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By P. P. Kim, M. Tangstad, T. A. Larssen

"The kinetics of MnO and SiO2 reduction in SiMn slags based on Assmang/Comilog ore and HCFeMn (highcarbon ferromanganese) slag were investigated between 1500 and 1650°C under a CO atmosphere. The results showed that charges containing HCFeMn slag had relatively faster reduction rates than those without. The difference in the driving force for MnO reduction was insignificant among the SiMn slags at 1500°C, which implies a low contribution of the driving force for reduction rate. The slag viscosities were also rather similar, around 1 poise at 1500°C, which could not explain the different reduction rates. Instead, the different charges containing various sulphur contents are believed to give rise to the varying reduction rates. The estimated activation energies for MnO reduction were around 500–920 kJ/mol for charges containing HCFeMn slag, and between 250–300 kJ/mol for those without. Based on the estimated kinetic parameters, the considered rate models were able to describe the reduction of MnO and SiO2 in SiMn slags between 1500 and 1650°C. IntroductionManganese ferroalloys such as ferromanganese (FeMn) and silicomanganese (SiMn) are important ingredients in steel production due to the beneficial effects of manganese on the physical properties of steel. Mn enhances the strength, toughness, and hardness of steel products, and both Mn and Si are used as deoxidizers to prevent the development of porous structures (International Manganese Institute, 2014; Olsen, Tangstad, and Lindstad, 2007; Subramanyam, Swansiger, and Avery, 1990; Tomota et al., 1987).The thermodynamic background of manganese ferroalloys is well established (Olsen, Tangstad and Lindstad, 2007), but kinetic information is rather scarce, especially for the SiMn process (Tranell et al., 2007; Tore-Andre Skjervheim, 1994). The absence of kinetic information makes it more difficult to understand the reduction mechanisms of MnO and SiO2. It is not clear how different raw materials affect the SiMn process. The main metal-producing reactions in the SiMn process are described by Equations [1] and [2]:"

May 1, 2019

By John B. Knaebel

Hammer machines are now widely used for underground sampling and exploration. Their application to such work can be divided into two classes - sampling and testing with ordinary drilling equipment to shallow depths of 22 feet or less, and "long hole" drilling with heavy machines and special equipment to depths of as much as 250 feet or more. In the first category hammer drills are employed for either of two distinct purposes: first, as a means of checking the results of grab or cut samples or, in certain types of ore deposits, as a substitute for these methods; and second, as a method of sampling the ground 5 to 20 feet beyond existing faces and thus aiding in the control of stoping operations or in the direction of development headings, as the case may be. The deep-hole drill, in the second category, has proved to be a valuable adjunct to the old established methods of exploring, end developing ore, provided it is employed under natural conditions to which it is suited, handled by men thoroughly familiar with the technique of its operations, and used with its possibilities and limitations clearly understood.

Jan 1, 1932

By R. A. Bloomfield

This report summarizes Bureau of Mines contract research on the disposal of retorted oil shale. A data base has been developed describing the physical-chemical properties, geotechnical engineering properties, and natural cementation characteristics of spent shale. Results of field compaction tests and seepage pond tests are presented, along with results of a partially saturated finite element seepage model used to predict infiltration and seepage rates. Preliminary engineering analyses are presented for underground disposal systems, which include material transport methods, and for a surface disposal system, which includes stability analyses.

