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By R. G. Reddy

Iron solubility's in spent pickling (HFHNO3 -H2O) solutions were determined as a function of HF and HNO3 acid concentrations. A chemical analysis of the industrial pickling solutions and sludges was performed. The stable phases observed in the sludges are FeF3.3H2O and (FeCr)F3.3H20. Pure Fe metal, AISI 316 stainless steel and AISI 416 stainless steel were used in this study. The results show, that the solubility of Fe increased as the concentrations of HF increased in the pickling solution at a fixed concentration of HNO3. A reasonable agreement between the experimental solubility data and the theoretical calculated data was obtained. X-ray diffraction analysis showed that the solid solubility product formed in the ternary solution containing pure Fe is mainly, at a high pH value, FeO(OH) compounds and, at a low pH value, Fe F3.3H2O compounds.

Jan 1, 1994

By Kai Nielsen

In underground mining coarse muck and large boulders lead to ineffective utilization of costly mining equipment, and extra expenses and delays caused by secondary blasting. Cost analysis in some Norwegian mines shows that these extra expenses may amount to 10% or more of total mine operating costs. A computer model has been developed for sensitivity analysis of underground longhole stope blasting. The basic idea of the model is : When increasing the blasting energy input and fragmentation costs, the fragmentation will be better. This will lead to cost savings for loading, hauling, secondary blasting and primary crushing. The blasting design giving the lowest overall costs will indicate the optimal practice. The model has been used with data from several underground operations in Norway. An example run with typical costs shows that the costs for drilling, blasting and secondary blasting are the most significant parameters in the optimization process.

Jan 1, 1986

By Bill Sayer

Cadman, a wholly owned subsidiary of Heidelberg Cement, is a leading supplier of sand and gravel as well as ready mix concrete in the greater Seattle area in western Washington State. Cadman's aggregate mine is located in North Bend, 34 miles east of Seattle, WA, and consists of a "Lower Pit" and an "Upper Pit." In 2005, Cadman planned the upgrade of the North Bend mine operation as follows: Upper Pit (Figure 1): 1. Crushing Plant, Stacker and Stockpile 2. Storage Reclaim Belt Feeders 3. Feed Conveyor 4. Downhill Overland Conveyor Lower Pit (Figure 2, Photo 12): 1. Radial Stacker 2. Storage Reclaim and Truck Load-out

Jan 1, 2008

By K. Hanumantha Rao, P. K. Sharma

A pure strain of Paenibacillus polymyxa and mineral- adapted strains are used to bring about surface chemical changes on pyrite and chalcopyrite and, thus, theirflotation. Paenibacillus polymyxa was adapted by repeated subculturing in the presence of pyrite and chalcopyrite. The surface chemical changes of bacteria due to adaptation and of minerals after their interaction with bacterial cultures are evaluated by electrokinetic and infrared spectroscopy and are discussed with reference to their flotation responses. Interaction of bacterial cells, bacterial metabolites and whole bacterial cultures affected the Hallirnondflotation behavior of the sulfide minerals. The Xanthate flotation results show that pyrite, but not chalcopyrite, is depressed when the tests are carried out after interaction with chalcopyrite-adapted Paenibacillus polymyxa. This investigation demonstrated that the surface chemical properties of bacteria can be manipulated successfully to achieve the desired effects in the flotation process.

Jan 1, 2000

By Tom C. Palanglo, Norbert Maerz

Control of crushing and grinding circuits ideally requires continuous particle size measurements on both in- and outgoing streams. Until recently, size distributions could only be obtained by screening methods, which were neither cost effective, frequent enough, nor timely. Input streams are often composed of large fragments, making screening prohibitive. Optical image processing systems, such as the WipFrag System, have been developed to the point that they are an extremely valuable tool to characterize, control, and fine-tune the comminution process. Although accuracy is less than that of screening, measurements are precise enough to detect relatively small changes in size distributions.

