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By J. C. Franklin

The U.S. Department of the Interior, Bureau of Mines, has developed a data acquisition system to continuously monitor radon, working level, absolute pressure, temperature, relative humidity, and air velocity. Data have been taken in intake and exhaust drifts, working stopes, and sealed-off areas of positive and negative ventilated uranium mines. Radon emanation rates, ranging from 1.7- to 12.2 x 2 10-l4 Ci/cm /sec were determined in four mines. The ratios of short duration, primary fan shutdown time to radon normalization time were 1 to 2 and 1 to 4, respectively, for-negatively and positively ventilated mines. Blasting and slushing caused radon increases of 160 and 67 percent, respectively.

Jan 1, 1980

By D. Leppert

Large deposits of natural zeolites may provide cost-effective alternatives for treatment of soil and water contaminated ) with heavy metals and radionuclides. Research on the Bikini atoll demonstrated that addition of clinoptilolite to the soil significantly reduces cesium uptake by plants. Re- search on the potential use of zeolites in soils at Bunker Hill, ID indicated only minor benefits at very high contamination levels vs. US Bureau of Mines (USBM) work on the use of zeolites for treatment of mine waste waters emphasized problems with natural waters that previous studies have not addressed. High levels of competing calcium in natural waters significantly decrease the effectiveness of zeolites for heavy metal sorption and may limit the usefulness in these applications.

Jan 1, 1991

By N. S. Dalal, Xianglin Shi

Metal ions, such as chromium (Cr) and vanadium (V) are found as trace impurities in mineral dust. Since metal ion mediated free radical generation has been implicated in many disease processes, we carried out a detailed investigation of the metabolism of these metal ions by biological redox systems and the possible oxygenated radical generation therefrom. We found that highly reactive Cr(5+) species are generated in the reduction of Cr(6+) by NADPH-dependent glutathione reductase, lipoyl dehydrogenase, and ferredoxin-NADP+ oxidoreductase. The reduced metal ion species react with hydrogen peroxide, to generate hydroxyl (•OH) radicals in a continuous cycle. The enzymatic catalysis processes also involves the reduction of molecular oxygen to the superoxide [(0-1 2)] radical. Thus only a trace amount of metal ions chemisorbed on mineral dusts, such as quartz, can catalyze the generation of the highly toxic oxygenated radical species from cellular hydrogen peroxide, suggesting a new biochemical mechanism for mineral dust induced chronic lung injury.

Jan 1, 1991

By D. E. Ranta, Neil D. O’Donnell, Thad B. Ostrowski

Ore reserve estimation at the Syncrude Canada Ltd. open-pit oil sands mine in Northern Alberta has evolved since the project's inception. Early techniques followed a conventional petroleum reservoir analysis format, with relatively widely spaced drill holes and semiquantitative grade data. Experience has developed a more standard mining approach, including classification of geological materials by both lithology and sedimentary origin, timely and multi-purpose drill holes, precise analytical data, empirical recovery factors, a computerized geological data base, and an orebody block model. Future efforts will involve enhancement of existing techniques, use of geostatistical algorithms, quantification of confidence limits, and improved control of the ore model by geological parameters.

Jan 1, 1992

By I. E. Lewis, W. R. Hopkins

Flowsheet improvements, such as series/parallel SX plant configurations, discontinuation of plant sumps and improved filter pumping concepts, the use of in-settler baffle systems, and the Krebs and combined mixer-settler designs offer opportunities to reduce SX plant cost. Today's plants employ permanent cathodes and mechanical stripping, and the increased capital cost can be offset by labor savings and higher current densities. The wider use of HDPE and new cell construction materials also reduce capital cost. The "Portelex" type of relocatable design embodies such new, cost-saving measures in a simple basic plant. Organic inventory and losses are reduced by new, fast-settling, hybrid organic reagents with improved kinetics and selectivity.

Jan 1, 1991

By Marian W. Otrebski, Julian A. Korneck

Long distance, overland conveyors require significant capital outlay of which up to 70% may be contributed to the cost of belting. Significant savings may be achieved by identifying possible risk areas and applying modern technology methods to reduce or eliminate risk. Recently, Sasol Coal commissioned an overland belt conveyor system comprising three belt conveyors of 7 km, 5 km and 4.5 km in length. These were designed and constructed taking the above into consideration. Contained in the paper are the belt conveyor system requirements, designing assumptions and methods applied in the designing process as well as ways and means to eliminate or at least reduce risks.