Jan 1, 1981

By Yongquan Zhu, Zhengguo Zhu, Zhichun Liu, Chao Kong, Xinqiang Gao

"The aim of the study is to have a good understanding of the change in the seepage field during and after the tunnel excavation in weathering alteration rock. Field tests are used to monitor the changes of the water table and the numerical model is used to analysis the influence of the seepage filed with different operation conditions during and after the tunnel excavation. Results indicate that the depth, diameter and pumpage of precipitation well are the main factors that have a great influence on the drainage effect. Results also indicate that different operation conditions had various effects on the decrease in water yield during tunnel construction and the recovery in groundwater level after construction.INTRODUCTIONAs a potential disease during tunnel construction, Gushing water not only affected construction schedule, increased construction cost, as well as affected tunnel stability and safety during operation, but also decreased ground-water level. What’s more, the fall of water table caused by gushing water in tunnel would have influenced surrounding residents’ living water, agricultural water and ecological environment around tunnel. In recent years, enough emphasis has been paid to the influence on environment due to the construction of tunnel as a result of the reinforcement of people’s environmental protection awareness.As a result of water collection and drainage after excavation, groundwater was discharged into the tunnel, which caused a loss of water resources in the adjacent mountain mass. Furthermore, during tunnel operation, it was difficult for groundwater level to resume its original condition, which caused a bad ecological environment, because drainage system during tunnel construction destroyed its original hydrologic dynamic balance.In order to study whether decreased groundwater level resulting from tunnel construction could be restored during operation to its original condition, this paper gave a field monitoring on tunnel displacement during construction and simultaneously, generalized model of regional hydrogeology was created according to field hydrogeology to carry out a calculation of stable seepage flow and draw comparisons between recovery conditions of various water levels."

Jan 1, 2015

By Kazuyuki Kikuta

MMAJ, a govemmental organization in Japan, has carried out a 4 year project for the development of the decontamination and metals recovering technology for the fly ashes from municipal waste incineration. Heavy metals (zinc, lead and copper) are recovered as raw materials for the non-ferrous metals production, without formation of any waste materials to be disposed. More than 500 thousands tonnes a year of fly ashes generation from the municipal waste incineration has been one of the main social issues in Japan, because most of them need to be disposed to the registered areas after decontamination, and occupy 5% of the municipal wastes disposed. The segregation, flotation and chemical process are applied to the treatment of the primary fly ash from municipal waste incineration, and MF (Mitsui-type blast furnace) Process after the chlorine removal to the secondary fly ash. The main results of experiments are -About 90% of heavy metals, zinc, lead and copper, can be recovered from the primary and the secondary fly ashes to the products for the non-ferrous metals production. -Both of the leaching residue from the primary fly ash treatment and the slag from the secondary fly ash treatment can be used as a raw material for the cement production, meaning that the decontamination technology for the ashes without the landfill has been established. -Dioxins in the primary ash can be decomposed satisfactorily, and the dioxins content in the segregation furnace gas is less than O.lng-TEQ/Nm3 without any gas cleaning system

Jan 1, 2003

By A. U. Christensen

THERMODYNAMIC data for many of the common interoxidic compounds are seriously lacking, and appraisal of possible ceramic or metallurgical applications depends upon dubious estimates. In particular, high-temperature heat-content estimates may be invalid because of unknown phase-transformations. This paper reports experimental heat-content values above 298.15° K. for five interoxidic compounds-the aluminates of lithium and sodium (LiAlO2 and NaAlO2), the ferrites of lithium and sodium (LiFeO2 and NaFeO2), and lithium titanate (Li2TiO3), as obtained by the Bureau of Mines. Sodium aluminate, sodium ferrite, and lithium titanate were found to have previously unknown transformations in the crystalline state. The heats and temperatures of these transformations were evaluated as were also the heats and temperatures of fusion of sodium ferrite and lithium titanate. The heat-content results are assembled in both tabular and algebraic-equation form for use in conducting thermodynamic calculations at temperatures in the range 298°-2,000° K.

