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By David A. Holmes

Zeolites are crystalline, hydrated aluminosilicates of the alkali and alkaline-earth metals. Their crystalline framework is based on a three dimensional network of SiO4 tetrahedra with all four oxygens shared by adjacent tetrahedra. The alkali and alkaline-earth cations are loosely bound within this framework structure and may be exchanged, to varying degrees, with other cations or molecular water. Most zeolites can be reversibly dehydrated. At present, close to 40 natural zeolite minerals have been identified and over 100 zeolites have been synthesized. Zeolites are a family of hydrous aluminosilicate minerals whose physical properties provide unique features for a wide variety of practical applications. Zeolites have been known for more than 200 years, but it was not until the middle of this century that their economic potential and widespread occurrence in sedimentary rocks were known. Since 1950, literally thousands of articles and patents have appeared in technical literature, and commercial pro¬duction of natural zeolites may now exceed 1 Mt worldwide an¬nually. In the past 40 years, the zeolite mineral group has changed from that of a museum curiosity to one of an established industrial mineral commodity. According to Breck (1974), zeolites are characterized by the following properties: 1) High degree of hydration, 2) Low density and large void volume when dehydrated, 3) Stability of the crystal structure of many zeolites when dehydrated, 4) Cation exchange properties, 5) Uniform molecular-sized channels in the dehydrated crys¬tals, 6) Ability to adsorb gases and vapors, 7) Catalytic properties. All zeolites are molecular sieves, but not all molecular sieves are zeolites. Activated carbon, activated clays, alumina powder, and silica gels are also molecular sieves. Molecular sieves are materials that can selectively adsorb molecules on the basis of their size, shape, or electrical charge (Clifton, 1987). Commercial application of zeolites is based on the following physical properties: molecular sieving, ion exchange, adsorption, and catalysis. Potential commercial utilization includes hundreds of possible applications. The principal uses at this time, however, are as fol¬lows: -Ammonium-ion removal in waste stream treatment, sewage treat¬ment, pet litter, and aquaculture, -Odor control, -Heavy metal ion removal from nuclear, mine and industrial wastes, -Agricultural use, such as soil conditioner and animal feed supplement. An estimated 800 kt to 1 Mt of natural zeolites were produced and consumed worldwide in 1991. Eight small operators reported collective production and consumption of an estimated 18 kt of natural zeolites in the United States during 1991, mostly for feed additives and for odor control, aquacultural, agricultural, catalytic, and ion exchange applications (Eyde, 1992).

Jan 1, 1994

By J. J. Webb

At Kerr-McGee's Galatia Mine in southern Illinois, the need for safe and efficient longwall moves prompted a detailed planning effort. Galatia Mine operates two longwalls on separate coal seams with different geologic conditions. An overview of the longwall move planning as related to manpower training, roof control, ventilation, transportation, equipment recovery and setup will be discussed. The impressive safety record achieved during each of the longwall moves at Galatia Mine verifies that health and safety planning does play a major role.

Jan 1, 1994

By R. M. Clowes

Lithoprobe is a collaborative, multidisciplinary research project which is providing new insights into the tectonic evolution of the North American continent through its work within ten study areas across Canada. For the mining industry, such results provide a well-constrained regional framework and better understanding of tectonic processes which lead to the development of ore deposits. In mining camps, seismic reflection methods have proven effective in imaging shallow to moderately dipping litho logic contacts as well as structural features, and in some cases have been used for the direct detection of ore bodies. Here, short case histories are provided for the Abitibi greenstone belt (VMS deposits) in Quebec and the Thompson nickel belt in Manitoba.

