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By John S. Ball

Aniline points have been used to some extent for more than 20 years. to indicate the types of structures in hydrocarbons and thus to analyze mixtures of hydrocarbons . This type of analysis has been applied - principally to the low -boiling hydrocarbons found in the gasoline range . Although there is some disagreement as to their merits , both aniline point and diesel index (aniline point in degrees Fahrenheit times A.P.I. gravity at 60 ° F. divided by 100) are used rather extensively for evaluating ignition qualities of diesel fuels . In recent years aniline points have been employed in the study of lubricating - oil fractions . They also have been used to predict : the tendency of different oils to cause swelling of synthetic rubbers.5/ Recent standardization of the aniline - point determination by the American Society for Testing Materials has encouraged wider use of this test . Considerable data concerning , aniline points and critical solution temperatures in aniline have been accumulated in the course of a study of related subjects . Thesc data , together with some original results , are presented here in the hope that they will prove useful to other worker's in this field ...

Oct 1, 1943

By R. M. Gooding

This paper presents a short history of the production of mineral-energy fuels and energy from waterpower in the United States, with brief discussions of the utilization of each of the fuels and hydropower, and a look at fuels competition and interchangeability. Basic data, in figures and tables, are brought together in this publication for the production of coal in the United States from 1800 to 1960, for crude petroleum, natural gas liquids, and natural gas from 1859 to 1960, and for hydropower since 1900. Production for each segment of the fuels complex in the principal producing States from 1946 to 1960 is shown. Data are not included for consumption as such or for imports and exports.

Jan 1, 1963

By R. M. Gooding

This paper presents a short history of the production of mineral-energy fuels and energy from waterpower in the United States, with brief discussions of the utilization of each of the fuels and hydropower, and a look at fuels competition and interchangeability. Basic data, in figures and tables, are brought together in this publication for the production of coal in the United States from 1800 to 1960, for crude petroleum, natural gas liquids, and natural gas from 1859 to 1960, and for hydropower since 1900. Production for each segment of the fuels complex in the principal producing States from 1946 to 1960 is shown. Data are not included for consumption as such or for imports and exports.

Jan 1, 1963

By Federico Pagliacci

"Many existing dams are subject to underwater seepage due to subsoil conditions, like deep alluvial deposits or pervious rocks or karst. Remedial works are necessary in order to install new cut-off walls to stop the water flow. In some cases the cut-off walls have to be executed at depths never reached so far, and difficult to reach with traditional foundation techniques. In many cases the Hydromill technology proved to be the best system to overpass rocky layers and ensure the required verticality. The maximum depth reached by the industry was in the range of 120-150 meters. This article describes the test performed to excavate and cast in place a 3.2x1.5 m panel to a depth of 250 m. The article will also describe the stratigraphy of the site down to 250 meters, as well as the technique adopted to achieve the said depth with deviations from verticality of 30 cm along the longitudinal axis (0.12%) and 20 cm along the transverse axis (0.10%), measured at the bottom of the excavation. The concreting of the panel, for about 1,100 m³, with plastic concrete in the lower portion and conventional concrete in the upper portion will be illustrated. Finally, the tests performed during the excavation and after concrete casting will be also described, with special attention to the continuous directional core drilling that was performed along the whole length of the panel to verify the results of the deviation from verticality, through the onboard instruments, and to control the quality of concrete at a depth never reached before. IntroductionMany existing dams are subject to underwater seepage due to subsoil conditions, like deep alluvial deposits or caves and cavities or acid solutions in the bedrock formations.Conventional remedial works generally consist in the construction of an additional cut-off wall throughout the dam body and the subsoil, in most cases being deeper than the original one. Today, many examples of successful remedial cut-off walls allow the engineers to design the most suitable solution according to the dam and subsoil characteristics and nature.The real difficulty stems from the depth at which the new cut-off wall has to be socketed in competent rock or soil, so as to eliminate underwater seepage. The maximum depth ever achieved with a cut-off wall is 122.5 m for the remedial work of Mud Mountain Dam, Washington, USA, in 1988-1990. This 0.85-1.0 m thick cut-off wall was realized by means of a Hydromill, by excavating single 2.8 m-wide secant panels."

