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By Douglas R. Shaw

Normal dodecyl mercaptan was evaluated as a collector for flotation of sulfide minerals and precious metals. The reagent is from the class of normal mercaptoalkanes (n-alkyl thiols), and is commercially available in the form of a mixture of n-dodecyl mercaptan and a dispersant, under the trade name Pennfloat(TM)3. Reported are results of bench-scale flotation experiments on many commercially treated base metal and precious metal sulfide ores. Dosages, points of addition, and flotation pH were among the uariables studied. Most notable results were increased copper, molybdenum, and precious metals recoveries. Dosages of dodecyl mercaptan on some ores were considerably lower than required for conventional collectors.

Jan 1, 1979

By Bordeaux Sciences Agro-INRA UMR 1065 SAVE, S. Piutti, E. Benizri, S. Lopez

Ultramafic soils display high concentrations of nickel (Ni) and a number of nutrient deficiencies (e.g. N, K, P). Ni-hyperaccumulator plants have evolved on such environments, developed specific metal homeostasis showing concentrations of Ni sometimes above 1% in their aerial biomass (Baker & Brooks 1989). Alyssum murale, a Ni-hyperaccumulator, is commonly found around the Mediterranean but can grow on non-ultramafic soils as well, with an altitudinal extension ranging from sea level to 2000 m.a.s.l. Rhizosphere bacterial communities associated with Ni-hyperaccumulator plants can differ from those of non-accumulating plants growing at the same site. Among edaphic factors that could influence the phylogenetic structure of the bacterial communities, altitude and metal-bioavailability and in particular nickel could be significant. However, most studies have focused on analyzing soils with techniques that provide little detail about the phylogenetic structure of these bacterial communities present in ultramafic soils. The objectives of this study were to understand the specific changes in the structure of A. murale rhizosphere bacterial community that occur across two gradients: 1°) elevation and 2°) Ni geochemistry, using pyrosequencing technique (454-pyrosequencing of 16S rRNA gene). It was found that the higher the soil chemically-available Ni contents, the higher the relative abundance of Proteobacteria and Actinobacteria. On the contrary, the abundance of TM7 decreased with increasing levels of available Ni. Moreover, Chloroflexi was present with 53 to 77% of relative abundance. These results demonstrate that soil chemically-available Ni drives the bacterial community diversity in the rhizosphere of Alyssum murale regardless the elevation gradient and other different soil physicochemical parameters. These results should now be confirmed in different ultramafic edaphic environments worldwide (e.g. ultramafic lateritic covers) and in the rhizosphere of different hyperaccumulator taxa.

Jan 1, 2016

By Umay Cinarli, Ahmet Turan

High-energy consumption in primary aluminum production (from bauxite ores) makes secondary aluminum production (from metallic raw materials such as scrap and dross) very critical. Aluminum dross, as a waste, arises in pyrometallurgical processes, and it is the mixture of metallic Al, Al2O3, other metal oxides, metal halides, and some other compounds like AlN. Aluminum dross has two subgroups (white and black) with respect to its metallic aluminum content. White dross is a secondary aluminum resource because of its high metallic aluminum content, whereas black dross, having low metallic aluminum content, is generally disposed in dumping areas. In the present study, it was aimed to develop a simple technique to valorize aluminum black dross in the form of alumina-based ceramic materials through pyrometallurgical (calcination) and hydrometallurgical (leaching) operations. Moreover, thermochemical simulations were conducted by using HSC Chemistry 6.12 software to simulate calcination conditions. After leaching experiments, an alumina-based ceramic containing approximately 36.8% Al2O3, 61.4% MgAl2O4 with 1.8% Na2FeO4, which might be available to use as a spinel refractory in steel smelting furnaces, was obtained in the experiment carried out in a solution containing 10 mLH2SO4 and 40 mL distilled water (3.5 M). Moreover, the sinterability of the alumina-based ceramic was investigated at the temperatures from 1350 to 1550 °C. In the sample which was sintered at 1550 °C, a density value of 3.15 g cm−3 and a hardness value of 69.58 HV were measured.

