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By C. A. Young, J. L. Bowden

"Cyclic voltammetry experiments were conducted on copper and chalcopyrite (CuFeS2) in the absence and presence of ethyl xanthate, and compared to mass-balanced EH–pH diagrams. The results for copper duplicate those found in the literature and confirm xanthate chemisorption. However, the, results indicate that chalcopyrite oxidizes to chalcocite (Cu2S) and only afterwards is chemisorption observed due to small currents appearing with xanthate. This phenomenon suggests that the mineral's hydrophobicity is induced by more than dixanthogen and copper xanthate. Hydrophobicity was found to be pH-dependent over a range of alkaline conditions (pH 7–11) at narrow potentials (0 to –200 mV). An EH–pH diagram for chalcopyrite with xanthate is presented to illustrate the conditions under which chalcopyrite would be hydrophobic and thereby more thoroughly explain the results in the literature. IntroductionSulphide minerals are generally concentrated from ores by froth flotation, a physiochemical process that induces separation based on differences in hydrophobicity. In this process, a gas is bubbled into a slurry and the minerals that are hydrophobic (water-repelling) adhere to the bubbles and float to the surface while the hydrophilic (water-loving) minerals remain in the slurry. With sulphide minerals, the hydrophobicity is generally established in two ways. The first is by the addition of a collector, which is a heteropolar molecule with a reactive inorganic head group and an inert organic tail. Typically, the head group bonds with the sulphide mineral surface by adsorbtion either chemically (chemisorption) or physically (physisorption) or by complexing with atoms that solubilize somewhat at the surface (surface precipitation). These interactions leave the organic tail protruding from the mineral surface, thereby inducing hydrophobicity. The second method is by oxidation of the mineral surface to form a layer that is metal-deficient/sulphide-rich or comprised of elemental sulphur. Because the layer mimics naturally hydrophobic sulphur, this enables ‘collectorless’ flotation. Furthermore, this oxidation phenomenon adds an electrochemical dimension to the understanding of sulphide mineral flotation."

Jan 1, 2016

By B. M. Kunar

It is well known that job-related hazards and individual factors influence occupational injuries. However, research involving coalminers has been limited. This case-control study assessed the relationships of job-related hazards and individual/life style factors with injuries among underground coal miners. It compared 245 cases with at least one injury during the previous two-year period with 245 matched controls with no injury. The data were gathered via personal interview and analysed using the conditional logistic model. The significant risk factors were materials handling (adjusted OR 5.15), poor environmental/working conditions (2.63), geological/strata control-related hazards (2.35), lack of formal education (3.00), sleep disorders (1.86), alcohol consumption (2.32), disease (2.23), having a large family (5.40), and risk-taking behaviour (9.40). Machine-related hazards, sleep disorders and alcohol consumption primarily affected workers aged less than 45 years; whereas, environment/working condition-related hazards, presence of disease, smoking, risk-taking behaviour and large family size were more likely among workers aged 45 or over. Keywords: Occupational injuries, sleep disorders, job hazards, alcohol, coal miners

Jan 1, 2010

Mining is a business involving extraction of commodities of value to society from non-renewable resources. Consequently there is only one opportunity to extract ore from the ore body in order to unlock the value potential encompassed in the asset. It is therefore imperative that the maximum value is unlocked during the extraction programme, considering the relative wealth generated for shareholders and society, the sustainability of society, the environment and the operation. The bulk of the value that is unlocked is usually embedded in the initial design process. How do you measure sucess The most common measure of success is the return on investment, which is unlocked during the extraction process. This is usually only determined and locked-in during the study process. Another measure of success is the profitability that is achieved on a monthly basis. A further measure would be the enhancement the asset affords to the share price of the operation. Increasing focus on sustainable development requires that the impact on the society and environment received high priority as well. All these measures are largely encompassed in the cash flow and the discounted cash flows. This paper focuses on the dynamics of the cash flow and the most significant elements influencing return in investment. These include the mine design, production volume, sustainability, risk and valuation techniques. When do you add the most value? There are many different phases and definitions noted by different authors to demonstrate and standardise the study process for new projects. This paper is based on a process with 3 major components namely a conceptual study, a prefeasibility study and a feasibility study.