Jan 1, 1998

By Steven A. Whittle, Robert E. Cook

Years ago, personal computers (PC) were pricey devices destined for who knows where in the process industry. Now their use runs the gamut from low end data acquisition systems to high performance windows into the process area. Their applications range from CAD, CAM, CIM, and CAE to factory floor scheduling, process planning QC, facility management, cell control, and publishing. This discussion traces the evolution of a zinc plant's control automation program beginning with a PC as an operator interface and migrating to higher level work stations. Included in this paper will be a discussion of an Open Industrial System and the role PCs have played in this facility.

Jan 1, 1993

By N. Choi, W. D. Cho

Distribution coefficients of gold and silver between matte and slag during the pyrometallurgical treatment of nickel-copper sulfide concentrates were evaluated as a function of matte and slag compositions in the temperature range of 1,250oC to 1,300oC. It was observed that the composition of the matte phase, including matte grade and copper content in the matte, significantly affected the distribution behavior of gold and silver in the matte-slag system. Both gold and silver preferentially concentrated in the matte phase as the matte grade increased With increasing temperature and copper content in the matte, the distribution coefficients of silver increased, while the gold distribution coefficients decreased. It was also, found that slag additives such as CaO, MgO, and A12O3 caused a significant decrease in the solubility of both gold and silver in silica-saturated iron silicate slag. An activity coefficient of gold in matte was derived from the experimenta1 results.

Jan 1, 1999

By F. G. Miller, M. Polat, S. Chander

Flotation was used to achieve improved separation of magnetite from the float and sink products obtained from heavy medium separation and to reduce the load of the medium cleaning circuit. The investigation was carried out in two successive phases. In the first phase, tests were performed on in-plant samples from the Homer City Coal Perdition plant to determine what effects variables such as medium density, particle size and magnetite source had on the efficiency of the process. In the second phase, the optimum conditions determined in the first phase were used to determine the applicability of the process to other selected coals from central Pennsylvania. It was observed that flotation was very effective in the separation of magnetite from coal. In most of the cases investigated, the magnetite recovery was approximately 99% with a magnetite grade ranging from 95 to 99%. The grade of the magnetite decreased as the ash content of the coal increased and the particle size of the magnetite decreased.

Jan 1, 1994

By R. D. Hansen, R. R. Klimpel

Previous papers by these authors on slurry rheology control grinding aids have emphasized the end-use results and application methodology involved. This paper emphasizes the chemical principles and the influence of various chemical structures behind slurry rheology control chemicals. Particular examples are shown which correlate chemical structure modifications to environmental factors involved in grinding such as pH, shear, ore type, water chemistry, and particle size.

Jan 1, 1990

By J. E. House

Creative ideas and endeavors require imaginative and positive responses, if they are to be reduced to practices. This lecture will define the plurastic roles of various technical disciplines which were important in the development of the LIX reagents. Specific personalities, facts, and events will be used to trace the development from an idea, to the exciting acceptance and practice of the technology. An objective analysis of the entire LIX reagent development, spanning twenty-five years experience of the author, will be given, these will be used as a basis for critical examination of how the various technical disciplines could improve their effectiveness in advancing future technologies.

Jan 1, 1990

By P. J. Brown, R. W. Nice

The Thalanga Copper-Lead-Zinc Concentrator in Northern Queensland was commissioned in early 1990. The design of a flotation process for the sequential production of separate copper, lead, and zinc concentrates has always been a most formidable mineral processing challenge. In 1988-1989 during the process design phase, sized fractions of various samples were subjected to quantitative and qualitative mineral analyses. These analytical techniques are collectively known as modal analysis. Modal analysis aided in the selection of key process treatment parameters for the initial laboratory testwork on the Thalanga ore. The work also guided the flowsheet development and quantified the mineralogically imposed limitations on the separation process. This paper describes in general terms how these modal techniques were used to guide the program of laboratory flotation testwork which constituted the flowsheet design phase of this project. During these design studies, the primary grind and regrind requirements were deduced and the basic flowsheet configuration selected. Recent operating plant performance data are to illustrate the value of modal methods in addressing complex metallurgical separation problems.

