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By Rakesh Sehgal, Pushkar Verma, Mohit Sharma

"SJVN Limited successfully commissioned its Rampur HEP (412 MW) in 2014. The project has been planned to operate in tandem by directly utilizing the Tail Water of SJVN’s prestigious Nathpa Jhakri Hydro Power Station 1500 MW located upstream. The initial filling of voluminous water conductor system of RHEP with 10.50 m diameter, 15 Kilometer long Head Race Tunnel, involved more than 1.5 million m3 of water. The filling operation of such a large diameter tunnel constructed in young folded Himalayas which always offer less ideal sites for tunnelling and their subsequent operations under pressurized conditions is worth sharing with tunnelling fraternity. The paper covers meticulous planning, execution, precautions taken, and performance monitoring during filling process keeping in view the fragile geology, low rock cover zones, shear zones in close vicinity of thickly inhabited areas, squeezing zones, hot water zones encountered during excavation.1.0 RAMPUR HYDRO POWER STATION IN BRIEFRampur Hydroelectric Project (412 MW), is located in Himachal Pradesh (India). This project is a downstream development of Nathpa Jhakri Hydro Power Station (1500 MW) constructed on river Satluj and commissioned during 2003. Both the projects today are now successfully working in tandem. The upstream NJHPS has been constructed on the left bank of the river while the downstream Rampur HPS is located on right bank of the river (Figure-1).The major length of HRT of Rampur project lies on right bank of river before it crosses under the river in its initial reach (Figure-2). The main features of the project are as below:• 10.50 m diameter 15 km long HRT ending in a 155.75 m deep, 38.00 m diameter surge shaft.• 3 steel lined pressure shafts, 5.4 m dia, 211-220m long.• Surface valve house 69 m long x 10.50 m wide x 23 m high housing 3 No. butterfly valves• 3 No. surface penstocks 5.4m dia 368-382m long, bifurcating into six penstocks, each of 3.80 mdia. to feed six generating units of surface power house 158 m long x 24.50 m wide x 48 m high, with Francis turbines each of 68.67 MW capacity."

Jan 1, 2016

By M. Barati, K. Ebrahimi-Nasrabadi, P. W. Scott

"The conversion of cryptocrystalline magnesite to caustic magnesia was studied experimentally at temperatures of 400–1,200°C and for calcination times of up to 8 h. A differential thermal analysis– thermal gravimetric analysis showed that decomposition begins at temperatures as low as 340°C and is completed at 600°C. Specific surface area, iodine adsorption number, crystallite size, and loss on ignition were measured to characterize the product quality. It was found that high-quality caustic calcined magnesia can be produced in a narrow temperature (600–650°C) and time range (1–4 h).RÉSUMÉ La conversion de magnésite cryptocristalline en magnésie caustique a été étudiée de manière expérimentale à des températures de 400 à 1200 °C et pour des temps de calcination atteignant 8 heures. Une analyse thermique différentielle – analyse thermique gravimétrique montre que la décomposition commence à des températures aussi basses que 340 °C et qu’elle est complète à 600 °C. La surface spécifique, l’indice d’adsorption de l’iode, la taille des cristaux et la perte au feu ont été mesurés afin de caractériser la qualité du produit. Il a été trouvé qu’une magnésie caustique calcinée de grande qualité peut être produite dans un petit écart de température (600 à 650 °C) et dans une période de temps variant entre 1 et 4 heures."

