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By Alain A. Sonntag

The MBS Solvent Extraction System utilises a unique design of mixer- settler having very high capacity per unit area and great flexibility. The development of the mixer-settler is traced through its various stages wherein the independence of mixing and pumping, reduction in settler area requirements and simplicity of plant layout were achieved. The laboratory, pilot plant and full scale tests contributing to the development of the machine are described. The existing KREBS SX plants in Europe and Africa are described as well as the plants presently under design. Results of recent testwork are also given.

Jan 1, 1981

By D. Wright, J. Samborski

DuPont’s Florida Plant has been mining in northeast Florida and supplying titanium-bearing minerals, zircon and staurolite for over 50years.The site has successfully implemented and “sustained” a land reclamation/habitat enhancement program that goes beyond regulatory requirements and standard industry practices. However, the term sustainability has been used by so many organizations, many with divergent viewpoints, that it is important for a mine to develop its over-all concept and approach to sustainable operation. As a foundation, the outstanding reclamation efforts at DuPont’s mine will be presented followed by a broader look at the overall sustainability strategies and tactics used at the site.

Jan 1, 2004

By Kyle L. Brennan, Scott Maybrier, Gang Chen, Scott Huang

Data from about 3200 drill holes in the offshore area at Nome, Alaska was digitized and processed. Most drill hole files have associated lithology, gold value, and blow count descriptions for each drill hole. The gold intensity was used to present the potential gold resource in the study area on the world wide web. A web page was created that gives background information on the project, descriptions about the Nome area, maps of the claim blocks that include all the normalized slices of gold deposits, and links to other relevant sites on the web. The site is located at http://mineral.uafsme.alaska.edu/nomeproject/nomehome.htm.

Jan 1, 2002

By Brian W. Hester

All gold occurrences in Tanzania are of Precambrian age and in geological settings similar to gold deposits in other parts the world. The three main areas of interest are perhaps the least prospected of areas of gold mineralization in Precambrian rocks in non- aligned, or market economy nations. Historic production exceeds 77.660 kg (2.5 million oz). Current results by small scale workers go unreported, but have been estimated to be as high as 11.000 kg (350.000 oz) annually. Gold occurs in both lower and upper Precambrian rocks. In the older. gold is associated with greenstones and iron formations typical of many cratonic areas of Precambrian age. The Tanzanian Craton lies in the north west quarter of the country where it is flanked on both east and west sides by mobile belts involving upper Precambrian rocks of high metamorphic grade. Gold occurs in fractures in the western belt within two distinct areas.

Jan 1, 1989

By Qiu Rongqing, Huang Kongxuan

This paper summarizes the results of treating arsenic­bearing refractory gold concentrates from six gold Mines of Chi­na by using bioleaching method and discusses the conditions of bioleaching processes. Results indicate that Thiobacillus fer­rooxidans T-3 Strain can intensely oxidize arsenopyrite, how­ever oxidation rate and degree differe considerably for different. During initial inoculation of 5 X 106 cell/ml. FeH contration generaly 4 -8 g/1. Sample size > 80 % - 3 20 mesh and pulp density 10 % ( w /v) and leaching time ,1 -- G clays, arsenic re­moval rate reached more than 80 % , Fe extraction ,10 - GO% desulfurization rate 30-45% after bacterial oxidation of 4-G days.

Jan 1, 1992

By F. Cappel

Except in a few special cases, it is necessary for solid fuel direct reduction in rotary kilns that iron-bearing materials be charged with a minimum grainsize of approx. 5 mm. For fines not usable in such form, the combination of sintering - as agglomeration step - and direct reduction were investigated. During reduction of sinter in rotary kilns prevail dependencies on sinter quality and varying reaction parameters, owing to the use of different coals, which led to a definite statement as to what quality sinter must have and which coals can be used.

