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By J. V. Calara, J. D. Miller

The sign of the surface potential for complex non-reactive ionic solids cannot be predicted solely from consideration of the hydration energy of gaseous ions which constitute the ionic lattice. Accurate analysis of these systems must involve the hydration energy of surface ions, which requires knowledge of the crystal structure, the identification of cleavage planes, and the calculation of binding energies of surface ions. Surface binding energies for ionic solids can be deter- mined if the Surface Madelung Constant is known. A computational technique was developed for the calculation of Madelung Constants for infinite lattices which gives excellent agreement with the values calculated by other more complicated methods reported in the literature. Extension of this technique permits the calculation of Surface Madelung Constants and binding energies of surface ions, ?Us, for semi-infinite solids. The hydration free energy of gaseous Ions, ?Fh, together with the calculated binding energy of surface ions, ?Us, allows calculation of the hydration energy of surface ions, ?Gh, as for the case of the ionic solid, MX:

Jan 1, 1976

By R. P. King

Direct observations of intergranular fracture during comminution are very difficult to make. The best indirect method is based on the measurement of interphase area before and after comminution. If intergranular fracture does not occur, the interphase area should be conserved during comminution, but it should decrease if significant amounts of intergranular fracture occur. The interphase area per unit volume can be determined by image analysis from measurements on sections of the unbroken ore and on sections through the particles after comminution. However, the measurements must be corrected for the effects of image resolution on the measured phase and particle perimeters. A correction procedure was developed, and the true interphase perimeter per unit volume was measured before and after comminution in a sample of chromite-serpentinite ore and two samples of Witwatersrand pyritic quartzite. The pyritic quartzite showed no significant evidence of grain- boundary fracture while the chromite-serpentinite showed a significant decrease in interphase area per unit volume of chromite, indicating that intergranular fracture occurred.

Jan 1, 1992

By Prasad Kummarapurugu, Maija Teijonsalo, Sirkka-Liisa Jamsa-Jounela

There has been a significant progress in the use of mathematical modeling and simulation in the minerals industry in the last decade. Process models have moved from academic world to important industrial tools. This paper reviews the status of mineral processing simulators and recent progress in simulator development and applications is discussed. The simulation for process design and optimisation is now an established technique, as evidenced by its increasing use of practising engineers through commercially available simulator software. The paper presents a systematic approach to the process study procedure for the control system development, clarified by practical case examples calculated by SimCon - a novel steady-state simulator for mineral processes. Examples of the application of SimCon in drawing flowsheets, calculating mass balances and making simulations for grinding and flotation processes are presented. At the end of the paper, the state-of-the-art and the future of computer-aided pro- cess study at mineral processing plants is discussed. Keywords: Simulators, modelling, object oriented programming, computer aided control system design

Jan 1, 1996

By Bobby J. Timmons

A few years ago during a Southeastern Geological Society field trip, a professor from a Florida university and a trip leader commented at one of the stops, "... and for those of you interested in the geology ...." More recently, in the spring of 1992, a geology faculty member at another southeastern university remarked, "Field geology is obsolete." An interviewee for a potential assistant position stated that he had never had a field class. This would-be assistant was to receive his Master's Degree in-Geology within a few days from yet another southeastern university. A regional illness? Certainly not, but symptomatic of the general health of Geology. Capitulation to Environmental Sciences seems to be in vogue with Geology becoming a four-letter word and the mention of mining is verboten regardless of the company. These trends permeate our profession while the demands for earth materials increase, often exponentially. Efficiency, a word lost on government, is routinely expected of business--our business--the industrial minerals geologist and producer. Our stage shrinks but the responsibilities expand. Are we meeting the challenge? Stay tuned!

Jan 1, 1995

By Abdullah Arik

The resource classification methodologies have always been a topic of research and debate. There are both traditional and Geostatistical methods used in practice. Because of the uniqueness of each ore deposit, it seems almost impossible to have a single industry-accepted norm for resource classification. Therefore, some practitioners have adapted the methodologies to suit the deposits they are working on, but many simply use the methods they are comfortable with. Another reason for the existence of varying classification methodologies is the lack of an easy and established way to measure the confidence in the estimates. Therefore, their classification becomes a subject of debate. In this paper, a new approach is offered to classify the resources using a "Resource Classification Index." The approach using this index takes into account the local variation, the spatial data configuration around the block being estimated, as well as the traditional distance measures. A case study for a gold deposit is presented to demonstrate how this new index can be used to classify the resources. The results from this approach are compared to those from two popular classification methodologies.

