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By A. S. Mustafinova, A. A. Zharmenov

"Production of electrolytic copper is characterized by large volumes of acidic spent solutions the utilization of which requires considerable expenditures of neutralizing agents. At present, an economically substantiated technology does not exist for treatment of sulfuric acid rinse solutions and spent copper electrolyte which will allow for repeated use of the acid and the metal salts. Therefore, for this aim the most advantageous is the use of electromembrane methods. In the paper there is stated the essence of developed technologies which are distinguished by low waste and provide the extraction from the solutions of metallic copper, nickel and sulphuric acid. There are also considered methods of copper electrolyte processing allowing to regulate its composition by that or another component (H2S04, Cu, Ni, As).On the base of the detailed study of the behaviour of various types of ion- exchanger membranes in copper-, nickel-, zinc-, arsenic- bearing sulphate solutions there is realized the selection of the most suitable membranes (MK -401, MA-411, MB-2 and MKL-l/MAL-2).Some variants of electro membrane processing of spent solutions of the hydrometallurgy process have passed productions tests on a number of copper-electrolyte enterprises of the countries of CIS (cooperation of Independent States). These tests showed high efficiency of developed methods."

Jan 1, 1997

By W. L. Dalmijn, E. A. Schokker, N. Fraunholcz, P. C. Rem

Many processes developed for the mechanical processing of Automotive Shredder Residue (ASR) suffer from high processing costs. We offer a distinct concept for low-cost mechanical processing still allowing high value-added recycling of the recovered materials. The basic idea behind this approach is to produce saleable pre-concentrates at the lowest possible costs that can be further processed in existing separation facilities. Our process includes screening, size reduction and magnetic separation. Preliminary studies showed that fibers in ASR are magnetic due to adhering rust particles allowing separation into a fiber fraction and a non-magnetic rigid fraction by high-intensity magnetic separation. The fiber fraction is most suited for thermal processing. The rigid fraction mainly consists of plastics and rubbers with up to 10 wt.-% of non-ferrous metals, some inert material and copper wires. This fraction is very well suited for mechanical processing by, e.g., sink-float separation in existing metal separation plants. The non-metal fraction can be processed further to recover the plastics and rubbers. The process proposed in this study is expected to be substantially cheaper than full thermal processing. In addition, as it mainly relies on existing separation facilities, it can be applied in the short term.

Jan 1, 2000

By Matthias Frommer, Carl-Peter Reipl, Reinhard Flende

"Today there is a growing demand for strip of superior steels with specifically tailored technological properties. Especially strips of high-strength, micro-alloyed steel grades applied to manufacture longitudinally and spiral-welded pipes are a growth market. Tubes are generally required to have high strength and sufficient toughness values and thus favour specific hot strip microstructures. The correlation of chemical analysis, process parameters and mechanical properties with microstructural features is still a challenging task. During the last decades, scanning electron microscopy (SEM) and electron backscatter diffraction (EBSD) have become useful tools for the characterization of complex microstructures. The EBSD data provides an immense variety of post-processing possibilities, e.g. related to grains, grain boundaries, misorientations or texture. This paper highlights the results of an advanced analysis of microstructures representing industrial produced hot-rolled strips and presents an approach to define and quantify some essential microstructural parameters.IntroductionHigh-strength microalloyed steels have been used for the production of welded pipes for more than 30 years. However, the alloy design of pipeline grades is being continuously modified and the process technology optimized because of the increasing high strength-toughness combination requirement for pipeline steels. Compact strip production (CSP®) technology is an upcoming promising route for the production of high-quality pipeline steel grades [1]."