Oct 26, 2020

By Shoukun Wei, Cong Wang, Lin Cheng, Zhiyu Qiao, Jingkui Liang, Weidong Zhuang

"The subsolidus phase relations in the Sm2O3-CeO2-CuO ternary system sintered at 1000°C in air have been investigated by X-ray powder diffraction. The system can be divided into two ternary phase regions and three binary phase regions. Solid solution Sm2-xCexCuO4-y is the only ternary phase in the system. The maximum solid solubility was confirmed to be x = 0.2. The crystal structure, oxygen content and superconductivity of the solid solution Sm2-xCexCuO4-y have been investigated.I. INTRODUCTIONAfter the first discovery of the superconducting ceramic system La-Ba -Cu-O[l] with Tc = 30 to 40K, other families of cuprate-based ceramics have been synthesized with higher critical temperature. These oxides include the R-Ba-Cu-O (R: rare earth) systems (Tc=90K or so)[2,3], the Pb-Sr-(R,Ca)-Cu-O systems (T c = 50 to 100K), the Bi-Sr-Ca-Cu-O systems (Tc=80 to 105K)[4], the T1-Ba-Ca-Cu-O systems (Tc=85 to 125K)[5], the Hg-Ba-Ca-Cu-O systems (Tc=90 to 150K)[6,7], and some others. The improvement of Tc is very rapid. The measurement of the Hall and Seebeck coefficients shows that they all are p-type superconductors. In 1989, Tokura et al.[8] discovered the superconductors R2_XCexCU04_y(R = Nd, Pr, Sm) with Tc=20 to 24K (onset) and found that the charge carrier is electron in contrast to their hole doped counterparts. This discovery increases the fundamental understanding of the cuprate-based superconductors by comparing their characteristics and mechanisms to those of the p-type superconductors.One of the outstanding features of these n-type superconductors is the difficulty in obtaining samples in good charactors, such as the difficulty in obtaining zero resistivity state in single crystal or bulk samples; the semi-conductivity of bulk samples in ordinary state (opposite to the superconducting state) and a reducing reaction involved before the superconductivity has been found[9]. Therefore, it is necessary to optimize the sample preparation of the n-type superconductors. All the n-type superconductors have been found· considerable solid solubility. The compositional variations play a governing role in the carrier doping of the superconducting phases. Also, it is vital to the ceramic processing of superconductors to identify the compatible phases in the phase diagram. Finally, there is always the possibility of finding additional compounds, both superconducting and non-superconducting, in an unexplored system."

Jan 1, 1996

By G. R. Smith

This report describes research carried out by the Bureau of Mines to develop new technology for electrorefining metals at much higher current densities than those normally used in commercial practice, preliminary studies using rotating-ring and cylinder electrodes to increase the mass transport of copper are discussed. Following this work, single- and multichannel cells were developed that utilized a high electrolyte flow in the channels formed by the anode-cathode pairs. Using these cells, copper was successfully refined at current densities in the range of 70 to 300 amp/ft2. The effects of flow rate, electrolyte composition, and grain-refining and leveling agents on the morphology and purity of electrodeposited copper were determined.

Jan 1, 1979

By Rustu S. Kalyoncu

A major goal of the Bureau of Mines is to conserve the Nation's mineral resources by developing improved performance materials. In support of this mission, a survey of the state of the art of chemically bonded refractories has been made, covering the scientific literature, government reports, and patents. This review includes research and development results for phosphate, silicate, oxychloride, oxysulfate, and other bonding agents used in refractories manufacture. A significant finding of the review was that references on bonding mechanisms, bond formation kinetics, and other important process parameters and conditions were few and universally vague. As a result, recommendations are made to expand research efforts to investigate the kinetics and mechanisms of reactions in chemically bonded refractories.