Jan 1, 1983

By A. Porvali, V. Agarwal, M. Lundström

Hydrometallurgical recovery of rare earth elements (REE) from NiMH battery waste can be performed using sulfuric acid leaching followed by selective precipitation as double salt (REENa(SO4)2•H2O) by adding Na2SO4 as a precipitating agent. The formed double salts can be treated further with NaOH solution to form REE hydroxides. This study focuses on metamodeling of a simulated flowsheet with design of experiments (DOE). Based on literature survey, a process flowsheet was developed using HSC Sim software. The created flowsheet focuses on circulation of solution containing Na+, K+, SO42- ions and impurities liberated in the NaOH treatment of double salt precipitate. The effect of seven parameters (P1-P7) on seven responses (R1-R7) were modeled using central composite design (CCD). INTRODUCTION Nickel metal hydride (NiMH) battery waste can be considered as an urban mineral due to the presence of valuable metals like: Ni, Co and rare earth elements (REE) (Larsson et al., 2013). In NiMH battery waste leaching experiments, sulfuric acid has often been employed as a lixiviant (Pietrelli et al., 2002,Zhang et al., 1999,Rodrigues and Mansur, 2010,Porvali et al., 2018). The key advantages of sulfuric acid are its stability and cost-effectiveness compared to other mineral acids such as HCl and HNO3. However, the usage of sulfuric acid in NiMH battery waste leaching poses simultaneous challenges and advantages. Limited REE solubility can be taken as benefit when recovering REEs double sulfates after solid-liquid separation. However, sodium and potassium hydroxide, present in electrolyte residues in the battery waste, can cause in-situ precipitation already during leaching due to limited solubility, thus decreasing the total REE recovery (Porvali et al., 2018). However, this problem can be circumvented by washing the electrolyte residues off the raw materials. Subsequently, the REEs may be precipitated in bulk as a mixed double salt out from the solution at very low pH with minimal co-precipitation of Ni and other metals. This relatively easy separation method can be extremely advantageous in the case of such a complex solution matrix with relatively high REE concentrations (conc.). Once REEs have been precipitated as double sulfates as per eq. (1) (Porvali et al., 2018), the resulting double salt precipitate lacks applications without further treatment. Direct thermal treatment would generate sulfur dioxide emissions and likely require high temperatures in order to transform double sulfates into REE oxides. Furthermore, the precipitate contains Na ions, which would need to be removed by chemical treatment from the calcined REE product. In the context of circularity of raw materials, it can be taken of a remarkable benefit if the sodium and sulfur present in the double salt could be reused instead of wasting them into the side streams. To that end, in this simulation study, the double salts are converted by dissolution and precipitation to hydroxides which are readily treatable, e.g. with total dissolution and solvent extraction, for further purification (Abreu and Morais, 2010):

Jan 1, 2019

By Fathi Habashi

SELENIUM AND tellurium are by-products of electrolytic copper refining. Copper anodes contain 0.01-0.2 % Se and up to 0.04 % Te; during electrolysis these deposit as a slime at the bottom of the cell. Such slimes contain 2-15% Se and 0.5-8 % Te, as selenides and tellurides of gold, silver, and copper. The following compounds have been identified in the slimes: (Ag, Au)Te2, Ag2Se, Ag2Te, CuAgSe, Cu2Se, Cu2Te. Anodic slimes from copper electro¬lytic refining are a grayish black powder, minus 200 mesh. When this complex mixture is decomposed in an acid medium, elemental selenium and tellurium can be obtained, while in an alkaline medium, both metals go into solution. Acid leaching The slime is charged in acid digesters of 800-900 lb capacity, heated to 260°C with 78 % H2SO4, for 8-12 hr. During digestion the following reactions take place:

