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By I. Ward, E. Milosavljevic, M. Botz

"The silver nitrate titration method is a rapid and acceptably accurate means of analyzing for cyanide in leach solutions that contain primarily free cyanide. However, in leach solutions containing elevated levels of copper, the titrimetric method overestimates the concentration of free cyanide and underestimates the concentration of weak and dissociable (WAD) cyanide. The authors have developed a modified potentiometric (MP) titration method for determining WAD cyanide that overcomes issues associated with high copper levels in solution. The new MP-WAD method involves addition of a chemical ligand to the sample prior to silver nitrate titration to release cyanide bound to copper. Once released from copper, cyanide in solution is no longer affected by the presence of copper, and titration results are quantitative rather than empirical. In multiple laboratory trials with synthetic solutions and complex actual leach solutions, analytical results obtained with the new MP-WAD method were found to be within about ±5% of analyses obtained with the USEPA OIA-1677 WAD cyanide analytical method.IntroductionThe silver nitrate titration method is widely used to estimate the concentration of cyanide in leach solution for purposes of cyanidation process control. Cyanide determined by silver nitrate titration is commonly referred to as “free” cyanide, but frequently should be referred to as “titratable” cyanide. By definition, free cyanide is the sum of the concentrations of aqueous hydrogen cyanide HCN(aq) and the cyanide anion CN- (ASTM, 2010). Titration will only yield a reasonably accurate measurement of free cyanide when metal-cyanide complex concentrations (e.g., cadmium, copper, mercury, nickel, silver and zinc) in solution are low. In other words, titration will only yield a reasonably accurate measurement of free cyanide if the solution primarily contains free cyanide."

Jan 1, 2015

By Irina Chernyshova, Erik Larsen, Hanumantha Rao Kota, Vladislav Slabov, Garima Jain

The separation of fine mineral particles, especially using environmentally friendly approaches, is one of the main problems in the processing of low-grade ores and the re-processing of mining tailings. This work assesses the potential of biosurfactants as collectors in the flotation of ultrafine (smaller than 20 μm) particles of hematite and malachite. As biosurfactants, we test acetylated acidic (ac-ASL) and lactonic sophorolipids (ac-LSL). In addition, n-dodecyl-β-D-maltoside (DDM) is used as a model non-ionic alkyl disaccharide surfactant, and sodium oleate (NaOl) is used as a reference. The biosurfactants are characterized using surface tension and foam analysis. The interaction of the minerals with the surfactants is characterized using zeta potential, solubility, and single-mineral flotation. The collecting properties of the surfactants are compared for the ultrafine (− 20 μm) and coarser (38–90 μm) particle size in the two-mineral flotation of hematite and malachite against quartz. The ultrafine particle size improves the grade in the oleate flotation of hematite, as well as the grades in the DDM flotation of hematite and malachite, which is explained by the weak interactions of the metal oxides with fatty acids and DDM. At the same time, the flotation with ac-LSL and ac-ASL is highly tolerant to the ultrafine particle size. These results indicate that biosurfactants are an interesting alternative to conventional petroleum-based surfactants in the flotation of Fe and Cu oxides. Moreover, a proper selection of surfactants can help combat the problem of fines.

Feb 23, 2023

By Arthur W. Ruff

Estimated reserves of high-grade iron ore at Serra dos Carajás total 16 billion metric tons and have an average grade of 66.7 percent iron, 2.2 percent combined silica and alumina, and 0.05 percent phosphorous on a dry basis. Hematite is predominant and no significant sulfur or other deleterious elements are present. Figure 1 illustrates the comparative magnitude of the Carajás reserves. Serra dos Carajás is located in northern Brazil, about 550 kilometers southwest of Belém, Pará. It is six degrees south of the equator between the Xingu and Tocantins Rivers. Both rivers flow northward toward the Amazon River. The greater part of the area is covered by thick jungle, and the most practical means of access is by air. Figures 2 and 3 show the location of Serra dos Carajás. Figure 4 shows the distribution of the major iron-ore deposits.

Jan 1, 1973

By CADEN VITTI, Barbara J. Arnold

Mine tailings, the byproduct of mining and mineral processing, are increasingly mass produced as a result of increased demand for metals and minerals as well as the advancement in technology that allows for the exploitation of lower-grade ores. Lower grades can increase the volume of tailings that may contain new gangue minerals that should be evaluated for the presence of critical minerals and other valuable metals. The practice of reprocessing, while relatively new, is crucial to reducing environmental damages, obtaining valuable critical minerals from waste, and contributing to more sustainable repurposing and disposal methods. With the increase in tailings dam failures in recent years, there is a large motivating factor in remining and removing the potential hazard to benefit the safety of potentially impacted communities. In analyzing the perspectives of various domestic and international studies, this literature review will determine the feasibility of reprocessing and reutilizing mine tailings waste for a more sustainable future while exploring current practices that have benefitted ecosystems and communities.

