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By N. K. Bohidar

Evaluation of the stability of a structure under given boundary conditions requires accurate knowledge of the state of stress as well as the mechanism of failure at the critical state of stress. This paper represents a part of the research done by N. K. Bohidar during 1965-1968 for his Ph. D. research in Mining Engineering at the University of Utah. It summarizes the determination of internal stress and failure phenomena around cylindrical openings in viscoelastic media subjected to lateral restraint and vertical uniaxial load. The conditions of lateral restraint and viscoelastic nature of the media represent conditions associated with subsurface openings in rocks. The financial assistance provided to the project from the University of Utah Research (Uniform School Fund), W. C. Browning Scholarship Fund, Earth Science Research Fund, and D. C. Jackling Loan and Scholarship Fund is gratefully acknowledged. The authors also acknowledge the assistance of S. Siugh, W. Jones, and K. McCarter during the project.

Jan 1, 1970

By Michael S. Moats, John Bailey Fletcher

Wear rates of grinding media can be misrepresented by marked ball wear tests (MBWT). Galvanic interactions between dissimilar grinding media can be affected by the chromium content in the media and the presence of oxygen in the environment. Corrosion, one component of wear, can be affected by many variables. Corrosion rates and corrosion potentials for modern high chromium white iron (HCWI) and high carbon steel (HCS) grinding media samples were obtained through electrochemical testing. In this study, the impact of chromium content in the grinding media and the dissolved oxygen in a simulated mill water solution on corrosion rates and potentials was examined. Increasing chromium content in HCWI above 15 weight percent increases the corrosion potential and decreases corrosion rate. Removing most of the oxygen from the solution lowers both the corrosion potential and corrosion rate of the materials tested. The electrochemical results were examined to model possible galvanic coupling effects on corrosion rates. Galvanic coupling between HCS and HCWI could cause differences in corrosion rates for almost all scenarios modeled. Based on the galvanic coupling analysis, MBWT results could be impacted by mixing HCWI and HCS in a ball mill charge. This impact is predicted to be more significant when dissolved oxygen is present in the mill water and as the chromium content of HCWI is above 15 weight percent.

Dec 21, 2022

By Rosa Malena Fernandes Lima, Kerollan da Silva Ramos, Joyce de Assis Silva, Geriane Macedo Rocha

This study evaluated the effects of collector type amide-amine compared with those of conventional etheramine acetate (both cationic collectors) on the surface properties of quartz and hematite. An examination of certain properties of the reagents indicated that the new collector amide-amine has CMC (critical micelle concentration) and pKa values (100 mg/L and 8.2, respectively) significantly lower than those of etheramine (800 mg/L and 9.4, respectively). Microflotation tests showed that the recoveries of quartz with amide-amine in all the concentrations tested were higher than those with etheramine. This is attributed to its lower CMC and pKa values. The selectivity window between quartz and hematite flotation using amideamine was higher at pH 10.5 (approximately 80% for 5 mg/L). Therefore, the use of starch is not necessary in siliceous itabirite flotation by amide–amine collector. Zeta potential measurements and infrared spectra reveal that the adsorption of amide-amine collector on quartz surface occurs mainly by electrostatic attraction. Considering the better collectability of amide-amine for quartz flotation and lower adsorption affinity for hematite surface than etheramine, the amide-amine is a promising collector to be used in reversal iron ore flotation.