Jan 1, 2017

By K. E. Stanfield

The Bureau of Mines oil-shale program, initiated in April 1944, is concerned with the future utilization of oil shale in the United States as a source of liquid fuel. One phase of this program is the accumulation of information on the location, extent, and richness of oil-shale deposits that may be suitable for processing to oil and related products. A previous publication5/ presented, by means of logs, the oil yields of sections of the largest known oil-shale deposit in this country -the shales of the Green River formation occurring in adjoining portions of the states of Colorado, Utah, and Wyoming. This present supplementary report presents the oil yields of cores from 48 holes drilled during 1952 to 1954 in the Green River formation of Colorado, which is distributed over an area of more than 1,000 square miles. The oil yields of the 48 oil-shale sections, involving the assay of 9,651 samples, representing 22,451 feet of core, are presented by means of logs. In addition, the oil yields of samples comprising the maximum sections of 15 gallon-per-ton shale are tabulated for these cores and for the 28 cores from Colorado which were logged in the previous report.

Jan 1, 1957

By J. W. Town

Studies were made by the Bureau of Mines to determine the influence of textural features on the beneficiation of phosphate minerals (pellets) from selected bed and composite samples representing different rock types of the Western Phosphoria Formation. The particle size of the samples was reduced by attrition grinding to minus 20-, 28-, or 48-mesh depending on ore grade and gangue matrix. Sizing of the ground material showed that the phosphate pellets would concentrate in the plus 200-, 270-, or 325-mesh size fractions sufficiently so that the phosphate content was above the 31.5 :cent P2O5 required for acidulation. The phosphate content of essentially pure phosphate pellets was shown to range from 33 to 39 percent P2O5. Microscopic identification of the particles in each size fraction showed that the phosphate was either in the pellet form and readily liberated or so intimately associated with the gangue matrix that size reduction necessary Co obtain liberation was impractical.

Jan 1, 1967

By Arthur E. Bruszak, Marcel Vanpée

In many practical combustion systems ignition may occur through contact with hot burned gases . Such a process plays a vital role in flame stabilization on bluff bodies . It is also of importance in the ignition of firedamp by the hot spent gases of explosives used in mines . Also , in the communication of flames through narrow channels , a problem of practical importance in flameproofing electrical equipment , the propagation of the flame is essentially a reignition process in which hot burned gases are the agent of ignition . In the actual ignition problem a great variety of conditions may be visualized . Ignition may occur where pockets of hot gases are surrounded by cold explosive mixtures or where pockets of cold mixture may be surrounded by hot gases . Alternately , a flowing stream of combustible mixture may be initially in contact with another stream of hot combustion products , or a jet of hot gases may flow into a cold quiescent mixture ; the jet may be laminar or turbulent , continuous or discontinuous . The hot gas may also consist of the oxidant ( air for instance ) and the cold combustible pure fuel . This study by the Bureau of Mines is concerned only with ignition produced by a continuous jet of gas ( hot ) flowing into a practically quiescent cold mix- The investigation of ignition by bursts of hot gases or by turbulent jets is outside the scope of this report , and work performed on this phase of the problem has been published elsewhere

Jan 1, 1963

By A Purvee, M F. Lee, L J. Mollison

Oyu Tolgoi is a large Cu-Au porphyry deposit in the south Gobi desert, Mongolia. The first of several deep, large-diameter, concrete-lined shafts, Shaft 1, is nearing completion. It will have a finished depth of 1380 m at a diameter of 6.7 m. These shafts will provide access to and hoisting capacity for block caving of deep underground ore. Geotechnical site investigations, and associated predictions of stability and ground support requirements, are compared against actual construction performance. Routine mapping is essential, along with checks against predictions and informing the contractor of ground conditions and variances.Advance rates are compared against predicted rock mass quality. A reasonable correlation exists between Qwall and advance rate. Overbreak and concrete liner thickness is related to the blockiness quotient, RQD/Jn.A ætool-bagÆ of just a few support elements (chain-link mesh, fibrecrete and 2.4 m long friction anchors and resin grouted re-bar bolts) was able to cope with the ground conditions encountered. QA/QC procedures are essential from the factory, through site storage to installation.

Jan 1, 2008

By Betânia Mendes Sena

Neste trabalho é apresentada a influência de diferentes processos de tratamentos térmicos sobre as microestruturas e propriedades mecânicas resultantes em tubos de um aço sem costura do tipo API 5L. Após tratamentos térmicos, o material foi estudado em três condições diferentes: apenas laminado, normalizado e temperado e revenido, objetivando obter os graus X42R, X42N e X70Q, respectivamente. Ensaios de tração, dureza e impacto foram utilizados para caracterizar o comportamento mecânico dos diferentes graus do aço. Técnicas de microscopia eletrônica de varredura foram utilizadas para caracterizar as microestruturas resultantes dos tratamentos térmicos e as fractografias dos corpos de prova de tração e impacto. Os resultados mostram que tubos de aço sem costura do tipo API 5L não precisam ser de graus tão elevados quanto os tubos soldados, pois graus intermediários relativos aos tubos sem costura possuem propriedades mecânicas similares aos elevados graus de aço relativos aos tubos soldados, o que evidencia a vantagem da rota de fabricação de tubos sem costura.

