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By Neha Shukla, Nikhil Dhawan

The current study examines the extraction of rare-earth elements from trichromatic phosphor of discarded tube lights via baking processes. The Y2O3: Eu3+ (YOX) and BaMgAl10O17: Eu2+ (BAM) phases completely decomposed during acid and alkali baking with > 90% Eu and Y extraction. Prior, selective acid leaching of the YOX phase enhanced the acid baking process at a lower temperature (< 230 ℃). Feed acid baking showed a maximum 87% Tb, 36% La, and 17% Ce extraction at 500 °C, 0.5 h, 1 ml/g H2SO4, and alkali baking yielded 16.1% Tb, 86% La, and 73% Ce at 300 ℃, 0.5 h, 50 wt.% NaOH. The acid baking of the acid-leached phosphor yielded 72% Tb, 95% La, 63% Ce, ~ 95% Y, and Eu extraction at 300 °C, 0.5 h, 1.05 mL/g H2SO4. Lower Tb extraction during the acid baking of acid-leached phosphor can be attributed to the formation of Ba3Tb( PO4)3 and BaTbO3 phases. Insoluble Si3Tb5 phase formation and partial decomposition of CeMgAl11O19: Tb3+ (CMAT) phase in the alkali baking route leads to lower Tb extraction. The acid baking process is suitable for extracting Tb, Eu, and Y, whereas the alkali baking process is suitable for La and Ce. The thermal analysis of phosphor and flux interaction depicts that alkali baking is less energy-intensive than acid baking. In comparison, the one-step acid baking process and the two-step alkali baking process yielded desirable extraction results (87% Tb, total RE (rare earth) 78.5% and 50.4% Tb, total RE 59.3%). The product yield in the acid and alkali baking route of feed, acid-leach phosphor is 36%, 29%, and 39%, 28.2%, respectively, with ~ 98% mixed rare-earth oxide purity.

May 5, 2022

By Robert M. Dreyer

Thirty years ago it was possible to locate a quarry site for crushed rock for concrete aggregate by finding the nearest solid rock bluff accessible by road, But times have changed and the location of a quarry site to furnish crushed rock for concrete aggregate now has become rather complicated, Although both sand and gravel can be used for aggregate, this discussion will be confined to crushed rock in the regions around a metropolitan area. Let us assume that a consultant has been retained to advise on the desirability, and the possibility, of opening a new quarry within a given area. The problems are geological and ecological. Since the geological problems are simpler, they will be discussed first. Generally, the first step is to make a market study of competitive aggregate sources within the projected area. Assuming that the quality of aggregate to be sold by competitors as well as their mining costs will, within narrow limits, be the same, the problem becomes essentially a study of haulage costs from established quarries into the projected new area. Since haulage cannot be effected along straight lines and since each quarry operator may have different unit haulage costs, a map showing lines of increasing cost intersecting points on roads available for truck haulage radiating from competitive quarries can be rather complicated. Such a map, more-over, changes each time a new haulage contract is negotiated by a

Jan 1, 1971

By Yanli Huang, Qiang Sun, Jixiong Zhang, Yuzhuo Jiang, Dan Ma

Mining accidents due to inrushing water are caused by sudden changes in seepage owing to structural damage to key strata of the aquiclude. The backfill mining method can be used to control the movement of the strata, weaken the evolution of fractures owing to damage by key aquiclude strata (KAS), and control the channel for inrushing water. This study develops a mechanical model of a composite beam on a non-uniform elastic foundation of the KAS by analyzing the coupling relationship between the filling body and the key water-resisting layer of the aquiclude. Equations of the deflection-induced deformation, bending moment, and maximum tensile stress of the KAS are analyzed, formulae to calculate the allowable tensile stress and backfill materials’ compaction ratio (BMCR) to ensure structural stability are derived, and are used to provide the critical BMCR for their structural instability. The results of field measurements show that the subsidence of the roof was 600–700 mm with an average BMCR of 80.63%. Damage to the overlying strata was controlled to ensure safe mining and the disposal of solid waste from the aquifer. The research here is useful for ensuring safety during mining while protecting water resources.