Jan 1, 2002

By Rodrigo Jerez

The mining business in general, and coal mining in particular, is exposed to frequent and significant swings in the business cycle. Marginal coal production enters the market place in a nearly perfect competition. It must be priced aggressively if market share is to be gained. The minimum price acceptable from the standpoint of the producer is reached at the point where total variable cost are recovered. Competition occurs as companies move to reduce their variable costs in an effort to cover some portion of their fixed costs at reduced market prices. Production planning and scheduling plays a critical role in reducing costs. Multiple scenarios based on changing market conditions require that competing firms have tools available to evaluate the economic impact of transportation, blending, and processing options. In certain applications, significant cost savings can occur as a result of blending or altering preparation levels. Linear programming provides a tool with which to evaluate options and acts as a like between the mine plan and marketing decisions.

Jan 1, 1992

By Kevin D. Lofftus

This paper presents a dynamic model for column flotation. The model equations are normalized and the dimensionless groups that are directly responsible in determining the column flotation behavior are identified. The resulting model equations are incorporated for computer simulation. Numerical results from computer simulations are analyzed to gather information about design and operation of column flotation devices.

Jan 1, 1988

By M. Hancer

The sign of the surface charge of selected potassium soluble salt minerals namely KClO4 , K2SO4 , KNO3, and KCl was determined from nonequilibrium electrophoresis measurements and found to be negative for each of the salt. Dodecylamine flotation of these salts revealed that the concentration of amine required for flotation increases in the order KClO4< K2SO4< KNO3<KCI. Precipitation of the amine collector colloid was not required for flotation of the oxyanion salts and in this case it appears that adsorption of the dodecylamine cation is sufficient to create the hydrophobic surface state. The order for flotation is explained in terms of surface hydration of these respective potassium salts based on contact angle measurements and FT Raman spectroscopic characterization of water structure.

Jan 1, 1999

By David M. Mchaina, Allan E. Hall, Siegfried Rohr, J. D. Botsford

Incidents associated with secondary dust ignitions in the mining of massive sulphide ore deposits are of major concern in Canadian underground metal mines. During stope or development blasting, a highly concentrated cloud of sulfide dust is created and may be ignited, resulting a secondary explosion which releases a considerable volume of sulphur dioxide and possibly other sulphur gases. The consequent pressure, heat and toxic gases can result in loss of life, significant damage to equipment and loss of production. These losses are expensive and should be prevented. Explosions of this type have occurred at the H-W mine of Westmin Resources mainly in the development headings and cut and fill stapes. This paper presents the results of a study conducted at the H-W mine to compare dust sampling methods for explosivity tests. The associated benefits and pitfalls of each sampling technique are examined. The investigative work conducted to develop and test preventive and control methods against sulphide dust ignitions is also discussed. The techniques which will minimize the risk of sulphide dust ignition in metalliferous mines are outlined. A review of current preventive and control measures practised at the H-W mine is also presented.

Jan 1, 1989

By W. A. Steingraber

This paper discusses the application of deep well disposal techniques to the problem of disposing of large volumes of low level radioactive wastewaters generated by the in situ uranium mining industry in Seth Texas. Data is presented on wastewater composition and volumes, geologic and hydrologic parameters of the disposal reservoirs, tell construction techniques, well operation, well monitoring requirements, and critical factors in evaluating the Safety and environmental impact of a deep injection well system.

Jan 1, 1980

By Wu Chao, Wang Pinglong, Meng Tingrang

This paper discusses the research results of sulphide ore properties with respects on self-heating and the assessment techniques on mine spontaneous combustion for several mines of sulphide ores in China. A group of experimental devices for testing the chemical behaviour of sulphide minerals, the geological structures, the rate of oxygen absorption, the initial self-heating temperature, and the ignition point of ore samples, etc. are also described in detail. These methods have been proved to be effective by several sulphide mines which all have the history of spontaneous combustion of sulphide ores. INTRODUCTION A fire disaster from the spontaneous combustion of sulphide ores in a mine can produce large quantities of toxic gases and heat to pollute the working environment, lead to large economic losses and loss of human life, and even compell the mine to be closed. Some mines of copper, lead, zinc, tin and iron in China are of high content of sulphur. It is of great importance to evaluate the potential of spontaneous combustion of sulphide ores before beginning to design and mine the ore deposits. At present, the mechanism of spontaneous combustion accepted commonly is that sulphide ores undergo slow oxidation on exposure to moisture air at ambient temperature, with the evolution of heat, gases and moisture. The heat generated, if not dissipated, gives rise to an increase in the temperature of the sulphide ores. As the temperature of the sulphide ores rises, the rate of oxidation increases. If this is allowed to proceed unchecked it can eventually result in the ignition of the sulphide ores. For pyrite (FeS2), it reacts with oxygen and water according to the following equations.

