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By Bruno Rodrigues Henriques

O entendimento, controle e otimização do rendimento de aço líquido, em uma aciaria LD, é uma tarefa complexa e desafiadora. Qualquer projeto que se disponha a otimizar o rendimento de aço líquido irá se deparar com enormes dificuldades técnicas e operacionais. A despeito de todas as dificuldades e em função da importância do rendimento de aço líquido, uma vez que o mesmo tem forte impacto no custo de produção, toda aciaria procura manter essa variável de processo sob estrito controle. Esse trabalho se propõe a mostrar todas as etapas da condução de um projeto, desenvolvido e implantado em 2014, que tinha como foco entender, controlar e otimizar o rendimento de aço liquido. Durante o desenvolvimento do projeto, foi encontrado um total de 19 desvios e foram implementadas 23 ações corretivas. O valor do rendimento, que antes do projeto estava em torno de 91,6%, evoluiu para uma média de 93,5% em 2015 e 2016. Esse aumento de 1,9%, em média, no valor do rendimento de aço líquido, proporcionou uma expressiva redução no custo de produção na aciaria.

Aug 17, 2017

By H. O. Hofman

WITH the exception of lead sulphate, all common metallic sulphates are completely decomposed upon heating into metallic oxide, sulphur trioxide, sulphur dioxide and oxygen. Some give up their trioxide readily at a low temperature, others require considerable heat and much time to be completely freed from sulphur. Kerl in 1881 arranged the principal metallic sulphates as they are decomposed by a rising temperature in the following order: silver, iron, copper, zinc, nickel, cobalt, manganese and lead, lead sulphate being decomposed only slightly at a white heat. The researches of Bradford, published in 1903, show, however, that ferrous sulphate is decom¬posed at 590° C., cupric sulphate at G53° C. and argentic sulphate at 1,095° C. By the present investigation it will be seen that zinc sulphate is decomposed at 739° C. As far then as our present knowledge goes, the order in which the decomposition of the leading metallic sulphates takes place is the one given in Table I.

Jan 1, 1905

By I. Cameron, S. Ramjee, A. M. Garbers-Craig

The cause of reduced workability and increased ageing of a blast furnace taphole clay was examined. The investigated taphole clay contained 60 mass% alumina, with phenol-formaldehyde resole resin and liquid pitch serving as the binder system. The workability and Marshall extrusion pressure of the as-manufactured clay samples were evaluated to assess the extent of ageing of the clay. The wettability of all the raw materials was investigated to confirm compatibility between the dry raw materials and both the resin and liquid pitch, while the dry raw materials were analysed using XRF, XRD, and SEM-EDS. The characterisation of the resin and liquid pitch, as well as an analysis of their interaction, was performed using viscosity measurements, Fouriertransform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). The analyses confirmed a chemical interaction between the resole resin and liquid pitch, where the chemical structure of the resole resin changed when mixed with pitch, preventing the typical curing behaviour of the resin. Upon ageing of the resin-pitch mixtures, the resin underwent premature cross-linking, causing the curing process to initiate at lower temperatures, i.e., earlier onset of curing. This premature cross-linking was likely due to secondary amines present in the liquid pitch, which acted as a catalyst for the curing process of the resin. This reduction in curing temperature after ageing was confirmed by an increase in binder viscosity, which was identified as the primary cause of reduced workability, accelerated ageing, and increased Marshall extrusion pressure of the taphole clay.

Jul 23, 2025

By F. J. Palumbo

An electronic color-sorting machine was tested for recovering colorless glass concentrates from mixed glass products. The tests were made using glass recovered from unincinerated (raw) urban refuse and residues resulting from the incineration of refuse. The results of the study revealed that concentrates analyzing about 86 percent colorless glass could be recovered from mixed unincinerated glass containing 54 percent colorless glass material. Recovery of the colorless glass was about 62 percent. Color sorting the incinerated glass was somewhat more difficult. Multiple-stage processing was required to recover 59 percent of the colorless glass material in a product analyzing 89 percent colorless glass. The feed material analyzed 41 percent colorless glass.

