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By Adrian Smith, Debra W. Struhsacker

13.1 INTRODUCTION Cyanide is, a generic term indicating the presence of the cyanide ion (CN-). Cyanide is a very common, naturally occurring compound produced by many biochemical reactions. Many plant species synthesize organic compounds which contain cyanide in the form of cyanogenic glycosides (Knowles, 1976). For example, trace amounts of cyanide are present in the seeds and leaves of many members of the Rosaceae (rose) family (Kingsbury, 1964). Many common items such as lettuce, maize, sweet potatoes, kidney beans, (Oke, 1969) almonds, and cigarette smoke contain cyanide. As examples, a recent chemical analysis of chocolate-covered almonds measured a total cyanide content of about two ppm (Steffen Robertson and Kirsten, 1987); and the U.S. Surgeon General (U.S. Department of Health, 1964) has shown that cigarette smoke contains up to 1,600 ppm total cyanide. The chemistry of cyanide solutions is complicated because the cyanide ion forms compounds and complexes with many elements. Some cyanide species are highly toxic whereas others are relatively inert and harmless. Molecular hydrogen cyanide (HCN) is the most toxic form of cyanide. Under most conditions, HCN exists as a gas which readily dissipates or reacts with the environment to form less toxic or nontoxic forms of cyanide. Thus HCN is an ephemeral toxin, and many naturally occurring geochemical processes reduce the HCN concentration of a heap system with time. As discussed below, free cyanide includes the two species, ionic cyanide (CN-) and molecular hydrogen cyanide. Free-cyanide toxicity in man, mammal s, and aquatic species is we1 1 documented (Doudoroff, 1976; Ecological Analysts, 1979; Towill et al., 1978). The lethal doses reported for human adults vary with the type of exposure as follows: • One to three mg/kg body weight if ingested; • One hundred to 300 ppm if inhaled; and • One hundred mg/kg of body weight if absorbed. Acute toxicity of free cyanide to freshwater invertebrates ranges from 0.028 to 2.295 mg/l, depending on species and test conditions. Generally, free-cyanide concentrations greater than 0.1 mg/l are expected to kill sensitive species in freshwater or marine environments (Doudoroff, 1976;

Jan 1, 1988

By G. D. Elliot, R. L. Grayson, G. L. Winn

For the years 1990 and 1991, West Virginia's underground coal small-mine fatality rate was approximately 10 times higher than the national coal-industry fatality rate. Although the number of fatalities went down from 22 in 1991 to 17 in 1992, West Virginia still led the nation in coal-mining fatalities. A team of mining and safety professionals from West Virginia, interfacing with the Mine Safety and Health Administration and the West Virginia Office of Miners' Health, Safety and Training, studied this problem. A clear path for formal intervention was determined and is presented here.

Jan 1, 1996

By L. P. Meade

The need to feed an established talc mill from a crude ore source located closer to the mill prompted the 1986 drilling of a previously mapped, talc-carbonate deposit. This talc-bearing rock had never been considered a potential source of crude talc ore because of the high carbonate content and other deleterious minerals observed in outcrops. Selective mining, in-pit grade control and creative processing have allowed this deposit to be developed into an ore body. By definition, an ore body has to be a source of positive cash flow. With industrial minerals, this is determined as much by market acceptance as by ore tenor.

Jan 1, 1994

By Daniel R. Hack

Mine planning software companies have recently focused some resources on the development of industrial minerals packages useful in the aggregate industry, which is years behind other mining industry sectors in the use of computer-based planning techniques. This paper presents and compares characteristics of aggregate / quarrying software packages currently on the market, each product having strengths beneficial under different circumstances. To be successful, the developers must confront the limitations of their packages under a variety of situations, address the unique characteristics of the aggregate industry, and pay particular attention to the applicability of their products in real situations.

Jan 1, 2002

By W. M. Shaver, R. Letourneau, W. R. Dengler

Dynatec Mining Ltd. contracted to sink a 1500-m (4920 ft) concrete-lined shaft for Falconbridge Nickel Mines in Sudbury, Ontario, Canada. The shaft has an inside diameter of 6.3 m (20.5 ft) and is equipped with steel furnishings. Dynatec used the owner-supplied, 4.6-m (15.1 ft) diam, double-drum hoist to sink the shaft. For muck removal, 12.5¬t (13.8-st) buckets were used. The capacity of the concrete-¬placement buckets was 4.6 m3 (162.4 ft3). One of the unique features of the shaft sinking operation was the use of a two-¬boom, electric-hydraulic drill jumbo permanently mounted in the shaft sinking stage. An in-the-hole (ITH) drill was used to drill a 200-mm (8-in.) cut hole for the 4.8-m (16 ft), full face rounds. This paper describes the performance obtained with the electric-hydraulic drilling equipment and the high-capacity muck removal and concreting equipment.

