the same time environmentally acceptable mining of small vertical ore bodies and veins to great depths has always been a challenge for miners. The Bauer cutter system, widely used in civil engineering, has been further developed for applications in exploration and mining, to a sustainable system for selective mining with a focus on small vertical ore bodies and veins, as well as residual ore in open pit operations. Current situation of conventional mining of small ore bodies and vertical veins Small ore bodies and vertical or near-vertical ore veins often pose a challenge to the mining industry. The relatively small size of the ore deposit over great depths or lengths, with only limited exposure to the surface makes economical mining difficult. Open pit mining of such ore bodies must either be terminated early because of the high stripping ratio and the enormous environmental impact or is unprofitable from the very beginning. The required massive stripping of waste rock leads to high material hauling times and costs, intensive roadway and bench construction and maintenance, possible safety hazards due to heavy vehicle movement, pit wall stability risks, intensive surface water management and massive waste dump requirements. In addition, it can be assumed that increasingly extensive rehabilitation measures will be required in the future after mine closure. Particularly in vertically oriented magmatic and hydrothermal deposits the technical, economic and environmental limits for further pushbacks, to extend the open pit depth, can lead to an early end of mine life even if a significant quantity of residual ore is left behind. Going underground is only a viable option in a limited number of mines with very high ore values and volumes. The high development cost of an underground mine, as well as the higher underground mining costs, often prevent further mining to greater depths.

Feb 1, 2023

By Neely H. Bostick

The primary and secondary organic matter in sedimentary rocks changes markedly when it becomes heated as a consequence of thick sediment accumulation and normal geothermal gradients, high geothermal gradients, hydrothermal fluids, or igneous events. Contact zones adjacent to small igneous dikes allow sampling of a single sedimentary bed that has been exposed to temperatures in a range as great as 30-500°C. Dike-heated rocks are, therefore, good sites for research on thermal effects because variation of the original organic matter is minimal, the range of heating is great, and the history of rock heating in a dike zone is relatively well established. In rare cases, such as at the dike near Wolcott, Colorado, described in this paper, the rock samples are sufficiently unweathered to allow analysis of secondary bitumens generated by the heating. We show by optical microscopy, scanning and transmission electron microscopy, and geochemistry the kinds of solid organic constituents in sedimen¬tary rocks and in ore deposits and the effects of heating. The primary phytoclasts that make up kerogen In sedimentary rock and in some ore deposits (pollen, resin, charcoal, humified woody remains, etc.) change in ways that are familiar to coal specialists. Progressive loss of moisture and other volatile matter yields residual kerogen that Is relatively higher in carbon and lower In oxygen and hydrogen, and has greater molecular or polymer ordering. In our contact zone examples, atomic H/C ratios of kerogen decrease from 0.8 (one case from 1.4) to 0.4, the hydrogen index from Rock-Eval pyrolysis decreases from 70 to 5, and the transformation ratio from Rock-Eval pyrolysis increases from 0.06 to 0.5 with increased heating. The visible effects of heating seen by scanning electron microscopy and light microscopy include formation of vesicles and flow structure, the development of optical anisotropy and mesophase, change of color, and increase in the refractive index, absorption, and reflectance. Some of these changes In primary organic matter are observed also in secondary organic matter, for example, in solid bitumens in sedimentary gold ores or In lead-zinc deposits. Quantification of color or absorption changes is difficult because it Is hard to make thin sections of organic matter with uniform thickness. However, natural objects with uniform thickness can be used. We show the colors of pollen In rocks from the Salton geothermal field at temperatures ranging from 100 to 300°C, and of pollen heated in laboratory bombs from 150 to 400°C. Measurement of vitrinite reflectance is a practical way to quantify thermal changes of kerogen and minerals of most sedimentary rocks because vitrinite is fairly widespread In sedimentary rocks of Devonian age and younger. For example, the reflectance of vitrinite rises from the regional level, as low as 0.4 % Ro, to more than 5% Ro adjacent to dikes that cut sedimentary rock. This is equivalent to the rank change from subbituminous coal to extreme meta-anthracite. The rise is most abrupt near thin dikes, but when the distance from the igneous contact is expressed as a ratio of dike thickness the reflectance rise is similar for all dikes. Controlled heating of vitrinite-bearing rocks In the laboratory provides a means to assign known temperatures to vitrinite-reflectance values. The derived plots of temperature In dike contact zones have the same shape and level as those predicted by heat theory, and the temperature lines extend toward dike contact temperatures that are about half those of most magmas, as expected if the intrusions did not flow past the sedimentary rock for a long time. The globular submicroscopic structure of vitrinite and Its heterogeneity, which we show by means of transmission electron microscopy, pose some problems In selecting a uniform type of vitrinite for measurement of thermal changes. At present, routine reflectance values of vitrinite dispersed in rocks have a relative uncertainty as great as 10%. Thermally caused chemical changes in the primary kerogen, especially decrease in the oxygen and hydrogen contents, lead to formation of secondary products in the contact zone. The measured changes of secondary organic products in these rocks include formation of peaks In concentration of total extractable organic matter and in hydrocarbons, and in the saturated/aromatic hydrocarbon ratio over the interval where primary organic hydrogen decreases most rapidly--then destruction or expulsion of these products at high temperatures. The odd carbon-number predominance of the C25-C31 n-alkanes In samples far from the dike disappears by about 1.3% Ro whereas the 13C: 12C ratios of the saturated and aromatic hydrocarbons increase over most of the thermal range. The saturated aromatic hydrocarbon ratio at first increases, corresponding to thermal generation of saturated hydrocarbons, then decreases in the most altered samples. One use of organic petrography, in addition to identifying organic fades or thermal alteration, is recognition of sample contamination such as the solid organic additives used in some drilling muds which may contaminate geochemical samples.

Jan 1, 2013