Jan 1, 1993

By Richard D. Harvey

Petrographic properties of carbonate rocks are useful guides to the utilization of these rocks in SO2-scrubbing systems. High porosity and fineness of grain are thought to be the principal properties that contribute to high dissolution rates of the rocks in the scrubbing liquor. Lake marls and chalks are the major types of carbonate rocks that have these properties. Lake marls are composed mainly of equant grains of calcite (mean grain size generally less than 4 microns) weakly agglomerated in- to larger, porous particles. The marls commonly consist of 80 to 90 percent CaCo3 as calcite and aragonite. Impurities are, for the most part, quartz silt and organic matter. The average pore volume for samples of lake marls (1- to 1.2-mm particles) is about 0.50 cc/g, which corresponds to a porosity of about 57 percent. The mean size of pores in these marls is generally between 1 and 2 microns in diameter. Surface areas of lake marls range from 0.8 to 6.8 m2/g. Chalks have grain sizes and shapes similar to those of lake marls, but they generally have smaller amounts of quartz and organic matter and minor amounts of clay minerals. Pore volumes differ from one chalk formation to another; the 1- to 1. 2-mm particles average about 0.20 cc/g, which corresponds to a porosity of about 35 percent. The mean diameter of pores in chalks tested ranges from 0. 15 to 0.76 micron. Surface areas of chalks range from 3. 2 to 20. 1 m2/g. In the United States lake marls are restricted largely to Pleistocene- age sediments that occur in the states around the Great Lakes. Chalk and chalky limestones are restricted mainly to the Upper Cretaceous and Tertiary strata in the Kansas-Nebraska-Colorado area and in the south- eastern states, from Texas to Florida. Results of laboratory tests of the relative dissolution rates of samples at pH 6 and 44°C indicate that, in addition to many lake marls and chalks, oolitic aragonite, pelecypod shells, and carbonate waste sludges from certain industrial plants also have high dissolution rates.

Jan 1, 1974

By R. P. King

INTRODUCTION It is now 21 years since Wiegel and Li published their paper on a random version of Gaudin&apos;s model for the mineral liberation phenomenon (Wiegel and Li, 1967). This paper was to revitalise interest in North America in one of the most fascinating, difficult and important problems in the field of theoretical mineral processing. Gaudin had many years previously (Gaudin, 1939) already presented a penetrating analysis of the problem and Wiegel and Li based their analysis very closely on the Gaudin model but they realised that the indeterminate geometrical structure of mineralogical materials demanded that only probabilistic models could provide the necessary quantitative information when working with real materials. They proposed and solved a randomised version of the Gaudin model but retained the essential geometrical simplicity of cubic mineral grains and a cubic fracture pattern. Although their model met with some limited success it was to be superseded in due course. During the 1940&apos;s and 1950&apos;s the classical field of geometrical probability spawned the mathematical discipline of integral geometry and as early as 1965, Bodziony (1965, a,b) showed that the techniques of integral geometry could accommodate the problems associated with the indeterminate nature of the geometrical mineralogical structure, provided that these were couched in probabilistic terms. In particular he showed that the quantitative description of the comminution process and that of liberation could be decoupled with the resulting economy of effort. This idea has profoundly influenced the course of research in liberation theory and has greatly facilitated its application and the measurement of liberation in a practical way. Bodziony demonstrated also that any theory that required the specification of the mineral "grain

Jan 1, 1989

By E. Sabah

A series of adsorption tests are carried out to understand the ability of cationic surfactants and metal ions to adsorb onto sepiolite. Adsorption tests conducted as a function of heat treatment reveal that sepiolite is rather conducive to the uptake of both organic and inorganic ions. An ion exchange mechanism between surfactant or metal cation and magnesium ion followed by chain-chain association is proposed to explain the incorporation of cationic surfactants into the structure of sepiolite.