Jan 1, 1999

By Mark R. Rybak, James Delmonte, Travis Hartman

The City of Phoenix, Arizona designed a 7.2 km (4.5 mi) long water transmission main from the South Mountain Reservoir to the Ahwatukee Foothills Reservoir to address the growing demand for drinking water in the southeast valley. The pipeline design called for a bored tunnel in a very environmentally sensitive area. The Reach3B contract included an 2.44 m (8 ft) diameter TBM excavated tunnel, 1,847 m(6,060 ft) in length. The geotechnical investigation revealed that the tunnel would likely pass through zones of loose to moderately cemented soils (caliche). The primary tunnel support would consist of rock bolts, circular steel ribs, hard wood lagging, and mine straps. A TBM that could handle the ground conditions and allow for efficient ground support installation was required. This paper describes the construction of a small diameter rock tunnel in challenging ground conditions.

Jan 1, 2003

By Thorvald Wetlesen

Computer controlled drilling is now proven technology. It was first introduced by the development of the Furuholmen system for a prototype three boom tunneling jumbo in Norway in 1978. Now, 13 rigs with this concept are in operation in Europe, 3. in mining in England and. 10 in tunneling elsewhere in Europe. The system is also adapted to roadheader guidance. Practical experience has shown that the computer control system makes it possible to drive tunnels with a more accurate contour thus reducing the total amount of rock excavated, and where a full concrete lining is required a reduction in concrete volume is achieved. The total tunneling economy is improved. In the future we expect to see a wider range of instrumentation on jumbos, from the simple direction instruments to computer guidance systems for monitoring only, as well as fully automatic drilling to a programmed drilling pattern. More compact and reliable electronics will be available. Systems with low power consumption will fit easily into flameproof applications. Cabling complexity will be reduced by connection of sensors to serial signal lines.

Jan 1, 1989

By F. B. Micheli

Introduction and Historical Background Although both sluices and devices using a simple flowing film are among the oldest known methods of concentration, they are still extensively employed in a variety of situations where they are not only efficient but also have a low operating cost. More particularly, they are valuable for making a bulk concentrate of high specific gravity minerals from alluvials and beach sand and in upgrading low value ores. The antiquity of some of the basic concepts can be seen in the fact that they are found in Agricola's De Re Metallica which was published at Basic in 1546, while in 1602, Carew114 gave a fairly clear account of tin ore dressing in Cornwall in which grass turves were used to catch the cassiterite. This is perhaps one of the forerun¬ners of the blanket strake. The planilla of Mexico, the lanchute of Malaysia and the old Cornish box huddle are also descended from these early strakes. In fact, a sluice with holes in the bottom for concentrate discharge was shown by Agricola, not unlike the principle used in the plane table and the lamflo sluice. The convex huddle for the treatment of sandy material appeared about 1848 and the concave form eight to ten years later. For the treatment of "slime" sizes, wooden dead frames which were manually worked were used in Cornwall for many years but gave way to the automatic water-operated type in 1860, and even a mechanically tilted frame was described by Henderson115 in 1857. Theoretical Considerations The behavior of solid particles in suspension depends to a great extent upon the pulp density and the size of the suspended particles. In a fairly dilute suspension, such as that normally used when dealing with small particle sizes, the behavior of particles in a flowing film results from two effects. These are the lateral displacement, which is determined by the time taken for each particle to penetrate the flowing film and reach the solid surface, and the resistance offered by each particle to further displacement after it has reached this surface. The initial penetration through the flowing film depends on the size and specific gravity of the particle and the thickness and viscosity of the film. As a result the smaller particles will migrate further before their movement is retarded relative to larger particles of the same specific gravity. The behavior on reaching the solid surface de¬pends on whether there is a single particle layer or, as is more often the case, a multiple layer or thin bed of material which is sufficiently dilated, permits the penetration of higher specific gravity grains. Thrust of Flowing Films. When a thin film of liquid flows over a plane solid surface, the layer next to the surface remains at rest but the velocity of the film increases with the distance from the surface and becomes a maximum near, but not quite at, the free surface. Therefore, a particle in suspension in such a film is acted upon by a greater force near the upper part of the film than at the lower part, resulting in an overturning effect. After a particle reaches the separating surface or an accumulated densely packed bed of other particles, the liquid flow causes it to move downstream by rolling, sliding, or by a movement involving alternating suspension and deposi¬tion (saltation). In rolling and sliding, which are brought about by a substantially noneddying stream, the large submerged particles are acted upon to the greatest extent and they move more rapidly than smaller ones, notwithstanding their greater mass. When two particles of the same size but of different specific gravity are considered, the higher density one moves more slowly by reason of its greater mass. As a result the particles tend to become arranged in the manner shown in Fig. 29. If any particle is so large as to stand above the water surface, the transporting force on such a particle, although the maximum available, will have less effect than that on a submerged one. Such large grains are therefore carried a lesser distance. Fluid Velocity in a Flowing Film It can be shown that if y is the distance within the flowing film from the interface, the fluid velocity v' at this point is given by IIn this equation p' is the fluid density, g the acceleration due to gravity, a the viscosity, a the angle made by the film to the horizontal, and 0 the film thickness (in cgs units). Furthermore, the volume Q of fluid per unit time and unit width is related to the film thickness and can be calculated, since which upon integration gives Consideration of the velocity v' (Eq. l) and the terminal falling velocity µ derived from Stokes law enables the horizontal travel dz in time dt to be calculated as follows: Again integration and substitution of Eq. 3 gives In this equation, z is the distance travelled before a particle of density p at the top of the fluid film has settled on the concentrating surface. From these expressions it can be seen that the depth of the flowing film varies as the cube root of the volume of fluid and inversely as the cube root of the sine of the plane surface inclination. Similarly the distance a particle can travel before reaching the surface is directly related to the quantity of fluid and its viscosity. The viscosity of pulp is greatly increased by the presence of near colloidal particles and consequently the penetration of the somewhat larger grains through the flowing film is retarded, resulting in them being carried further across the concentrator deck. Obviously this effect can be reduced by prior removal of some or all of the ultra¬fine particles. The detrimental effect of kaolin on the separation of fine ferrosilicon from quartz has also been demonstrated by Johnston,116 the relationship between viscosity and efficiency of separation being shown in Fig. 30. The pH value also has a very marked influence on the viscosity and the use of acid mine water, for example, can increase viscosity materially and thereby result in lower efficiency. Dilation of Multi-Particle Systems Except during washing (when a single particle layer may exist) concentration usually takes place in a bed of particles which is partially dilated or stirred by eddy currents. The extreme case is seen in various forms of the sluice where the flow of water and the presence of riffles combine to create a fluid bed in which reverse classification takes