Jan 1, 2000

By S. Saklar, i. Bayraktar

The effect of the feed size distribution on the kinetic parameters in pyrite flotation was studied. The kinetic parameters of the particular sizes were determined as a function of whether other particle sizes were present. From the data, a relation between the pyrite flotation rate and the particle size distributions was obtained. It was shown that the flotation rate constant (k) is a function of the size modulus (dt) of the Gates-Gaudin-Schuhmann distribution, and its variation may be expressed as k = a • exp(b . d,) for either individual size fractions or composite feed. Parameters a and b are dependent on the particle size distribution of the feed. Specifically, parameter a increases linearly as the distribution becomes coarser. The above relationship was also tested under conditions in which the collector (KAX) dosage was varied from 130 to 278 g/t. It was shown that the established relation was not dependent on the collector dosage.

Jan 1, 2002

By Charles T. Staniek

Following a dragline relocation at Agrico's Fort Green phosphate mine in 1986, the recovery plant experienced a significant decrease in flotation performance. Through weeks of trial and error testing, we discovered we could restore recoveries by conditioning feed at pH's higher than we had used historically. The higher pH's essentially increased flotation cell kinetics, although we still do not understand the exact mechanism at work. Armed with new-found appreciation of pH modification, we initiated a program to determine the optimum modifier for us, from both a performance and environmental perspective. Environmental considerations were important because ammonia, the standard industry modifier, is a plant nutrient and higher usage rates could affect the quality, of our recycle process water. This paper describes the research and development work spanning a 3 year period that culminated in making a major change in our reagent suite when we replaced ammonia with soda ash on a permanent full-time basis.

Jan 1, 1993

By D. Tao, B. K. Parekh

Fine coal particles are difficult to separate effectively from liquids or other solids. Ultrasonic energy may be used to enhance the efficiency of the conventional fine-particle separation processes widely used in the coal and mineral industries. Flotation, settling and dewatering tests were conducted using several fine coal samples to study the effects of ultrasonic treatment on these processes. Process variables such as particle size, ultrasonic treatment time and solids concentration were investigated for their impacts on ultrasonic treatment effectiveness. The results obtained from this study showed that ultrasonic treatment is an effective approach for enhancing solid/solid separation in flotation and solid/liquid separation in sedimentation and dewatering of fine coal. SEM microphotographs demonstrate that ultrasonics cleaned particle surfaces, which is, in part, responsible for the observed improvement in fine coal separation processes.

Jan 1, 2000

By Alan A. Campoli, Michael D. Zuber, Frank E. McCall, Gerald L. Finfinger

Injecting water under pressure to wet the coalbed in advance of mining reduces mining-generated respirable dust. Owing to economic and geological barriers, water infusion for longwall dust control in the United States is currently limited to the Pocahontas No. 3 Coalbed in Virginia. Water is pumped into the coalbed through underground boreholes drilled horizontally from the headgate toward the tailgate side of retreat longwall panels. This paper theorizes that the barriers to widespread utilization of water infusion for longwall dust control could be overcome by long-duration, low-pressure water infusion through vertical gob gas boreholes. Currently, 43% of the 72 longwall mines in the United States employ vertical gob gas boreholes. Computer coalbed reservoir simulation suggests that one vertical surface borehole could infuse the same longwall panel area as four horizontal boreholes in the current water infusion system for longwall dust control in the Pocahontas No. 3 Coalbed.

Jan 1, 1995

By J. G. Henning, R. Edrissi

This paper describes a practical methodology, based on numerical modeling, for the prediction of progressive failure of underground-mine stopes having cable-bolt support. A case study of the 40-761 scope at the Kidd Creek mine, Timmins, Ontario, Canada is presented. Scope 40-761 was mined by blast hole open sloping in 1986 and was a lead scope within a mining block located between levels 36-1 and 38-2. Initially designed to peak at level 38-2, the scope back caved upwards =40 m towards level 36-1. After caving began, cable bolts were installed above the stope from level 36-1. The stope eventually stopped caving when the falling rock mass encountered a sufficiently high cable density. This paper provides details of the geomechanical data and modeling results of the case study. Numerical modeling of cable bolts around the mine stoke was carried out using a finite-element modeling software. The software, known as e-z tools, was developed by the first author.

