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By F. C. Nicolli, J. P. Barbosa, P. S. M. Soares, A. V. Estevez

INTRODUCTION Spent household dry cell batteries are frequently disposed of with metropolitan wastestream (MSW) in landfills where they can leak due to handling or aging. Frequent rain and sun cycles, especially in tropical environments, coupled to the action of leachate, dissolve their metal constituents which will eventually reach rivers, lakes and underground water. It is well known that some of these metals are fundamental to sustain life and that is why living organisms concentrate them through their metabolism, but it has been also recognized that beyond specific limits they can definitely be deleterious to the environment. In other words, high concentration of heavy metals are proven to cause chronic or acute diseases and toxic reactions, by acting on mammals' kidneys, liver and nervous system. In addition, some metals frequently used in household batteries, as mercury and cadmium, are said to be carcinogenic (Landis et al. 1995, Silva et al. 1988). Occasionally, plants to treat MSW are coupled to compost production. Household batteries present in MSW can be dragged into these plants, contaminating their products and eventually reaching vegetables making them not proper to consume by people and animals. Alternatively, batteries are also conveyed to incinerators and burned, throwing into the atmosphere volatile species. These can either act as contaminants as toxic vapor species or be delivered by winds and scavenged by rains contaminating soils and water far away from their source. In conclusion, despite the treatment applied to MSW, one can say that battery residues are potentially environmentally hazardous. The careful assessment of the environmental impact caused by residues of household batteries it is not an easy task and it can be referred as a multivariable problem. First, many different household batteries are produced by industry and the potential environmental hazard associated to their disposal depends primarily on the type of battery and manufacturer's technology. These characteristics will dictate how resistant the battery case is to handling and the

Jan 1, 1998

By E. M. Van Eeckhout

The National Uranium Resource Evaluation Program (NURE) has produced a mass of geochemical data in the form of data files on tapes. This paper presents a methodology for utilizing those tapes in a simple, practical manner. An example is given of an analysis of the Butte quadrangle, Montana, tape obtained from the Los Alamos National Laboratory (LANL). The example details the sequence of splitting the data file, plotting histograms, cumulative frequency curves, concentration plots, and methods for evaluation. All programs are written in FORTRAN. The case study was performed using a mini- computer (DEC PDP 11/70) and standard plotting subroutines.

Jan 1, 1982

By Bernardo Portillo, Alejandro Perez, Daniel Norrgran, Joseph Wernham

High gradient permanent magnetic separators (termed "Ferrous Wheel") are described as used to recover the iron bearing minerals from mill tailings at the Grupo Acerero del Norte's Hercules iron mines in Coahuila, Mexico. The pilot scale test work as well as the "in-plant" test work provided the basis for a 385 MTPH plant expansion to be commissioned late in 1995. Approximately 6 million metric tons of flotation tailings averaging 50 percent iron, mostly as hematite, are contained in two separate ponds. The tailings are relatively fine at 93 percent -200 mesh and 72 percent -500 mesh. After testing various recovery methods, a high gradient permanent magnetic separator was selected to produce a preconcentrate prior to flotation. The separator uses a flux converging matrix to generate high gradient magnetic fields and capture the hematite. The advantage of the Ferrous Wheel high gradient permanent magnetic separator is the use of permanent magnets as opposed to electro-magnets. Further the vertical rotating ring is much more conducive to matrix cleaning as opposed to the conventional horizontal ring separators. This feature also allows the use of a wide range of matrix materials to achieve the optimum metallurgical response

Jan 1, 1995

By G. T. Adel

Hindered-bed separators are often used in the minerals processing industry to classify particles according to size and density. A new technology, known as the Eriez CrossFlow, was recently developed to overcome some of the limitations associated with hydraulic separators. The innovative feature of this unit is a novel feed presentation system that improves separation efficiency and capacity. In the present work, a detailed process engineering evaluation was conducted to determine the basis for the improved performance of this unit. The evaluation included controlled separation tests using well-characterized feeds, particle and liquid tracer experiments and mathematical modeling studies. Data obtained from this work show that the new separator is capable of maintaining good separation efficiencies at higher solid feed rates than traditional designs due to improved hydrodynamics in the separation zone. This paper reviews the operating principle of the Eriez CrossFlow separator, discusses the results of the tracer experiments and modeling studies and presents test data obtained from recent laboratory and plant trials. Key words: Size classification, CrossFlow separator, Hindered-bed separator, Hydraulic separator