Jan 1, 1994

By J. A. Herbst, Y. C. Lo

This paper attempts to answer whether or not the mill performance at Bougainville could have, in fact, been predicted by the population balance approach, or whether other special considerations are required to explain their behavior. In recent studies, the plant tests were performed at Bougainville and batch tests were carried out at the Utah Comminution Center. In all tests power measurements were made and several levels of energy input to grinding were evaluated. Also, tracer tests were performed for mill residence time determination. The performance of Bougainville's 5.5x6.4-m mill has been very successfully predicted by population balance methods. The prediction errors are only about 1% on product size distribution and 4% on power with a mill volume scale-up of 3790:1. It is significant that this approach will reduce the risk of failure in large mill design that has been recognized in traditional methods.

Jan 1, 1987

The problems of toxic, noxious, and explo¬sive atmospheres caused by gases and dusts are certain special environmental considerations in underground mining. Some other problems unique to underground mining are design of stable structures in the strata and their support, lighting the workings, and control of noise in confined spaces. These affect the health and safety of the workmen and deserve critical analyses. Some of the most important environmental parameters of underground mining are summarized in Table 1. The list is not exhaustive but illustrates the scope of environmental planning in underground mining. This chapter will discuss the use of computers and computer models in mine atmospheric environmental planning.

Jan 1, 1979

By Harrison R. Cooper

INTRODUCTION AND SUMMARY Phosphate matrix beneficiation is the process of providing a mineral product suitable for downstream chemical processing to yield high analysis chemical fertil- zers. Extraneous contaminants, clays and gangue solids, are separated by screening and flotation. Reject materials always carry with them some phosphate mineral values, however. A continuing objective is minimizing phosphate losses discarded with tailings as a principle factor in maintaining beneficiation efficiency. The quest for efficiency, and improved productivity, during beneficiation is hampered by disturbances arising from among the following: o Natural variance of phosphate deposit compositions, o Minimal control over managing ore matrix supply to the plants, o Screening and flotation mechanical upsets and inefficiencies. Production personnel, in recognizing these factors, attempt corrections for changed process conditions. This response usually has limited effect. Efforts of product- ion personnel to correct for upsets of the process may often diminish efficiencies rather than improve them. Lack of prompt data for analysis of process streams is an important contributing cause of inefficient operation. Discussion in this paper examines methods for improved process control in Florida phosphate beneficiation with particular emphasis on use of on-stream analysis to aid gaining productivity. The Florida Institute of Phosphate Research has supported demonstration of on-stream analysis applicable to improved process control. Concurrently, work is proceeding world-wide in the phosphate industry toward practical on-line analysis technology. Table 1 summarizes viable methods for real-time analysis data as result of work by individual companies and research organizations. A recently completed investigation (sponsored by the Florida Institute of Phosphate Research) of beneficiation efficiency was carried out in two Florida beneficiation plants using a newly developed on-stream analyzer for phosphorus (1). BPL measurements were taken at frequent intervals over two to three weeks of routine operation. Grades are expressed in "BPL", with one BPL, or bone phosphate of lime unit, equal to 0.46 P^Y2^YO^Y5^Y. The time series of feed and tailing BPL data were evaluated by statistical procedures. Results show avoidable losses can be five per cent or greater of mineral values in feed. Use of modern process control methods in Florida phosphate mining began several years ago (2, 3). Benefits of stabilizing control used in one of the two plants where data were collected for the investigation, in comparison to manual control in the other, are outlined. Process control technology developments reported from European and South African phosphate mining operations are also noted (4, 5). It is now well accepted that advanced control techniques can increase beneficiation productivity by better management of losses. However, to make advanced control effective, real-time measurements are needed of feed and tailings BPL as well as mass flow rates.

Jan 1, 1993

By J. J. Kellar, W. M. Cross, H. Du, C. D. Struckman, D. A. Boyles

Silane coupling agents have been used in the filler industry for years. One particularly unique feature is the ability of the coupling agents to enhance the adhesion between filler and polymer matrices. This paper will review the use of coupling agents for polymer matrix composite applications and discuss a new approach to coupling agent chemistry, namely, direct formation of a silicon-carbon non-hydrolyzable linkage between glass and coupling agent. The grafted silane monolayers were evaluated by infrared spectroscopy to ascertain their surface coverage and relative stability. Finally, composite specimens were fabricated and their mechanical properties were compared with traditional silane coupling agent treatment.