Jul 30, 2021

By J. Pascoe, J. H. van Laar, J. H. Marais, F. J. L. Matthee

Advanced measurement and verification (M&V) is a process where the impact of an energy initiative is determined in real time. Data prediction models can be used to predict and compare energy consumption with a predetermined baseline. Deeplevel mines can benefit from advanced M&V as the impact of operational changes can be identified in real time. Ultimately, this can ensure that informed decisions are made regarding energy management based on the impact and severity of the occurrence. Previous studies on advanced M&V do not account for operational changes to the model’s baseline. These changes can significantly impact the performance of both the mine and related activities. The aim of this study is to propose a method that can accurately predict the energy consumption of a deep-level mine regardless of operational changes. To achieve this objective, nine different data predictive modelling techniques were considered. The proposed method is based on the Moving Average (MA) modelling technique due to its simplicity, flexibility, and rapid development time. The coefficient of variation for the root mean square error (CV(RMSE)) was used to statistically analyse the modelling error. If the predictions exhibit an unsatisfactory CV(RMSE), the model dynamically adjusts to reduce the prediction error. The model was developed to adapt to operational changes in scenarios where the standard model becomes irrelevant. The method developed in this study was able to predict the future energy consumption of deep-level mines with an accuracy of 99%, improving the mine’s energy and finance management.

Dec 13, 2023

By Greg Struble

The Homestake Gold Mine is one of the deepest and most extensively developed hardrock mines in North America. The mine is divided into five divisions which produce a total of 1.7 million metric tons of ore per year. In the past, labor intensive mining methods such as open cut-and-fill, shrinkage, and timber stoping were utilized. In recent years there has been an extensive change to the more productive methods including Vertical Crater Retreat and Mechanized Cut-and-Fill. Also, the percentage of production from the lower divisions below the 4850 level is increasing while upper level reserves are beginning to decline. Combined, these factors have strained the ventilation resources to the limit. By early 1984 it became clear that future production trends would require a detailed study of future ventilation resources. By November of 1984 the Ventilation Department completed a study to project these future requirements. This paper will detail the first phase of a scheduled two phase upgrade: the installation of a new surface fan.

Jan 1, 1987

By D. P. Bryan

An aggregate resource study was done for southern Washoe County, Nevada, which contains the Reno-Sparks metropolitan area and a population of about 300,000. The study included an inventory of existing operations, projection of future demand, identification of potential aggregate resources based on geology, and determination of economic potential of these resources. Economic potential was determined by the integration of GIS layers that included aggregate potential, distance from market, distance from major and minor transportation arteries, and elevation. The investigation resulted in a determination that resources of high quality aggregate sufficient for future consumption are present in southern Washoe county; the limiting factor for future utilization is accessibility.

Jan 1, 1996

By A. K. Raina

Blast induced damage to the final wall of rockmass in any civil or engineering application is a major concern to the rock excavation engineers. There are at least four distinct techniques practised by blasting engineers to minimise the damage to the parent rock during blasting that are classified as contour blasting. One of the methods to achieve a smooth wall or rock surface in blasting is pre-splitting, where blastholes in the final row are mildly loaded with explosives and fired first in sequence before the rest of the holes in a round of blast to achieve a split in rockmass. Since blasting is one of the most adopted methods for achieving a final wall in a desired shape, while maintaining the rockmass integrity, the design of pre-split blast assumes importance. There are several variables that determine the final shape of the pre-split face including the rock type, the drill diameter, the explosive characteristics, the orientation of major joints with respect to drill hole, the linear charge density, the spacing of drill holes and inclination of the drill holes. This study attempts to determine the importance and sensitivity of variables in pre-split blasting using historical data from open excavations of a hydroelectric project in India. Keeping in view the multitude of variables, low correlation of independent variables with responses and high level of interactions between the variables that define the blast results, it was found suitable to use ANN to determine the importance and sensitivity of the variables involved. A new method to determine the blast induced damage to rockmass, namely, undamaged area (AUD%), is introduced. Half Cast Factor (HCF%) and AUD%were calculated for a high wall and trenches by digital image analysis technique using the Fragalyst software. Joint spacing and linear charge density emerged as most controlling variables in determining the final result of pre-blast. The relative importance of other variables assuming significance in the case of both the designed outputs is also discussed. A comparative analysis of HCF%and AUD%on the basis of results obtained from ANN analysis is also presented. A futuristic approach concept has also been introduced.