Jan 1, 1960

By James R. Holden, Frederick E. Wang

Through both single-crystal and powder X-ray diffraction methods, ten A6B23-type compounds have been confirmed to exist between lanthanides (A) (plus scandium and yttrium) and manganese (B); A = Y, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, and Lu. The formation of a compound of this type is shown to he extremely atomic size-sensitive; hence it can be classified as a "size-factorH compound. The "enveloping effect", a geometrical consideration observed in its crystal structure, is proposed as the reason for the A6B23-type compound being size-sensitive. The approximate ideal geometrical ratio of the radii R/r is 1.31 while experimentally A6B23-type compounds have a radius ratio lying within the range 1.2 to 1.4. FLORIO t al.' characterized the structure of Th6MnZ3 as fcc, space group Fm3m, with 116 atoms in the unit cell. Since then, a number of isotypic binary compounds, and recently Gd n,,' have been confirmed to exist. The fact that strontium and barium form A6Bz3-type compounds with magnesium strongly suggested the possible existence of Ba6Liz3. However, investigation3 showed the compound Ba6LiZ3 to be absent. Since both strontium and barium are group 11-a elements and are therefore "open metals",6 the nonexistence of Ba6LiZ3 can hardly be explained satisfactorily by valence-electron considerations. On the other hand, the consistent atomic-radius ratio, (R/r),* observed for the known A6Bz3-type compounds,3 strongly suggests that the formation of compounds of this type is atomic size-sensitive. Therefore, one is tempted to explain the nonexistence of Ba6LiZ3 entirely on the basis of the atomic-size difference between strontium and barium. However, this approach is not entirely without objection. Atoms are not rigid spheres and are known to vary in size within certain limits.7 Since the atomic-radius difference between strontium and barium (0.07 to 0.09A) is within these limits, it is reasonable to assume that the size difference would have a negligible effect on the formation of Ba6LiZ3. This view is further supported by the fact that the radius ratio, R/r, in other known "size-factor" compounds is observed to range widely—for example, from 1.08 to 1.45 for ABz-type compounds (C15, MgCuz type)' and from 1.37 to 1.58 for AB5-type compounds (D2d, CaZn5 type).g The present investigation was undertaken in order to find a more satisfactory explanation for the non-existence of Ba6LiZ3 and, consequently, a better understanding of the nature of the A6Bz3-type compound. The primary objectives are to confirm the previous conclusion3 that the A6B23-type compound is indeed a "size-factor" compound and subsequently to determine the atomic-radius ratio range in which the A6Bz3-type compound can exist. In order to achieve these objectives, stoichiometric A6Bz3 alloys, where manganese (B) was alloyed with various lanthanide elements (A), were selected for investigation. The atomic-radius ratios of lanthanide elements with manganese range from 1.26 for Lu/~n to 1.46 for Eu/Mn. This radius ratio range includes and exceeds the range of all previously reported A6Bz3-type compounds—1.32 for Th/Mn' through 1.38 for Sr/Li. Furthermore, the atomic-size difference between successive elements of the lanthanide series in order of atomic number) is of the order of 0.01A (europium and ytterbium are exceptions). The series of lanthanon-manganese alloy systems is ideally suited to a precise determination of the limits of allowable atomic-radius ratio for A6Bz3-type compound formation. EXPERIMENTAL PROCEDURE The lanthanide metals, in ingot form, supplied by Michigan Chemical Corp. (St. Louis, Mich.) and Nuclear Corp. of America (Burbank, Calif.), were guaranteed by the suppliers to be at least 99.9 wt pct pure (traces of silicon, calcium, and other minor constituents present on occasion, not to be more than 0.05 wt pct) as shown by spectrographic analysis. Manganese metal, in polycrystalline form, was redistilled from the commercial, chemically pure grade and was analyzed to be at least 99.95 wt pct pure. In all cases, the atom ratio between the two elements in each charge was A (rare-earth meta1):B (manganese) = 6:23 and a constant weight, 3 g, of

Jan 1, 1965

By W. J. Boone

Experimental determinations were made of vapor-liquid equilibria data for a helium-nitrogen-methane system. A mixture composition was chosen to approximate the crude helium to be produced Or conservation that will eventually be further refined to obtain pure helium. Although there are publications of studies of the vapor-liquid equilibria of helium-nitrogen, helium-methane, and nitrogen-methane binary systems, there is little indication of work done on the ternary system of helium-nitrogen-methane. The experimental data presented in this report supplement the information available for the binary systems. The equilibrium vapor-liquid data and equilibrium vaporization coefficients are presented in tabular form. Graphs are employed to show an extensive amount of the data.

Jan 1, 1963

By Martin P. O'Connell

"IT IS INDEED A PRIVILEGE to address a group representing a sector of the Canadian economy so important as is the mining sector. Important, not only today, but certainly of great importance for the future development of Canada, for employment, for our trade balance and indeed, when one looks at what we are calling increasingly an industrial strategy, for the future. Surely mining will have a very significant role to play in fulfilling that. It's of special interest to me, as the Minister of Labour - and I ought to confess at the very beginning that I am just two months into this function - of special interest for me to know that you are giving such attention to labour-management relations. I think it is timely that, from my point of view at least, you do this, because for the first time in twenty four years major revisions of the Canada Labour Code as it relates to industrial relations and disputes settlements are currently in the House of Commons going through their second reading, after an easier introduction and some changes which I would be very pleased to describe later this morning. It is very timely too, I think, that we should be looking at this area because public interest is certainly at a high level. It is not only at a high level but it expresses a good deal of irritation with the current status and procedures and results in collective bargaining and there is some urgent search for more sophisticated or modified procedures for settling differences in labour-management relations. The public wants different kinds of results. I think that is apparent to all of us. They want results in terms of justice and equity on both sides. And it means that a Minister of Labour and certainly governments who often are representing, or are the third party in discussions, have a very important and complex role to play in attempting to create a balance as these two parties come to contracts and come to agreements."