Jan 1, 1970

By Eleanora I. Robbins, Motoaki Sato

Many problems associated with acid mine drainage (AMD) are caused by the complex way molecular oxygen (O2) oxidizes reduced matter at surface temperatures. In aqueous solution, O2 kinetically "prefers" to go through the formation of hydrogen peroxide (H2O2) as an intermediate. Being innately unstable, H2O2 is quickly decomposed back to water and oxygen in the presence of dissolved Fe and Mn, both catalysts for the decomposition. Direct addition of H2O2 to AMD produced similar results. Ozone (O3) is a much faster and stronger oxidizer than either O2 or H2O2. In the laboratory, O3 rapidly precipitated Mn, Fe, Ni, Co, Pb, and Ag even in acidic solutions. The experiments indicate that AMD can probably be processed with ozone and metal oxides/hydroxide recovered in flow systems using only septic-tank-size reactors and small sedimentation ponds.

Jan 1, 2000

By A. D. Davis

Environmental impacts from acidic mine drainage are growing national concerns that are particularly acute in the headwaters of the Rocky Mountain region. In the Black Hills of South Dakota, approximately one thousand mines are inactive or abandoned, most of them in the headwaters of major drainages. This paper examines the Bear Butte Creek basin, a heavily mineralized watershed with significant historical mining impacts and a surface gold mine permitted in 1997. The watershed loses its surface discharge to swallow holes in the karstic Madison Limestone. The integrity of the aquatic ecosystem was monitored with a suite of site-specific bio-indicators. Stream surveys covered the entire reach of Bear Butte Creek from near its headwaters to the swallow holes in the Madison aquifer. Data from the stream surveys, water-quality sampling, and bio-indicator surveys clearly showed that water-quality impacts are limited mainly to Strawberry Creek and to the area of Bear Butte Creek near and downstream of the town of Galena.

Jan 1, 1999

By Richard A. Bideaux

Using computer applications to solve mining problems began in the early 1960s, utilizing the large (for that day) centralized computing facilities at a few universities and major mining company headquarters. Many years passed before technology was adequate to allow any of those applications to be run at the mine sites to provide immediately available solutions. One of the first mining applications attempted was for ore reserve analysis and long- to medium-range mine planning. As these are among the most frequent and familiar minicomputer applications at the mine site, it is interesting to follow the evolution of computing and communications hardware which has finally allowed effective transfer of this technology.

Jan 11, 1981

By R. L. Urie, L. Burdzinski

Non-operational mine facilities are subject to placement on the EPA's National Priority List (Superfund). Once a mine site is undergoing investigation and/or remediation, MSHA regulations for health and safety may no longer be applicable. This paper addresses the changes in the applicable and relevant standards that apply to health and safety and public health related to site contaminants. The implementation of health and safety plans, and the development of public health risk assessments are described. Examples are presented from Superfund activities at the Eagle Mine, near Minturn, Colorado; the Anaconda Smelter near Mill Creek, Montana; California Gulch near Leadville, Colorado; and Bunker Hill, Idaho.

Jan 1, 1991

By W. Kemp Wait

Electronic ore sorting has been in use for over 15 years at many mining operations worldwide. Photometric ore sorting, which operates on the basis of measuring light reflectance levels of a rock surface, is in use at various locations on ores such as limestone, magnesite, gold, talc, spodumene, tungsten and coal. Radiometric sorters have been employed on uranium deposits in the western U.S.A. as well as at certain South African go1 d mines where preconcentrating gold is achieved using uranium association as a detector. A new ore sorter, employing two sensing parameters has been developed. Utilizing both photometric and conductivity sensing modes, this system has application to many gold ore types of North America. The first production machine has been installed at a gold mine near Beardmore, Ontario for the purpose of preconcentrating ore both from waste dumps from past production as well as within the ongoing mining operation.