Jan 1, 2012

By Dirce H. Jacomo, Jaciele G. Teixeira, Anibal Y. Abreu Castillo, EsperidianaA. B. Moura, Yalquiria A. Silva, Rene R. Oliveira, Michelle G. Gomes

"Composites consisting of poly(vinyl alcohol), starch and sugarcane bagasse ashes, using glycerol as plasticizer agent, were prepared by solution casting method. Composites prepared were subjected to electron-beam radiation treatments, at radiation dose of 50 and 80 kGy using a Dynamitron electron beam accelerator, at room temperature in the presence of air. The composite samples obtained were evaluated for their water absorption, mechanical and morphological properties.1. IntroductionThe potential of biodegradable polymers and more specifically of biocomposites obtained from agro-resources have long been well established [1-3]. Starch, derivate from variety of botanical sources (cereals, legumes, and tubers) is widely available raw material and one of the most studied and promising agro-resources for the production of biodegradable polymers as matrices for biocomposite applications. However, starch itself is very brittle, hydrophilic and its mechanical properties are very poor for many applications [3 - 5]. The blending of starch with conventional polymers is a promising approach to improve its drawbacks. Recently, many efforts have been made to blend starch with biodegradable synthetic polymers [5, 6]. Polyvinyl alcohol (PYA) is a particularly well-suited synthetic polymer for the formulation of blends with natural polymers, as it is highly polar and can also be manipulated in water solutions, and depending upon its grade, in functional organic solvents as well [3, 7]. PY A has been reported to be an option to blend with starch. Most of the starch/PY A composites have been prepared by casting. However, it is well known that starch/PY A composites has poor in water resistance and mechanical properties after absorbing water [3,8]. Attempts to improve the mechanical properties and to decrease the water absorption property of the starch/PY A composites are made by adding the cross-linkers and plasticizers. Park et al. prepared starch/PY A/citric acid films by the casting method. They also studied the effect of (spell out) citric acid on the mechanical properties and water resistance of composites [9]. Zhai et al. prepared the starch/PY A hydrogels using electron-beam radiation [10]. Different kinds of lignocellulosic fibers have been investigated in blends for formulation of biocomposites."

Jan 1, 2013

By Bradford C. Wesstrom, Omar Araujo

"Impurities from an electrolytic refinery are typically extracted from the electrolyte utilizing conventional electrowinning cells. These cells are arranged in series with cascading solution flow and are commonly referred to as liberator cells. The Freeport McMoRan Copper & Gold El Paso Refinery has optimized the removal of arsenic in cascading liberator cells by utilizing two separate feed solutions. The primary feed solution is recycled liberator electrolyte and the secondary feed solution is ""neat"" tank house electrolyte. The secondary feed solution is added based on the voltage response across the individual cells utilizing independent variable frequency drive (VFD) pumps. When the voltage across a cell changes, a signal is sent to the VFD pump to maintain a cell voltage of 1.98 volts. By maintaining this voltage the copper content in each cell exits at 2-4 grams per liter. This safely optimizes the arsenic removal as copper arsenides on the liberator cathodes.IntroductionDuring the electrolytic refining of copper, impurities from the copper anode report both to the bottom of the electrolytic refining cell as slimes and to the electrolyte. The impurities which enter the electrolyte are arsenic, antimony, bismuth and nickel. The impurities that report to the electrolyte during the electrolysis process gradually increase. As these impurities increase, they are incorporated into the refined copper cathode. There are many processes that have been used to remove these impurities from refinery electrolytes. Some of them are listed as follows: solvent extraction, ion exchange, hydrogen sulfide reduction, bioreactor, adsorption onto a low - solubility metal-oxide hydrate, adsorption onto activated carbon and EMEW cells. The conventional process used by the copper refining industry for controlling the level of impurities in electrolyte involves multistage electrolytic cascading liberator cells. In these cascading liberator cells copper, arsenic, antimony and bismuth are removed as various mixed deposits from the electrolyte. Removal of these impurities is achieved through an increase in voltage resulting from the depletion of copper in the electrolyte through electrowinning. With this higher voltage, the Group Vb elements, arsenic, antimony and bismuth are deposited on the copper cathode and report as slimes to the bottom of the cells. Nickel is removed in a subsequent process."