Jan 1, 1996

By T. M. Barton, M. Gauna, A. A. Campoli

Coal mine bumps, the violent failures of overstressed coal, present a safety hazard to miners when longwall mining is conducted in deep, bump-prone coal mines. Two different longwall gate entry systems were evaluated in a southern Appalachian coal mine located in the Pocahontas No. 3 coalbed under approximately 610 m (2000 ft) of overburden that included a massive sandstone member. Both gate entry systems employed a center abutment pillar flanked by yield pillars. The original design used a 24.4-m (80 ft) square abutment pillar, while the new design employed a 36.6-m x 54.9-m (120 ft x 180 ft) abutment pillar. Rock mechanics instrumentation data analysis and in-mine observations indicated that this increase in abutment pillar size significantly decreased bump potential. The new design in worst-case conditions increased effective bearing area 62%, with only a 9% increase in gate entry system width, and eliminated face bumps that were experienced with the original gate entry design.

Jan 1, 1993

By A. S. Trimble, J. C. Hower

The petrographic composition of sized coal produced through the progressive grinding of a Central Appalachian high-volatile bituminous coal blend was analyzed for multiple sets either by removing fine, -200-mesh, coal after each test iteration or by retaining the fine coal in progressive test fractions. With prolonged grinding, coarser fractions tend to become depleted in vitrinite and vitrinite-rich microl ithotypes, leading to progressively harder-to-grind coal remaining in the oversize, +200-mesh, fractions. The latter trend is shown both by the maceral and microlithotype composition of the coal and by the increased slope and fractal dimension of size frequency distribution, implying an increase in hardness and resistance to grinding of the oversize coal.

Jan 1, 2000

By Norbert Patzelt, Johann Knecht, Wolfgang Baum

High pressure roll grinding (HPGR) is a mature but still expanding comminution technology. In the metals mining industry, HPGR is slowly gaining acceptance as a cost-efficient, high-throughput alternative for plant optimization. The increasing need to treat ores with progressively lower grades, complex mineralogies, refractory metal occurrence and variable rock types requires an energy-efficient comminution technology that reduces metallurgical problems inherent in conventional crushing and grinding, while stabilizing leach and flotation circuits and increasing metals extraction. This paper will summarize our latest HPGR pilot test results for gold and copper projects in the United States and South America and their confirmation through the first HPGR operation in copper mining. This paper will also stress the use of the high pressure grinding roll as a metallurgical tool. The application of HPGR for the treatment of heap leach SX-EW ores, semi-refractory gold ores, waste rock material and concentrator feeds will be illustrated.

Jan 1, 1998

By Harrison R. Cooper

Composition data is needed as input for executing process control and management of particulate separation for flotation control. While requirements for composition data can be satisfied in many cases by manual sampling and analysis, automatic sampling and assay systems are now viewed as justified for all but the simplest or smallest processes. On-stream X-ray fluorescence analysis (XRFA) has satisfied requirements for the main portion of metalliferous sulfide ore flotation processes as XRFA technology evolved in reliability and sophistication from its beginnings in the late 1950's. In recent years, advanced on-stream analysis technologies have reached levels of development suitable for use in process control to increase efficiencies of important processes in mining and minerals industries such as coal fines flotation and industrial minerals beneficiation (particularly phosphate beneficiation) where XRFA methods have been inapplicable. Recent technical developments pertinent to use of advanced technologies as well as improvements to established on-stream composition analysis methods are discussed.

Jan 1, 1989

By K. A. Natarajan, J. M. Modak, P. Anand

A microbial survey of Jamnagar bauxite mines in Gujarat, India, revealed the indigenous presence of a variety of autotrophic and heterotrophic bacteria and fungi associated with the ore body and water ponds in the vicinity. Among these, bacteria belonging to the genera Thiobacillus, Bacillus and Pseudomonas are implicated in the weathering of aluminosilicates; the precipitation of iron oxyhydroxides; the dissolution and conversion of alkaline metal species; and the formation of alumina, silica and calcite minerals. Fungi belonging to the genus Cladosporium can reduce ferric iron and dissolve alumina silicates. Biogenesis thus plays a significant role in bauxite mineralization. Various types of bacteria and fungi, such as Bacillus polymyxa, Bacillus coagulans and Aspergillus niger, were found to be efficient in significant calcium solubilization and partial iron removal from bauxite ore. Probable mechanisms in the biobeneficiation process are analyzed. Biobeneficiation is shown to be an effective technique for the removal of iron and calcium from bauxite ores for use in refractories and ceramics.