Jan 1, 2003

By E. Kokinou

The main scope of the present study is to investigate the suitability and sensitivity of the magnetic susceptibility as a pollution monitoring tool in urban areas. For this purpose, a municipal park located in the centre of Chania city, which may be affected by traffic and domestic heating pollution, was selected as the study area. In the context of the present work, magnetic susceptibility measurements were conducted in two phases. Surface soil samples were collected in 2006 from the area under investigation and they were analyzed in order to estimate the spatial distribution of the magnetic susceptibility. One year later, mapping of the magnetic susceptibility has been contacted in situ using Bartington MS2D and MS2F sensors. Additionally, soil samples were collected from selected positions in order to compare the values of the magnetic susceptibility with that estimated in 2006 research. Both investigations indicate high values of the magnetic susceptibility around the park near the roads and in a small area inside the park where a café is located.

Jan 1, 2008

By A. C. Burrow, R. P. King

A dynamic model that predicts the variation of carbon content with time in the argon-oxygen decarburization (AOD) process has been developed. The model recognizes three distinct zones in the AOD vessel: the tuyere region in which the blown oxygen reacts very rapidly with the metal components in the molten alloy; a region in which bubbles of inert gas and oxide drop lets rise through the molten alloy; and a zone in which the slag layer can interact with the molten alloy. The process is dynamically controlled by the rate at which dissolved oxygen, produced on the surface of rising oxide droplets, and dissolved carbon diffuse through the molten alloy to react at the surface of the rising bubbles. The rate at which carbon and oxygen react on the bubble surface is assumed to be intrinsically very fast. Predicted decarburization rates compare reasonably well with rates measured in the AOD vessel at Middleburg Steel and Alloys. The model has been developed primarily to allow development of a time-optimal blowing stategy for the AOD vessel.

Jan 1, 1990

By F. N. Kissell

The Bureau of Mines used sulfur hexafluoride (SF6) tracer gas to evaluate the effectiveness of gob ventilation and/or sealing practices at three coal mines, each having different problems associated with their mined-out areas. The purpose of these ventilation studies was to better understand whether current techniques employed for ventilation or sealing are successful at minimizing the potential for gob fires and explosions. The work performed at each mine is discussed: One is a longwall operation that uses ventilation to carry off hazardous gases, and two are room-and-pillar operations, each with far different concerns, that seal off the gobs to isolate them from the main mine ventilation. In all cases, employment of the Bureau's SF6 tracer gas technique resulted in answers to questions raised by the mine operators concerning the effectiveness of their gob ventilation or sealing practices in preventing mine fires.

Jan 1, 1987

By Richard R. Klimpel

INTRODUCTION Froth flotation is the most widely used and economic means of concentrating metal sulfide ores such as those containing copper, lead, zinc, nickel, molybdenum, and pyrite. Also recoverable are other metal species that are often associated with sulfide ores, such as cobalt, platinum, gold, silver, etc. Flotation of metal sulfide ores has been successfully practiced at the industrial scale for more than 50 years. It is the relative technical/economic ease of floating metal sulfide minerals that has been a major driving force behind the rapid expansion in the supply/demand of metals over this 50 year period. It is estimated that 1.6 billion tons of feed sulfide ores are processed each year in the free world based on the froth flotation process, Klimpel (1987) and the manufacture/use of associated chemical reagents is a major portion of the 1.5 billion dollars (U.S.) free world mining chemicals business, Klimpel (1988b). The use of froth flotation appears to be increasing partially due to the ever decreasing feed grades and liberation sizes of the feed minerals. Froth flotation has shown itself to be a flexible process that lends itself well to many solid/solid separations. Thus, with surprisingly little equipment modification, separations can involve very different particle sizes and densities, and relative weight ratios of materials to be separated. In addition, the flotation process is economic, especially when compared to size reduction, its associated precursor process. Flotation also lends itself to continuous operations with a variety of equipment configurations. Such operations exhibit an ability to vary feed rate of solid to the process by as much as 50% without a total collapse of separating efficiency. In addition, the widely used mechanical flotation cell is scalable from 2.8 to 57 or 85 m3 (100 to 2000 or 3000 cu ft) with surprising ease relative to other unit engineering operations over the same relative size increase. The separating medium used is water. Most of the chemicals required -- pH regulators, frothers, collectors, activators, and depressants -- are all relatively inexpensive and common. They are not usually used in large quantities. While there has been a tendency for the quality of metal sulfide ores in any one geographic location to deteriorate over time due to mining intensity, the overall global supply of sulfide minerals is still very ample. Thus, the physical supply side of sulfide ore concentrates has not been under strong technology improvement pressure with increasing metal demands. Part of this is due to the ability of capital to consistently move to new geographic sources having suitable-grade sulfide ores. In these moves, the actual froth flotation technology used (including collector chemicals) has had to change little. As an illustration of this trend, of the approximately 80,000 metric tons of thio collectors used commercially (1980) in the free world, almost 987 were known and manufactured in some form 25 years ago. This is clearly not typical of reagent development in other process-related industries. In addition, the industrial-scale practice of froth flotation applied to sulfide ores has proceeded since the 1920's with often little direct (predictive) scientific explanation due to the extreme complexity of the flotation process. Empirical testing has been a mainstay of industrial flotation reagent development and use. Even today there is often strong disagreement between researchers as to the mechanisms of chemical flotation practices that have been performed successfully on an industrial scale for many years. Thus the industrial process of froth flotation, especially as applied to the recovery of sulfide minerals, poses a dilemma: such a process is widely used, economic, versatile, forgiving, etc. and yet is still not very well understood in a mechanistic sense leading to prediction of results from fundamentals even after 50 years of usage. Lack of such predictive ability has not limited the general over-all industrial use of froth flotation in sulfide mineral recovery. Rather the lack of