Jan 1, 2015

By A. R. T. Denues

"INTRODUCTION The orienting phases of the current investigation of cushioned blasting in the Explosives Division of the Bureau of Mines were indicated in a previous publication (5) 3/. Pertinent literature reviewed therein indicated a highly controversial field. This emphasized the need for experimental studies of many factors that affect the health and safety of miners and the efficiency of mining operations. Results of some orienting tests showed marked effects on practical hazards. Further, they emphasized the necessity and importance of the contemplated investigation. The scope and general plan of these practical inquiries into the safety of cushioned blasting were indicated.This investigation of cushioned blasting relates to the various means employed to reduce the intensity of application of energy from explosive actions in boreholes. It has been suggested (from p. 19 of reference that the divisions of this work would correspond to the salient hazards affected by cushioned blasting. These include the ignition hazard, hazards from poisonous gases, and other practical hazards in the blasting technique. The ignition hazard was resolved into two components of approximately equal weight. These include studies of effects upon (1) the incendivity of blown-out shots and upon (2) the occurrence of such shots. Experimental studies of effects on the incendivity of blown-out shots were first undertaken. Questions of the best procedure for making these evaluations have been adduced, and the interpre-tation and utilization of the results of gallery testing seemed to require detailed attention; some preliminary general considerations of such testing were therefore necessary."

Jan 1, 1943

By Ian R. Muirhead

Over the past year or so, a number of mining companies have been meeting to examine the role of research in surface mining and, in particular, how to establish a collaborative research effort for the surface mining industry. A review has been completed which has identified the topics that are of interest to the surface mining companies for undertaking collaborative research. This has identified key subject areas such as Operations & Equipment; Maintenance; Environment & Reclamation; and Stability. Specific research projects for the initial research effort have been selected which include Wireless Data Communications, Analysis and Management; Application of GPS in Mining; and Tires for Heavy Haulers. In addition, attention has also been focussed on finding a suitable low cost, but effective, organization to coordinate and manage the collaborative research. The recently formed CONRAD Organization (Canadian Oilsands Network for Research and Development) appears to be a suitable candidate and discussions are ongoing with that group. This paper provides a summary of the review of surface mining research needs and of the status of the establishment of a collaborative research body for surface mining.

Jan 1, 1996

By G. C. Yao

Branch and needle-shaped intermctallic compounds of iron, silicon and aluminum normally exist in the molten aluminum. If a suitable amount of manganese metal is added into molten aluminum, the shape of the intermallie compound particlcs may become lumpish and spherical. According to the difference in electric and magnetic properties of these impurity particles and molten aluminum, these impurity intermctallie compound particles can be separated by applying an alternating magnetic field. In this experiment the alternating magnetic field was formed by a "C" type loop with AC (50Hz) current. The inner vacuum of the fireclay refractory separator is 25>< 15" 130mm3 with a lateral baffle inside. The separator was put into the interspace of the "C" type loop. It was found that the longer the separation time, the larger the amount transferred of impurities. The amount of transferred impurities increases with the increase of separation time and intensity of magnetic field. The addition of manganese metal enhanees signifieantly the efficiency of impurity separation.

Jan 1, 2003

By Alistair James, James Alcorn, Chaitan S. Sandhu, Andy Small

The Risk-Informed Decision Making (RIDM) working group is a group of industry professionals formed under the joint initiative undertaken by United States Society of Dams (USSD), Tailings Dam Safety Committee and Canadian Dam Associations (CDA) Mining Dam Safety Committee (MDC). The working group was organized to develop a guideline on implementation of a RIDM process relating to the design of mining water dams and Tailings Storage Facilities (TSF). Since its formation in 2022, the group has completed a literature review of more than one hundred (100) cross industry publications on applications of RIDM in mining water dams and TSFs, has held two industry workshops in Niagara Falls, Ontario in 2024 and Saskatoon, Saskatchewan in 2025 to capture industry input relating to the understanding and application of RIDM. The working group has subsequently formulated a process that constitutes good industry practice as it relates to application of RIDM in mining dams and TSFs. The authors, through their engagement and leadership in the working group and facilitating the two industry workshops in 2024 and 2025, are of the opinion that the successful application process of RIDM across Canada and United States (U.S.) is still not clear to many industry practitioners. There is confusion over terminology, good versus poor RIDM, and in some cases reluctance to use the RIDM terminology. This paper addresses critical knowledge gaps identified in the RIDM implementation for mining water dams and TSFs through three years of stakeholder engagement. It provides clarity of the process via a joint position statement and implementation roadmap, resolves terminology confusion, and documents contradicting industry opinions to promote adoption of good RIDM practices in Canada, U.S. and beyond.