Jan 1, 2007

By G. A. Bezuidenhout

Lonmin Platinum installed a concentrated mode dual-alkali scrubber at the smelter in Marikana in 2002. The dual-alkali scrubber was the technology of choice at that time as a sulphur fixation plant, due to the perceived benefits of handling both the high SO2 concentrations of converter off-gas and the swings in SO2 concentration that are linked to Peirce-Smith operation. Owing to current and impending legislative requirements for air quality and waste, Lonmin is currently considering additions to the dual-alkali plant, but is also evaluating alternative technologies for sulphur fixation. This paper reviews the decision of Lonmin to install a concentrated mode dual-alkali scrubber and presents plant performance achieved. It also describes the important control variables and sensitivities of the plant, and the final product that is produced by the operation of the plant. The legislative requirement that drives the Lonmin technology evaluation is also discussed.

Jan 1, 2012

By R. G. Jurd

This paper considers the introduction of large-scale longwall mining into South African coal mining, instead of the conventional mechanized bord-and-plllar mining that is widely practised at present. The two methods are compared, and longwall mining is found to have the advantage in several respects in some seams. The most cogent reasons for the introduction of the longwall method In some seams are associated with safety strata control and increased labour costs.

Jan 1, 1978

By F. E. Steffens

The application of kriging in assessing the area rainfall in a weather modification experiment is complicated by the presence of many zero rainfall recordings on a given day, and the fact that the variograms seem to be quite different for the rainfall on different days. Indicator variograms are shown to be directly related to two sets of conditional probabilities. Probability kriging is used in estimating the probability of rainfall amounts above any cutoff at any point

Jan 1, 1987

By S. T. L. Harrison, A. Kotsiopoulos, J. R. Amaral Filho, J. L. Broadhurst

The land disposal of voluminous fine-grained tailings from the processing of mined ore bodies poses a long-term risk to the surrounding environment and local communities, while also representing a loss of valuable natural resources; including water, land and mined minerals. To date, the development and practical implementation of alternative approaches and technologies for removing risk and reducing the burden associated with these wastes, particularly in South Africa, remains limited, and value recovery is largely limited to the extraction of precious metals. To this end, researchers at the University of Cape Town have developed a programmatic multi-phased approach to explore and develop opportunities for the valorisation of large-volume mine wastes, based on the innovation value chain. This paper outlines this conceptual approach and presents key outcomes from its application for the specific case of sulfide-bearing coal processing wastes from South African collieries. Through the application of a combination of qualitative and quantitative tools and methodologies, a number of potentially viable opportunities and processing routes for value recovery and bulk re-purposing of these wastes have been identified and tested on a laboratory scale. Studies have, however, also shown that there are several technical and non-technical factors currently constraining commercial application of these opportunities. Overcoming these constraints will require a commitment to innovative waste management approaches and effective multi-sectoral collaboration. Keywords: Coal processing wastes, physical separation, waste re-purposing and utilisation, technology transfer

Jan 1, 2020

By D. Ackerman, S. Cole, G. Langefeld, I. Parker

The removal of gravel from the seabed using a hydraulic mining tool is a complex multi-phase problem that cannot be analysed using traditional continuum based simulation techniques. One potential approach is to simulate the behaviours of the solid phase via the discrete element method and the liquid phase via finite volume based computational fluid dynamics. The interaction between the phases is accounted for by Eulerian coupling. The feasibility of using the combined computational fluid dynamics-discrete element method to simulate gravel entrainment from an idealized seabed is evaluated. The simulation results are validated using experimental data. It is concluded that while the current approach appears feasible, further work needs to be done to improve the accuracy of the simulation and to evaluate the approach?s ability to model more complex behaviours.

Jan 1, 2007

By Q. G. Reynolds

The presence of dust and fume suspended in the freeboard region is a common feature of the operation of direct current (DC) plasma smelting furnaces. This occurs primarily as a result of the use of fine feed materials together with the open-arc, open-bath operation of such smelters, and is exacerbated by the high velocities and turbulent mixing of the gas in the vicinity of the arc jet. Dust and fume losses into the furnace off-gas system can be significant in some cases and may have economic, operational, and environmental impacts on the process. A computational modelling study is presented in which the concentration of dust material was considered as a continuous field subject to a governing partial differential equation. Settling behaviour was calculated as a function of particle size, local gas/plasma temperature, and other physical properties. Development of the coupling between the concentration field and a magneto-hydrodynamic description of the arc is shown, and the resulting models were used to compute various aspects of the behaviour of the concentration field in the arc region for a variety of furnace conditions. Time-averaged as well as transient models of the arc were used to generate the results presented. Qualitative case studies produced several practical suggestions for furnace operation, including increased dust capture by the bath when feed ports are located closer to the electrode, and the possible effects of feed segregation in the furnace freeboard based on dust particle size and density.