Aug 17, 2017

By Henry H. Ginsberg

The effectiveness of 0.01 pct. molybdenum, as ammonium molybdate impregnated on coal, on the hydrogenation of a high-volatile bituminous C coal at 8,000 p.s.i.g. and 460° to 480° C. has been studied in a pilot plant by the Federal Bureau of Mines. Under these conditions, the Bureau obtained 98 to 99 pct. conversion5/ of coal to liquids and gases at throughputs of 29 to 101 lb. of m.a.f. coal per cubic foot of reaction space per hour. At 460° C. the indicated yield of oil ranged from 63 pct. (based on m.a.f. coal) at a throughput of 35 lb./c.f.h. (pounds per cubic foot per hour) to 68.5 pct. at a throughput of 58 lb./c.f.h., and the yield of gaseous hydro-carbons ranged from 25.5 to 19 pct. at the same throughputs. The maximum measured yield of oil boiling under 325° C. was 47 pct.

Jan 1, 1960

By Ying Qin, Shujing Zhu

The characterization of adsorption of natural and composite bentonite in lead aqueous solution has been studied. The results showed that adsorption of both natural and composite bentonites strongly depended on the pH values of the solution. At lower pH values, the mechanisms that govern the adsorption of bentonites were dissolution of crystal structure and competition between the metal ions and the H+. To composite bentonite, the lead ion removal capacity was close to 250 mg/g. At higher pH values, formation of lead hydroxyl species might lead to either participation to the adsorption or precipitation onto the bentonites. Hence, a rapid increase in the equilibrium removal capacity of lead was obtained when pH > 7.0. An increase in the initial lead ion concentration led to the increase in the equilibrium adsorption capacity increased to a certain degree; and then, a plateau was obtained at higher concentrations. As a result, the adsorption performance of composite bentonite was better than the natural bentonite in both physical and chemical changes. The data fitted well with both Langmuir and Freundlich isotherms.

Mar 1, 2017

By Gene R. Block

The most economical method of reclaiming land that has been mined, whether it be in urban areas or in rural areas, is when the final configuration of the mining area is that which is required by the subsequent use. Surprisingly, there are a number of examples of this situation. In the arid southwest where water production for the expanding population is a problem, many urban sand & gravel excavation areas subsequently serve as holding basins for ground water recharge. In other areas of the county where water is not in short supply, sand and gravel excavations can be planned in such a way that subsequent land uses such as parks and homesites can be enhanced by utilizing the excavated areas as a water amenity. Reclaiming land for agriculture is another example of utilizing the excavated area for a subsequent use providing the excavated area has not been mined too deep. Other than replacing the layer of topsoil on the excavated area, the final configuration of the mining area is in many cases ready for the subsequent agricultural use.

Jan 1, 1984

By Ronald S. Conti

The Bureau of Mines conducted a comprehensive laboratory study of the thermal ignitability of various carbonaceous dust clouds with particular emphasis on various ranks of coal dust. The tests were conducted using a new 1.2-L furnace. Autoignition temperatures of dust clouds were obtained as a function of coal volatility and particle size. Dust particles and gas samples were collected by a rapid-sampling system in order to study the reactions involved in preignition and postignition processes. The autoignition temperatures measured in the new 1.2-L furnace were significantly lower and therefore more conservative than those measured previously in the Godbert-Greenwald furnace. The combined effects of thermal and electrical ignition of dust clouds were also studied in the 1.2-L furnace using electrical discharges of varying energies at ambient and elevated temperatures. The minimum spark energy necessary to ignite a dust cloud decreased significantly as the temperature of the dust cloud increased.