Feb 22, 2026

By Richard W. Lawrence

Leaching of copper from sulfide minerals using biooxidation offers a potential route for copper recovery. Oxidation of . sulfide sulfur can proceed either; to sulfate or to elemental sulfur depending on mineralogy and process conditions. The advances in commercial application of biooxidation for sulfidic gold ores has made available operating and cost data which allow the derivation of conceptual costs for copper ore processing for comparison with conventional processing routes. Although costs for copper biooxidation generally remain high relative to conventional smelting, application might be competitive in specific cases. Biooxidation becomes more competitive in the general case if the cost ofS02 emissions in pyrometallurgical processing were to be internalized to a greater degree than currently required. This paper describes the technical aspects of biological processing of copper sulfide ores and concentrates, specifically with respect to the fate of sulfur. The environmental and economic implications of the biooxidation route are discussed in relation to conventional processing.

Jan 1, 1996

"The Garfield plant of the American Smelting & Refining Company is situated about seventeen miles west of Salt Lake City, on the Los Angeles & Salt Lake Railroad, and has freight service by the Denver & Rio Grande Western, Western Pacific and Bingham & Garfield Railways.The site lies between the picturesque Great Salt Lake, with its mountain islands, and the northern point of the Oquirrh Range, which forms the western boundary of the Salt Lake Valley.The location includes several hundred acres of land rising from the southern shore of the lake, selected on account of its adaptability to the economical handling of materials by gravity methods.The smelter is a custom smelter, treating copper ores and concentrates produced in Utah and adjoining states.The ores treated consist mainly of oxides from the Tintic and Park City Districts, sulphides from Bingham District, and concentrates from the mills of the Utah Copper Company, from mills in California, and copper precipitates from the Ohio Copper Company. The last product comes from low grade ores of Bingham Canyon.The following figures represent approximately the daily consumption of materials:Ores and Concentrates…2,700 tonsLime sand…100 ""Coal…350 ""Oil for Roasters…240 Bbls."

Jan 1, 1925

By W. D. Guo, Y. M. Zhu, B. B. Luo

The main chemical constituents of waste cooking oil are higher fatty acid glycerides, which can be used to produce anionic fatty acids for most non-sulfide flotation. However, using the mixed fatty acids (MFA) produced by waste cooking oil as collectors directly, the flotation effect is usually not satisfactory, especially at lower temperature or room temperature. There are very rare systematic studies about the reason for poor flotation performance of waste cooking oil. This study aims to investigate the flotation and adsorption characteristic of different types of fatty acids in waste cooking oil to find out what kind of fatty acids results in the poor flotation performance. This will provide technical supports and theoretical guidance for the waste cooking oil application in the field of mineral processing. In this study, MFA were produced from the waste cooking oil, and then separated into saturated fatty acids (SFA) as well as unsaturated fatty acids (UFA), which possessing different flotation properties. The properties of the MFA, SFA and UFA were analyzed by iodine value, melting point measurement, Fourier transform infrared (FT-IR) spectroscopy and quartz micro-flotation tests. The results showed that UFA was composed of fatty acids containing group—(CH=CH—CH2)n—, having an iodine value of up to 162.90, a melting point as low as -17.3 ? and stronger low-temperature floatability. In contrast, the SFA was made up with saturated fatty acids and a few oleic acids, with an iodine value of 48.97 and a melting point of 38.8 ?. SFA had shown poor collectability and required a flotation temperature higher than 35 ?. The results of zeta potential measurements, solution chemistry calculation and FT-IR spectra revealed that both UFA and SFA can be adsorbed on the quartz surface activated by CaCl2 via the chemical and hydrogen bonding. The reason MFA having a poor flotation performance is the SFA has an extremely high melting point which affecting the dissolution of the dispersion.