May 30, 2021

By Erika Moonin, Jim Nickerson, Claudio Cimiotti, Roberto Bono

"In response to the severe drought on the Colorado River basin and in order to preserve existing water capacity to the Las Vegas Valley, the Southern Nevada Water Authority contracted a new deep-water intake (Intake No. 3) located in Lake Mead. The current project (Contract No. 070F-01-C1) includes 5 km (3 miles) of tunnel with very difficult geological conditions and a 200- m (650-ft) deep shaft and marine works. This paper will present the current status of the design-build contract being constructed by Vegas Tunnel Constructors and the challenges and problems faced and the innovative solutions developed to handle the difficult conditions encountered during tunneling with up to 15 bars of pressure.ProjectbackgroundThe Las Vegas Valley receives the majority of its water from Lake Mead, which is located approximately 30 km (20 miles) east of the Las Vegas, NV metropolitan area. Due to the severe drought that has hit the southwest region of the United States, the water level in Lake Mead has receded from its high water level of 372 m (1,221 ft) above mean sea level (amsl) to a low of 330 m (1,076 ft) amsl in June 2015. Should the lake level continue to fall, at elevation 320 m (1,050 ft) amsl, the current water intakes will not be able to draw enough water to meet the needs of the local area. The risk of losing water capacity has prompted the construction of a new deeper intake. Not only is the new Intake No. 3 situated at a lower elevation in the lake at 262 m (860 ft) amsl, the new Intake No. 3 is also located to draw better quality (Fig. 1).Project challengesThe project has had several difficult challenges to overcome:• The work consisted of a 1.2 kt (1,300 st) structure constructed on a barge and lowered 100 m (330 ft) into Lake Mead anchored with 9,200 m3 (12,200 cu yd) of tremie concrete.• The drill-and-blast starter tunnel was impacted by three inflow events, resulting in a one-year project delay.• One of the main challenges was selecting the tunnel boring machine (TBM) and excavating the tunnel with expected hydraulic head pressure of as much as 17 bar (16 bar was the highest pressure recorded during the drive), crossing faulted areas, low rock cover and the risk of tunnel instability due to direct connection with the lake.• Extensive pre-excavation grouting with a constant head pressure ranging from 12 bar to 15 bar.• Structural repair of the cutterhead in difficult hydrogeological conditions [water inflow of approx. 800 m3/hr (4,000 gpm)].• Complete repair of the cascade sealing system for the main bearing and two replacements of the pinion bearings.• The TBM approach to the intake structure."

Jan 1, 2015

By Adabala Raja Venkata Sai Naresh, Radhakanta Koner

Particle size distribution (PSD) is an essential parameter in assessing the overall efficiency of blasting operations in mines and the subsequent mine-to-mill process in the mining industry. Despite some drawbacks of 2D image analysis techniques in accurately estimating particle sizes in PSD, the mining industry has relied on them for the last three decades. This study proposes the 3D rock fragmentation measurement (3DFM) technique for deducting the accurate dimensions of 3D rock particles for the PSD. 3DFM has utilized different processing algorithms. Images of different views of the non-touching rock particles of varying sizes have been acquired as a data acquisition step of structure from motion technology for generating sparse point cloud. Dense point cloud reconstruction is used to avail finer details of the point cloud using clustering views for the multi-view stereo algorithm. Random sample consensus (RANSAC) algorithm coupled with an unsupervised classification using the density-based spatial clustering of applications with noise (DBSCAN) classifier is employed to extract the rock clusters from the 3D point cloud. Finally, the accurate rock sizes are derived using the hybrid bounding box rotation identification (HYBBRID) algorithm with a root mean square error (RMSE) of 0.10 cm for length, 0.10 cm for breadth, and 0.32 cm for depth. The PSD of rock fragments obtained from the proposed 3DFM technique is found to be matching with the results of mechanical sieving and manual gauging with an R2 values of 0.98 and 0.99, respectively. The 3DFM method can be considered cheaper, more accurate, and computationally faster in determining the rock dimensions for the PSD determination method to enhance the productivity of the mining industry.