Jan 1, 2012

By Wankun Wang, Shixing Wang, Jinhui Peng, Zebiao Zhang

"Germanium leaching from germanium dust and fume was carried out using sulphuric acid. Response surface methodology (RSM), based on a five level, four variable central composite design (CCD), was employed to obtain the best possible combination of liquid/solid ratio (Xi: 2-10), leaching time (X2: 1-5 h), sulphuric acid concentration (X3:3.15-15.75mol/L) and leaching temperature (X4:50-90 *C) for germanium leaching. The obtained experimental data were fit to a one-order polynomial equation using multiple regression analysis and also analyzed by analysis of variance (ANOVA). The 3-D response surface plot and the contour plot derived from the mathematical models were applied to determine the optimal conditions. The optimum extraction conditions were: liquid/solid ratio of 10, leaching time of 1 h, sulphuric acid concentration of 15.75 mol/L, and leaching temperature of 87.8 'C. Under these conditions, the germanium leaching extent was 65.14%, which is in close agreement with the value predicted by the model. The samples were characterized before and after leaching using X-ray diffraction (XRD).IntroductionResponse surface methodology (RSM) is one of the relevant multivariate techniques which can deal with multivariant experimental design strategy, statistical modeling and process optimization [1-15]. It is used to examine the relationship between one or more response variables and a set of quantitative experimental variables or factors. This method is often employed after the vital controllable factors are identified. It is also used to find the factor settings that optimize the response. Designs of this type are usually chosen when a curvature in the response surface is suspected [6], The process optimization of the sulphuric acid leaching of germanium from germanium dust and fume has not been reported in the literature. Hence the present work intends to assess the effects of variables such as liquid/solid ratio, leaching time, sulphuric acid concentration and leaching temperature and to identify the optimum conditions using RSM. The characteristics of sample before and after leaching are assessed using the advanced analytical instruments such as X-ray diffraction (XRD)."

Jan 1, 2012

By Songlin Zhang

"The McCoy/Cove mine, located in Eureka-Battle Mountain trend of Nevada, is a gold and silver deposit. Case studies of recoverable reserve estimation for gold and silver were made using multiple indicator kriging and volume variance correction. The grade tonnage distributions of recoverable reserves were constructed and compared with the distributions defined by blast hole assays. Optimal pits were generated by Whittle 4D pit optimization package to analyze the impact of different processing recoveries at different economic cutoffs. The results were compared with ordinary kriging. The study indicates that the proposed method for multi-mineral recoverable reserve estimation is more accurate than kriging in tenns of grade and tonnage. The method of using recoverable reserves for pit optimization will maximize global reserve recovery and revenue, and is more efficient than condition simulation regarding computing power.ABSTRACT ONLY"

Jan 1, 1997

By Ray D. Peterson, Annette Revet

The optimization of secondary aluminum furnaces is critical to the efficient operation of a recycling facility. Since all metal loss occurs in the drosses, physical and chemical analyses of these by-products are valuable diagnostic tools. Dross analyses can provide information concerning total furnace metal recovery efficiency as well as identifying areas for potential improvements. A complete dross analysis is a labor-intensive process that requires significant care both in sampling and performing the analytical techniques. Experiments can be done at a bench- or plant-scale depending on the facilities available. This paper outlines the benefits and information that can be generated through dross studies. Furthermore, several analytical methods are discussed as well as the special requirements needed to gain accurate results. Experimental data from industrial studies is provided to demonstrate the use of dross evaluations for ~ace optimization.

Jan 1, 2000

By J. Miernik, D. Krupka, B. Ochab

The electrolytic zinc plant, with a capacity 75,000 tonnes per year, is part of Zaklady Gorniczo-Hutnicze BOLESLAW. It is the biggest zinc producer in Poland. The electrolytic zinc plant started up in 1955 with a capacity 15,000 tonnes per year, and multiplied its production by 5 till nowadays. At the beginning, the plant processed only calcine from zinc oxides (60% Zn, 3-4% Pb, 0,03 % Cd) which were produced from Waeltz fumes by calcination in a rotary kiln. Participation of calcine from zinc sulfide concentrates in the feed grew during the BOLESLAW plant expansion. Currently, only roasted sulphide concentrates, calcine from fluid-bed roasters, is processed. This paper presents a general description of the ZGH BOLESLAW plant and discusses the processes of roasting, leaching, purification and electrolysis. Also shown are the chemical analyses of the various process materials.