Jan 1, 2018

By M. Firdaus, M. A. H. Shuva, M. A. Rhamdhani, G. A. Brooks, S. Masood, M. A. Reuter

Declining grade of primary ores and resource efficiency have led us to process more alternative metal resources such as e-waste. One of the processing routes for extracting valuable metals from e-waste is through the black copper smelting. However, the underlying knowledge of the thermodynamics behaviour of the valuable metals contained in e-waste during smelting are limited which prevent us from developing an optimised process to recover all the metals. These different metals clearly will have different favourable conditions for their extraction. To illustrate this, the distribution behaviour of germanium (Ge) and palladium (Pd) between liquid copper and ferrous-calcium-silicate slag during black copper smelting was analysed. It was demonstrated that oxygen partial pressure and slag composition affect the partitioning of these metals to the copper phase and the favourable slag chemistry for recovering these metals is opposing. Considering the available thermodynamic data of these metals, an analysis for the optimum conditions is presented.

Mar 1, 2017

By B. J. Moore

This publication contains analyses and related source data for 252 natural gas samples from wells and pipelines in 17 States. All of the samples were obtained and analyzed during calendar year 1976 as a part of Bureau of Mines investigations of the occurrences of helium in natural gases of countries with free market economies. This survey has been conducted in the United States by the Bureau of Mines since 1917. In late 1965, the survey was expanded to include foreign gasfields. The analyses published herein were made by mass spectrometer and a special helium analysis apparatus, which are described in Bureau of Mines Bulletins 4862 and 576.3 The results of the investigation of the occurrences of helium are published annually to make the information available as soon as possible to the gas industry and the public in general. Eighteen previous publications have presented the results of 11,065 gas analyses prior to 1976. The first 3, Bulletins 486,4 576,5 and 617,6 contain analyses and related source data on 5,218 gas samples collected from 1917 through 1960. The other 15

Jan 1, 1977

By D Craw, C Smith, C Martin

The Wangaloa coal mine closed in 1989, and an attempt to grow Pinus radiata on quartz-rich overburden dumps was not successful. The site is currently being rehabilitated with re-profiling and native plant establishment. Plants are being established in a range of substrates that consist of variably disaggregated Tertiary coal measure sediments derived from the mine sequence. This material has low organic matter content (typically &lt;10 %), originating from coal fines or carbonaceous sediment. Substrate samples were collected during December 2003 from a range of sites varying in age, slope, and parent material. Nutrient analysis includes nitrate, ammonia, total N, total P, available P and readily exchangeable base cations. Total nitrogen and phosphorus are low on areas of recently disturbed, quartz-rich overburden, with total N =1200 mg/kg, and total P =200 mg/kg. Background forested areas have total N ranging between 2800 - 3300 mg/kg and total P of 420 - 500 mg/kg. Quartz-rich overburden sites contain available nitrogen levels of less than 6 mg/kg, while background forested areas are generally &gt;20 mg/kg. The soils and water runoff are generally acid, with pH down to three. Water samples have been collected from both ground and surface resources on a monthly basis since December 2003. The main lake on the site had pH of 4.6 in 1999, and this remained relatively unchanged when 850 tonnes of lime were added in 2002. However, the lake pH changed to 6.4 within a one month period in 2004, and has fluctuated since that time.