Jul 12, 2022

By N. O. Lotter

The reliability of a set of flotation results is key to minimizing project risk, either at the commissioning of a concentrator or at the point of implementing an improvement to an existing concentrator operation. High-confidence flotation testing (HCFT) was developed for this purpose and is part of the list of technologies at various scales used by Xstrata Process Support (XPS) in addressing these projects. The methodology is based on two principles: one, to ensure that the ore sample is representative and has been well-blended and subsampled; two, to perform the flotation tests in sufficient numbers of replicates with appropriate quality controls, so as to improve the reproducibility of the test data. Across ten years of research on this methodology at Xstrata Process Support, Sudbury, several improvements to the HCFT method and complementary connections between sampling and quantitative mineralogy have been developed. Two case studies are reviewed. These show the capability of this system in both optimizing an existing concentrator operation and in serving a new mine scenario. Further work to improve the efficiency of this procedure has been identified. Key words: Flotation testing, Flotation

Jan 1, 2010

By Z. Y. Hu

This paper reviews the past and presents the present state of industrial minerals in China. The resources, reserve and production of major non-metallic minerals are given. The mining and milling operations are reviewed. The future development and plans of Chinese non-metallic minerals industry are summarized.

Jan 1, 1990

By Justin Reed, Sara Bewley, Dwight M. Kinnes, Maryam Sadeghi, Ed Hart

This study compares wet gravity and dry magnetic separation for preconcentrating an allanite-rich rare earth ore from the Halleck Creek deposit. Material in the –300/+86 μm size range was treated to define a flowsheet that maximizes total rare earth oxide (TREO) recovery. The ore is dominated by feldspar and quartz, with hastingsite, an iron-bearing aluminosilicate. Because hastingsite’s density and magnetic response closely match allanite, it is difficult to reject using conventional methods. Two separation approaches were evaluated: MG12 spirals for gravity concentration and an Induced Roll Magnetic Separator (IRMS) for dry magnetic upgrading. MG12 spirals performed well in the rougher stage but provided limited gains when used as cleaners. When IRMS was applied as the cleaner stage, TREO grade and recovery improved substantially, showing that a dry magnetic cleaner circuit can effectively replace the wet gravity cleaner step. MG12 spirals remain suitable for highcapacity rougher duty, but dry magnetic separation delivers higher selectivity, simpler operation, and eliminates water use—offering a more efficient and sustainable preconcentration route in water-constrained environments.

Feb 22, 2026

By David A. Summers

In May 1975 the U. S. Bureau of Mines contracted with the University of Missouri-Rolla, Rock Mechanics and Explosives Research Center to develop a Hydrominer modification to a long-wall shearer unit, wherein the rotating pick-laced drums and connecting gear drives are replaced by a water jet cutting head.1 The concept of the water jet cutting head is based on using the high localized energy of the water jets to isolate a slice of coal by cutting a slot under, at the back of, and at the top of the web. The plow blade of the head then advances into the cut and wedges the pillar over onto the conveyor (Figure 1). There were several potential advantages foreseen for the system of which perhaps the most significant were the elimination of coal dust from the working area2 and the ability, with a variation in nozzle geometry, to cut webs of greater depth with a small increase in equipment horsepower. The University initially designed the head, based on experiments carried out in the laboratory, under an earlier Bureau of mines contract. The experiments showed that it was more advantageous to work at a pressure of 10,000 psi with an estimated flow rate of 50 gpm than go to the higher pressures and lower flow rates which have been advocated elsewhere.