Jan 1, 1971

By Charles Prasky

The objective of this investigation by the Bureau of Mines was to determine the response to sulfatization of diverse low-grade manganiferous materials in the iron formation of the Cuyuna district. In line with this objective a bench-scale sulfatizing procedure was developed that was less expensive and more rapid than pilot-plant methods. Samples from the central and south- western parts of the North range were tested. Results of evaluating a total of 46 pelletized samples, originating in areas with an estimated potential resource of 94 million long tons with a manganese content of 7 percent, indicates that approximately 87 percent of the manganese may be recovered as a synthetic manganese ore. This is equivalent to more than 12 million long tons of a metallurgical-grade ore, containing 46 percent manganese. It is anticipated that a premium product, containing over 50 percent manganese, may be obtained by sulfatizing procedures. This report is part of a continuing investigation5 6 of Cuyuna iron range manganese deposits in Crow Wing County, Minn. Lewis and coworkers describe the manganiferous iron formation in the bedrock of the Cuyuna district and include a description of a high-temperature differential sulfatizing process for recovering a ferrograde manganese product. The low-grade manganiferous

Jan 1, 1961

By Magda Moreira Pinto

Durante a fabricação do aço as grandes siderúrgicas possuem usinas térmicas integradas aos seus processos industriais. Uma operação bastante comum na indústria siderúrgica é a geração de vapor, normalmente utilizado para a produção de trabalho mecânico em turbinas (vapor superaquecido) ou em processos de aquecimento, nos quais se emprega o vapor saturado. Estes vapores de processos também podem ser utilizados na geração de energia elétrica. Para isto, foi importante assegurar a qualidade da água e do vapor de baixa pressão (VBP) enviado para Termelétrica. Foi com este intuito que a TKCSA se preocupou em padronizar o (VBP) gerado na Caldeira Auxiliar da área de Utilidades e Caldeiras da Aciaria. O desafio era transformar o (VBP) na mesma qualidade do vapor produzido nas caldeiras recuperadoras de calor (HRSG). O procedimento adotado foi á modificação no tratamento químico, a instalação de uma monitoração química contínua e eficiente para assegurar os parâmetros químicos dentro da especificação técnica recomendada pelo EPRI - Electric Power Research Institute, Inc. Com este tratamento foi controlada as dosagens químicas, a operação da caldeira e a geração dos efluentes líquidos para o tratamento químico ambiental. Contudo foi possível tornar um mecanismo dinâmico e econômico para a empresa viabilizando a utilização do vapor na termelétrica.

Jul 31, 2018

By P. Kim, M. Tangstad, T. Larssen, R. Kawamoto

The reduction rates of MnO and SiO2 were investigated for various charge compositions. The empirical activation energies of MnO and SiO2 reduction from SiMn slags were calculated between 1500 and 1650 °C under CO atmospheric pressure. The amounts of metal produced at different temperatures were compared, and the Arrhenius plots were described for each slag A, slag B and synthetic slag, which shows that the raw material have significant influence on the reduction rate. The rate of Mn-produced in slag A was faster than slag B despite of the relatively lower driving force. The lower rate constant in slag B implies that other kinetic factors, such as viscosity, affects the reduction rate. The estimated activation energies of MnO were 920, 304 and 975 kJ/mol MnO for slag A, slag B and synthetic slag, respectively. The rates of Si-produced were similar and slow for all slag types. However, the different activation energies of SiO2 between industrial ores and synthetic materials implied that the trace elements can have catalytic effects toward SiO2 reduction in SiMn slags. The estimated activation energies of SiO2 reduction were around 800 kJ/mol for slag A and slag B.

Mar 1, 2017

By J. B. Gayle

A half-ton experimental coke oven was installed at the Southern Experiment Station, Tuscaloosa, Ala., in 1948. Designated as the Tuscaloosa oven, this unit features a 17-inch carbonizing chamber, globar heating elements, and silica-brick walls designed to simulate as closely as possible the carbonizing conditions for commercial, slot-type ovens. The reasons for constructing an oven of this Size, the details of the design, and the operating characteristics of the oven have been given in previous publications.3/4 The present report deals with the reproducibility of test-oven data and the effects of variations in flue temperature on the physical properties of the cokes produced. Also included are the results of 2,400° carbonizing tests for several coals and coal blends not included in the earlier reports.

Jan 1, 1955

By Gabriel Oliveira Glória

Como uma boa alternativa a outros materiais, o número de materiais ecológicos está aumentando. As fibras naturais estão substituindo fibras sintéticas, por exemplo, a fibra de vidro. Além dos aspectos ambiental, as fibras naturais são mais baratas do que os sintéticos. A caracterização do FTIR é um indicativo sobre a possibilidade de integração de fibras com as matrizes de polímeros e compósitos ambientais. Portanto, o presente estudo analisou a fibra de PALF por meio de espectroscopia FTIR. O espectro mostrou principais bandas de absorção típicas de interacções moleculares específicas de fibras PALF. A análise FTIR do permitiu a identificação de grupos funcionais moleculares de fibras PALF e as suas características de vibração.

Aug 17, 2017

By Alfonso Guzmán da Silva

El análisis del trabajo señala la importancia y aplicación del proceso Sink & Float en la aceleración de la industria minera metálica, la no-metálica y la del carbón del Perú. Dicho procedimiento que implica la separación de una mezcla de partículas de densidades distintas a través de la diferencia de las mismas, tiene como ejemplo más próximo de su ejecución, a la compañía minera Milpo S. A., así como la primera planta instalada para la pre-concentración de minerales en el Perú, la corporación minera Castrovirreyna, en Huancavelica.