Jan 1, 1985

By Dean S. Rogers, R. A. Metz

The conventional role or exploration, development and grade control is examined in this paper within the context of the many and varied types of gold occurrences which are found at the Dome Mine. The account endeavours to trace the development of the total ore evaluation process, from diamond drilling through the exploration and drifting stage, to the stope development and planning phase of the operation, with an emphasis on sampling techniques and assaying procedure. The concept of ore reserve calculations is developed and the practice of grade control is described. In summary, the role of the geological, the engineering and the mining department is presented in relation to the contribution each has to make in the evaluation and exploitation of ore from one of the world's classic Archean gold deposits.

Jan 1, 1992

By T. Carageorgos

The removal of arsenic from process streams as ferric arsenate compounds is being practised by mining industries. Therefore, the solubility and stability of these solids is of considerable importance to the mining plants that have to keep the environment free from pollutants. There is some information on the solubility of the ferric arsenate compounds, mainly on scorodite, obtained from synthetic solution. However, there is not so much work on ferric arsenate compounds formed at high temperatures (175 - 230°C) during the leaching process. In the present work, the solubility of the ferric arsenate compounds formed during acidic pressure oxidation of arsenopyrite is presented. The results of the solubility tests showed that the ferric arsenate compounds formed at high temperatures (200 - 230°C) and high pressures (1034 - 1551 kPa 0,) released arsenic into solution in amounts less than 1.2 ppm and iron in amounts no higher than 1.0 ppm. So, they seem to be potential compounds for arsenic and iron disposal.