Jan 1, 1982

By James K. B. Booth

The natural crustal abundances of the principle metals of commerce are examined in relation to production and prices for each metal. Two factors, the abundance x price ratio (BP factor) and abundance/production (B/T factor) are listed for each metal. Ideally, for these desirable commercial metals, each factor should be a constant and the same for all metals; comparing the divergences for the full list of metals allows conclusions to be drawn on the relative degree of natural availability of each metal and the ease or difficulty of winning the metal from the earth's crust. Plotting the two factors for each metal over the past decade of steady industrial usage illustrates the anomalous position of copper and, to a lesser degree, molybdenum and it is concluded that over the long term the price of copper will continue to rise steeply. Possible future prices for copper are examined and a suggested preferred order of ranking of the metals as exploration targets would be copper, nickel, tin, zinc, silver, molybdenum and lead, for the near term, with molybdenum possibly increasing its ranking in the list within the next decade.

Jan 1, 1971

By P. G. Semple

For the last four years, the Kilborn Group of Companies has been involved in several major projects in the Confederation of Independent States (CIS). These include the Kumtor project, the Kubaka gold project, the Kazgold project, the Aginskoe project and the Jerooy project. These projects are all in various stages of detailed engineering and construction. Western mining companies are pursuing mining opportunities throughout the world in search of ore bodies for development. The quest for profitable mining ventures has led mining companies to South America and Asia and, more recently, to the former Soviet Union. When considering the CIS, several factors should be considered. The most notable are geography, mining culture and previous mining production.

Jan 1, 1996

By J. Zou

Open-cut method is most widely used for shallow utility lines installation. In urban areas, unexpected utility lines buried underground potentially turn open-cut construction into a highly risky operation, increasing the construction cost while presenting additional safety hazards. Examples include: breaking existing water main leads to flooding the downtown area; hitting an unexpected gas line causes an explosion. To prevent those accidents, the current practice is to stake out the underground utility lines before the open-cut construction based on the as-built information collected from various utility companies and government agencies. However, the as-built information is not always complete and accurate. To verify the locations of some important utility lines and protect them against damages caused by open-cut construction, new techniques and technologies are used but have their limitations in revealing underground utility lines, such as hydro vacuum method and ground penetration radars (GPR). The emerging technology of ultra-wide band (UWB) radar holds the potential to provide a cost-effective, non-destructive detection method. In this paper, a critical review of current practices and established methodologies is given. The functionality and working mechanism of UWB radar technologies are described. Application potential in open-cut construction is demonstrated by conducting lab experiments. Testing set-ups for detecting unexpected utility lines in soil along with preliminary results are presented. The effects of soil moisture content on the detection range are discussed. Research findings are summarized and constraints are discussed in conclusions.

Aug 1, 2013

By In-Hyeok Choi

Currently, spent V2O5–WO3/TiO2 catalysts contribute significant amounts of solid waste following increasing levels of global demand. V2O5–WO3/ TiO2 catalysts usually consist of TiO2 anatase as a supporting oxide, vanadium as a catalytic agent, and other promoters such as tungsten, silicon, and calcium. Although vanadium is the main catalytic agent, a relatively high content of tungsten (WO3, 7–10 wt%) typically exists compared to vanadium (0.5–1.5 wt%). Considering the irreplaceable properties and industrial importance of tungsten, a feasible method for the recycling of spent V2O5–WO3/TiO2 catalyst should be established to utilize it as a secondary source. This paper presents a process to recover tungsten from spent V2O5–WO3/TiO2 catalyst. The processes proposed here involving roasting, decomposition using HCl, ammonia leaching, and crystallization. Within the process, ammonium paratungstate (71 wt% as WO3) is obtained as a final product. The total yield rate of tungsten from feedstock was found to be 96.3%.