Jan 1, 2003

By G. E. Mellor, R. E. Lippoth, T. B. Faddies

The Little Rocky Mountains host epithermal- gold-silver bearing vein and stockwork deposits in a syenite intrusive complex. Pegasus Gold Ltd. is currently mining these oxidized deposits by open-pit methods and recovering gold and silver by heap-leach processes. A geologic program has been designed to effectively determine the basic ore characteristics; 1) mineralization; 2) oxidation; 3) structural setting; 4) lithology; 5) alteration; and ultimately, 6) the leachability of the ore. Geologic mapping, sampling, drilling, assaying, and testing are routinely used in exploration, development, production control, mine planning, and ore reserve estimations. Timely and accurate assay results are essential for the program's success.

Jan 1, 1992

By M. K. Larson, R. G. Wade

Researchers at the National Institute for Occupational Safety and Health (NIOSH) are studying the time- dependent response of rock stressed along weakness planes. The objective is to improve mine safety by reducing the number of roof falls that cause injuries and fatalities to miners. Researchers conducted direct- shear tests on mudstone overcored from a coal mine roof. Results showed frictional strength weakens with displacement along the shearing planes. Results of direct-shear creep tests also showed time-dependent deformation. Test measurements were compared to classical analytical models. Results suggest that the risk of roof collapse may be decreased through layout and support design to reduce creep rates and thus slow progression toward failure.

Jan 1, 2002

By Donald J. McKee

The product sizing and tonnage from a grinding circuit are the end result of a series of linked size reduction stages which always involve: fragmentation in mining; degradation in transport of ore; crushing and finally grinding. A case study is presented which illustrates the substantial effect on autogenous mill throughput of different mining practice. It is shown that it is possible to model each of the size reduction steps of fragmentation, degradation, crushing and grinding. The way in which this predictive capability is used is dependent on the operating constraints of each mine-mill combination.

Jan 1, 1998

At periodic intervals-typically at the end of each month, quarter, and year- the accounting department in each division of a company distributes a set of reports to the division's managers. These reports describe the financial performance of the division and its major departments over the time period. They identify the revenues generated from the division's products and the costs incurred in their production. The results from individual departments are combined to determine divisional results, and the results from individual divisions are in turn consolidated to determine the results for the overall corporation. Cost reports for each of these activities show actual amounts, budgeted amounts, and the differences between the two. This reporting is carried out for the individual period and for the year to date.

Jan 1, 1999

By I. Iwasaki

As the world tension relaxes and as the interest and taste for consumer products change, complacency is beginning to prevail over the needs of minerals and primary metals. The current trend towards resources and energy conservation calls for miniaturization of consumer goods, and lowers the demand for virgin materials to produce goods and services. Challenged by the third world countries with high grade ores and low labor costs, industrialized nations with lower grade ores are being pressed into more efficient operation through technological innovation, while protecting the environment. In many countries, domestic mines were forced to close since the oil crises due to rapidly rising energy and labor costs. Research in conventional mineral processing needs to be directed towards breakthrough technologies in order to maintain the competitive edge in the global marketplace. Research activities will provide new challenges in the processing of solid waste and waste water for environmental remediation as well as for resource conservation, in the preparation of new functional materials of extreme purity and/or unique properties for high technology applications and in the development of such future resources as deep sea minerals and extraterrestrial materials.

Jan 1, 1995

By S. J. R. Lowrie, J. S. Edwards, A. D. Jones

A small scale model has been constructed to simulate air and gas flows on a full scale retreat longwall coal face. Scaling relationships were derived to define how the main aerodynamic properties of the full scale could be preserved in the small scale model. These scaling requirements include: a minimum value for the Reynolds number for the flow on the face in order to maintain turbulent flow with a constant non-dimensionalised coefficient of turbulent dispersion; a constant Richardson number to maintain similitude for the formation of layers of buoyant gas; scaling of the permeability of the waste so as to obtain the same proportion of seepage flow through the waste; pressure gradients due to the ventilation and to the density difference (between the air and the gas layer) were kept in proportion; and in the waste, the relative contributions of inertial dispersion and molecular diffusion were approximately in proportion. The complementary roles of computational fluid dynamics (CFD) and aerodynamic scale models for simulating mine ventilation are discussed. The physical model is described and an example presented of simulations of the effect of changes in mining condition on the effectiveness of gas control in retreat longwall coal faces.