Jan 1, 2022

By G. M. Bernard

The Andacollo gold mine is located near the small town of Andacollo, Chile (population 14,000) in the fourth region. It is approximately 35 miles by paved road from the coastal city of La Serena, and Santiago lies about 300 miles to the south (see map.) Site elevation varies between 3300 feet and 4200 feet. The climate at the site is moderate but arid, with an average annual rainfall of only five inches. Because there is little rain, and the temperature varies only a few degrees (57"F to 75°F); there are no freezing, solution dilution, or pad saturation problems. The climatic conditions are ideal for heap leaching.

Jan 1, 1996

By S. Castro, L. Gutierrez

A classification of flotation processes carried out in concentrated electrolyte solutions, e.g., seawater, is proposed using the most obvious features of these processes: low or high content of Mg2+ and Ca2+ ions, pulp ionic strength, and pH. The first distinguishable group is the processes carried out in NaCl/KCl solutions, about 0.5 M in the case of salt flotation of inherently hydrophobic minerals, and at concentrations about 10 times higher in the flotation of potash ores. In the flotation of sulfide ores, such as nickel or copper ores, with xanthate-like collectors, the xanthate collector is apparently not affected by pulp ionic strength and only adjustment of frother may be required. Content of Mg2+ and Ca2+ ions in seawater is the main difference between such systems and fresh water. The presence of these metallic ions can adversely affect flotation in the pH ranges over which these ions hydrolyse. The successful flotation of Cu-Mo ores typically requires depression of pyrite at high pH values achieved with the use of lime. However, in seawater, flotation of Cu-Mo ores requires removal of the hydrolysis products of the Mg2+ and Ca2+ ions or the use of a pyrite depressant that can be effective over the pH ranges that are much below the pH of hydrolysis. Mg2+ and Ca2+ ions also affect flotation of phosphate ores with fatty acids. In this case, the depression mechanism is not caused by precipitating magnesium hydroxides on the mineral surface but by precipitation of collector insoluble salts, and the same ions are responsible for depression in both cases. In the seawater flotation of Cu-Mo sulfide ores and phosphate ores, the practical solution involves either removal of Mg2+ and Ca2+ ions prior to the flotation or complexation with other reagents.

By A. H. Farazi, C. Quamruzzaman

The freezing and subsequent solidifying of unstable, weak (sands, silts and clays) and/or wet soil to form a desired-shape frozen barrier around a construction area are possibly the main features of the freezing method for shaft sinking. The barrier, along with strengthening the soil, provides a dry environment to ensure sustainable subsurface construction work before placing a permanent lining. The freezing method requires the installation of freezing pipes in boreholes around the construction area and the circulation of chilled salt water through these pipes and has long been a proven technique for dry shaft sinking through unstable and water-bearing seam around the world. As removing heat from the ground is the main feature of the method, an efficient thermal design of the freezing process is mandatory to ensure success of the shaft sinking operation. This applies to both the sustainability and economy of the intended structure. The design presented in this paper is aimed at figuring out the heat-removing ability and operating time of the refrigerative equipment using some simple formulae. The authors adopted a theoretical approach to determine the quantity of heat to be removed from the ground. The amount of energy for the equipment was found to be greater than that for freezing, which proved the validity of the design. The active freezing period was calculated to be 121 days. The authors followed the structural design of the freezing process they proposed in their previous work (Farazi and Quamruzzaman, 2013). Though the first coal seam in the coalfield was encountered at a depth of approximately 352 m in the subsurface, the target depth for cooling and freezing was decided to be 162 m. The formation demands extra care to nullify its risk of the temporary structure collapsing and water rushing in (Farazi et al., 2012). Discussion on the determination of refrigerative equipment parameters was excluded from the scope of this work.