Jan 1, 1983

By Kuniaki Murase

Cadmium telluride (CdTe) semiconductor has been well investigated as a CdS/CdTe heterojunction solar cell material since its band gap is suitable for energy conversion from sunlight into electricity. In this paper a new electrochemical processing of thin-layered CdTe using basic aqueous electrolytes is reviewed from the standpoint of thermodynamics using a potential-pH diagram. The cathodic electrodeposition of the stoichiometric CdTe with a flat surface morphology took place at more positive potentials than that of the Nernst potential for the bulk-Cd deposition and at more negative potentials than that for the hulk-To. In this potential region deviation from the stoichiometric composition of eleetrodeposited CdTe was controllable by the Cd(II)/Te(IV) concentration ratio, pH, or concentration of complexing agent for Cd2+ ions of the electrolytes, The deposition behaviors for ammoniacal media were well accounted for by the potential-pH diagram of the Cd-Te-NH3-H2O system devised by a combination of those of the Cd-NH3-H20 and the Te-H2O systems, Diagrams for other complexing agents, ethylenediamine and diethylenetriamine, were also constructed to investigate and discuss the electrodeposition conditions regarding the corresponding media.

Jan 1, 2003

By Sebastian Ernst Volkmann, Felix Lehnen

"INTRODUCTIONWhile today’s mine planning of land-based ore deposits follows methods, which are well established, mining standards for the deep-sea have not established. Having gained a basic understanding of geological settings, there is still a lack of tools and methods to assess and plan future mining projects in the deep-sea. In the framework of the “Blue Mining” research project (2014-2018) technologies and methods for the exploration and exploitation of deep-sea minerals are developed that will bring deep-sea mining a step closer. The “Blue Mining” project receives funding from the European Commission (EC; Framework Programme 7; GA No. 604500) and addresses all aspects of the value chain in the field of deep-sea mining. The project philosophy is that deep-sea mining is planned and executed in the most responsible manner: Ensuring societal benefits and profitability at acceptable resource utilization and lowest possible environmental footprint (Volkmann 2014).Inspired by the high-tech farming industry, a concept to mine seafloor manganese nodules (SMnN) was developed. Mining is considered to be similar to the potato harvest on land (Figure 1), which involves mining a field partitioned into long, narrow strips (Volkmann and Lehnen 2017). The proposed mining system composes of one mining support vessel (MSV), one or two self-propelled, crawler-type seafloor mining tools SMT(s) and different types of underwater vehicles. The MSV follows the mining route of the SMT(s), picking up the about potato-sized nodules from the seafloor. The ore is pre-processed in situ and is lifted on board of the MSV, where the ore is dewatered and loaded onto bulk carriers for transport to the purchaser. Processing and refining of ore is not subject of “Blue Mining” research."

Jan 1, 2017

By S. H. Ash

THE MAGNITUDE of the anthracite industry's drainage problem in the Northern field of Pennsylvania is realized when it is known that, for the 8-year period 1944-51, all pumping plants in this region pumped an average volume of 112.5 billion gallons of water from the mines to the surface each year. This is over 214,000 gallons per minute pumped against an average hydrostatic head of 400 feet each year for that period (12).4 By comparison, Lake Wallenpaupack, the largest artificial body of water lying wholly in Pennsylvania, contains 71 billion gallons of water in its 24-square-mile area; the average volume of water pumped from the mines in the Northern field each year during the 8-year period was 58 percent more than the volume impounded in Lake Wallenpaupack. The natural configuration of the drainage area overlying the Northern field subdivides the total area into two major drainage areas-the Lackawanna River drainage area and the Susquehanna River drainage area overlying the Wyoming Basin. Although the 169-square-mile drainage area overlying the Wyoming Basin is slightly less than half that of the Lackawanna River drainage area (10), the total volume of water pumped to the surface from mines in the Wyoming Basin is 21 percent more than the total volume pumped to the surface from mines in the Lackawanna Basin. From this, it is apparent that the Susquehanna River and the pervious deposits in the buried valley over which it flows in its course across the coal measures of Wyoming Valley is the greatest single source of mine water affecting mines in this area. Because of its relatively flat terrain, the wide flood plain of Wyoming Valley does not facilitate rapid runoff; consequently, much of the surface water seeps directly into the buried-valley deposits and eventually into the mine workings.