Jan 1, 2014

By M. Kannenberg

When coal properties are estimated geostatistically for mine planning in the hardcoal industry, there is one important supposition which influences the reliability of prediction of economically profitable parts of the deposit. This is the fact that activities in hardcoal exploration and mine planning are characterized by distinct levels of information and knowledge upon which decisions of economic import must be based, for example, whether exploration should proceed or not, or which methods and strategies should be used to maximize search efficiency. To get more reliable results for mine planning, in particular, advanced kriging methods (e.g. conditional simulation) have to be introduced and checked for their reliability in historical analyses (post-mortem studies). By using this feedback, kriging results from underground samples or production data can be compared with results gained by advanced geostatistical methods from exploration boreholes.

Jan 1, 1987

By G. A. Bezuidenhout, J. P. T. Kapusta, D. K. Chibwe

"Peirce-Smith converters (PSCs) are extensively used in the copper, nickel, and platinum group metals industries to remove iron and sulphur from the molten matte phase. This technology has not changed significantly since its inception in the early 20th century. The typical converting operation involves lateral purging of air/oxygen-enriched air into molten matte through a bank of tuyeres. This blowing operation occurs at low air pressure from the blowers, and the induced bubbling regime is considered inefficient from both a process and an energy utilization perspective. Inherent drawbacks include recurrent tuyere blockage, inevitable tuyere punching operation to clear airways, and low oxygen efficiency as a result of substantial air losses due to leakages.Investigations in the 1980s demonstrated1 that jetting into Cu and Ni converters could reduce or eliminate some of the process difficulties. In spite of these findings, very little progress has been made in the application of these concepts for converting of non-ferrous melts on a commercial scale.As part of its operational improvement and energy reduction initiative, Western Platinum embarked on a full-scale industrial evaluation of generating a jetting regime by using sonic injection. Prior to full-scale industrial evaluation, a numerical assessment was conducted to ascertain the feasibility of implementing sonic injection on Lonmin converters. The work included flow characterization at high injection pressures achieving sonic velocity at the tuyere exit. The 2D and 3D simulations of the three-phase system were carried out using the volume of fluid (VOF) and realizable k- e turbulence models to account for the multiphase and turbulence nature of the flow, respectively. These models were applied using the commercial CFD numerical code FLUENT.This paper discusses the key findings regard ing understanding of gas plume extension, velocity distribution, shear wall stress analysis, and phase distribution characteristics in the system. Plant trials are also discussed with reference to the commercial aspects of a fullscale implementation of sonic injection in the smelter."

Jan 1, 2014

The optimal design of production phases and ultimate pit limit for an open pit mining operation may be generated using conventional or stochastic approaches. Unlike the conventional approach, the stochastic framework accounts for expected variability and uncertainty in metal content by considering a set of equally probable realizations (models) of the orebody. This paper evaluates the performance of a new stochastic network flow approach for the development of optimal phase design and ultimate pit limit using a gold deposit as the case study. The stochastic and conventional frameworks as considered here utilize the maximum flow and Lerchs-Grossman (LG) algorithms, respectively. The LG algorithm is restricted to considering an estimated (average-type) orebody model, while the stochastic maximum flow algorithm is developed to simultaneously use a set of simulated orebody realizations as an input. The case study demonstrates that, when compared to the conventional LG algorithm as used in the industry, the stochastic approach generates a 30 per cent increase in discounted cash flow, a21 per cent larger ultimate pit limit, and about 7 per cent more metal, while it maintains a consistency in phase size.

Jan 1, 2012

By K. Sasaki, Y. Oriia, Shigeto Kuroiwa, H. Miki, Yuji Aoki, T. Hirajima, G. P. W. Suyantara

The effect of a sulfite reagent on the floatability of chalcopyrite and enargite was investigated in this paper. The flotation tests using single and mixed minerals were performed under various concentrations of sulfite. The flotation tests using a single mineral showed that the sulfite reagent depressed the natural floatability of both minerals at pH 9. Surprisingly, enargite was floated after the addition of potassium amyl xanthate (PAX) following the sulfite treatment, and the floatability of chalcopyrite depressed under a similar condition. X-ray photoelectron spectroscopy analysis results showed that the sulfate species increased after the sulfite treatment on both minerals. However, the addition of PAX removed this sulfate species and rendered the enargite surface hydrophobic. This phenomenon was not observed on the chalcopyrite surface. FTIR analysis and PAX adsorption studies were performed to support this finding. The flotation of a mixed mineral was in agreement with the flotation of a single mineral, indicating a possibility for selective flotation of chalcopyrite and enargite using the proposed method. Keywords: Flotation, chalcopyrite, enargite, sulfite, potassium amyl xanthate