Jan 1, 2014

By A. J. Richins, M. G. Nelson, R. Dunne

From the inception of flotation in the late 1800s, coarse particle recovery has been a challenge to practitioners. By the early 1900s, flotation processes included oil flotation, skin flotation, agglomeration flotation, and froth flotation, and for each there was a proliferation of flotation equipment. Ensuring good coarse particle recovery included desliming of the feed and proper conditioning were required. Froth flotation was at first used mainly to treat finer materials from grinding circuits. The maximum size for coarse particles was from 3.18 to 4.78 mm. In froth flotation, large particles with high specific gravity tend not to be recovered. Coal and minerals of low specific gravity and flaky minerals such as graphite, mica, and talc can be floated in larger sizes. In the early 1960s, the phosphate industry began using column cells to recover coarse particle by froth flotation, but early columns suffered from poor bubble generation and sanding at the flat base of the column. Recently, improved coarse particle recovery has been the object of new cell designs—the Eriez HydroFloat™, the Jord NovaCell™, the FLS coarseAir™ cell, and the Cidra P29 integrated system. The paper will follow the development of coarse particle flotation with a focus on the development, laboratory assessment, and operation of the new flotation equipment and technology designed to recover coarse particles.

Feb 22, 2026

Micro-computers have made it practical to install a high-speed acquisition system to collect data from a longwall face in near real-time. By simultaneous data analyses using neural networks and fuzzy sets, information regarding longwall mining performance and underground behavior can be provided and forecasting longwall instability and detecting geological anomalies is feasible. This paper presents details of the application of neural networks and fuzzy sets in developing on-line evaluation of longwall roof behavior. Techniques for interpreting longwall shield pressures and characterizing roof conditions are discussed.

Jan 1, 1996

By R. K. Sinha, B. S. Choudhary, Desh Deepak, A. K. Mishra, Hemant Agrawal, Shankar Kumar

Despite several methods (empirical, statistical and machine-learning tools) to calculate blast-induced ground vibration, it is not easy to predict and simulate blast vibration precisely under varying blasting loads and strata conditions due to complications in the blasting procedure. In this study, field blast data were simulated in Ansys software using explicit dynamics, and ground vibrations for 20 single-hole blasts were monitored. The densities of emulsion explosives were in the range of 0.9 to 1.15 g/cm3. In the laboratory, rock properties were determined from rock samples collected from the mine site before blasting. The in-hole velocity of detonation (VoD) and density of the emulsion explosive were also determined and used in numerical analysis to know the ground vibrations at specific points. The results of ground vibrations predicted by the model were validated using field data.

The last time Mining Engineering presented an issue with a special focus on Canadian Mining (ME, August 2008 pp. 28 to 40) things were going well. A feature story took a look at Xstrata?s Nickel Rim South Mine in Sudbury and the booming Canadian oil sands were discussed at length. Potash prices were soaring, large diamonds were being found and British Columbia was launching plans to find more workers. How things have changed in six short months. What began as a mortgage crisis grew into a credit crisis, then mutated into a financial crisis, that has taken its toll on the value of bonds, loans, stocks, real estate and commodities. Miners that were flying high on unprecedented commodity prices six months ago have begun scaling back with delays, shut downs and layoffs as they struggle to survive this most recent economic downturn.

Jan 1, 2009

By S. Al-Thyabat

In this work, the floatability of Jordanian phosphate slime (-38 µm) was evaluated in a batch column flotation cell, 100 cm high and 5 cm inner diameter. Flotation was conducted using sodium oleate as a collector and methyl isobutyl carbinol (MIBC) as frother. Rougher flotation yielded concentrate assaying 29.19% P2O5 with 90.29% recovery at the following flotation parameters: 2.6 cm/s superficial gas velocity, 20 ppm frother dosage, 0.205 mM collector concentration and 40% weight solids. It was also found that conditioning with the same collector dosage but with a different solids weight percent gave different flotation results. However, pulp collector concentration was the key operating parameter; increasing collector dosage at the same solids weight percent decreased flotation recovery by 3%, while increasing solids weight percent at the same collector dosage increased phosphate recovery by 18%.

Jan 1, 2011

By S. C. Tadolini

The use of resin-grouted cable supports to control large ground movements in several types of underground mines has increased substantially since being introduced in 1991. Cables offer several advantages over traditional support systems, having large support capacities coupled with the flexibility to be used in low openings. Cable slings have been designed to be installed on-cycle using no-spin technology or a two-piece unit that can be placed with hand-held drilling equipment. Additionally, yielding cable supports have been developed and are being used to control large amounts of movement in coal and evaporite deposits.