Jan 1, 2000

By P. J. Harrington

The recovery and recycling of low concentration metal and other ions has traditionally been carried out using adsorption or ion exchange processes which, however, become uneconomical at higher concentrations, such as those that occur with many intermediate or waste streams where recycling is now being required. This paper describes the development of a process based on non-dispersive solvent extraction for the recovery of chromium (VI) from electroplating rinse water. During the chromium plating of steel, the concentration of chromium (VI) in the rinse bath rises to concentrations in the order of 100 mg/L when it becomes unusable and is then disposed of. The aim of this work was to investigate processes for recovery and recycling of the chromium in the rinse bath. The recovered chromium is required to be concentrated and purified before reuse. Tertiary amines have been shown capable of concentrating and purifying the chromium (VI) in solution. However, solvent extraction processes that have been applied to the recovery and reuse of metals from waste streams have had only limited success in the past, primarily because of the relatively high solvent losses when existing contacting equipment is used on low feed concentrations. Attempts to eliminate losses by immobilizing these complexing agents on substrates have not been successful. In order to control the losses and maintain specificity, a hollow fibre-contained liquid membrane has recently been trailed in a pilot plant to recover chromium from chromium plating waste streams. Details of the trial and modeling of the results are presented, and show that the level of losses is significantly reduced. However, issues relating to fouling still need to be addressed. This type of equipment has many applications in the recovery and recycling of a range of materials in the manufacturing processes.

Jan 1, 2003

By Anne C. Chinellato, Alejandra T. Soria, Nelida L. del Mastro, Amanda C. S. Pereiral, Esperidiana A. B. Moura, Anibal V. Abreu

"This work presents a comparative study of the thermo-mechanical and morphological properties of sugarcane bagasse fiber/HDPE composite treated with electron-beam and gamma radiation. The composite samples obtained by extrusion and injection molding processes were irradiated at 50 and 90 kGy using either a 1.5 MeV electron beam accelerator or gamma irradiator EMI-9, at room temperature in presence of air. The irradiated and non-irradiated samples were submitted to mechanical and MPI tests, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), sol-gel analysis and X-Rays Diffraction (XRD) and the correlation between their properties was discussed. Improvement of the bagasse fiber/HDPE composite properties, using electron-beam or gamma radiation, was found.IntroductionResidues of sugarcane bagasse fiber are widely produced in Latin America and other countries: in Southern Africa, Egypt, South-Eastern Asia, India, China, Australia, Cuba, among other producers, as by-products of the sugar and bioethanol industry. The sugarcane industry in Brazil and Uruguay is well established and expanding with large potential to increase the production of sugarcane bagasse in the next years [1-3]. Although the major portion of the bagasse is currently burnt for energy supply in the sugarcane industry, the disposal of this byproduct is still inefficient and, consequently, it is critical for agricu1ture profitability and environmental protection. Sugarcane bagasse is a lignocellu1ose fiber mainly constituted by around 46 % cellu1ose, containing hemicellu1ose, lignin, fat and waxes, silica and other elements [3, 4]. Studies have reported that sugarcane bagasse can be used to produce thermoplastic polymeric composites with excellent properties for many applications. [5-8]. Based on this survey, the transformation of bagasse into high quality industrial products, such as bagasse-polymer composites, can provide its more effective utilization."