Jan 1, 1989

By Owen E. Owens

INTRODUCTION This paper deals with the main components in exploring for and developing a gold ore deposit. It addresses geology, exploration drilling, ore reserves, and evaluation criteria in an integrated manner to present an overall picture. Gold forms such a small component of a gold ore body, that particular care should be taken in dealing with the data from a developing deposit. The paper lists the main gold ore deposit types and their character. Their differences, as well as differences to other types of ore deposits, are important to understanding exploration approaches, and problems of ore reserve definition. Gold exploration has enjoyed a great boom in recent years. Many new ore deposits have been developed but experience shows that definition of gold is not a simple straight forward process and this outline attempts to point out some of the important aspects of ore reserve definition including some pitfalls. GOLD DEPOSIT TYPES The Witwatersrand deposits in South Africa produce about 50% of the world's gold. The gold occurs as fine grains in thin beds within gently dipping quartz pebble fan conglomerates usually with associated pyrite grains. It is characterized by rather uniform distribution of gold along thin layers within the conglomerate.

Jan 1, 1988

By Frederick T. Graybeal

Silver Bell is located about 56 km (35 miles) northwest of Tucson, AZ. It is a classic porphyry copper deposit containing enriched disseminated chalcocite ore in altered porphyritic rocks with chalcopyrite in adjacent skarn zones. The discovery of Silver Bell was an evolutionary process that occurred over a 75-year period. Recorded mining activity began about 1865 on Boot Hill east of El Tiro pit (see Fig. 1) where outcrops of altered limestones were found to contain 425 to 482 g (15 to 17 oz) Ag mixed with copper oxides. By 1874, the Young America Copper Co. was mining shallow occurrences of 30% Cu along the north side of the present Oxide pit. The ore was shipped by wagon to Yuma, AZ, and then by boat to San Francisco for smelting. By 1881, the district supported several mining companies, two small smelters, and was being favorably compared to Bisbee in local newspapers. Most of the ore mined in the period 1865-1903 came from pods of massive sulfide or their oxidized products which were distributed in an unpredictable fashion through a large skarn zone in Paleozoic limestone east of El Tiro pit. Ore grades varied from 5 to 10% Cu.

Jan 1, 1991

By Paul G. Schmidt

Exxon Minerals Co. was exploring for mineral deposits in Precambrian terranes of the US portion of the Lake Superior region in the late 1960s. Exploration drilling and other activities had been concentrated on massive sulfide prospects in northeastern Minnesota, but general exploration studies and competitor scouting were conducted in other areas of the region. These activities drew attention to Wisconsin in 1969 when it became apparent that Bear Creek Mining Co. had made a discovery near Ladysmith in the northwestern part of the state. Observation of their drill hole pattern suggested that a massive sulfide deposit, since named the Flambeau deposit (Schwenk, 1977), had been found. With this background, Exxon initiated an exploration program for Precambrian massive sulfide deposits in northern Wisconsin in 1970 (Figs. 1 and 2). Northern Wisconsin is extensively mantled by Pleistocene glacial drift and bedrock outcrop is sparse. Other than iron mines in the extensive iron formations along the Wisconsin-Michigan border and Jackson County, no significant mineral deposits were known in the Wisconsin portion of the Precambrian Shield until the discovery of the Flambeau deposit. Until the mid-1970s, the only specific published literature on the Wisconsin Precambrian consisted of old outcrop locations and descriptions in journals of the Wisconsin Geological and Natural History Survey (Chamberlain, 1882; [ ] Weidman, 1907; Hotchkiss, 1915) and the summary maps of Dutton and Bradley (1970).