Jan 1, 1987

By R. Y. Wan

Recent research efforts have shown have shown selective solvation extraction of a gold cyanide ion-pair complex from alkaline cyanide solution is possible with organic phosphorus esters. These alkyl phosphorus esters such as tributyl phosphate (TBP) and di-n-butyl n-butyl phosphonate (DBBP) can selectively load gold to rather high levels, even in excess of 30 gpl. However, traditional stripping techniques are not particularly effective. In this regard, gold recovery by direct electrolysis of the organic phase has been found to be an interesting possibility. Further, the rate of direct electrodeposition from the organic phase can be improved significantly by using an aqueous/organic mixture. Direct electrodeposition of sheet gold from loaded DBBP was successfully accomplished at a current density of 8x10 4 amp/cm2 and 55°C from such a two-phase mixture with the aqueous phase as the continuous phase. No appreciable degradation the DBBP was found after 5 cycles of extraction and, electrodeposition. Finally, the applicability of the process strategy for an industrial situation was demonstrated by the successful treatment of waste gold cyanide electroplating solutions.

Jan 1, 1986

By D. Hodouin

Abstract. Dynamic experiments were performed in a continuous open-circuit 40x40 cm ball mill using a pseudo-random binary sequence of the feed rate and measuring the variations of the discharge particle-size distribution. The impulse response is calculated by a cross-correlation technique. Then a model involving a discrete transfer function and a time-series stochastic equation is calibrated using maximum likelihood methods. Based on this empirical model. a minimum variance controller with constrained input is designed and its performances are compared. by simulation, to the performances of a conventional PID regulator.

Jan 1, 1987

By Juan L. Sepulveda

An MPSI KW-20 Tower mill has been tested at the Butte Molybdenum plant of Anaconda Minerals Company, as a substitute for the conventional 1.5x3.0 m (5x10 ft) tumbling ball mill currently used for regrind purposes. The Tower mill was operated in both open and closed continuous circuits. These results were complemented with a series of batch grinding tests to determine some of the operational features of this mill. The relative grinding efficiency of the Tower mill with respect to the tumbling ball mill was determined and the applicability of this new mill to a plant/heavy duty environment was assessed. Experimental results obtained on the regrind of moly concentrates indicate that approximately 40% energy savings can be realized by using the Tower mill instead of the ball mill.

Jan 1, 1984

By Steven W. Hunt, Jane A. Kettler, Barry R. Doyle

A sewer tunnel being constructed through an urban commercial area was to pass the site of a former gasoline service station. The site was known to have contained leaking underground storage tanks. An environmental assessment of soils on the alignment was performed, and measures were implemented to handle expected contaminants. Despite these precautions, an explosion occurred in the heading when liquid gasoline was encountered. Four workers were injured. This paper presents the findings of an investigation into the cause of the explosion, and examines how concerted efforts by the parties involved failed to prevent it. The level of guidance provided by OSHA Code provisions for tunneling in gassy conditions is discussed.

Jan 1, 1997

By James Charles McHardy

During 1980-2000, the Florida Phosphate industry will deplete its Central Florida Polk County reserves. As a result, new mines will be built in the ?so-called? Southern Florida Reserve areas. These new mines will require new mining, beneficiation and tailings disposal technologies in that the southern reserves have different characteristics than have been encountered in the Central Florida deposits furthermore, government regulations will necessitate the development of new tailings and clay disposal methods. This paper reviews these challenges for the phosphate industry and how these opportunities can be expected to effect plant design and plant operating practices.