Jan 1, 1998

By Tianzu Yang, Weifeng Liu, Lin Chen, BOYI XIE, DUCHAO ZHANG, HUI XIAO

The oxygen-rich bath smelting process of copper dross was simulated using Factsage software. It was found that the two-step simulation results agreed better with the industrial data, especially in the speiss. Bi, Pb, Sb, As, and Cu contents in the speiss by two-step simulation differed from the industrial data by 0.6 wt.%, 0.8 wt.%, 2.6 wt.%, 7.2 wt.%, and 8.6 wt.%, respectively. Twostep simulation results indicated that the speiss partitioning of Sb, As, and Cu increased from 60.1%, 32.3%, and 27.5%to 81.6%, 67.8%, and 47.2%, respectively, with the smelting temperature increasing from 1050 °C to 1250 °C. While the metal partitioning of Sb and Cu increased from 0% and 2.7% to 15.2% and 13.3%, respectively, with the separation temperature increasing from 400 °C to 700 °C.

Oct 19, 2020

By E. Milosavljevic, C. H. Bucknam, K. L. Gabby, T. C. Eisele

"Since mercury is chemically similar to silver, it tends to dissolve along with the silver and gold during cyanide leaching. Ultimately, mercury is recovered along with the silver as mercury/silver/gold amalgam, which requires retorting to remove the mercury prior to refining the silver and gold. A possible approach to separating mercury from silver and gold in cyanide leach solutions is to take advantage of the replacement reaction between [Hg(CN)4]2- and Ag2S, which results in precipitation of mercury as HgS while dissolving silver as [Ag(CN)2]-. Results are presented demonstrating that mercury can be removed from cyanide solutions with high effectiveness while, at the same time, recovering additional silver in solution. Initial experiments with static flasks in the laboratory showed a high degree of mercury removal could be achieved. Results using actual metallurgical plant products in bottle roll tests indicate the process works on a larger scale, but also results in significant gold losses if the solution being treated has high gold levels, such as carbon stripping pregnant eluent solution. IntroductionThe dissolution of mercury along with precious metals during cyanide leaching is a long-standing problem, which can result in significant mercury toxicity issues (Washburn, 2003). Mercury is first dissolved by the cyanide solution, and then, since it has a great deal of chemical similarity to silver, it follows silver throughout the concentration and recovery processes, ultimately being recovered as a silver/ mercury amalgam when the metal is precipitated by either the Merrill-Crowe process or by electrowinning.While it would be desirable to either prevent mercury dissolution entirely while still allowing silver dissolution, or to selectively capture mercury before the precious-metals recovery step, there is not yet an effective and economically practical approach to doing this (Grosse, 2003; Ravichandran, 2004; Misra, 1998; Pai, 2000). There are a few processes that have been proposed, such as differential adsorption. While activated carbon, as used in the carbon-in-pulp process, is not highly selective between mercury and silver (Washburn, 2003), it may be possible to achieve some separation by selective elution of the carbon to produce high-mercury and low-mercury eluates (Bunney et al., 2010). Certain synthetic resins were shown to be selective for gold but are more expensive than carbon, requiring special equipment, and have not yet been shown to be selective for mercury (Grosse, 2003). There may be potential for differential dissolution approaches, as thiosulfate leaching does not dissolve mercury sulfides as readily as it dissolves gold (Oraby et al., 2010), and it is possible that it may be similarly more selective for dissolving silver relative to mercury. Some work has also been done with selective precipitants, such as sodium polythiocarbonates (Bucknam, 2007), and 1,3-benzenediamidoethanethiol (Matlock, 2002). Common problems with these approaches include introduction of a solid:liquid separation step, reagent costs, the need to measure the mercury concentration for process control for minimizing silver losses, and regulatory requirements to retort otherwise stable mercury concentrates."

Jan 1, 2015

By Roger G. Rowe

The Crandon deposit, located in northern Wisconsin, is a 65.8 million ton Precambrian volcanogenic massive sulfide deposit which averages 1.4% copper and 5.8% zinc. The deposit is classic in origin, mineralogy and shape. Comprehensive understanding of the geology of both the deposit and the project site has been fundamental to the credibility and success of Project feasibility studies and regulatory permit preparation. Mine development in the current investment and regulatory climate requires thorough and timely application of geologic tools. From 1977-1980 geologic activities were focused on the typical objectives of orebody delineation, reserve estimation, depositional geology, and general site investigation. Results from these programs formed the basis for the Project's preliminary feasibility studies. Since 1981 further geologic investigations have provided criteria for project design, site management, and operational permitting. Activities have included mine entry position definition drilling, developing geostatistical reserve modeling, large diameter (150 mm) core drilling for mill pilot samples, rock mecha¬nics testing, and evaluation of the glacial overburden/deposit geohydrology for computer simulation.