Jan 1, 1998

By Wenhua Wan, Jan M. Mutmansky

Many concerns have been expressed worldwide regarding the use of diesel equipment in underground mines due to the potential health risks associated with diesel particulate matter (DPM). In assessing the risk to the health of miners and designing control strategies for DPM, it is important to know the concentration of DPM in the working areas of a mine. In some mines, significant stratification occurs due to the characteristics of the diesel exhaust, affecting exposure and the ability to measure DPM concentrations accurately. This study outlines some of the concentration profile data obtained during sampling at three mines where diesels were employed. Mine #1 (a gold mine) employed large openings in which a diesel-powered roof bolter was used. Mines #2 and #3 are both room-and-pillar operations with varying conditions. Mine #2 is an experimental mine where two stationary diesels were utilized for sampling purposes, while Mine #3 is a traditional evaporite operation using two mobile diesel vehicles for section haulage. These field studies indicated that some level of stratification occurred in all the mines, but the stratification was not as pronounced in the case of Mine #2 due to the complex pattern of exhaust emissions generated by the vehicles. The stratification seemed to depend on the distance from the vehicle, the mine air velocity, whether the vehicles were moving or stationary, and whether the exhaust was diluted by equipment design features. The concentration of DPM was generally higher at samplers located near the roof and lower at samplers located near the floor. However, this was not found in all cases. This paper provides conclusions on how knowledge of stratification patterns can be utilized in sampling and control of DPM in mine atmospheres.

Jan 1, 1997

By Matthew J. Hrebar

Dragline stripping operations account for over one-half of the U.S. bituminous coal production mined by surface coal mining methods. The dragline is a popular stripping tool because of its flexibility in varying overburden depths and relatively low operating costs per cubic yard of overburden. Because of the relatively high capital costs of the machines and their use as a primary stripping tool, the selection process is an important step in the mine planning procedure.

Jan 1, 1979

By Douglas W. Fuerstenau

This paper concern the specific adsorption of sulfate anions on nonmetallic minerals and its role in flotation. The specific surface affinity of sulfate ions in various systems has been observed in the results of electrokinetic measurements that show conditions under which sodium sulfate can reverse the sign of the zeta potential. The electrical double layer model provides a means for interpreting the results and for estimating the free energy of adsorption of sulfate ions. Because of their surface activity, sulfate ions not only can function as a depressant in the flotation of oxide minerals with physisorbed anionic collectors but also can function as an activator for flotation with physisorbed cationic collectors. Their role in depressing or enhancing the flotation of the sparingly-soluble mineral barite is also explained in terms of the double layer model.

Jan 1, 2005

By Bradford F. Townsend, Gary Peach, Roger Rothenburger

From the experience of the authors on recent large infrastructure Design-Build projects this paper reviews major lessons for Contractors and Owners in the delivery of large Design-Build infrastructure projects and some major pitfalls and warnings to both Owners and Contractors. The paper is written from both the Design and Construction perspective. A case history is presented that details the approach employed to ensure a quality project consistent from the initial design phase through construction and outlines the strategy used to guide the Design-Build process to an acceptable completion. Suggestions are made for Contractors and Owners for handling the Design and the Construction elements of Design-Build contracts.

Jan 1, 2003

By Bryan A. Bartley

About 1,000 machines around the world are breaking rock and hard abrasive materials by a very economic, high intensity, autogenous process, but this method is largely ignored by the mining industry. This vertical shaft autogenous impact crusher has impact velocities around 70 m/s, which compare with those of Cascade and SAG mills of up to 10 m/s. The autogenous impact, breakage processes are all at higher intensity levels and the products reflect this difference. The topic of liberation is breifly considered. A series of tests with a laboratory scale machine are reported to illustrate a number of the characteristics of the process. This paper highlights topics for further evaluation and research.

Jan 1, 1992

By Ulf Marklund, Stig Markstrom

Pioneering work with pilot scale autogenous grinding started in Boliden 1956. From 1961 to 1991 eleven fully autogenous grinding (AG) circuits have been installed at various concentrators within the Boliden company. A compact two-stage grinding system was de- signed in the beginning of 1970s. The system included a pebble extractor which feed the secondary grinding stage with grinding media. The APC grinding system (Autogenous/Pebble/Crusher) is a further development of the AG concept. A new design of the Boliden pebble extractor together with improved control strategy make the performance of the APC system suitable to almost any ore quality. The Boliden AG concept is probably the most cost efficient grinding system of today.

Jan 1, 1998