Jan 1, 1977

By L. Yan, T. Lutz, J. Noll

"Mine disasters, such as fires and explosions, can create a hazardous atmosphere due to the generation of carbon monoxide (CO). After a mine disaster, contaminated mine air can enter the refuge alternative (RA) as miners enter. Most built-in-place (BIP) RAs use an air delivery system to provide an unlimited supply of breathable air through a borehole which also serves to purge contaminants. In order to determine what levels of contaminants enter the RA, researchers from the National Institute for Occupational Safety and Health (NIOSH) conducted testing in NIOSH’s Pittsburgh Experimental Mine using groups of 5, 15, and 30 subjects entering the RA. The experiment used sulfur hexafluoride (SF6) as a tracer gas that was released into the air outside of the BIP RA to establish a uniform concentration. After the human subjects entered the BIP RA, the SF6 levels inside the RA were measured to quantify how much of the tracer gas entered the BIP RA. In tests conducted while the borehole air supply was left off as test subjects entered, interior contaminant levels were less than 3% of the exterior concentration. In tests conducted with the borehole air supply activated as test subjects entered, the interior contaminant levels were measured at less than 2% of the exterior concentration. Considering a mine disaster can result in 10,000 ppm of CO in the mine atmosphere, these percentages indicate that unhealthy CO concentrations that may lead to headaches, dizziness, and loss of judgement can occur in a BIP RA. This information will help mines make decisions concerning air locks, air delivery systems and a determination if purging mechanisms are necessary. INTRODUCTION The Mine Improvement and New Emergency Response Act of 2006 (MINER Act) was enacted in the wake of three mine explosions/fires that claimed 19 lives that year. Intended to help improve underground coal mine accident preparedness, the MINER Act includes provisions that target mine safety issues in areas such as emergency response planning, adoption of new technology, training and education, and enforcement of mine safety standards (MSHA, 2006). Section 13 of the MINER Act specifically directs the National Institute for Occupational Safety and Health (NIOSH) to provide for research into the effectiveness and viability of RAs for underground coal mines. This mandate culminated in the 2009 adoption of changes to the 30 CFR mining health and safety regulations, requiring underground coal mines to provide RAs capable of maintaining a life-sustaining environment for persons trapped underground. Such RAs can be either pre-fabricated or BIP shelters. The regulatory changes also include provisions establishing requirements for Mine Safety and Health Administration (MSHA) approval of RAs and their components, and among these provisions are numerous criteria for providing a safe, breathable atmosphere within RAs."

Jan 1, 2018

By John N. Murphy

The environmental status of underground mining operations is critical to the health and safety of the miners; particularly in a large mine, the multitude of interacting parameters that can favorably or adversely affect the environ-mental status makes the manpower requirement of the routine checking of specific areas and conditions a formidable one. While the concept of environmental monitoring for miners has been considered for some time, until recently the availability of sensors to reliably measure the parameters of interest severely limited the utility of such systems. The status of sensors for mine use and the evaluation of environmental monitoring systems is reviewed.

Jan 1, 1977

By G. H. Friedrich

The distribution of mercury in soils, rocks, and ore was studied in three areas of the Pachuca-Real del Monte District: (1) An area north of the town of Pachuca where ore veins have been found at or near the surface. The mercury content of soil samples taken near the vein zones is far above the background value. The highest value was 1900 ppb (parts per billion) mercury in a soil sample above Veta Vizcaina; the background is about 50 ppb Hg. (2) In the area north of the town of Real del Monte where only a few of the veins are known to crop-out. Regardless of exposure, soils collected over veins show anomalous mercury values ranging from 250 ppb to 1900 ppb. (3) In an area south of the town of Real del Monte. Here, although vein outcrops are lacking, mineralization is known at a depth of about 120 m. All soil samples taken at 50 m. intervals along an east-west traverse contain anomalous amounts of mercury, with peaks corresponding with the known location of the veins.

Jan 1, 1965

By A. D. Davis

The Bear Butte Creek watershed, in the northern Black Hills of South Dakota, shows the effects of past mining activities in the form of dissolved metals and arsenic in stream water. Bear Butte Creek, during normal flow periods, loses all of its discharge to sinkholes that recharge the Madison Limestone aquifer. This work focused on the geochemical transport and fate of arsenic and on understanding ground-water flow conditions in the Madison aquifer through development of a three-dimensional ground-water flow model that was coupled to a geographic information system (GIS). Stream sampling and discharge measurements helped determine sinkhole losses and loading rates. Column laboratory tests provided data on arsenic adsorption and the mixing of stream water with aquifer water, which also was simulated with the geochemical models, pHREEQE and NETPATH. The models and GIS can be updated with new information and will be useful in managing the water quality of the Madison aquifer.