Jan 1, 1995

By J. E. Hoffman, T. J. Keefe, Michael E. Stout, O&apos

M.A. Industries, Inc. has developed and is now offering on a commercially available basis, complete systems to recover and recycle lead from spent SLI batteries. The system begins with the breaking and separation of the component parts of the batteries and subsequent treatment of the effluent water produced by this operation. The recyclable materials recovered from this process are metallic lead, lead paste and polypropylene. The lead paste is introduced into a process to convert it from a lead sulfate to a lead carbonate. The process also regenerates the salt solutions into reusable carbonate. The lead carbonate is then leached into an acid bath where it is later recovered by a proprietary electrolytic process. The metallic lead is recovered in a short rotary furnace producing metal for further refining and alloying. The polypropylene is further washed and then introduced to a reclaim extruder along with the proper modifiers and additives. The resulting resin can then be sold on the open market to injection molding processors. This complete system greatly reduces the amount of waste to be disposed of and completely complies with all applicable EPA guidelines.

Jan 1, 1993

By J. E. Gebhardt, P. E. Richardson

External control of the electrochemical potential of a bed of mineral particles was investigated by the US Bureau of Mines as a method for controlling particle interaction with organic collectors and, thus, flotation response. A cylindrically shaped, 200- to 300-g bed of sulfide mineral particles was used as the working electrode in an electrochemical-flotation cell. In a pH 9.2 sodium tetraborate buffer, chalcocite floated with ethylxanthate at applied potentials [=] - 0.25 V (versus the standard hydrogen electrode) ; pyrite floated at potentials [=] 0.15 V. Differential separation of a chalcocite-pyrite mineral mixture was obtained by controlling the potential, but the flotation response of the mixture did not follow the behavior predicted from measurements on the individual mineral beds. Chalcocite dissolution products had a deleterious effect on chalcocite-pyrite separation by activating pyrite so that it floated below the potential (~ 0.13 V) at which xanthate is oxidized to dixanthogen. A pyrite bed activated with a copper(II) sulfate solution exhibited a flotation response with a potential dependence between that of chalcocite and pyrite. Pyrite dissolution products had no effect on chalcocite flotation.

Jan 1, 1988

By T. R. Ellis

The author attempted to concurrently apply the US Uniform Standards of Professional Appraisal Practice (USPAP) and the Australian VALMIN Code to a complex mineral property appraisal assignment and previously to some modest assignments. This led the author into many severe difficulties. These difficulties included the high standards needed in the work of others and information and statements required from the client under the VALMIN Code. The exercises highlighted many positive features of both sets of standards. However, the author concluded that, without modification, VALMIN is incompatible with USPAP and the US regulatory environ¬ment. The author found that VALMIN violates US legal decisions regarding real property appraisal due to its requirement to include many items of business value. The US Securities and Exchange Commission's prohibition on reporting quantitative resource estimates proved to be a severe problem under VALMIN. Some VALMIN requirements could not be met due to the extent and quality of documents specified. Implications and thoughts regarding the development of a set of US minerals appraisal standards are discussed. Management considerations for complex mineral-property appraisal assignments are also presented.

Jan 1, 2000

By Bruce E. Nesbitt, Paul G. Lhotka

At Lupin mine gold is spatially and genetically linked to zones of hydrothermal alteration in iron-formation which are symmetrically developed adjacent to late Archean quartz veins. Immediately adjacent to the veins, coarse grained, typically gold- and sulfide-poor, calc-silicate rocks are often present. These rocks comprise hedenbergite + quartz ± grossular garnet ± epidote ± scheelite ± calcite. Sulfides (pyrrhotite, arsenopyrite and loellingite) and gold are concentrated in the next zone and occur with hornblende-rich rocks comprised of hornblende, quartz, hedenbergite and grunerite. Furthest from the veins are gold- and sulfide-poor, grunerite-rich iron formation comprising grunerite, quartz, hornblende and sometimes magnetite. Although the alteration assemblages have similarities with skarns, they develop in iron formation, and are at best indirectly related to intrusive igneous rocks. Geological and geochemical data clearly indicate the calc-silicate rocks are metasomatic in origin.

Jan 1, 1990

By R. Bhima Rao

Performing a magnetizing roast in a furnace or kiln is a well-established technology. However, the use of microwave heat for the magnetization of hematite in the beneficiation of ferruginous bauxite is a new approach. This paper reports on an investigation of this procedure, which is followed by comminution and magnetic separation. The results of this investigation indicate that a nonmagnetic product containing 80% A1203 and 2.5% Fe203 with a recovery of 80% can be made from a crude bauxite ore containing 55.9% A1203 and 5.6% Fe203. This product is suitable for refractory use. The mechanism is explained by the ability of the microwave radiation to heat specific points within the bauxite. These heat-specific points are at the location of iron minerals. In a reduced atmosphere, the microwaves promote faster conversion of the iron minerals to a magnetic phase, which improves the magnetic-separation process.

Jan 1, 1997