Jan 1, 2020

By T. Marsden

The demand for continuous improvement in the industrial world is an ongoing process. Some sectors, where the competitive forces are well established, have led the development of new and reliable technological innovations. Although the metallurgical industry can rightfully be proud of its process improvements, there is still work to be done in materials and in material handling. In some cases, the improvements will be as simple as adopting technologies that have been perfected in other processing or manufacturing industries. This paper discusses the next design generation for copper tankhouses which will yield: ?Improved copper quality ?Improved equipment availability ?Lower life cycle costs ?Safer operations. These benefits will be realized through new developments and design improvements in: ?Permanent cathodes ?Cathode washing ?Cathode stripping machines ?Anode preparation machines ?Improved lead anode design ?Recycling of lead anodes and refurbishment of cathodes. The demand for base metals, and in particular copper, has led to more research into improving efficiencies in electrowinning and refinery plants around the world. One of the areas previously taken as a matter of course was the production of lead anodes and stainless steel cathodes. In South America alone there are over 600 000 cathodes and anodes in circulation?a very significant figure.

Jan 1, 2009

By E. J. Magri, A. Couble

Kriging estimates of geological resources are sometimes conditionally biased because the kriging plan contains too few samples. This may be done purposely in order to match the variance of the estimates to the true block dispersion variance. This work aims at evaluating the influence of conditional bias over the ultimate optimum pit design in relation to its shape, size and NPV (Net Present Value of profits). It has been restricted to two real case studies: a ‘carrot shaped’ gold porphyry in northern Greece and a manto-typeexotic copper deposit located in northern Chile. The methodology applied to each deposit consisted of generating a ‘real block model’ and four resource estimates by the use of conditional simulation and the application of four different kriging plans to the drillhole databases respectively. The estimation models vary in smoothness and conditional bias. Ultimate optimum pits were determined for the ‘real’ and the four different kriging models. Pit comparisons lead to the following conclusions: •In the worst case, conditional bias overestimated the project's NPV by 32% and 5% for the gold and copper deposits respectively. •The overestimation of high grades is more relevant than the underestimation of low grades. This resulted in a tonnage over-extraction of 148% and 1% for the gold and copper deposit respectively. This difference was attributable to the vastly different geometry of the deposits. •The smoothing effect of kriging, without or very little conditional bias, produced open pits that were different to the ‘true’ (ideal) ones and furthermore, underestimated the project's NPV by 10% and 6% for the gold and the copper deposits respectively. •Other factors that influence the optimum open pit design and to some extent control the effect of conditional bias are: the cut-off grade, the orebody geometry and distribution of grades within it and the amount of over-burden. Keywords: conditional bias, ultimate pit design

Jan 1, 2003

By L. Lorig

"Two types of extreme event, earthquakes and rainfall, potentially affect open pit slope stability. In the case of earthquakes, there are rather well-developed analysis procedures and acceptability criteria. The analysis procedures relate mainly to selection of the dynamic loading either through design earthquakes and/or pseudo-static seismic coefficients. The acceptance criteria are typically expressed in terms of a minimum safety factor in pseudo-static analyses. The acceptance criteria are often promulgated by governments despite the fact that no open pit slope has ever been adversely affected by an earthquake. This paper explains why open pit slopes are seemingly more resistant to dynamic loads than natural landforms, which can experience catastrophic landslides.Extreme rainfall events are much more likely to cause open pit slope problems than earthquakes. Two types of problem are common – slope erosion and slope instability. Slope erosion is often mitigated by appropriate surface water controls. Slope instability due to elevated transient water pressures is more difficult to mitigate. Analysis procedures and acceptability criteria are rare. This paper will discuss the mechanisms for rainfall-induced slope instability, as well as analysis methods. Examples will be discussed and analysis methods are proposed. IntroductionTwo types of extreme event, earthquakes and rainfall, potentially affect open pit slope stability. In the case of earthquakes, there are rather well-developed analysis procedures and acceptability criteria. The analysis procedures relate mainly to selection of the dynamic loading either through design earthquakes and/or pseudo-static seismic coefficients. The acceptance criteria are typically expressed in terms of a minimum safety factor in pseudostatic analyses. The acceptance criteria are often promulgated by governments (e.g., Peru, Chile) despite the fact that no open pit slope has ever been adversely affected by an earthquake. This paper explains why open pit slopes are seemingly more resistant to dynamic loads than natural landforms, which can experience catastrophic landslides.Extreme rainfall events are much more likely to cause open pit slope problems when compared to earthquakes. Two types of problems are common – slope erosion and slope instability. Slope erosion is often mitigated by appropriate surface water controls. Slope instability due to elevated transient water pressures is more difficult to mitigate. Analysis procedures and acceptability criteria are rare, but do exist. In Peru, for example, slopes are required by law to be designed for a 100-year storm."