Jan 1, 1972

By K. K. Kelley

Synthetic fluorphlogopite mica (KMg3AlSi3010F2) is a relatively new product developed at the Norris (Tenn.) Station of the Bureau of Mines, Thermodynamic data have applications both in the production and use of this product, and the work described in this paper was undertaken to fill the need for such data. Measurements were made of the heat of formation at 298° K., the heat capacity between 50° and 298° K., the entropy at 298° K., and the heat-content and entropy increments between 298° K. and a maximum of 1,804° K. These basic data are combined to obtain heats and free energies of formation of the mica from the elements and from molecular constituents at temperatures ranging from 298° to 1,800° K. Minimum heat requirements to form melted mica from commonly used ingredients were calculated.

Jan 1, 1959

By Liyuan Chai, Qin Liu, Bing Peng, Jia Wang, Qiang Zhang

"Electrolytic Manganese Residue (EMR) was used as the main material to prepare cementing material activator for the utilization of the residue from electrolytic manganese dioxide (EMD) or electrolytic metallic manganese (EMM) production. The effects of chemical activation, thermal activation and mechanical activation on retarding activity and excitation activity of EMR were investigated according to the setting time and activity index of EMR-slag cementing material. The results showed that the EMR exhibited good activating performance after being ball-milled for 18 min and then treated for 1-2 hours at temperature range of 350-450 ?. The optimal properties of cementing material activator were achieved at the weight percent ratio 30 : 3 : 5 of EMR/Ca(OH)2/cement clinker.IntroductionMany hazardous industrial solid wastes such as blast furnace slag, fly ash, steelmaking slag, chromic slag and electrolytic manganese residue [1] are generated n China and their amounts increases every year. The accumulation of the solid wastes during past years is very huge and they could be hardly recycled effectively as a sustainable resource. 2.35 billion tons of industrial solid wastes have been produced up to now [2]. It is estimated that they would exceed 3.3 billion tons by the end of 2015 [3]. On the other hand, the quick development of Chinese infrastructural construction needs more cementing materials. The production of traditional building materials consumes lots of natural resource such as clay and limestone and discharges at least 1 ton CO2 and other pollutants per ton clinker [4]. Therefore, it is necessary to develop new types of cementing materials instead of clinker [5,6]."

Jan 1, 2012

By Charles T. Ford

In 1971, Bituminous Coal Research, Inc~ established a program to provide the coal industry with the necessary information and technical capability to investigate and evaluate potential problems concerning trace elements in coal and coal-related materials. The initial efforts at BCR in developing or adapting analytical procedures for the precise determination of trace elements in the parts per million to parts per billion range were detailed in a report titled "The Development of Analytical Methods for Determining Trace Elements in Coal and Coal-related Products." A subsequent reports contained descriptions of reliable analytical methods refined by BCR for determining mercury in coal and coal ash and also in coal mine water. his paper reports initial progress in applying recently-acquired trace-element analytical capabilities to solving potential coal industry problems. In this case, the effect of a coal-cleaning process on the distribution and removal of potentially harmful trace elements in coal was evaluated. Coal cleaning offers the possibility of controlling potentially harmful emissions resulting from combustion of large tonnages of coal by removing the pollutants prior to combustion.

Jan 1, 1977

By R. G. Hall

WHEN we want to interpret some problem which faces us at the present, if that problem be a social or political movement, we turn to the pages of history for 'information. If the problem be one of science or of industry we turn to the library of the subject and endeavor to translate the present from the experience of the past. I wonder if you would bear with me for a few minutes as I look back to the time when I was going through mining school and looking forward with hope, it is true and with confidence also, but still with some trepidation and an occasional qualm, to the month of June when the class of 1897 would be hunting jobs. Those were the years 1893 to 1897. Those years saw the Treasury of the United States so empty of gold that the President had to appeal to financiers to accept the country's promises to pay in return for $100,000,000 in gold. And the invectives that were hurled at both their heads for such a betrayal of the people sound strangely similar to those you read today being daily written and screamed at another President for taking us into the League of Nations or for not issuing bonds in huge amounts for unemployment relief, or for not adopting somebody else's particular specific for the relief of hard times.