Jan 1, 1995

By C. Abbruzzese, L. Piga, P. Fornari, S. Ubaldini, R. Massidda

The effects of certain variables on the extraction of gold by thioureation have been investigated on a quartzose gold-bearing ore using a statistical multifactorial strategy. The factors taken into consideration were milling time (which corresponds to a given grain size), oxidant concentration, thiourea concentration and liquid/solid ratio. The influence of these four variables was ascertained first by a full factorial design at two levels for each variable (16 runs). This permitted the estimation of first-order effects of the factors affecting the process. Then 9 runs were added whose levels were both in the centre of and outside the axes of the previous plan thus originating a central composite design. This permitted estimation both of second-order effects of the factors involved and of parameters of a second-order polynomial model. The results show that extraction of gold depends only on milling time and oxidant concentration, at least in the experimental range considered. The equation fitting experimental data, as calculated by the least squares method, allows a response surface to be drawn. Due to the low gold grade of the ore (6 ppm) statistical analysis could lead to contradictory results, hence strict observance of Gy's rules for sampling and very accurate and precise chemical analyses were required.

Jan 1, 1995

By K. Terhaar, K. Prisbrey

The objective was to determine operating protocols for a lead and silver column flotation cleaner being considered for installation at Sunshine Precious Metals Inc. 's Kellogg mill in Northern Idaho. In this column, tetrahedrite and galena were floated, and pyrite and other gangue minerals, including siderite and silica, were depressed. The procedure was to develop a dynamic simulation using a linear transfer function approach. The transfer function related cause-and-effect variables such as the influence of collector and depressant dosages on recovery and grades. Bench-scale flotation tests followed by pilot column testing provided the data used to develop a linear transfer function. The transfer function was derived using a spreadsheet. This model was applied to simulate how the flotation column could be made to respond to disturbances in feed grade. The results were that xanthate, zinc sulfate and sodium cyanide were found to be suitable controls for grade and recovery. Simulations showed the best sequence of manipulations of these reagents, and these sequences are useful for future operator training. The conclusion was that linear transfer functions were able to simulate lead and silver recovery, develop scenarios for operator training and provide a foundation for future on-line control.

Jan 1, 2002

By Gerhard Mücke

Geothermal and operational reasons in the German coal mining industry make it necessary to an increasing extent to climatize coal faces and headings by means of refrigeration plants. Air coolers installed on coal faces as well as in gateroads play an important part in such climatization. They must transfer, under difficult conditions, the refrigerating capacity supplied by central or de-central refrigeration plants from the chilled water to the air in the workings. The performance data of two new types of coalface coolers and of two different types of gateroad coolers were measured in two testing stations under different thermo- dynamic conditions with dust-free fresh air. As air coolers must be installed particularly at working points with a high .dust load the heat exchanging surfaces are fouled for the most part causing an essential reduction of the refrigerating capacity. The investigations therefore were extended to measurements with a certain dust load in the intake air of the coolers.

Jan 1, 1980

By Takashi Sakaguchi, Akira Nakajima

Some attempts were made to recover and remove heavy metal elements, such as uranium, copper and chromium, from aqueous systems by using several phosphate compounds. The phosphorylated derivatives of polysaccharides, chitin phosphate, chitosan phosphate and cellulose phosphate, have high abilities to accumulate heavy metals, such as uranium, copper, manganese, cobalt, cadmium, zinc, nickel and chromium, compared with non-phosphorylated polysaccharides. In order to obtain basic information on the recovery and removal of uranium that may be present in industrial effluents, mine waste water and seawater, the adsorption of uranium by chitin phosphate and chitosan phosphate was investigated in details. The adsorption of uranium by chitin phosphate and chitosan phosphate was much greater than copper, cadmium, manganese, zinc, cobalt, nickel, magnesium and calcium. The adsorption of uranium was very rapid and was affected by pH of the solution, temperature. granule radius and co-existence of carbonate ion. The amounts of uranium adsorbed on the adsorbents increased linearly as the external uranium concentration increased. Uranium adsorbed on chitin phosphate easily desorbed with diluted sodium carbonate solution. On the other hand, uranyl and cobalt ions were separated from each other by using chitin phosphate. Along with these fundamental research, some attempts were made to recover uranium from seawater.