Dec 29, 2023

By Ergin Arioglu, Werner Burger

"SUMMARY The Istanbul Strait Road Crossing Project includes a 3.34 kilometer subsea tunnel excavated by TBM with an excavation diameter of 13.71 m. The tunnel will incorporate two road decks, each employing two traffic lines and shoulder with the daily capacity of 100,000 light vehicles. The tunnel alignment crosses full face rock sections with heavily fractured zones due to tectonic events as well as a long central stretch of difficult mixed face and very variable soft ground conditions. The demanding ground conditions and the large diameter in combination with realized face pressures well above 10 bar required a highly specialized and well adapted TBM. The paper describes the project challenges and the related technical solutions incorporated within the TBM design as well as the real site experience. INTRODUCTION In 2013, a 13.71 m diameter Mixshield was manufactured in Germany for the Istanbul Strait Road Crossing Project. The delivery of the TBM in late 2013 was a major milestone for the Istanbul Strait Road Crossing Project, also known as the Eurasia Tunnel Project. The Eurasia Project (www.avrasyatuneli.com.tr/en) consists of a 14.6 km route including a 5.4 km tunnel segment in its central part crossing the Bosphorus. The 3.34 km subsea section of the tunnel was excavated in closed mode using a Mixshield TBM. The remaining tunnel length is constructed by sprayed concrete lining (SCL) method followed by a cast in place (CIP) lining or by cut and cover (CC) structures for the TBM transition boxes (Figure 1, right). Other project sections on the European and Asian side consist of upgrading and widening surface access roads towards the tunnel. Conceptual ideas of connecting Asia with Europe via a tunnel crossing the Bosphorus have been around for an extended time and only became realistic towards the end of the 20th century based on significant technical developments in mechanized tunneling. Feasibility studies for a new Bosphorus crossing in 2003 and 2005 confirmed and suggested a road tunnel in its present alignment as the preferred solution. Following an international tender process the Ministry of Transport, Maritime Affairs and Communications of Turkey assigned ATAS, a special purpose company formed by Yapi Merkezi (Turkey) and SK E&C (South Korea), to design, build and operate the Eurasia Tunnel Project. The Implementation Contract was signed in February 2011. In 2012, Herrenknecht AG was selected as the supplier for the 13.71 m Mixshield TBM."

Jan 1, 2016

MINExpo International is billed as the largest exposition for the mining and mineral processing industry. And the 2012 edition, scheduled for Sept. 24-26 in Las Vegas, NV, is no exception. Put on by the National Mining Association (NMA), attendance at this year?s show is expected to be significantly more than the 38,500 who attended the last MINExpo in 2008. The exhibit will also be quite a bit larger in 2012 than it was at the previous MINExpo. More than 1,800 companies, representing more than 30 countries, will fill the Las Vegas Convention Center. The more than 850,000 sq ft of exhibit space will include the North and Central halls as well as South Halls Nos. 3 and 4. And the Silver Lot outside of the front door, under construction in 2008, will be filled with more exhibitors. The 2008 show attracted about 1,220 exhibitors occupying more than 600,000 sq ft of exhibit space.

Jan 1, 2012

By John Drew Ridge

Tables showing world trade in metallic mineral raw materials during the years 1953 through 1957 have been prepared for the following twenty-one commodities: alumina, aluminum, bauxite, chromite, copper concentrates, partly refined and fully refined copper metal, iron ore, pig iron, iron and steel (simple shapes), lead concentrates, lead metal, manganese ore, mercury metal, nickel ore, concentrates, and matte, nickel metal, raw pyrites, sintered pyrites, tin concentrates, tin metal, zinc concentrates, and zinc metal. In each instance, the amounts given by the importing country were used except when statistics from the importing nation were lacking, incomplete, or misleading. To show the considerable divergence between importing and exporting country totals for the same years, the complete mercury table is given and, in parallel columns, shows the comparable tonnages of importers and exporters. Tables for the other twenty commodities are presented in summary form. The data of the concentrate tables are used with those of the corresponding metals as a basis for a discussion of trade in concentrates versus trade in metals. The data of all twenty-one tables provide the basis for testing the thirteen rules governing international trade in metal raw materials which I first published in Mining Engineering for July 1955. Because the 1953 through 1957 data are far more complete and considerably more extensive than those on which the 1955 rules were based, it was found possible to deduce five additional rules and to modify three of the original thirteen appreciably. The full text of the eighteen rules is given.