Jan 1, 1931

By Márcia Maria da Silva Monteiro Pereira

Durante o lingotamento contínuo de aço, partículas de ZrO2 adicionadas na escória de molde facilitam a nucleação heterogênea de cristais devido à sua limitada solubilidade. A adição de ZrO2 promove a cristalização da fase cuspidina, o que auxilia na redução da transferência horizontal de calor no molde, amenizando desta forma o problema das trincas longitudinais. Outro benefício da adição de ZrO2 em pós fluxantes é reduzir a taxa de desgaste da válvula submersa (SEN) na interface metal/escória; a erosão da SEN é um problema sério. Através de testes de laboratório e de testes industriais concluiu-se que a adição de ZrO2 em pós fluxantes reduz a taxa de transferência de calor horizontal no molde durante o lingotamento contínuo de aço, considerando os dois tipos de pós fluxantes que foram analisados no presente trabalho. Além disso, observou-se que a adição de ZrO2 reduz a taxa de desgaste da válvula submersa na interface metal/escória.

Aug 16, 2017

In this U.S. Bureau of Mines report, two drill-split mechanical excavation mining system concepts are described, casted, and cost compared with conventional drill-blast mining systems. The concepts for the two drill-split mechanical excavation mining systems presented are (1) a method for steeply dipping narrow veins 0.6 to 1.2 m wide and (2) a longwall method for fiat-lying tabular ores. In the proposed systems, 70 to 80 pet of the ore is disposed of underground as backfill. For sortable ores, face area crushing, sorting, and direct stowage of run-of-mine waste and low-grade ores are proposed. The underground sorting and stowing of waste reduce materials handling, processing, and waste disposal costs by reducing the quality of ore transported to the surface by 70 to 80 pet (by volume). Because many of the tools and techniques proposed for use in these systems have little or no historical mining industry use, cost assignations are heavily influenced by engineering judgments and presented as prefeasibility-level cost estimates. These estimates, presented as discounted-cash-flow-rate-of-return (DCFROR) values, show the proposed systems to be at least as profitable as, and in some cases 50 pet more profitable than, conventional drill-blast mining.

Jan 1, 1994

By Y Ren

The algorithms employed by the commercial tools are either heuristic algorithm or iterative optimisation of a subsystem. This often results in a suboptimal schedule. In this paper, the author presents a new scheduling algorithm that incorporates with a novel stockpile configuration system, an improved algorithm on multiple processes and a mixed-integer linear programming (MILP) global optimisation model. It can simultaneously optimise stockpiles, blending, multiple processes as well as multiple mines. In addition, it allows the user to interact with the solution to adjust the solution to be practical and desirable.CITATION:Ren, Y, 2013. A simultaneous optimisation tool for open pit mine scheduling, in Proceedings World Gold 2013 , pp 427-432 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By Pedro Augusto Silva de Lima

As ligas do sistema Cu-Al-Ni sofrem Transformações Martensíticas Reversíveis (TMR) e podem apresentar Efeitos Não Elásticos, incluindo o Efeito de Memória de Forma (EMF). Elas podem ser utilizadas nas diversas áreas e são promissoras para substituir ligas do sistema Ni-Ti. Neste trabalho foram estudadas três ligas distintas: monocristalina e policristalina Cu-Al-Ni e policristalina Cu-Al-Ni-Mn-Ti, dando atenção a análise da estrutura e comportamento mecânico, em seu estado inicial e após tratamento de betatização. Nas três ligas foram identificadas as fases martensitas ß1 e Y1e as fases R e ß1. A liga Cu-Al-Ni-Mn-Ti ainda apresentou o composto Cu2AlTi. Durante a deformação, as três ligas sofreram TMR, induzidas por tensão, com reorientação das fases envolvidas. O tratamento de betatização aumentou a plasticidade, sendo mais notável na liga policristalina Cu-Al-Ni. A liga Cu-Al-Ni-Mn-Ti se mostrou como a mais frágil, sofrendo a fratura antes de alcançar 10% de deformação. A liga monocristalina se mostrou a mais promissora para realizar EMF, revelando maior deformação armazenada no patamar de pseudoescoamento.