Jan 1, 2004

By G. A. Morrison

Iron ores associated with the Oriskany formation extend from the West Virginia border to the southwestern corner of Virginia. The deposits have been mined at many places, and the district is credited with the production of approximately 13,000,000 tons of ore to 1925, when mining operations ceased (fig. 1). The Oriskany iron-ore deposits occur in the Alleghany Mountains throughout their extent in the State. The name Oriskany was originally given to the limonite ore that was supposed to occur in the Oriskany sand-stone. At present, the name applies to all iron-ore deposits occurring in the lower part of the Devonian shale, Oriskany sandstone, and Helderberg limestone. The principal ore-bearing minerals are goethite and limonite. This report deals principally with the occurrences in Allegheny, Bath, Botetourt, and Craig Counties, Va. The Bureau of Mines, as part of the strategic-minerals program, began a project to develop the reserves of the area in November 1943; and continued until December 1944. Work started near Oriskany and extended northeast for nearly three-fourths of the area of the more important deposits. During the program 163 holes were drilled, totaling 11,651 feet; 256 feet of prospect tunnels were driven; 1,346 samples were collected; beneficiation tests were performed; and bulldozer trails and trenches wore excavated. The work served to delimit and appreciably extend the reserves of several areas. Analyses of channel samples are -given in appendix A, and diamond-drill and churn-drill hole logs and sample analyses are given in appendixes B and C, respectively.

Jan 1, 1950

By SANDEEP KUMAR JENA

This paper reviews the recovery of potassium from different rocks and mineral sources. Global demand for potassium is rising steadily due to the growth of agricultural production. Fertilizer manufacture consumes the majority of the world’s potassium production, with other uses including those in the pharmaceutical, glass, ceramic, food and detergent industries. The availability of soluble potash (K2O) minerals, such as sylvite, kainite and carnalite, in countries like Canada, the United States, Israel and Russia makes them major potash producers, whereas agriculture-based countries like Liberia, Somalia, Central African Republic, Thailand, Indonesia, Malaysia and India meet their potassium requirements through imports only. In these countries, the huge availability of potassium-bearing rocks/minerals like nepheline syenite, feldspar, mica and glauconitic sandstone, containing around 4 to 17 percent K2O, brings up the prospect of commercial production of potassium. Potassium recovery from minerals/rocks is complicated due to the uniform distribution of potassium throughout the crystal structure. Different physico-chemical separation methods like bioleaching, chemical leaching, flotation and roast-leaching have been discussed for the successful recovery of potash values from these rocks/minerals. Although seawater is vastly available, the recovery of potassium from seawater using chemical precipitation, solvent extraction, membrane separation and ion-exchange methods is not cost-effective due to low concentration of potassium.

By D. Scott Barr

The Zarafshan/Newmont Joint Venture operates the Muruntau heap leach project, located in the Kyzylkum desert of central Uzbekistan. The mine produces more than 12.4 t/a (400,000 oz/year) of gold from low-grade oxide ore stockpiles adjacent to the Muruntau open pit. It is op¬erated by the Navoi Mining and Metallurgical Combine and is one of the largest gold resources known (Fig. 1). Since commissioning in 1995, total heap leach production has exceeded 21 t (675,000 oz). The joint venture uses four-stage crushing and screening to produce a final product for heap leaching, Merrill-Crowe processing and local refining.

Jan 1, 1998

By A. Noble

"In coal and mineral processing, several numeric parameters are used to quantify the separation performance of unit operations. For density-based separations, the partition curve is used as the starting point for many stages of diagnostic analyses. The curve is often quantified by its midpoint slope sharpness, and this single value is subsequently used for technical evaluation, benchmarking, and comparison. While this analytical approach does depict misplacement by relative density class, it inherently prioritizes middling separation and does not consider process economics or the micro-price value of individual classes. An alternative parameter, the organic efficiency, does indirectly consider process economics, but it does not reveal information on the root cause of lost revenue or misplacement. In this paper, a new analytical approach, the partition moment of inertia, is introduced. This parameter reconciles the technical misplacement data derived from the partition curve with the economic data derived from micro-pricing. The result is a new analytical procedure that promises better use of performance data. IntroductionPartition curves are commonly used in the characterization, evaluation and simulation of various physical separators. In mineral processing, partition curve analysis is routinely applied to hydrocyclones, screens, density separators and other beneficiation technologies that are based on intensive physical properties. Graphically, the partition curve depicts the recovery of particles as a function of the physical property on which the separation is based, such as particle density, size or magnetic susceptibility. Given the probabilistic nature of many real separators, the partition curve often exhibits a characteristic S shape (Fig. 1), similar to a cumulative normal distribution. Other geometric features of the curve are also depicted in Fig. 1, including the high and low closeout, or bypass, values; the midpoint slope; and the separation cut point, defined as the property value with 50 percent recovery.Partition curve analysis was originally proposed to evaluate coal washability (Tromp, 1937). Given the limited computational resources at the time, the analytical methods relied heavily on graphical construction and interpretation of the curve. Owing to the simplicity of calculation and interpretation, many of these graphical approaches are still widely used for performance analysis today. The most common calculations are based on the slope of the partition curve at the midpoint. Increased slopes correspond to enhanced separation performance, as a perfect separation exhibits a stepwise transition from 0 to 1 at the desired cut point, that is, an infinitely large slope. One common formulation of this slope, the Ecart Probable, Ep, is derived by evaluating the slope between the 25 and 75 percent recovery points:"