Jan 1, 1998

By A. M. Gaudin

The recent study by R. M. Hays(l) prompted the study summarized in this paper. In his Interesting paper, Mr. Hays shows fine results to be attainable by a relatively complex flowsheet on a semi-taconite, a manifestly difficult ore to treat. We obtained a semi -taconite from Minnesota, and treated this sample by wet magnetic separation alone. The device in which the separation was accomplished is the standard pilot-plant, laboratory separator in use at Magnetic Engineering Associates' laboratory (MEA) in Cambridge, Massachusetts. It consists of a cylindrical space which can be magnetized by turning on the magnet of the separator. In this cylindrical space, there is a canister which provides the special configuration of the magnetic field and magnetic field gradients that MEA considers to be required. The ore pulp is made to flow through the canister while the current is on. A portion of the pulp is retained in the canister, and the rest is evolved as a non-magnetic fraction. The laboratory device is cyclic, but it accurately predicts the results obtainable by an Industrial unit of either cyclic or continuous type (moving matrix). The ore tested was 99.5°%o -325 mesh, and approximately 75% -500 mesh. The concentrate from this ore was, therefore, eminently suitable for pelletizing. In passing the ore through the magnet, we had the choice of repeatedly passing the concentrate from the first step through the operation, or of repeatedly passing the non-magnetics. In our experiments, the first method was clearly superior from the stand¬point of the cleanliness of concentrate. Of the many tests which we have made, we think that we have to retain two which

Jan 1, 1971

By V. B. Achanti

Laboratory studies were carried out at West Virginia University to investigate the rock fragmentation mechanism by continuous miners using an automated rotary cutting simulator. The primary factors influencing the: fragmentation process were found to be: bit spacing, bit geometry, depth of cut, and cutting drum rotational speed. This paper presents the influence of these parameters in achieving optimum energy consumption and minimizing dust generation during rock fragmentation process. Three bits were used simultaneously on Indiana limestone while the bit tip angle was varied from 60° to 90°. Bit spacing was varied from 2.54 cm (1 in.) to 5.08 cm (2 in.) while the cutting process was assessed for varying cutting depths. Respirable dust generated during the course of the experiments was analyzed utilizing cascade impactors. Assessment of these parameters has led to a better understanding of the cutting mechanism by continuous miners in terms of energy consumption and dust generation.

Jan 1, 1997

By K. Hanumantha Rao, K. S. E. Forssberg, H. R. Manouchehri

This paper summarizes the practical considerations of the various electrical separation methods used in mineral processing. The effective factors related to mineral characteristics and equipment attributes are described and analyzed with reference to conventional industrial applications of the electrical methods. Some new aspects of electrical methods application and their potential for mineral beneficiation, apart from the mineral systems that have been successfully beneficiated, are also presented. In addition, wet dielectric separation, which now appears to be promising, is briefly cited.

Jan 1, 2000

By R. K. Rajamani

The theoretical model based on fluid mechanics, in conjunction with the laser-Doppler velocimetry (LDV) measurements, elucidate the size-classification mechanisms in an industrial hydrocyclone. The model has no adjustable parameters and involves solving the Navier-Stokes equations to predict the liquid-phase velocities. The spatial-concentration gradients were determined considering the particle phase in the Lagrangian frame and the classification curve was determined by balancing the forces acting on the particle. The force balance requires liquid velocities, which in turn depend on the local volumetric concentration of the particles. Hence, complete modeling work involves coupling both the concentration and liquid-phase velocity calculations until convergence is reached. Finally, the experimental and predicted classification curves were presented for 250-mm hydrocyclone operating at high-percent solids.

Jan 1, 1994

By B. K. Mishra

This paper focuses on the use of a numerical tool known as the discrete element method (DEM) to study the motion of ball charge in ball mills (14-18 ft). DEM is employed to simulate the motion of individual balls. While doing so, the effect of liner design on the grinding performance of the mill is studied. Two important factors such as the configuration of the liner and the geometry of the lifting surfaces are correlated with the overall mill performance. An attempt is made to show the effectiveness of the lifter bars in transmitting power from the mill shell to the interior of the mill with particular emphasis to large diameter mills.