Jan 1, 1991

By T. S. Mackey

The industrial types, sources, and quantities of US tin residues are identified and the methods of treatment reviewed. The effect of a lower tin price, due to a current major world surplus of tin metal, is mentioned and covered in some detail. The names and locations of over 100 US firms recovering tin residues are listed. Current smelting and refining charges are included to convert the residues into tin metal and alloy. The impact of the complete with-drawal of the LME daily tin price since Oct. 24, 1985, and the collapse of the International Tin Council, which at one time supported the Buffer Stock Manager, are reported with comments.

Jan 1, 1987

By R. V. Ramani, R. Srikanth, R. Zhao

A two-part study was conducted to understand the factors affecting respirable dust generation potential or dustiness of coal seams. In the first part, the data from three prior comprehensive laboratory studies was analyzed to establish quantitative relationships between respirable dust generation potential and coal characteristics. This analysis indicates that respirable dust generation rate is positively correlated with Hardgrove Grindability Index (HGI), fuel ratio (fixed carbodvolatile matter), Vitrinke Reflectance (VR), and Level of Organic Metamorphism (LOM). In the second part, specially-designed single breakage experiments were conducted to determine the primary dust generation potential of 17 coal samples obtained from four continuous miner sections, three longwall sections, and the Penn State Coal Data Bank. The single breakage study indicates that primary dust generation rate is positively correlated with fixed carbon content, fuel ratio (fixed carbon/volatile matter), VR, and LOM. Since VR and LOM are strongly influenced by the process of coalification, differences in respirable dust generation rates in different coal seams may be explained by the thermal metamorphism of sedimentary organic matter during subsurface burial.

Jan 1, 1995

By Laurel E. Burns

Alaska is in competition with the rest of the world for exploration dollars. Providing a "seed package" of airborne geophysical data for the state's numerous mining districts encourages companies to begin more detailed exploration in more areas than they could have afforded on their own. When data are already available, the initial risk decreases for people involved in exploration. Airborne magnetic and electromagnetic data help ge¬ologists and geophysicists determine what rocks and structures are present under overburden and vegetation. These data form a fundamental package that exploration companies want before intensively exploring most regions. Individual mining companies have conducted their own geophysical surveys during the past several decades. However, these data are not available to other companies. The companies able to afford geophysical surveys have less money for ground exploration after purchasing expensive, private geophysical data. Therefore, they are not able to explore as many places as they might. Additionally, since data are not shared with other exploration companies, the proprietary surveys do not foster intercompany competition to move projects forward. Individual prospectors and small companies can not afford their own geophysical surveys. "It is more often than not the grassroots exploration efforts of the smaller operator that leads to significant discoveries," said Klaus M. Zeitler, senior vice president for development and exploration at Teck Exploration. Acquiring and releasing the geophysical data to the public produces several benefits. The increased explo- [ ]

Jan 1, 1998

By S. J. Czehura

The Butte quartz monzonite is the host rock for early porphyry copper style mineralization and subsequent mesothermal-epithermal, enargite-gold style veining that transects the district. The east-west Anaconda system veins: including the Emma, Anaconda-Original, Syndicate, Badger-State, and Alice-Rainbow veins, each with strike lengths of over 12,000 feet and vertical continuity in excess of 4,500 feet, along with mining widths from 5 to 50 feet, are unique to Butte. The incredible dimensions and tenor of these veins have yet to be surpassed and Butte is still touted as being the “Richest Hill on Earth.” The Anaconda Company was formed in 1895 to develop underground copper reserves in the district and eventually consolidated all operations under one company. Production from underground mining continued through the mid-1970’s. Open pit mining in the Berkeley pit began in 1955 with the extraction of supergene ores, along with the remnants of deeper horsetail zones inaccessible to the underground mines. Operations in the Berkeley pit were suspended in mid-1982 because of the rejection of high arsenic, copper concentrates at major smelting facilities throughout the world. Bulk mining of porphyry style mineralization in the Continental pit began in January 1980 to supplement copper production while stripping “C” pushback in the Berkeley pit. The Anaconda Smelter closed in September 1980. A molybdenum circuit was added to the Butte Concentrator in 1981 and mining continued in the Continental pit to produce copper and molybdenum concentrates. A blend of Berkeley and Continental ores were processed to dilute penalty metals in the final concentrates marketed to toll smelters. All mining operations ceased mid-1983 when Anaconda closed the Continental pit and offered the property for sale. Montana Resources reopened the Continental pit in June 1986 to produce copper and molybdenum concentrates. Operations were suspended mid-2000, because of exorbitantly high power prices, but resumed in November 2003 with rising metal prices. Bulk open pit mining of the early porphyry style mineralization has sustained production over the past twenty years and mining is expected to continue in the Continental pit with favorable prices. Future mining will eventually develop a 500 million-ton geologic resource incorporated in a supergene enrichment blanket situated between the Berkeley pit and the Continental pit. Grades in this enrichment blanket range in the neighborhood of 0.5% copper.