By Gerald C. Dohm

INTRODUCTION After a mining company has discovered a mineral deposit, the problem is then how to mine and process that deposit the best way. The principal problem facing managers or engineers who must decide on mine plant size, equipment selection, and long-range scheduling is how one can optimize a property not only in terms of efficiency but also as to project duration. Mine opti¬mization is dependent upon the interaction of con¬tributing parameters which leads to maximizing the net present value (NPV) Realistic mine planning is the key, to the analysis. The process is to be used when evaluating undeveloped properties or when a complete revamping of existing facilities is scheduled The proc¬ess is not intended for detailed mine design but rather for property evaluation and feasibility studies. The derivation of the various input parameters will only be discussed to the point where a meaningful correlation can be made with the overall analysis. The interrelationship of the parameters will be the central point because most company guidelines and financial analysts have their own standards when deriving the various inputs. Assume that the data is totally acceptable and pro¬vides at least the following categories of information and guidelines- (1) mineral and waste inventory; (2) geologic, hydrologic, and geotechnical criteria; (3) topographic layout including property boundaries; (4) metallurgical flowsheet, recovery and design criteria; (5) access, water, power, and environmental base-line study; and (6) financial constraints (minimum rate of return, payback period, etc).

Jan 1, 1979

By Longjiang Li, Mao Jiang, Zhihui Shen, Guizhou University, Yin Pan

This paper aims to study the influence and action mechanism of collector Y-89 on the flotation of auriferous pyrite. The measurement to identify adsorption quantity, IR and XPS spectrum analysis and flotation experiment made on the pure mineral were conducted. The research results show that when the dosage of MIBC is 20 mg/L, and pH of 8, the dosage of Y-89 over 60 mg/L, the pyrite recovery rate is greater than 80%.And when the dosage of Y-89is 60 mg/L, dosage of MIBC 20 mg/L, the pH in a wider range (pH=4~9), the recovery is greater than 75%. When the pH is above 10, the pyrite is depressed and its recovery rate is found to be dramatically dropping. Adsorption quantity measurement also shows that the strong alkaline conditions inhibit the adsorption of Y-89 on the surface of auriferous pyrite. IR measurement indicates that chemisorption of Y-89 occurs on the surface of auriferous pyrite. XPS spectrum analysis indicates that without adding Y-89, oxidation reaction occurs on the surface of pyrite. But when Y-89 is added, the chemical environment of Fe on the surface of pyrite has changed. Such findings indicate that with Y-89, chemisorption occurs on the surface of auriferous pyrite.

Jan 1, 2014

By G. E. Johnson

LEAD SMELTERS AND REFINERS in 1932 were confronted with the problem of adjusting operations and costs to curtailed production and consumption at reduced prices, a problem which has been partially solved at least by improvements in operating technique and increased efficiency. At the Mount Isa properties in Australia, a third blast furnace and additional Dwight-Lloyd sintering machines were installed during the year, designed to increase the production to 6,000 tons of bullion per month. The large proportion of lead carbonate in the ores to be treated has presented metallurgical problems. Of the total lead contained in the concentrates to be smelted, two-thirds is Dresent as carbonates and one-third as sulfides. In the iiitial operations, the resulting Dwight-Lloyd sinter was soft, contained an excessive amount of fines, and was easily fusible. When charged to the blast furnaces it developed accretions in the upper part of the furnace owing to the easily fusible lead carbonates softening and fusing at the top of the charge column. This was remedied by the addition to the sinter feed of diluents of higher melting point, granulated slag and crushed limestone. The sinter feed consists of concentrates, Cottrell dust and wind-box cleanings, totalling 57 per cent of the charge; return sinter fines 15 per cent; granulated slag 23 per cent; and crushed limestone 5 per cent. The sinter produced contains 34 per cent lead and 0.5 per cent sulfur. Experiments indicated that double sintering under these conditions was of no advantage, so the original plan of single sinter treatment was retained.