Jan 1, 1992

By Robert M. Belesky, H. R. Hardy

A methodology to detect the presence and monitor the stability of shallow cavities is presented in this paper. The approach incorporates surface-wave seismic and acoustic emission/microseismic (AEIMS) techniques. Application of tomography to the seismic data is made to enhance the ability to locate cavities. Zonal and hit-sequence location techniques are introduced into AE/MS monitoring schemes. These source location techniques simplify the analytical procedure yet still provide sufficient information regarding the region of AE/MS activity. The concept of unique velocity data for conventional, least-squares, source location routines is discussed. A hypothetical case utilizing the algorithm is presented. The method described has been successful based on preliminary studies. Areas of current and future research are identified.

Jan 1, 1986

By Priscilla P. Nelson, Francis L. C. Fong

Introduction Fracture mechanics is the study of the behavior of cracks and their modes of propagation. During cracking, energy is consumed in creating new surface area. The more energy a material absorbs, the higher is its fracture resistance. This fracture energy is provided either by work done externally, by the release of elastic strain energy within the cracked body, or by a combination of these two effects. Fracture resistance is measured in terms of either the stress intensity factor, K, or the energy release rate (also referred to as crack driving force), G. For linearly elastic materials, these two quantities are related by the following equation: [ ] where [u] is Poisson's ratio and E is the modulus of elasticity. Both K and G are direct functions of the applied force and the crack length. The process of rock cutting with full-face tunnel boring machines (TBMs) involves the indentation of a rock surface by rolling disc tools. Excavation occurs as fractures, extending from the locus of chip indentation, propagate between concentric disc grooves and liberate rock chips from the intact rock face. Since disc cutting is achieved by a fracture process, it is logical to anticipate that differences in cuttability of a variety of rocks should be related to the variation of fracture material properties among the rocks. Such a relation has been demonstrated between the performance of full-face TBMs and the critical crack driving force for excavation in relatively high strength, brittle, low porosity, isotropic rock (Nelson et al., 1985). The objective of this paper is to report on the results of a continued investigation of the relationship between fracture material properties and the effectiveness of disc cutting. Additional reliable data on full-face TBM performance is difficult to obtain, so that the results of disc linear cutter tests performed by the Transport and Road Research Laboratory (TRRL) (U.K.) are utilized in this study. Fracture Material Property Evaluation If a crack tip is subjected to a perfectly plain strain condition, many materials will behave in a brittle manner, and the material resistance to fracture is constant during crack growth. This resistance is referred to as the plain strain fracture toughness, believed to be a material property. The standard testing procedure for this parameter is given in the American Society for Testing and Materials (ASTM) test designation E399. To ensure plain strain conditions, acceptable specimen geometries are specified. Unless these geometric specifications are adhered to, the measured fracture resistance is regarded as the apparent fracture toughness, and a subscript Q is used, as [ ]. The methodology adopted by ASTM E399 is within the framework of Linear Elastic Fracture Mechanics (LEFM). This approach assumes that material resistance against cracking is developed instantaneously, without initial stable or subcritical crack extension. Prior to crack advancement in rock, however, much of the crack driving energy is absorbed in a localized volume in front of the crack tip, referred to as the plasticity or microcracking zone. This capability for energy absorption substantially increases material resistance, and a crack may be arrested unless an increased crack driving force is applied. The LEFM or plain strain assumptions would underestimate the actual fracture resistance of such a material. Such a conservative approximation may be desirable in the design of structures against fatigue or brittle failure. In mining or tunneling, however, an underestimation of crack resistance can lead to the selection of underrated excavation equipment and a decrease in production efficiency. The development of fracture resistance in rock is best described by the material resistance curve, or R-curve, which is a plot of fracture resistance as a function of crack extension. Typically, peak resistance is only reached after a finite amount of subcritical crack growth. The