Jan 1, 1953

By J. Fellowes, V. Landais, J. Robson, J. Carr

"Aerospace Al-Zn-Mg-Cu (7xxx) alloys are known to be susceptible to environmentally assisted cracking (EAC). This phenomenon has been studied intensively for many decades, leading to empirically adopted methods to mitigate this problem through overaging and composition design. In parallel, many theories have been developed to explain EAC in 7xxx, but none is yet universally accepted. Today, a number of emerging techniques offer potential to shed new light on EAC in 7xxx. The purpose of the present paper is to demonstrate how X-ray tomography (XCT) combined with electron microscopy can be used to identify the true crack path in 3-dimensions, and hence identify material for site specific electron microscopy analysis. Composition mapping over large areas to high accuracy has been performed using a modern electron microprobe analysis system. This has been combined with transmission electron microscopy to investigate local composition in matrix and precipitates at high resolution. This combination of techniques across length scales offers the potential to provide new insights into the links between local composition, microstructure, and EAC resistance.INTRODUCTION Environmentally-assisted cracking (EAC) is a phenomenon which dramatically decreases the performance of metals and can cause premature failure of large structures. Observed in situations where components were not subjected to critical loads and no widespread corrosion was involved, this type of brittle failure is extremely difficult to predict. The EAC designation covers a number of phenomena, e.g. stress corrosion cracking (SCC), hydrogen embrittlement (HE), corrosion fatigue (CF), etc. Initially identified in steels, EAC can also affect other metals such as high-performance aerospace aluminium alloys, and this phenomenon has been a concern for industries for decades. Extensive research has been conducted on the effects of various environments (moist air, saline water, dry hydrogen gas, etc.) on microstructures and crack propagation, however no consensus has been reached and the exact nature of the mechanisms that control EAC is still being debated (Birnbaum & Sofronis, 1994; Gangloff, 2007; Holroyd & Scamans, 2013; Lynch, 2012; Oriani, 1972; Scamans, Alani & Swann, 1976, Young & Scully, 2002)."

Jan 1, 2018

By Corale L. Brierley

Bacteria, algae and fungi react to heavy metals in their environment by immobilizing, mobilizing and/or transforming metals. Microorganisms carry out these changes by (1) precipitating metals outside of the microbial cell, (2) binding and complexing metals to the outside of the microbial cell's protective coating, (3) accumulating metals inside of the microbial cell, or (4) transforming metals by oxidation, reduction, methylation or demethylation. Most of these mechanisms are operative in constructed aerobic and anaerobic wetlands for metal's remediation. Several more advanced biotechnologies for metal's removal from aqueous streams have been introduced, but have not been widely accepted commercially.

Jan 1, 1995

By G. B. Harris

Much has been written over the past decade concerning the disposal of arsenic from metallurgical processes. In Canada, there are proposed regulations which would classify arsenic in the Primary Group of twenty one persistent, toxic pollutants to be banned or phased out. Since many nickel and cobalt ores, not to mention those of copper, gold and uranium, contain significant amounts of arsenic, it is pertinent to assess the current state-of-the-art of its disposal. The literature is reviewed, and it is demonstrated that from a purely chemical point of view, the family of ferric arsenates largely immobilize arsenic. There is clear evidence from laboratory studies that both crystalline ferric arsenate (scorodite) and amorphous ferric arsenates in which the molar Fe/As ratio is at least three (Fe/As = 3) have very low arsenic solubility; plant data are given to support this. The debate over the long term stability of these compounds continues however; the evidence presented for long term stability and for compound breakdown is critically reviewed in the light? of the recent structural studies, and the role of base metals in these compounds evaluated. Finally, conclusions are drawn as to the viability of a purely chemical process for the long term disposal of arsenic from metallurgical processes.

Jan 1, 1993

By Lowell Stroud

Since 1929, the Helium Activity of the Bureau of Mines has operated a helium-extraction plant at Amarillo, Tex. The natural gas that supplies this plant is obtained from the Cliffside geologic structure 12 miles to the northwest and over the years, has become known simply as "Cliffside gas," There is need for published data on the low-temperature phase equilibria of helium-bearing natural gases. To date, little information has been published on the equilibrium phase compositions, solution of helium in condensed natural gas, condensation characteristics, or equilibrium vaporization coefficients for methane, nitrogen, and helium in helium-containing systems. A windowed phase equilibrium apparatus (8)6 was used to obtain 105 equilibrium samples, representing 35 experimental conditions of condensed Cliffside gas at pressures of 100, 200, 300, 400, and 500 p.s.i.a. and temperatures from 0° to -270° F. Data on equilibrium vapor-liquid composition for Cliffside gas are presented in both tabular and graphic form and are discussed in detail to show their relationship to certain criteria that must be met to effect an efficient separation of helium from natural gas by means of low-temperature processes. Facts about condensation characteristics and solution of helium in the liquid phases are included, The important relationship of these two factors in decreasing the percentage of total helium lost by solution in the liquid phase is discussed.

Jan 1, 1961