Jan 1, 2016

By Dongjie Zhang, Zeyu Liu, Shuxin Liu, Yang Liu

Lateral pressure provided by caving rocks plays an important role in keeping the stability of the sidewall rock mass and controlling the rock movement. Taking Xilinhot Fluorite Mine as an engineering background, we studied the control mechanism of the granular media lateral pressure on the rock movement by combining physical experiments, theoretical analysis, and field monitoring. The results indicated that with the increase of the granular media depth, the lateral pressure provided by the static granular media presented two stages of rapid growth and slow growth. The lateral pressure on the footwall was negatively correlated with the dip angle of the orebody, and the lateral pressure on the hanging wall was positively correlated with the dip angle of the orebody. Ore drawing only caused the granular media lateral pressure near the drawing point to decrease. As the granular media moved, the granular media lateral pressure outside the pressure reduction area further increased, and this part of the granular media would play a key role in limiting surface rock movement. On this basis, the improved calculation formula of GLMP was given, which could be better applied to calculate the GLMP and critical granular media column with different dip angles. The action mechanism of the GLMP in the control of the surface rock movement was clarified. The granular body in the collapse pit was mainly composed of three parts: the bottom loose granular media column, the middle compaction granular media column, and the upper critical granular media column. The critical granular media column was the most important area to control surface subsidence and rock movement. Finally, through field practice, after effective filling of the collapse pit, the surface vertical displacement of the hanging wall and footwall was decreased by 56.8% and 55.6%, respectively, and the control effect of surface rock movement was remarkable.

Sep 18, 2023

By Douglas Tesarik, Mark K. Larson, Habte Abraham, Heather E. Lawson

Dynamic failures, or "bumps", remain an imperative safety concern in underground coal mining, despite significant advancements in engineering controls. While many factors have been empirically linked to the occurrence of dynamic failure events, identifying a consistent, repeatable set of criteria within a field setting has proven elusive; conditions generally associated with dynamic failure might produce an event at one site, but not another. Conversely and more troubling, dynamic failure could occur where relatively few of these factors exist. The presence of spatially discrete, stiff roof units, such as paleo channels, are one such feature that has been linked to the occurrence of dynamic failure events. However, an empirical stratigraphic review investigating the relative frequency of discrete units in bumping versus non-bumping deposits indicates that no significant difference exists based on this criterion alone, and that instead an apparent relationship exists between reportable bump history and the overall character of the host rock with respect to stiffness. Due to the complexity of the bump problem, however, these results are not conclusive, as they do not take into account any variable other than the presence or absence of stiff members in the roof lithology; To weight the relative impact of changes in a single variable, such as the thickness or location of sandstone members, it must be examined in isolation-i.e. in a setting where all other variables are held constant. Numerical modelling provides this setting, and the effects of variability in a stiff discrete member in a hypothetical longwall mining scenario are investigated within the context of three stratigraphic "types'', as determined by the ratio of stiff to compliant stratigraphic members; Compliant, Intermediate and Stiff A modelling experiment examines changes in rupture potential in stiff roof units for each stratigraphic type as discrete unit thickness and location are manipulated through a range of values. Results suggest that the stiff-to-compliant ratio of the host rock has an impact on the relative stress-inducing effects of discrete stiff members. In other words, it is necessary to consider both the thickness and the distance to the seam, within the context of the host rock, to accurately anticipate areas of elevated rupture induced hazard; acknowledging the presence of a discrete unit within the overburden in general terms is an insufficient indicator of risk. Through modelling of anticipated changes in the placement and dimensions of discrete units within their stratigraphic setting, elevated rupture-induced bump hazard can be anticipated on a case by case basis. Were similar modelling studies conducted at mine sites in tandem with tracking of problematic discrete stiff units, areas of elevated rupture risk could be anticipated in advance of mining. Developing this predictive capability beyond identifying rupture potential in discrete roof members is essential to the eventual elimination of dynamic failure related worker injuries and fatalities. As stress is a necessary component in the occurrence of dynamic failure events, this finding helps to refine our understanding of the role of individual stiff, strong roof members in bumping phenomena, and suggests that a more holistic view of overburden lithology, combined with site-specific numerical modelling, may be necessary to achieve greater miner safety.