Jan 1, 1997

By Jürgen. F. Brune, CLAIRE STREBINGER, ADITYA JUGANDA, Gregory E. Bogin Jr

The abstract highlights the risk of methane gas explosions in underground coal mines and the potential of computational fluid dynamics (CFD) modeling to simulate such events and assess their impact on mine ventilation. The study focuses on developing CFD models for large-scale explosions in longwall mines, specifically simulating methane gas explosions resulting from face ignition during coal cutting. The research demonstrates the integration of a combustion model into a longwall mine ventilation model and shows how the availability of explosive gas mixtures significantly affects flame propagation and explosion pressure.

Mar 27, 2022

By A. Rajoria

A dynamic process model for predicting the fluidized bed roasting of copper concentrates with high arsenic content is presented in this work. Mass and energy balances were performed based on roasting mechanism derived from thermodynamic data of species. The reaction rate data, obtained from pilot plant studies on major reactions, were used in tuning the kinetic parameters of the model. DEAS, a dynamic simulation package, is used in setting up the fluidized bed roaster plant model. The effect of process parameters such as concentrate feed rate, concentrate composition, airflow and cooling water rate on the temperature and conversion of roasting reactions are analyzed. The plant model captures the highly transient conditions occurring during the plant start-up, shutdown and other process perturbations. The application of this model in constructing a virtual plant environment for validating the operating procedures and operator training is presented.

Feb 23, 2014

By S. K. Kawatra

Many mineral oxide and multi-component oxide (basalt) specimens break down into powders upon expo-sure to sodium vapor at elevated temperatures for extended times. This paper examines several possible mechanisms of oxide breakage by sodium vapor, both experimentally and from a thermodynamic viewpoint. The oxides for which reduction by sodium was thermo-dynamically favorable all exhibited some degree of fragmentation. The oxides which were not favorable for reduction by sodium did not exhibit fragmentation, with the exception of rutile, a titanium oxide. The rutile fragmentation was caused by the reduction of iron that was in solid solution in the rutile crystal structure.

Jan 1, 1995

By R. W. Wittkopp

The Relief Canyon gold deposit is located approximately twenty- four kilometers east of the town of Lovelock in Northwestern Nevada. At Relief Canyon, the Late Triassic Grass Valley Formation has been thrust over the Late Triassic Natchez Pass Formation. The lower plate Natchez Pass Formation is composed of massive gray dolomitic limestone which is locally silty and sandy. The upper plate Grass Valley Formation is composed of shale, siltstone, argillite and quartzite. Gold mineralization at Relief Canyon occurs along the highly brecciated thrust contact between these two formations. Weak gold mineralization often occurs above the thrust in the Grass Valley Formation, however, most of the ore grade mineralization is present below the thrust in the brecciated Natchez Pass Formation or where the two formations are mixed as a result of movement along the thrust. Several types of gold mineralization have been recognized at Relief Canyon. A large amount of the ore is present as a jasperoid breccia, however, significant amounts of ore occur as a mixed breccia composed of upper plate rock, fresh limestone, clay and jasperoid breccia. Gold ore also occurs in a fresh limestone breccia which contains a large amount of clay. Below masses of jasperoid, jasperoid stringers containing gold extend into the fresh limestone. Gold mineralization at Relief Canyon appears to be truly disseminated and has the typically associated trace elements of arsenic, antimony, mercury and fluorine. The Relief Canyon deposit can be classified as a structurally controlled disseminated gold deposit. Other deposits that fit this classification are the Pinson and Dee gold mines.

Jan 1, 1984

By Richard E. Gray

Virtually all structures show some signs of distress due to deterioration of the building components, to changed loads, or to changed support conditions. Changed support conditions result from ground movements. In mining regions many cases of structural distress are attributed to mining without considering alternative causes. This is particularly true of coal mining since it occurs under extensive areas. Coal mining is estimated to have already undermined more than eight million acres and may eventually undermine 40 million acres in the United States (HRB Singer, Inc., 1977). Other nonmetal and metal underground mines impact much smaller areas. Although it is sometimes difficult, even with careful study, to identify the actual cause of damage, persons responsible for underground coal mining should at least be aware of possible causes of building stress other than mine subsidence. This paper presents information on distress to structures and briefly reviews a number of causes of ground movements other than subsidence: Mass movements, dissolution, erosion, frost action, shrinking and swelling, yield into excavations and compressibility