Jan 1, 2006

By M. A. Ackerson, R. E. Griffin, W. H. Pomroy

Two automated fire detection system configurations have been used successfully in underground mines: the pneumatic "tube bundle" approach and the electronic telemetry approach. The electronic telemetry approach is more widely used, owing to its greater speed, flexibility, and capacity to both monitor other underground conditions, and remotely control underground equipment. However, depending on specific mine conditions and layouts, pneumatic detection, or a combined pneumatic/telemetered system may offer significant advantages over the telemetered approach alone. This paper describes research by the U.S. Bureau of Mines to design and in- mine test a rapid response pneumatic fire detection system tailored to the unique requirements of multilevel metal mines. The relative merits of pneumatic detection are discussed in the context of typical multilevel mine layouts and environments. A Bureau developed proto- type system is described with emphasis on design features which counter commonly perceived and/or experienced pneumatic detection system operating problems. Finally, the results of a 3-yr in-mine performance evaluation of the prototype hardware are discussed. Included are descriptions of system layout and coverage, response time, tube leakage, sample dilution, elimination of accumulated water from sample lines, and system maintenance and reliability.

Jan 1, 1989

By H. Reginald Hardy, Xiaoqing Sun

Rheological models are widely accepted as a means of describing the mechanical behavior of geologic materials. It has been found, however, that rheological models developed for a specific stress level on the basis of linear visco-elasticity generally are not satisfactory at other stress levels. It has been suggested that the parameters of such models should be functions of stress level (Hardy, 1965; Kim, 1971). In this paper, continuous functions of stress have been utilized to obtain the required variation of Burgers model parameters with stress level. The model developed using these functions provides a constitutive relation which reflects the real time-dependent behavior of rock materials. The new model is capable of predicting the creep behavior over a wide range of stress levels and also predicts mechanical behavior under different loading condition (e.g. constant stress rate). It is also interesting to note that the mechanical behavior of individual elements in the model appear to reflect the different stages of brittle fracture in rocks (Bieniawski, 1967), namely; crack closure, elastic deformation, stable fracture propagation and unstable fracture propagation.

Jan 1, 1986

By Z. Sartowski, M. J. Pearse

The authors present laboratory and plant results illustrating the benefits to be gained by using chemical additives, namely flocculants and surfactant dewatering aids, in the Bayer process. Advantages of synthetic flocculants over starch are illustrated in terms of more efficient solid/liquid separation in both the initial settling of blow-down slurries and in the CCD wash train. In addition, it is shown that the use of synthetic flocculants considerably reduce the levels of organic contaminants present in the process liquor. Secondly, very significant improvements in moisture removal were obtained by the application of dewatering aids to hydrate filtration/ washing operations.

Jan 1, 1984

By O. V. Bush

Most governments recognize that energy efficiency represents a partial solution to reducing global capital shortages and environmental crises that threaten to seriously impede economic growth. Much of the United States and many foreign countries are embracing the concept of Integrated Resource Planning (IRP) which incorporates Supply Side Management (SSM) and Demand Side Management (DSM). Since SSM comes at twice to three times the cost of DSM, it makes economic sense to employ the energy conservation techniques of DSM. This paper will explain these concepts and some of the incentives being put forward by governments and utilities to promote DSM.

Jan 1, 1995

By Enrique Jelvez, Nelson Morales Varela, Christian Ihle, Joaquin Silva

All mineral beneficiation processes require water for its execution. Therefore, the availability and adequate management of water are key to the existence of any mine operation. However, many mines’ operations are affected by water scarcity and risk an increase of operational costs or even production in some cases. This paper proposes a model to minimize the losses of water due to evaporation and re-absorption by adjusting the active and inactive periods of the discharge in different points of the tailing. When applied, the model determines optimal or nearly optimal discharge operation in all the scenarios that were evaluated.

Jun 25, 2023