Jan 1, 2012

By Paykan Safe

The primary source of fugitive gas emissions in most copper smelters are the Peirce Smith converter operations. The modem trend is towards installation of secondary gas collection systems which are intended to collect fugitive gases from charging, standby, and skimming operations. These have been installed with varying degrees of success. Often, the major source of emissions from the converter area is leakage of process gas from the primary hoods when the converter is blowing. This gas is typically collected by the secondary system and discharged to atmosphere or scrubbed with an alkaline agent. Those smelters considering installation of secondary hoods or scrubbing of gases from secondary systems should first address the issue of gas leakage from the primary hoods. Improving the primary hood gas collection efficiency will often be more cost effective than installing secondary hooding. In the case of secondary gas scrubbing, it will significantly reduce the reagent consumption and operating cost of the scrubbing system. This paper examines the parameters that determine whether or not a primary hood will effectively collect process gases without leakage and demonstrates, using Computational Fluid Dynamics (CFD), the effects of variations in these parameters on the overall performance of the hood. It also looks at the application of CFD techniques in the design of secondary hoods and presents a summary of measured emissions from converter buildings.

Jan 1, 2002

By G. T. Lapidus

One of Society’s major concerns with hydrometallurgical processing is the large amount of water that is quintessential to its nature. This is especially troubling in arid areas, where the population struggles to procure potable water for their daily needs. For that reason, it has become our responsibility to conceive, design and implement processing schemes that not only use as little water as possible, but recycle streams within the plant itself and minimize waste that exits its perimeter. With this in mind, the conference will center on the importance of selecting the appropriate chemical systems and integrating material balances to avoid reagent overkill and to detect impurity accumulation. The three “R’s” (reuse, recycle and recovery) of aqueous solutions within the processes are emphasized. Examples of processes for the recovery of lead, copper, precious and PG metals from minerals and waste materials will be presented.

By Jan Steinhoff

The design options of a gravity separator are still limited and rely on the study of settling behavior. A methodology will be presented where an experimentally given inlet droplet size distribution (DSD) is the basis for the calculation of the dispersion layer in a gravity separator. A pilot-scale continuous gravity separator is presented and CFD (computational fluid dynamic) results are validated. A transmitted light measurement technique for the determination of the DSD is presented up to a holdup of 15% dispersed phase. The resulting DSD was in the range of 20–2000 μm depending on flow rate and phase ratio. Furthermore, correlations of the real DSD with the settling behavior of the dispersion in a settling cell are discussed. The new approach to the description of gravity separators will be presented and the applied CFD methods showed good results with the system water/paraffin.

By D. L. Stewart

"Melt loss is usually one of the highest individual cost items in the operation of ah ingot casting facility. While melt loss and the resulting cost for the entire facility is usually well known (at least via standard cost accounting), dross generation and melt loss for individual unit operations within the plant are usually not known. Thus, the financial impact of various practices, alloys and scrap types is not known. Development of an accurate, relatively low-cost technique for measurement of melt loss at commercial scale would aid in understanding melt loss for existing units, as well as evaluation of the melt loss impact of alternate processes.This paper will describe a methodology developed at Alcoa for accurate and inexpensive measurement of melt loss at commercial scale. The methodology has been used to evaluate the impact of scrap type, melting practices, and dross treatment technology on melt loss."

Jan 1, 2000

By F. Tailoka

In order to decrease the voltage required for electrorefining, a recessed electrode cell has been developed in which the anode and cathode have recesses machined into their faces. The anode and cathode plates are separated by a thin refractory cloth and the cell is filled with fused salt. Bismuth containing 10 to 90 % lead with copper and silver as minor impurities has been electrorefmed at a current density of 10,000 to 20,000 Am-2. The cell voltage was between 285 and 635 millivolts and the bismuth was refined to a purity of 99.9 %. Flow patterns were observed in a room temperature model of the recessed channel cell using water and mercury to simulate molten metal and the fused salt electrolyte. The flow in the electrode recesses is characterized by discrete droplets when the liquid flow rate is low and thin streams and rivulets at higher flow rates.