Jan 1, 1986

By Jan A. Nemcik

Steel mesh has been used successfully for many years to control friable roof conditions and prevent loose roof and rib material from caving into the roadway. Despite its extensive use, the installation of steel mesh is difficult to automate and many other products have been evaluated as an alternative for skin control. Ideally, the properties of these new products should be similar or better than those of the steel mesh. In particular, development of a strong and resistant shell that minimizes movement along the fractured rock and coal surfaces between the bolt anchors is recommended. A strong surface adhesion and the strength of a reinforced polymer skin can provide the necessary toughening mechanism required to enhance roadway surface support by forming a reinforced polymer/rock surface layer. Most of the Thin Spray-on Liners (TSL) evaluated in the mines are weak with slow curing times, and the plastic mesh currently used to support the coal ribs is relatively weak. Therefore, neither material can seriously compete with steel mesh. Currently, a new polymer product that cures in seconds and forms an instantaneous strata binder that surpasses the properties of steel mesh is under development at the University of Wollongong.

Jan 1, 2009

By D. K. Grubbs

Anorthosite is an abundant, domestic source of alumina with reserves in individual deposits ranging from a few billion to hundreds of billions of tons. While anorthosite contains less alumina than does kaolinite, its CaO and Na20 contents are significantly higher (Figure 1). Alumina can be produced from anorthosite by alkaline, soda-lime sinter or acid processes. CaO and Na20 are advantageous because they are reactants consumed in alkaline processes. Acid processes require high calcium plagioclase feldspars (bytownite-anorthite) to obtain high alumina extraction because the lower calcium plagioclase feldspars (andesine-labradorite) are not as readily dissolved during digestion. The layered Raggedy Mountain Gabbro group in the Wichita complex in southwest Oklahoma is a high calcium anorthosite that could be processed by acid, sinter, or alkaline methods. Chemical grade limestone in the Arbuckle Group is located within 45 km of the anorthosite (Figure 2).

Jan 1, 1980

By A. M. Raichur

The selective adhesion of hydrophobic Mycobacterium phlei to coal particles is responsible for flocculation of fine coal from associated ash forming minerals. The driving force for the differential adhesion is the hydrophobic interactions between the fatty acid surface of the organism and hydrophobic nature of coal. The effect of Mycobacterium phlei on surface hydrophobicity, surface charge and mechanism of adhesion on coal and associated minerals are controlled by several factors including hydrophobicity and surface and solution chemistry of the system. Adhesion measurements indicate that maximum adhesion occurs below the isoelectric point (IEP) of the coal particles. While massive adhesion of Mycobacterium phlei is observed on coal, however, negligible amount of Mycobacterium phlei attaches to mineral pyrite and quartz.

Jan 1, 1995

By M. A. Gibson

Ilmenite-rich lunar deposits can be converted to liquid oxygen to support lunar base operations and space transportation propulsion needs by a Carbotek-developed process. Iron oxide in ilmenite is reduced at elevated temperatures by hydrogen in a fluidized-bed reactor to water vapor which is electrolyzed to product oxygen and recycle hydrogen. Reaction rate, thermodynamic equilibrium, and lunar-gravity fluidization behavior are key factors which have been considered. Fluid-solids behavior has been modeled from data taken at lunar gravity conditions aboard NASA KC-135 flights. Large-scale pilot plant operations are planned to complete the development.

Jan 1, 1991

By K. Hanumantha Rao, K. S. E. Forssberg, F. Su

The influence of reagents dosage, pH, temperature, and particle size on the kinetics of apatite flotation response from magnetite has been investigated. The first-order models characterizing rectangular distribution and fast and slow distributions (F-S model) of floatabilities gave an excellent fit to the results of apatite flotation when compared to other models. However, the latter model is found to be better than the former in the goodness of fit and also in the description of flotation performance. The kinetic parameters in the F-S model are estimated by using a nonlinear least squares fitting program. The ratio of fast and slow rate constants is observed to be an important parameter for identifying the optimum levels of the variables and to outline the selectivity between apatite and magnetite. The influence of collector dosage is realized from the model parameters by relating it to the fraction of slow- floating particles. An attempt has been made to describe the apatite flotation behavior with the determined model parameters.

Jan 1, 1999