Aug 17, 2017

By Michael DeLallo

Clean Coal Technology (CCT) ?Technologies designed to enhance both the efficiency and the environmental acceptability of coal extraction, preparation and use?. These technologies reduce emissions, reduce wastes, and increase the amount of energy gained form each ton of coal extracted and converted into energy. ?? Carbon Capture and Sequestration are an integral part of CCT either as constructed or on a future retrofit basis.

May 1, 2008

By Vinícius Cunha de Souza

Dispositivos atuatores com componentes de ligas de NiTi podem ter seu desempenho modificado quando submetidos a distintas taxas de aquecimento e/ou resfriamento resulte numa transformação de fase. Por outro lado, por norma, as temperaturas de transformação de fase (início, pico e fim) devem ser estabelecidas a partir de taxas fixas de 10ºC/min (tanto no aquecimento como no resfriamento) através da técnica de Calorimetria Diferencial de Varredura (DSC), sem levar em conta a dinâmica do material durante a transformação em aplicações reais. O presente trabalho procura observar a transformação de fase do material avaliando a capacidade de resposta do mesmo, quando submetido a ciclos em um DSC sob diversas taxas de resfriamento e aquecimento, entre 1 e 10ºC/min em uma liga de NiTi rica em Ti, com formação de fase R durante o resfriamento e/ou aquecimento. Os resultados de DSC foram submetidos a um tratamento de dados com o intuito de melhor determinar as temperaturas de transformação de fase associadas as frações transformadas. Pode-se verificar que valores de taxas de resfriamento e de aquecimento superiores a 7°C/min permitem que ocorra uma tendência para um incremento do intervalo entre as temperaturas de início e fim das transformações direta e reversa.

Aug 16, 2017

"Ground control research in underground coal mines has been ongoing for over 50 years. One of the most problematic issues in underground coal mines is roof failures associated with weak shale. This paper will present a historical narrative on the research the National Institute for Occupational Safety and Health has conducted in relation to rock mechanics and shale. This paper begins by first discussing how shale is classified in relation to coal mining. Characterizing and planning for weak roof sequences is an important step in developing an engineering solution to prevent roof failures. Next, the failure mechanics associated with the weak characteristics of shale will be discussed. Understanding these failure mechanics also aids in applying the correct engineering solutions. The various solutions that have been implemented in the underground coal mining industry to control the different modes of failure will be summarized. Finally, a discussion on current and future research relating to rock mechanics and shale is presented. The overall goal of the paper is to share the collective ground control experience of controlling roof structures dominated by shale rock in underground coal mining.INTRODUCTIONThe National Institute for Occupational Safety and Health’s (NIOSH) Office of Mine Safety and Health Research (OMSHR), formerly the United States Bureau of Mines, has been conducting research on ground control safety for over 50 years. The overall objective of the research is to reduce underground mining injuries and fatalities by characterizing roof conditions, improving roof support performance and application, and optimizing pillar design and mine layout. Underground mining has one of the highest fatal injury rates of any industry in the United States—more than five times the national average compared to other industries (CDC, 2012). Roof fall injuries can be severe, resulting in lacerations, bone fractures, amputations, and death. Non-injury roof falls can also be problematic, resulting in lost production, delays, blockage of primary escape routes, disruption to ventilation, and hazardous rehabilitation conditions.Coal mining is increasingly subject to more adverse geological conditions. Weak roof can be found in all coal mining regions in the United States, but there are a few geographically isolated areas with higher roof fall rates contributed to by particularly poor roof conditions, as represented in Figure 1. This figure shows that when non-injury roof fall rates are normalized to production, the Illinois Basin and Central/Northern Appalachia regions have the highest rates. These isolated regions have inherently weak roof even before mining has occurred, and this roof is easily damaged during the mining process. The weak roof in these regions consists primarily of shale. Shale can be troublesome in underground coal mining because it can appear massive but easily splits along bedding planes and is often moisture-sensitive."

Jan 1, 2015