Jun 20, 1954

By J. R. Riding

In situ solution mining of uranium has environ- mental advantages over conventional mining. The leaching of uranium, however, alters the groundwater quality in the aquifer where the mining occurs. Currently, regulations require that the groundwater be restored to approximately its original condition. This paper, a summary of a study funded by the Bureau of Mines, reviews the state of the art in restoring groundwater quality after in situ uranium leaching. Current restoration practices discussed include disposal of liquid wastes in deep disposal wells and evaporation ponds, producing from all wells during restoration, and recirculating water purified in surface plants. Methods for predicting the effectiveness and cost of current techniques are presented. Possible alternative techniques are also described. Two restoration operations are discussed.

Jan 1, 1979

By Liu Jin

"In order to reduce the dosage costs and increase the economic benefits of a full floating process in a low grade complex multi-metals W-Mo ore, based on the study of the magnetic characteristics of the main gangue minerals, a joint process by magnetic separation and floatation technology is adopted. The first step of the flowsheet is to recover magnetite by magnetic separation, then remove the magnetic gangues by high gradient magnetic separation (HGMS) and finally recycle the W-Mo from the magnetically separated tailings by flotation. Results of the lab experiment show that in comparison with the full flotation process, the floatation feed tonnage of the combined flowsheet are only 46%. The grade and the recovery of Mo in the rough Mo-Bi concentrate is similar with the original one while the WO3 in the tungsten rough concentrate is increased from 3.85% to 6.64%. The dosage costs are reduced by 53%. The new process can significantly improve the plant economically. INTRODUCTION With the continuous exploitation of scheelite resources, the easily obtained resource is gradually depleting. The ""lean, fine and complex"" scheelite resource has become the main research object of tungsten beneficiation (Lou et al., 2010) (Xiao et al., 2013). The passive situation of tungsten beneficiation can be reversed by enhancing technological innovation and investment in science and technology, changing the business philosophy and mode of production, optimizing the process structure and process conditions, improving various technical indexes and reducing production costs of reagents, which will maximize economic benefits (Jiang et al., 2012 ) (Zhu et al., 2016). A polymetallic deposit of tungsten molybdenum bismuth original process adopts a full flotation process. With the expansion of stope mining, the content of valuable metals in the ore continues to decrease, resulting in a high cost per ton of concentrate produced and a low output value (Li et al., 2015)."

Jan 1, 2018

By Derek J. Fray

"A need exists for fast and accurate analysis of species in various phases at elevated temperatures. Although modern analytical techniques are very efficient, the equipment is usually situated some distance from the industrial operation and time is spent taking the sample and sending it to the analytical facility. Several minutes can easily lapse and, during this time, heat must be supplied in order to keep the system molten and, if the composition is changing rapidly due to a refining process or reaction with the environment, the information may only be of retrospective use. Perhaps more important reasons for the use of on-line sensors are that instantaneous analysis gives better control, process optimisation and the minimisation of energy losses and pollution. To date oxygen has been the only element which is measured widely using solid electrolytes. However, the analysis of many more elements is required and possible electrolytes for other species are discussed. For some elements, ~here is no suitable conducting electrolyte and, therefore, a different approach is adopted where the electrolyte, in which one species is mobile, comes to equilibrium with another species. IntroductionThere is an ever increasing demand for the development of sensors for on-line measurements in most areas of technology and, in particular, metal processing. This is especially relevant in situations where greater control can be achieved by monitoring the chemical composition of the melt during processing and where a minor constituent in the melt can have a major effect on the properties of the finished alloy. Although modern analytical techniques are fast and reliable, the equipment due to its complexity, is frequently situated away from the process area and valuable time may be spent in sampling and transportation. During this period, heat may have to be supplied to prevent solidification and the refining reactions may be continuing, and, therefore, the analytical information may not be of direct use."