Jan 1, 1993

By Bryan C. Smith, Duane R. Skidmore

Volumetric mass transfer coefficients and gas holdups were measured in a concentric tube airlift reactor designed for the microbial desulfurization of coal. The slurries were comprised of an acidified basal salts solution containing thirteen different weight percents of coal (74 µm Ohio #1) at three temperatures. An enhancement in the mass transfer coefficient, KLa, with respect to that measured in pure solution was found at weight percents of 5 (volume fraction solids, ES = 0.035) or less, the greatest enhancement being as great as 37% at approximately 2 weight percent (ES = J 0.014). At higher solids fractions, the mass transfer coefficient decreased with further solids additions, decreasing by as much as 91% at 40 weight percent coal (ES = 0.315). KLa increased with temperature at all solids concentrations, the greatest increase being 392% at 72°C vs that measured at 30°C. Gas holdup, EG decreased with all increases in solids loading by as much as 65% and increased by as much as 67% with temperature. KLa and EG were correlated with operating conditions separately, and the separate correlations combined to yield overall correlations for the mass transfer coefficient and for the gas holdup. The correlations are suitable for inclusion in system models devised earlier for microbial coal desulfurization processes, and may be used for design, operation and cost estimation for such systems.

Jan 1, 1989

By P. C. Cochrane, I. S. Clelland, S. H. E. Phillips

Geological and hydrological conditions in the strata overlying the Salado Formation vary considerably in the Carlsbad, NM, area. The first four shafts sunk at International Minerals and Chemical Corp. (IMC) property have been located in competent and essentially dry conditions, while other shafts on adjacent properties have had such adverse conditions that ground freezing has been chosen as the water and ground control technique for shaft sinking. At the location of the IMC No. 5 shaft there has been extensive erosion and salt dissolution in the Rustler Formation, leading to collapse of some zones of the strata. Both ground freezing and pregrouting were considered as alternative methods of stabilizing the extremely poor ground conditions and controlling the potentially very heavy water inflows. It was decided that pregrouting the shaft was feasible and would offer substantial cost and time saving over a ground freezing technique. This paper describes the pregrouting techniques used and illustrates the requirement for flexibility in a grouting program so that it can be modified to reflect any new or additional information obtained during the progress of the grouting.

Jan 1, 1987

By P. K. Crane, S. C. Gambrell

The work reported herein compares the support characteristics of two different types of roof truss subjected to the same force in the horizontal tension member. The major differences between the two trusses are in the sequence of tensioning the horizontal and inclined members and in the design of the loading brackets. A photoelastic model was used to compare stresses at points along the roof of the mine opening and at the junction of the roof surface and the rib. The effects of simulated subsidence on stress in the roof and on tension in the horizontal member were analyzed. Results indicate that there are significant differences in the overall support characteristics of the two trusses. Conclusions are drawn relative to which type of roof truss provides the most favorable support if the horizontal members are tensioned equally.

Jan 1, 1986

By Frank W. Bowdish

During the early 1960's, a method was developed for refining sand from the Arkansas River to produce a feldspathic product that was proposed for use in making colorless glass. Because of the need for chemical uniformity, a cooperating glass manufacturer specified certain ranges of percentages for each chemical constituent of the sand. These specifications were met by fulfilling the single requirement that alumina vary by no more than 20.1 percent from the specified value. This translated to a total variation of only about 1 percent in the feldspar content of the mixed quartz-feldspar products. Because the feldspar was lighter than the quartz, the average density of refined sand varied depending on composition. Densities, determined to five significant figures, of several samples were correlated with their chemical analyses, and the correlation could then be used with density determinations to more reliably indicate compositions than by chemical analyses only. The effects of several variables on the composition of refined sands were studied. There was a regular variation in the proportion of feldspar with screen size. A series of samples with their natural size distributions were more nearly uniform in composition than the same sands after screening and recombination. The screening and recombination process was done so that the sands had identical size distributions. Variations in the refining showed little effect on composition. A pile of flow-back sand from a construction sand washer was found to be severely segregated. However, samples taken from many points in the river near the sand plant and from the flow-back discharge pipe over several weeks very nearly met the uniformity specification. If care was taken to avoid segregation either before or during processing, it should be possible to meet the uniformity specifications for a feldspathic glass sand.

Jan 1, 1978