Jan 1, 1986

By Erika Moonin, Jim Nickerson, Marcus Jensen

"This paper will explain how the Contractor and Owner avoided a contractual dispute involving characterization, impacts, and final remedy for challenging ground conditions encountered during drill and blast excavation of the starter tunnel required for launch of the tunnel boring machine (TBM). During excavation more than 600 feet underground, the Contractor encountered a large complex fault zone subject to more than 14 bar of water pressure. Successive ground inflows from the fault complex over a six-month period presented significant technical and partnership challenges for the team and ultimately delayed the project by nearly one year. This paper will discuss how the Contractor, Owner, and their respective consultants worked together to address these challenges, make decisions, and ultimately move the project to successful completion. PROJECT BACKGROUND AND NEED Seven states of the western United States of America rely heavily on the Colorado River and its tributaries for their water supply. The primary source of water for the Colorado River is winter snow that falls in the mountains ringing the Colorado River basin, including the Rocky Mountains, the Wind River Mountains, and the Uinta Mountains. Flows in the Colorado River vary significantly from year to year, depending on the amount of snow and rain deposited in the basin. During the 1980s and 1990s, snowfall was relatively abundant and Colorado River flows were high on average. Beginning in the year 2000 and continuing to the present day, snowfall has been well below documented historical averages and Colorado River flows have diminished. In fact, a trend toward diminishing flows is evident during the period of the historical record. This variability in Colorado River flows and the trend to lower flows is represented in the following Figure 1."

Jan 1, 2016

By C. C. Clark

The National Institute for Occupational Safety and Health (NIOSH), Ground Control Engineering Branch is investigating the use of shotcrete in weak rock mass mines with the objective of reducing fatalities and injuries resulting from rock fall accidents. When shotcrete is used as part of a multi-element ground support system there is a need to know when the material has developed a threshold early compressive strength of approximately 1 MPa (145 psi) for safe re-entry of miner and machine into shotcreted mine workings. This equates to the material having developed enough strength to be self-supporting and allow for emplacement of the remaining support elements that require drilling of the shotcrete layer without degradation. NIOSH researchers have developed methods and portable test equipment to measure shotcrete strength on-site in the first six hours after application using the ASTM C 116-90 (1990) standard. These advances were demonstrated in tests on five commercially available shotcrete mixes, sprayed as dry shotcrete using the field expedient methods and equipment. The strength values from these tests allowed for real-time identification of the early strength threshold and were consistent with strengths reported using laboratory-type equipment. The findings of this NIOSH research for determining shotcrete early strength can improve mine safety by providing a method for determining initial site specific material property values to be used for design and as a means to conduct on-site quality control and monitoring during production.

Jan 1, 2010

By Jason Swartz, Gerardo Gomez, Henry Leighton

San Antonio has experienced sustained growth for decades, putting increased pressure on existing wastewater infrastructure. In June 2013, San Antonio Water System (SAWS) reached a Consent Decree agreement that requires significant improvements to the wastewater system over a 10-year period to reduce Sanitary Sewer Overflows. One of the critical projects was the W-6 Upper Segment Tunnel project to reduce sanitary sewer overflows on an existing sewer main running through Lackland Airforce Base. The replacement project consisted of a new tunnel nearly 29,000 LF of primarily 104" FRP. The project also includes nine shafts and multiple trenchless crossings to make near surface connections to the new works.

Jun 23, 2024

By C. J. Webb

Abandoned uranium mines in the southern Black Hills of South Dakota were sampled for uranium, radium, and rare earth elements during 1992 and 1993. Analyses of water samples from several shallow ponds in the mine pits showed pH values between 3 and 4 with uranium concentrations between 1600 and 2600 ppb. Rare earth elements and their respective isotopes were analyzed with an inductively coupled plasma mass spectrometer and were referenced to a shale normalization pattern. All samples showed an enrichment in the middle rare earth elements. Rare earth levels often were greater than 0.2 ppm. At one site, the concentrations of lanthanides were 150,000 times above background levels. While the southern Black Hills have long been known for rich uranium ore deposits, these analyses show that significant levels of rare earth elements also are present, indicating that the potential exist for future development.

Jan 1, 1995