Jan 1, 1995

By Tugba Basargan Çagatay Morall, Gülhayat Nasun-Saygili

"The aim of this study is to prepare the apatitic material using colemanite mineral (2CaO.3B2O3.5H2O) which was obtained from Eastern Anatolia, Turkey. For this purpose, colemanite mineral was reacted with different phosphate sources, namely, dipotassiumhydrogen phosphate, ammoniumhydrogen phosphate and ortophosphoric acid at various temperatures and time periods. Experiments were run in batch system. The apatitic material was prepared by a wet method and followed by heat treatment at various temperatures. Structure of the samples was analyzed by XRD, FTIR, XRF and SEM. The particle size analysis was also made for the result product. The experiments showed that reaction temperature, contact time and heating temperature are important parameters to transform the colemanite into apatitic structure. Reaction of colemanite with dipotassiumhydrogen phosphate and ammoniumhydrogen phosphate results in amorphous, non-stoichiometric hydroxyapatite type structure, while acid based phosphate source gives brushite and monetite type product before and after heat treatment, respectively.IntroductionBoron which has properties intermediate between metals and non-metals is a member of semiconductor group of elements. Its atom is very small and has three valence electrons. Boron exists in Earth's crust (from 5 mg/kg in basalts to 100 mg/kg in shale) and in the oceans (4.5 mg/l) [1]. Turkey has 60% of world's boron reserves which is mostly in the form of colemanite (2Ca0.3B203.5H20). Colemanite is the most important calcium containing commercial borate mineral with 5 mol of crystal water [2].Calcium phosphate cements are very useful for bone repair applications because of its chemical structure. They are injectable, easy to shape and can be maintained locally. Because of those reasons calcium phosphate cements are very effective to fill bone defects with an irregular shape [3]. Hydroxyapatite (Ca10(PO)6(OHh) is the major component of the bone (70 wt%). However, hydroxyapatite stoichiometry, composition and crystallinity differ in human skeleton system [4, 5].The main objective of the present work was to study the transformation of colemanite to apatitic material using different phosphate solutions at several time spans and temperatures. The experiments were run in a batch system, change in pH and also weight loss were measured after the experiments. Several analysis methods were used to investigate the chemical and structural changes."

Jan 1, 2012

By Tzu-Chien Lin, Jack Tsai, Ming-Yu Lin, Der-Ray Huang, Jiin-Sen Chen, Jing-Xuan Lin

"In this paper, some DVD-R discs have been selected for long time light exposure test and high temperature and humidity test. Generally, recordable media under long time light exposure maybe be defected seriously. If we use Jitter value 8% as a reference to determine the life time of DVD-R samples, some discs defect after 5 hours of light exposure while some discs can endure over 25 hours. Also if we use reflectivity 45% to determine the life time, some discs defect after 30 hours light exposure while some discs can endure over 40 hours. From our results, the good samples show good characteristics of PI error. The absorption spectrum of recordable media is a good reference to justify the quality of dye media. These results can be used to estimate the life time of recordable discs.IntroductionIn general, the life time of DVD-R with a layer of organic dye recording layer is required for preservation in decades. In addition to optical characteristics and thermal properties, we still need to consider the stability of the dye in recording media. The presentation of the color on organic dye is not only related to the material's property but also related to the light exposure. In this study, we focus on the absorption characteristics and reflectivity of organic dye in optical recording layer after light exposure. The optical properties of discs depend on the functional groups and molecular structure [1]. According to ""DVD Specifications for Recordable Disc (DVD- R)"", the reflectivity should higher than 40%. From measured reflectivity, we can confirm that the important issue is whether dye be affected by light exposure or not. Because each specific functional group absorbs the specific spectrum, we can check the characteristics of functional groups from their UV/Visible Spectra. We also use High-performance liquid chromatography (HPLC) to detect the different components of dye on the recording layer [2]. The jitter value test is to test the error cause by digital signal of recording media. If we use jitter value 8% as a reference to determine the life time of DVD-R samples, the purpose of this study is to investigate the jitter values of recording media after high light exposure and high temperature/humidity test. The results of these test will be helpful for the development of long-life optical storage media."