Jan 1, 1960

By G. Barbery

In Mineral Processing, the objective of most processes is the separation of mixtures of minerals, which are originally associated in composite particles. Feed preparation processes grinding for instance, which take place before beneficiation or separation processes do not usually break particles at the boundary between mineral phases. They produce composite ("middlings") as well as liberated particle. It is therefore necessary, in a particulate system, to determine the proportion of particles which are liberated as well as, ideally, the size distribution of minerals which remain associated in composite particles. Up to now, there has been a lack of experimental techniques to characterize completely composite particulate systems. Heavy liquid separation which is commonly used to obtain information of this type can only be applied to simple binary cases for which one mineral has a low density (lower than e.g 2.8 ). The technique which is proposed in this paper involves the measurement of parameters on polished sections of particles mounted in a matrix, and the use of mathematical transformations to reconstruct in three-dimensions the information obtained from these measurements .

Jan 1, 1977

By J. M. Wempen, R. D. WEYHER, M. K. McCarter

Beam theory is a proxy for the behavior of intact, deforming roof strata above underground openings. Strong, stiff, intact strata have the ability to store significant strain energy when underground openings have large spans, as is typical of longwall operations. When strata fail, they may release some or all of this strain energy. Released energy is partitioned between fracture, thermal, and seismic energy. The tensile failure surface in simply supported beams is predicted to be free of shear stress. This prediction and the kinematic inability of crack slip during fracture make significant dissipation of energy by friction unlikely. In this study, the failure energy partitioning of Nugget Sandstone specimens is examined. Tensile fractures in specimens were induced using three-point loading tests. Elastic waves emanating from fracture events were recorded using an array of accelerometers. Accelerometers were placed within two crack lengths of the fracture surface, and the acceleration records are similar to strong motion seismic records. Spectral analysis was performed and used to develop synthetic, well-behaved, acceleration signals. Synthetic velocity signals were used to estimate radiated seismic energy generated by fracture. These estimates of radiated seismic energy demonstrate a potential means to constrain the minimum seismic partition. Fracture testing was performed on additional samples to estimate the fracture toughness of the sandstone. Synthesis of this data demonstrate a potential means to constrain a maximum seismic partition. Bounding the seismic partition for this type of fracture event could aid the detection and evaluation of seismicity emanating from longwall operations. Having better information about the location and magnitude of mining-induced seismicity within longwall overburdens could lead to better understanding of extraction sequencing and rock behavior in general. These energy estimates also support the hypothesis that dissipation of thermal energy by friction is small in bending tensile failure.

Jul 1, 2020

By James E. Lawver

At the present time, the Florida phosphate industry is experiencing one of the worst marked slumps in its one hundred year history. Recent agriculture over-production has caused low grain prices such that the net income of U.S. farmers is expected to drop to its lowest level since the 1932 depression. The farmers' low income, along with high interest rates that preclude them from borrowing to purchase fertilizer, make the immediate U.S. phosphate market outlook bleek at best. The export outlook is also pessimistic due to world recession and the U.S. dollar's high exchange rate. In June, 26% of the phosphate industry's workers were laid off for an indefinite period of time. Despite the immediate painful slump, the long-term outlook for the industry looks good. Florida has enormous reserves and will continue to produce a third of the world's phosphate supply simply by making changes in the present system of mining, beneficiation, waste disposal and land reclamation.