Jan 1, 1933

By A. F. Banfield

"IntroductionELEMENTAL sulphur occurs in three types of deposits: in salt domes in the Gulf Coast region of the United States and Mexico, from which over 90 per cent of world native-sulphur production is obtained; in sedimentary deposits such as those in Sicily, which are thought by some authorities to contain the largest world reserves of elemental sulphur; and as surface deposits, associated now or in the past with some phase of vulcanism, the type which bas the greatest world-wide distribution.Deposits of the volcanic type are the subject of this paper.From antiquity until the successful development of the sulphur-bearing salt domes at the beginning of this century, important sulphur production for local needs was obtained from volcanic deposits in many parts of the world. Due to technical and economic factors, however, producers could not compete in price with sulphur from salt domes. •The result has been that, except in Japan and Chile, little sulphur was produced from volcanic deposits from about 1910 until the start of the Korean war in 1950. Shortly after the outbreak of the Korean war, an acute world sulphur shortage developed and prices skyrocketed in many countries up to several hundred dollars a ton. Interest in volcanic deposits was renewed and exploitation of many was undertaken. Few of these operations have been successful, mostly due to inability of management to solve technical problems.While important volcanic deposits of elemental sulphur have not been reported ( 1) in Canada, and it is doubtful that any will be found, data presented in this paper may be of interest to students of ore genesis.This paper is based on field examination of numerous deposits of the volcanic type in North and South America."

Jan 1, 1954

By Carl O. Nickle

"IntroductionIF I WERE ASKED what are the two most important single factors in shaping the growth of Canada to date, and in building its future, the answer would be: first, the treasure house of natural resources on and below the surface over the length and breadth of our country; and two, the pioneering spirit and 'get up and go' of many of our people. The two factors are inseparable. Without the pioneering spirit, the natural resources of land, forest, stream, and the subsurface would have continued •to be useless,. Idle assets. With the pioneering spirit, Canada's natural resources have been and are creating economic revolutions.Western Canada oil and natural gas rank high on the list of such revolutions. Calgary, your meeting place today, is the birthplace of this economic revolution, one that has already sharply altered the economy .of the middle half of Canada, particularly that of Alberta; is increasingly making its weight felt on the economy of all Canada; and is helping re-shape world thinking on sources of vital petroleum supply for both peace and war. Calgary is today the 'operation headquarters' for the great bulk of a huge exploration and development programme that now extends over a quarter of a million square miles of Canada's West. As a Calgarian, •therefore, I am particularly happy to have this privilege of talking about oil and natural gas to members of the C.I.M.M., who play a key role in the development of all Canada's varied natural resources."

Jan 1, 1952

By A. D. Kalogeropoulos, T. N. Michalakopoulos

This paper deals with the numerical simulation of rock cutting laboratory tests using the discrete element method. The main objective is to provide a method for calibrating numerical DEM models of rock cutting in a systematic way so that realistic results are yielded. The numerical models are developed with the discrete element code Yade, which models rocks as a collection of bonded spheres. The models are calibrated in a four-step process based on the design of experiments method and optimization. The calibrated models are evaluated both quantitatively and qualitatively against actual laboratory cutting tests, in terms of the ratio of the simulated mean cutting force to the actual one and the cutting force time series, respectively. The fully calibrated models showed that the simulated cutting process matched qualitatively the actual cutting force recordings and underestimated the mean cutting force by approximately 3%. It is concluded that well-calibrated numerical simulations of the rock cutting process can provide not only a better understanding of the process itself but also quantitative data regarding the cutting force and energy requirements.

Dec 28, 2022

By John Mould, Gordon Chen, Michael Oakland, William McElwee

"This paper will discuss the design analysis of sheet pile cofferdams for static and dynamic blast loads. Following construction of the new Willis Avenue Bridge across the East River between Brooklyn and Manhattan, in-river piers No. 9 and No. 10 from the former bridge were demolished, partially by explosive charges. The blast at Pier 10 was conducted first and though the demolition charge was relatively small, it gave confidence that the sheeting could be designed to resist the blast load. This paper primarily summarizes our analysis and performance of a sheet pile cofferdam at Pier 9 used to withstand the larger blast loads, contain the blast debris, and allow excavation of the pier below the existing river bed mudline. The program NLFlex was used to predict stresses and deformations of the cofferdams under dynamic blast loads, using simplified equations to estimate the underwater blast pressures. Specifically, the analysis focused on the stresses in the struts, waler beam, sheet pile interlocks and connection of the sheeting to the waler beam. Design included allowing plastic deformations and limited rupture of the sheet pile interlocks under the blast loading. Comparisons are made between stresses assessed by the dynamic finite element modeling and empirical relationships used within the industry. The performance of the system after the actual blast is discussed as well as details of the performance of welded vs. bolted connections within the system. IntroductionThe Willis Avenue Bridge is one of the major access ways from the Bronx into Manhattan. The location is shown on Figure 1. The original bridge constructed in 1901 was a swing bridge over the East River. The bridge was in disrepair and outdated with regards to its ability to handle the flow of traffic resulting in numerousaccidents.In 2007, Kiewit Constructors Inc./Weeks Marine, Inc., A Joint Venture was selected to construct a replacement bridge. The $612 million project included construction of a new bridge just to the south of the original bridge. The most notable aspect of the construction was floating and lifting the new 350 ft. long swing span in place as a single piece. However, another significant challenge was using blasting to demolish two of the abandoned piers which were within the East River. The blast would be near existing structures in both Manhattan and Brooklyn and would be within 30 ft. of the new bridge."