Jan 1, 1998

By William Petruk

Performance assessments are carried out to monitor operations, to evaluate performance and to identify processing problems. The assessment involves collecting and analyzing representative samples from critical points in a flowsheet and interpreting the data. Sample analysis techniques include chemical analyses, mineralogical investigations, mineralogical analyses, and materials balancing. Chemical analyses provide the lowest cost assessment and should be used liberally, particularly in monitoring a process. Materials balances performed on chemical assays for a suite of samples are used as a first step in evaluating a process. Mineralogical investigations are more expensive than chemical analyses but need to be used only at the beginning of mining and metallurgical operations and as a second step in assessing processing problems. Quantitative mineralogical analyses combined with materials balancing provide the most complete performance assessment, but the procedure is expensive. On the other hand, the assessment has the potential of a large payback when carried out where warranted.

Jan 1, 1991

By L. M. Gochioco

The Seismic Interactive Interpretation Workstation (S//W) provides a wide spectrum of utilities ranging from improving field acquisition techniques, data processing and interpretation of coal seismic data. The power of the workstation lies in the interpretation process where various sets of geophysical and geological data are integrated to form a network of information that is stored in a database. Computer models are generated from known borehole and geologic information and later cross-correlated with the processed seismic data. Structural and stratigraphic modeling techniques add another dimension to the interpretation process. Complex trace attributes highlight subtle features not easily observed in black and white sections. Using the computer workstation, the explorationist gains valuable insight and conducts more intelligent interpretation of seismic data through a more comprehensive network of data analysis.

Jan 1, 1992

By J. E. Murphy, R. Y. Wan, K. R. Sandgren, M. C. Fuerstenau

As part of a U.S. Bureau of Mines program to evaluate alternatives to sodium cyanide in gold leaching, three organic nitrile compounds were tested for their effectiveness as gold lixiviante. The organic compounds examined were malononitrile, acetonitrile, and cyanoacetamide. The reagents were tested on an oxide ore, two carbonaceous ores, and a eulfidic ore. Acetonitrile and cyanoacetamide were shown to be ineffective gold leachante. Malononitrile was the most successful of the organic lixiviants. On an oxide ore, malononitrile performed shilarlyto sodium cyanide with extractions of around 80 pct. For carbonaceous "preg-robbing" oree, sodium cyanide was completely ineffective while malononitrile extracted 24 pct of the gold. When using a resin-in-leach technique, extraction with sodium cyanide increased to 60 pct and the extraction with malononitrile increased to 80 pct. On the sulfide ore, sodium cyanide and malononitrile performed similarly with 80+ pct extraction as long as the pH of the malononitrile solution wae maintained above 10.5. Malononitrile is six times less toxic than sodium cyanide as measured by LD, levels. Therefore, malononitrile has a significant advantage over eodium cyanide, but its high cost and undemonstrated usefulnees make it unlikely to gain acceptance.

Jan 1, 1993

By J. C. Watts

Ball mill grinding circuit control has received increasing emphasis in the past few years due to such factors as declining ore grades, increasing production costs, and advances in analytical devices and minicomputer technology. Since ball mill circuits have been a traditional bottleneck in mineral processing plant throughput, control systems often improve through- put without requiring additional processing equipment. In addition, much of the variability of the grinding product size and consistency is often removed, allowing better process operation downstream. Among the problems which arise in designing and implementing a process control strategy for ball mill circuits are circuit constraints imposed by processing equipment and local management, proper instrument selection, installation and maintenance, and use of calculated or inferred variables for process measurements. This paper discusses these problems and attempts to identify valid approaches to their solution.

Jan 1, 1979

By Rudolf E. Greuer, Xintan Chang

Mine fires have always been of great concern to mining engineers and their behavior has been studied for a long time. Although an abundance of observations exist, no satisfactory mathematical model for their interpretation and extrapolation has become known. The paper presented here tries to close this gap, making use of the laws of chemical kinetics, energy and momentum conservation. To overcome the mathematical difficulties, the fire zone is axially divided into segments and radially into sections, each one with an extension of only a few inches. Conditions in segments and sections are updated in time intervals of one second or less. To solve the large number of resulting equations, a numerical solution is performed. The model has so far been tried on timber fires. It confirms experimental observations on the ignition phases and equilibria of these fires.

Jan 1, 1987