Jan 1, 1983

By Francois E. Heuze

The mined geologic burial of high-level nuclear waste is how the favored option for disposal. The underground repositories must keep the waste away from the biosphere for very long times - several thousands to tens of thousands of years. Also, access must be maintained to the vaults for several tens of years, so that the waste can be retrieved, if necessary. Both the excavation of the underground chambers, and the radiogenic heating will disturb the rock mass. The overall rock mechanics problem is to understand and predict the processes associated with these perturbations, and their impact oh the isolation and containment of the waste (3)**. The specific rock. mechanics issues which have been identified for the three candidate hard rocks (basalt, granite, and tuff), are summarized in Table 1. The table also indicates the level of adequacy of our knowledge in the areas of the various issues. Such an evaluation is consistent with the general consensus of the rock mechanics profession, as explained in several key reports and publications (1 to 11). The main shortcomings of today's rock mechanics for waste repositories can be summarized as: ? lack of resolution for remote mapping of fractures in rock masses ? great difficulty in testing large volumes of rocks to determine their mechanical properties.

Jan 1, 1981

By Steven I. Majtenyi

INTRODUCTION The heavy risk inherent in all underground construction projects contributes significantly to the high cost of transportation tunnels. First, the knowledge of this risk leads the engineer to design conservatively. Second, the cost overruns are still common with a high proportion of them originating from corrective measures needed when unforeseen problems develop during excavation. These unforeseen problems includes - encountering unexpected objects, materials and water conditions - experiencing an unforeseen behavior of the materials - damaging property beyond the expected range of influence of the tunnel construction. To minimize these expenses, more emphasis is being placed on well planned and interpreted site investigation programs in the final design and planning stages of the project. It is well known that the cost of a planned excavation is less than the cost of dealing with the same conditions when they are encountered unexpectedly. Therefore, the objective of site investigation is to provide a complete set of reliable data for designers and contractors that is continuous along the projected tunnel alignment. Two alternatives axe available to achieve this objective; - for shallow tunnels, it is often feasible to generate continuous data by drilling appropriately spaced, vertical bore holes and applying sensing techniques for interpolation (1, 8). - for deep tunnels, or certain urban tunnels under existing structures, closely spaced, vertical bore holes are not feasible except for narrow zones at the portals. In such cases direct horizontal penetration may be required that may be complemented by radial sensing to extend the range of information.

Jan 1, 1976

By Larry F. Brown

Mining has been the mainstay of the Woods Creek Valley for more than a century. The head of the valley is at the Continental Divide, about 50 miles west of Denver, Colorado. First, it was the quest for gold and silver that drew people to the valley. Then, when molybdenum was classified as a strategic metal by the U. S. Government during World War I, it was the valley's molybdenum mineralization which attracted the most attention. Molybdenum is used primarily as an alloying material in superior grades of steel. Circumstances responsible for providing the label "Urad" are unknown, but Urad is variously reported to be an acronym for "Uranium Research and Development" or "Uranium Research of America Division". The search for uranium was fruitless as no ore grade uranium exists in this area. The moly orebody was first developed and mined by the Primos Exploration Company from 1914 to 1919. During World War II, the mine was purchased by the government and turned over to the Molybdenum Corporation of America to operate. In 1963 AMAX Inc. purchased the property for $2 million. After spending nearly $30 million for exploration and development, AMAX put the mine into production again in 1967.

Jan 1, 1984

By Katarína Gáborová, Marcela Achimovičová, María Florencia Márquez‑Zavalía, Jaroslav Briančin, Oľga Šestinová, Pavel Škácha

In this paper, the structure, morphology, chemical composition and leaching of naumannite ( Ag2Se) were studied. Mechanical activation of Ag2Se in a planetary ball mill resulted in increasing its specific surface area. The influence of milling time on the particle size was studied by particle size distribution analysis and scanning electron microscopy. The leaching kinetics of non-activated and mechanically activated samples in 3.5–7.9 mol/L HNO3 solutions were examined. Subsequently, the effect of leaching temperature in the range of 25–50°C on the recovery of silver from mechanically activated naumannite was documented. The maximum yield of silver 94% was achieved after 120 min of leaching in 7.9 mol/L HNO3 at 50°C for the sample mechanically activated for 30 min. Based on calculated activation energy values from the Arrhenius equation, a mixed leaching mechanism consisting of diffusion and surface chemical reaction as the rate-controlling steps of the solidliquid reaction was assessed.

Mar 4, 2023