Jan 1, 2017

This paper examines the feasibility of combining network modeling and computational fluid dynamics for modeling of underground mine ventilation systems. Both simulation methods have specific advantages and disadvantages for analysis of mine systems. Network modeling is widely utilized by many operations and allows for assessment of current systems and simulation for planning purposes. Alternatively, CFD has been utilized only marginally by operations and is typically a research tool, requiring considerable computational power, complex models, and careful analysis and calibration of results. Network modeling allows for a holistic approach to the ventilation system, giving quantity, velocity and pressure in every branch, but CFD modeling can resolve the flow regime in 2-D or 3-D, which is idea when examination of an area on a more detailed basis is useful, such as dust and gas control. Integration of the two can allow for more flexible systems analysis. The feasibility of integration, along with application to limited underground mine data are examined.

Feb 23, 2014

By K Ionkov

The oolitic iron ore reserves in Lisakovsky, North Kazakhstan represent quite a challenging deposit both from a technological and from a resource point of view. The difficulties in processing such types of ore are connected with the extremely fine dissemination of phosphorus and gangue minerals inside the oolitic formations. The goethite crystals are cemented in their structure by aluminosilicates with quartz and other gangue minerals and dissemination is so fine that they are not separable by physical methods. The laboratory tests performed for dephosphorisation show that the combination of alkaline roasting followed by low intensity magnetic separation and acid leaching enables the obtaining of high grade iron concentrate. The magnetic separation performed ahead of leaching is effi cient as a means of buffering the high pH by washing out the soluble salts and the excess of base and after leaching facilitates the removal of secondary liberated gangue minerals in the non-magnetic fraction. As a consequence, phosphorous content is dropped to a more acceptable level for the ferrous metallurgy and iron grade and recovery reach 61.6 and 80.8 per cent respectively.

Jul 11, 2011

By K. Taylor

In surface coal mining, the performance of a shovel through blasted muck is one of the key performance indicators of the blast. Historically, performance has been measured qualitatively based on operator feedback or visuals of the muckpile. More complete shovel data, such as loading times and GPS location, is available from most fleet dispatch systems that are already in place at most truck and shovel operations. With some database and analysis skill, the drill and blast team can take advantage of this data to make targeted improvements to drill and blast designs. An area typically known to cause trouble for shovel operators at this operation are blast boundaries. Blast patterns with and without design changes along the boundaries were studied in this case study. The instantaneous loading times for each shovel pass were analyzed for 75 blasts across two subsequent benches with similar firing direction and shovel paths. The benches were split into three categories: Main body of pattern, boundary with design change, and boundary with no design change. The loading times from the main body of the patterns and where the design change was utilized in the boundary had similar prevalence of good loading times. However, boundary areas without the deign change had approximately 2% more prevalence of poor loading times compared to the main boundary of the pattern. Improving the dig rates through the boundaries up to the average loading time would result in approximately 280 hours taken off the total loading time for one bench. By quantifying the shovel’s performance by GPS location, the drill and blast team can decide how much of a design change is needed, can target precisely only the areas that require it and measure the impact of any changes made

Jan 1, 2024