Jan 1, 1983

By R. W. Plume

Gold extraction along the Carlin trend requires large withdrawals of ground water, which can be perched, unconfined at shallow depth, and (or) confined at depth. Five hydrogeologic units-Quaternary basin-fill sediments, Tertiary basin-fill sediments and sedimentary rocks, Tertiary volcanic rocks, Devonian to Ordovician siltstones, and Devonian to Ordovician carbonate rocks--form the framework for two aquifer systems that discharge along some reaches of the Humboldt River and its tributaries and are recharged by streamflow along other reaches. Ground-water withdrawals eventually could affect these stream-aquifer interactions. Further work is needed to quantify regional hydrologic processes and evaluate potential effects of mining on water resources.

Jan 1, 1992

By S. Tuylu, D. Adiguzel, U. G. Akkaya, A. Bascetin

"One of the main problems for storing of the tailings is acidity occurrence due to several factors such as existence of sulfuric minerals and also the pollution in seepage waters by mobilization of metal ions, which holds great risks in terms of environmental regulations. Because of these specified reasons, tailing materials to be used in a SPD formula should have comply with some specifications. Among these properties; oxygen content, temperature, matrix suction and pH are the most important parameters. In the study, the relationships between the parameters mentioned are investigated to reveal optimum paste design layout. The lowest amount of seepage water obtained from the paste layers in the pilot cabinet was found as 2150 ml from 3rd layer. As for the maximum seepage water and the average of the all 11 layers were found as 4909 ml from 6th layer and 3273 ml respectively. The reactions occurring according to the oxidation, as seen at seepage water of second and third layers, decreased the pH of system to the under of 7 value. Additionally, when the seepage water of first layer’s EC value is 2.93 mS/cm, the EC value of second layer is increased at 3.54 mS/cm. The other parameters are evaluated with the obtained results of the tests to determine the optimum storing conditions for SPD.INTRODUCTION Conventional waste disposal methods, although widely used, pose great environmental risks. One of the most important issues is acid mine drainage (AMD). Tailings of metallic mines contain heavy metals, aggressive chemicals and hazardous materials. In the presence of oxygen and water, an oxidation reaction can occur, causing a decrease in pH of the environment, and heavy metals that are present in the environment can dissolve easily. Subsequently, heavy metals can pollute underground water basins, creating a great amount of danger for the ecology and potable water resources. Another important risk associated with conventional waste disposal methods is accidents related to the waste dam. Higher volumes of water and tailings (usually 15% solids and 85% water by weight) are sent to waste dams, making it very difficult to control the stability of the dam under conditions such as static and dynamic loads (seismic activities, vibrations caused by blasting, etc.), flooding, and seepage. In case of an accident or failure, the spread of great amounts of mud containing hazardous chemicals and heavy metals can harm the environment of the dam site significantly (Bascetin et al., 2014). In the paste technology, depending on the type of ore, tailings used in the paste mixture can contain sulphide minerals (such as pyrite and pyrrhotite). These minerals are known to be reactive with water and oxygen to produce acidity (sulphuric acid)."

Jan 1, 2015

By S. L. Ducummon

Inactive underground mines now provide essential habitat for more than half of North America's 44 bat species, including some of the largest remaining populations. Thousands of abandoned mines have already been closed or are slated for safety closures, and many are destroyed during renewed mining in historic districts. The available evidence suggests that millions of bats have already been lost due to these closures. Bats are primary predators of night-flying insects that cost American farmers and foresters billions of dollars annually, therefore, threats to bat survival are cause for serious concern. Fortunately, mine closure methods exist that protect both bats and humans. Bat Conservation International (BCI) and the USDI-Bureau of Land Management founded the North American Bats and Mines Project to provide national leadership and coordination to minimize the loss of mine-roosting bats. This partnership has involved federal and state mine-land and wildlife managers and the mining industry. BCI has trained hundreds of mine-land and wildlife managers nationwide in mine assessment techniques for bats and bat-compatible closure methods, published technical information on bats and mine-land management, presented papers on bats and mines at national mining and wildlife conferences, and collaborated with numerous federal, state, and private partners to protect some of the most important mine-roosting bat populations. Our new mining industry initiative, Mining for Habitat, is designed to develop bat habitat conservation and enhancement plans for active mining operations. It includes the creation of cost-effective artificial underground bat roosts using surplus mining materials such as old mine-truck tires and culverts buried beneath waste rock.