Jan 1, 2016

By M. Tanaka, T. Oishi, K. Koyama, S. Alam

"A novel hydrometallurgical process for copper recovery from waste printed circuit boards has been proposed, which consists of selective leaching of copper metal as Cu(I) by Cu(II) in ammoniacal alkaline solution, purification, and electrowinning. The distinct feature of this process is much lower power consumption during the electrowinning than that during the conventional one from acidic copper sulfate media, because the deposition of copper metal from Cu(I) at the cathode and the oxidation of Cu(I) to Cu(II) at the anode take place in the present method. In the laboratory-scale tests using waste printed circuit boards, high purity copper which contains 1.1ppm of impurities was obtained in a chloride system. INTRODUCTIONThe recovery of various metals from waste materials is an important issue in order to conserve the environment and metal resources. Copper is used for cables, electric appliances, etc., and is currently a very important material for industries and will continue to be in the future. Among the wastes that contain copper, one of the most complex recycling materials is electronic scrap like printed circuit boards (PCB), which generally contain 10-30% copper as well as plastics, fibreglass and other metals. There are two ways to recover copper, either pyrometallurgical or hydrometallurgical. Hydrometallurgical treatments generally have more flexibilities in the process scale and control. The separation processes tend to become complicated because of the poor selectivity during the leaching in the sulphuric and hydrochloric acid media. On the other hand, the use of ammonia as a complexing agent, gave a higher selectivity for copper leaching (Nigo, Majima, Hirato, Awakura, & Iwai, 1993; Majima, Nigo, Hirato, Awakura, & Iwai, 1993; Zhou, Shinme, & Anezaki, 1995; Koyama, Tanaka, & Lee, 2006) .In this study, recycling process containing leaching, copper deposition at a cathode and oxidation of copper(I) at an anode from ammoniacal alkaline solutions containing Cu(I) or Cu(II) is introduced. Furthermore, copper recovery from a waste printed circuit boards and impurity behaviour was examined in ammonia-ammonium sulfate (sulfate system) and ammonia-ammonium chloride (chloride system) systems."

Jan 1, 2012

By Youn-Bae Kang

Evaporation mechanism of S from liquid Fe–C–S alloys at 1873 K was proposed by analyzing available experimental data. It has been known that increasing C content in liquid alloy increases activity coefficient of S ðfSÞ, and it could raise driving force for the evaporation reaction S = S(g). However, experimental data of the evaporation of S in the Fe–C–S alloys could not be accounted for only by considering the increases of fS. In the present study, formation of carbosulfides, CS(g) and CS2(g), was additionally taken into account in order to explain role of C for the accelerated S evaporation. Surface adsorption of S was also taken into account, which retards the evaporation rate of S. An evaporation model equation was formulated. It can be applied to calculate the evaporation rate of S over wider C content (from zero to its saturation to liquid alloy).