Jan 1, 1988

By Arthur Notman

TO present some idea of the magnitude of the gold-mining industry of Canada and the world, the records of 106 gold-mining companies currently paying dividends have been studied. Forty of these are in Canada, and 37 on the Rand in South Africa, these being all the straight gold-mining companies that paid dividends in the two areas in 1938. None of the base-metal companies that produce gold as a by- product, or even as a major fraction of the value of their total product, have beezl included. In addition, a group of 29 similar companies from Southern Rhodesia and the Gold Coast in Africa, India, Australia, Manchuria, Philippine Islands, the

Jan 1, 1939

By Y. M. Shneerson, V. M/ Shpaer, E. E. Zhmarin, A. Y. Lapin, E. M. Vigdorchik

This paper describes studies of zinc concentrate oxidizing pressure leaching using the method of mathematical modeling. The concept of a kinetic function was taken as a basis for mathematical modeling of the leaching process. The kinetic function describes dependence of the unreacted component share OJ on the relative time x (the relative time is the ratio of the test duration and the time of complete dissolution). This kinetic function is determined in accordance with the results of batch laboratory tests. The laboratory tests have been carried out on zinc concentrate produced from Kazakhstan zinc-copper ores. Zinc concentrate consisted mainly of three types of minerals: sphalerite (70%), pyrite (13%) and chalcopyrite (10%). Oxidation reactions of sphalerite, pyrite and chalcopyrite have been considered as principal ones. The kinetic characteristics of the process (kinetic function, reaction order, activation energy, duration of complete dissolution of the concentrate components) have been calculated in the course of laboratory tests. The mathematical model was used for estimation of the main technological leaching process parameters (such as process rate, degree of metals extraction, autoclave capacity, heat balance, etc.). Mathematical modeling based on the kinetic function concept allows safe designing of metallurgical equipment and scaling the technology to industrial capacity.

Jan 1, 2004

By John Manka

Emulsion explosives consist of an aqueous oxidizer phase, a fuel phase, and an emulsifier. The ability to use lower-cost sources for any of these raw materials presents an obvious economic advantage to emulsion manufacturers. This paper focuses on using low cost waste drain oils as the fuel phase in emulsion explosive applications. Laboratory studies showed that emulsions made from waste drain oils and agricultural ammonium nitrate prills were usable for emulsion explosives though their shear stability was weak. Customer field results proved that waste crankcase drain oil could replace half of the virgin diesel fuel in emulsion explosives to make an effective emulsion explosive product with a very low cost.

Jan 1, 2003

A combination of the needs of business, employee desires and safety and health considerations is stimulating increasing attention to the time spent by people at work and the timing of that work. Particularly we are seeing: - innovative work schedules for 24-hour mining businesses; and - response from industry to accommodate the needs, even the desires, of employees in return for systems which are more productive and more capital efficient. There appears to be an evolutionary trend for business management to become more sophisticated and responsive to the need for achieving close to best cost work schedules to sustain continuous improvement. The underlying motivating forces driving this trend for improved techniques in organising attendance at, and time spent at work, is the seemingly inseparable combination of technological advance and ever-increasing accumulation of capital. The mining industry has not remained untouched by this thrust for ever-increasing need for best use of labour, to adopt advances in technology and to provide attractive opportunities for putting accumulated capital to work. An essential component of this on-going thrust is a substantial effort by the mining industry to improve the performance of labour by providing most-productive work schedules.

Jan 1, 1996

By Nobumasa Kemori

Six kinds of copper '90ncentrates. were treated individually in a ,pilot scale. Outokumpu flsah smelting furnace ~n order to study their ?flash smelting behavior with respect to oxygen efficiency and dust generation. The copper concentrates tested were selected from the more than twenty sources which are treated at the Sumitomo Toyo copper smelter, so as to provide a wide range of chemical composition in terms .of Cu, S,Fe, Pb + Zn + As, and Si~ content. Oxygen efficiency 'and dust generation rates obtained in 'the experiments ranged from 80% ,to 108% and 11% to 20%, respectively. Relationships between these results and experhnental conditions such as chemical and mineral composition of the copper concentrates, flux ratio, fuel consumption and so on are also discussed quantitatively in this paper.

Jan 1, 1998

By Richards RG, Cross MS

The development of alluvial mining, processing systems and associated gravity separation technology over the last 30 years is largely linked to the mineral sands industry. Attention has been focussed on Australia in these areas of mineral resource development and technological Advancement.

Jan 1, 1986

By Neel Gupta, Dustin M. Crandall, Brijes Mishra

X-ray computed tomography (CT) images of rock specimens often contain artifacts which must be corrected before scientific analyses are performed. This paper presents a new workflow of automated image processing to utilize poor-quality X-ray CT scan images. The workflow runs on the open-source image analysis software and efficiently separates desired features from low-contrast scanned images. The new workflow is a two-step technique using contrast enhancement and automated feature segmentation to generate noise-free binary images. The results of binary images using the proposed workflow and using a conventional thresholding technique are analyzed to show the quality of the proposed method. The paper also presents a workflow of estimating the structural geometries of features in two and three dimensions. The results of the structural feature analyses and computational time were compared between the open-source (ImageJ) and commercial image analysis software (Bruker Computed Tomography Analyzer). The commercial software was more computationally efficient, but the task-specific macros in open-source software enabled the user-desired automation in image processing and data extraction of desired structural features of comparable quality.

Sep 8, 2022