Jan 1, 2012

By Cheng Gong-jin, Chu Man-sheng, Liu Zheng-gen, Zhang Yong, Liu Jian-xing, Xue Xiang-xin

"High chromium vanadium-titanium magnetite is one kind of Fe-V-Ti-Cr composite ore resources, which owes high utilization value. Owing to lacking systematic study on the sintering of this ore home and abroad, effects of carbon addition and basicity on sintering process and sinter metallurgical properties, such as sinter yield, vertical sintering speed, tumbler strength, sinter machine utilization coefficient, and low temperature reduction degradation were investigated systematically under laboratory conditions in the paper. The results shows that, when high chromium vanadium-titanium magnetite proportion is kept unchanged as 13% in sintering feeds, sintering process index and metallurgical properties are the optimum under carbon addition 5.0% and basicity 2.70, which meets the requirements of blast furnace burdens. This research provides technical parameters for practical sintering production of high chromium vanadium-titanium magnetite.IntroductionHigh chromium vanadium-titanium magnetite (hereinafter abbreviated as hi§h-Cr V-Ti magnetite), in which Fe is closely symbiotic with Ti and isomorphous with V and Cr1'- l, is one kind of typical vanadium-titanium magnetite resources with high comprehensive utilization value but the difficulties are extremely high due to complex chemical composition and mineral structure. At present, the feasible and mainstream utilization process of high-Cr V-Ti magnetite should be the route of agglomeration-blast furnace smelting. Thus, sintering production is the foundation for high-Cr V-Ti magnetite utilization. However, till now there are few research documentations on high-Cr V-Ti magnetite sintering home and abroad. Under the above background, this study focused on detailed researches of high-Cr V-Ti magnetite sintering. Sintering process uses the powders or fine iron ores to produce artificial rich ore with good metallurgical properties 4l Solid fuel provides 90% heat requirement during sintering15J. The appropriate amount of fuel and flux should be added during sintering in order to provide necessary heat and maintain the desired basicity16l. That is to say, carbon addition and basicity are two key factors affecting metallurgical properties of sintering products17J. Therefore, the effects of carbon addition and basicity on sintering process and metallurgical properties, including sinter yield, vertical sintering speed, tumbler strength, sinter machine utilization coefficient, and low temperature reduction degradation, are systemically investigated under laboratory conditions in the study, on purpose to achieve the optimization of sintering process for high-Cr V-Ti magnetite."

Jan 1, 2013

By Riyad N. Ahmad-Bita, Shadia J. Ikhmayies

"SnO2:F/CdS:In structures were prepared by the spray pyrolysis technique on glass substrates at a substrate temperature Ts = 450°C. NH4F and HF were both tried as the sources of fluorine in the precursor solution of SnO2:F. A comparison between the properties of structures obtained by using the two doping compounds was performed. X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmittance measurements were used to characterize the films. The structures prepared by using HF as a fluorine source were found to have more ordered crystal growth, larger grain size and sharper absorption edge. From the inspection of the first derivative of the absorbance it is expected that more interdiffusion on the SnO2:F/CdS:In interface takes place in the structures made by using HF. These results confirm that these films are better as forecontacts for CdS/CdTe solar cells.IntroductionThin film CdS/CdTe solar cells built in the superstrate geometry rely on transparent conducting oxides (TCOs) to make the front contact The investigation of combined CdS-TCO films has recently been developed owing to the great interest of better understanding the effect of these bilayers on the absorbers [1]. Usually SnO2 is utilized as a front contact for these solar cells. Optimizing the properties of the SnO2/CdS structures is an important step on the way to get high performance CdS/CdTe solar cells.There are different methods to prepare SnOz thin films, such as reactive sputtering [2], evaporation [3], chemical vapour deposition [3, 4], dip coating [5] and spray pyrolysis [6-9]. At the same time CdS thin films can be prepared by different techniques such as chemical bath deposition [10], thermal evaporation [11], screen printing [12] and spray pyrolysis [7, 13]. However, the spray pyrolysis technique is a very low cost and simple technique that enables intentional doping and getting large area and uniform thin films [14]. For these reasons it is choused to prepare SnOz and CdS thin films in this work. To improve the properties of these compound semiconductors, SnOz was doped with fluorine and CdS was doped with indium where such doping is well known for these compounds."

Jan 1, 2012