Jan 1, 1981

By C. W. Fitzgerald

INTRODUCTION Continuous mining machines are used in regular flat ore beds having uniform thickness. Since coal is the most common type of material occurring in such beds, most continuous miners are used for the extraction of coal from underground mines. The first continuous mining machine for under¬ground coal mining was introduced in 1948. In one machine, the continuous miner combines the functions performed by a conventional face drill, a cutting ma¬chine, and a loading machine. It breaks or digs the material out of the surrounding solid and transfers the material back through the machine chassis by means of a chain conveyor. The conveyor carries the material to a haulage system, usually a rubber-tired vehicle known as a shuttle car. Generally, continuous miners are used in seam heights from 890 to 3660 mm (35 to 144 in.). For seam heights of 1070 mm (42 in.) or less, the haulage system may be a multiple-bridge conveyor or battery-powered tractors that haul low-bed trailers. Proj¬ects are being undertaken by private industry and through government contracts to develop a continuous haulage system for all seam heights. As of 1976, the majority of continuous miners were of two types. The first type is the drum miner, which mounts the cutting elements on a series of drums across the cutting head of the machine, sometimes using a cutting chain to cut clearance for the gear drive. In the drum-type machines, the cutting head rotates parallel to the material face. The second type is the auger miner, which utilizes cutting elements mounted on two auger-type cutting heads. One head is located on each side of the machine, with the heads mounted per¬pendicular to the material face. Chain-head ripper-type miners/miners having rotary cutting elements with oscillating motion and twin-head boring-type miners have all been popular within the last 15 years. Although these are considered obsolete, some machines are still being supplied for specialized applications. GENERAL DESCRIPTION This chapter describes only continuous mining ma¬chines available as manufacturers' production models as of September 1976. Figs. 1 through 11 illustrate some typical machines currently in use. Cutting Elements The cutting elements are the interface between the machine and the material being mined. In describing the cutting elements, consideration must be given to the differences between the drum- and auger-type machines, the bit-tip speeds, and the bit types. Drum-Type Continuous Mining Machines: Three of the four principal manufacturers of drum-type miners use multi-motor designs that provide separate a-c motors for driving the cutting elements. Gear trains are used to reduce the speeds of the motors to the rotational speeds of the cutting elements. One of the three suppliers drives the cutting elements of its low-seam models with a heavy-duty drive chain that is equipped with cutting bits; all other functions of this machine have separate motor drives that are either electrical or hydraulic. The fourth principal manufacturer generally provides two a-c electric motors, utilizing gear reducers, drive shafts, and hydraulically operated engaging clutches to power all of the operating functions, including the cut¬ting elements. Some drum-type miners use trim chains, equipped with cutting bits, to cut clearance for the gear drives. These trim chains vary from two 305-mm (12-in.) chains to one 760-mm (30-in.) chain per machine, de¬pending upon the manufacturer's design concept. In all machines other than the low-seam models that use chains to drive the heads, the trim chains are driven by sprockets on the drive shaft of the final cutterhead drum; therefore, the trim chains are not used for power trans¬mission to the cutting elements. In addition to cutting clearance for the gear drives, the trim chains provide uniform bit spacing all the way across the head and assist in moving the cut material to an area where it is either loaded directly into the miner's conveyor or is easier to load into the conveyor. On a drum-type mining machine, the cutting ele¬ments all rotate from the top to the bottom. Therefore, the recommended procedure is to raise the cutterhead to the maximum seam height, sump the entire machine forward to maximum depth by means of a crawler drive, and then shear downward until the cutter elements reach the floor level. The maximum sump depth varies ac¬cording to the drum diameter, the type of material, the floor conditions, and the operator's abilities. It normally varies an average of 460 to 760 mm (18 to 30 in.). Cutter drums are supplied with two types of cutting bit holders. Weld-on holders are attached permanently. Pin-on holders are replaceable at the face. Cutter-drum diameters over the bit tips vary from 660 to 965 mm (26 to 38 in.), depending upon the chassis height of the machine and the range of cutting heights. Auger-Type Continuous Mining Machines: As cut-

Jan 1, 1982

By John K. Hollmann

The use of the direct method of determining coal methane content has grown in the last decade from a research technique into a practical coal exploration tool. However, the literature available on the subject is somewhat lacking in site-specific guidance and observations on the conduct of the method and the use of the resulting data. This study discusses some practical lessons learned in conducting a large scale direct measurement project at an operating mine, describes the initia1 interpretations and uses of data from the project, and presents observations from subsequent mine operations into the success and limitations of using direct measurement data in mine planning. The site studied is in central Pennsylvania on the Appalachian Plateau and includes coal seams in the Allegheny series.

Jan 1, 1987