Jan 1, 1997

By J. -M. Lopez-Cuesta, C. Petter, B. Otazaghine, M. Batistella, R. Sonnier

"Kaolinite is a dioctahedral aluminosilicate widely used as paper filler and coating pigment. At the best of our knowledge, kaolinite is not widely used in polymer industry. Therefore, in this study, the flame retardant effect of kaolinite in ethylene vinyl acetate copolymer (EVA) and polypropylene (PP) were studied and compared with an alumina trihydrate (ATH) and Talc. Cone calorimeter results shows that the weight percentage of ATH in EVA/ATH composites must be at least 50 wt. % in order to reach an improvement in fire retardancy in terms of pHRR. In the case of EVA/kaolinite, even with 35 wt. % the pHRR is largely reduced. Comparing PP/Talc and PP/kaolinite composites at 30 wt. %, both fillers leads to same reduction in pHRR with a slightly better performance for PP/kaolinite composites. In both cases an intumescent behavior of kaolinite composites was observed that could slow the rate of the rising degradation products, allowing radical recombination reactions. Also, it was observed that kaolinite forms a protective layer on the surface of the samples, which could insulate the material. These behaviors (intumescence and formation of a protective barrier) could reduce the transfer of the degradation products to the flame and explain the better performance of kaolinite composites. INTRODUCTION The use of mineral fillers as fire retardants in polymer matrix are well known and widely studied [1]–[10]. Aluminum and magnesium hydroxides (respectively ATH and MDH) are the most widely used inorganic fire retardants. To achieve fire retardancy with these mineral fillers, about 50-60% loading is required which decrease the physical properties of the composites. The fire behavior of composite EVA has been the subject of many studies [4], [7], [9]–[15]. EVA copolymers are commonly used in the cable industry, due to their high ductility, even at high loading rates. In such applications, the flame retardant systems should be introduced into the polymer to improve the fire reaction. Many flame retardant systems have been tested but the most used industrially relates to formulations based on hydrated mineral fillers (aluminum hydroxide and magnesium hydroxide). Their low cost and reduced fumes generation explains their success. However, to obtain good performance with this type of flame retardants, it is necessary to incorporate high levels (up to 65 wt %), which severely impact other properties such as processability and mechanical behavior. The main modes of action of these flame retardants are the dilution of the gas phase, the endothermic decomposition and a barrier effect created by the inorganic oxide residue which may be improved by the incorporation of other components such as montmorillonites, silicas or talcs."

Jan 1, 2015

By EDER DOMINGOS OLIVEIRA, Leandro Viana Teixeira, Carlos Antonio Morais, Ruberlan Gomes Silva

Special attention must be considered in the production of high-grade rare earth products, such as mixed rare earth oxalates or carbonates. In the main minerals used industrially, the rare earth elements (REEs) are finely associated with impurities like calcium (Ca), magnesium (Mg), manganese (Mn), iron (Fe), aluminum (Al), thorium (Th), uranium (U) and phosphorus (P). Most of these impurities must be removed to avoid losses of rare earth oxides (REOs) as well as to prevent product quality degradation and low operational performance in the downstream steps of solvent extraction or ion exchange. The present study aims at investigating the conditions required to precipitate REEs, either as rare earth oxalates or carbonates, from purified rare earth sulfuric liquor with low Al3+ and UO22+ concentrations and very high Ca2+, Mg2+, Mn2+, and SO42− impurity contents.