Jan 1, 2016

By J. R. Percival, L. Ip, M. D. Piggott, S. J. Neethling

Component wear due to particle-laden flow is a significant challenge in the minerals processing industry in the handling and transportation of abrasive mineral slurries. Studying wear through experimentation is time-consuming and expensive; therefore possessing the ability to accurately simulate, understand and predict wear in these complex environments is highly desirable. The ability to predict wear is important in both the design of equipment in order to maximise the performance over the wear life of the components, as well in minimising potentially costly and dangerous failures and unscheduled maintenance.. Particle-induced wear is a complex problem, requring an understanding of coupled fluid-solid motion, geometry deformation in response to fluid-solid behaviour, moving geometries and wear modelling. Although the literature demonstrates that rebounding particles and changes to surface profiles can have a significant effect on subsequent wear rates and patterns, the challenge of implementing a model to account for this effect in complex geometries has been addressed by only a few authors in the literature. This paper describes a new wear simulator, leveraging fluidity, an open-source, massively parallel, finite element based CFD simulator capable of unstructured adaptive meshing. The wear simulator includes the ability to model particle-laden flow using representative Lagrangian particles and dynamic remeshing of geometry in response to wear and component movement. These capabilities are demonstrated using wear and the associated dynamically deforming boundaries within a Coriolis tester arm, with the results comparing favourably with the experimentally observed wear patterns. Keywords: CFD, wear, two-phase flows, anisotropic mesh adaptivity, boundary deformation

Jan 1, 2020

By El-Sayed M. Sherif, J. D. Comins, Erasmus R. M.

Corrosion of copper in aerated acidic chloride pickling (0.5 M HCl) solutions and its inhibition by 3-amino-1,2,4-triazole-5-thiol (ATT) have been investigated using electrochemical techniques and weight-loss measurements, along with Raman spectroscopy. Electrochemical measurements for copper after varied immersion periods of 0, 24 and 48h showed that the presence of ATT and the increase of its concentration significantly decrease cathodic, anodic, corrosion (jCorr) currents and corrosion rates (KCorr), as well as the dissolution currents at 300 mV vs. Ag/AgCl, while increase polarization resistance (Rp), degree of surface coverage (?) and inhibition efficiency (IE%) to a great extent. Weight-loss measurements after different immersion periods of 6 ~ 48h revealed that the dissolution of copper decreased to a minimum and the corresponding IE% increased with ATT concentration increases. The detection of ATT molecules on the copper surface by Raman spectroscopy indicated that inhibition of copper corrosion is achieved by strong adsorption of ATT molecules onto the copper surface. Aerated acidic pickling solutions; 3-Amino-1,2,4-triazole-5-thiol; Copper corrosion; Corrosion inhibition; Raman spectroscopy

Jan 1, 2006

By F. G. Hill

The paper reviews the restrictions imposed by the Department of Mines (now the Department of Mineral and Energy Affairs) on the surface use of ground that has been undermined at shallow depths (down to a depth of244m). The reasons for the restrictions are discussed, with special reference to the early records kept by the Department of Mines on subsidence and fracture of the surface. A discussion of the nature of the strata overlying the ore-body, and the effect of undermining, is followed by a detailed account of investigational work, particularly since 1970, on the stability of shallowly undermined ground. The significance of the data collected during the investigations is considered next, with special reference to the social and economic implications. These are so farreaching, that it is proposed that the already flexible approach of the Department of Mineral and Energy Affairs in considering what structures may be built on undermined ground should become even more flexible. To this end, the appointment of a Commission is proposed to collect as much information as possible on the stability of ground undermined at shallow depth, and to revise the current overrestrictive conditions or guide lines that are in use.

Jan 1, 1981

By T. Feroze, B. Genc

"Blind headings in room and pillar coal mines are a major source of methane and coal dust. Most methane and coal dust explosions therefore occur in the blind headings. The primary cause of these explosions is the disruption of the local ventilation system. Line brattice (LB) ventilation systems are used to ventilate blind headings by directing air from the last through road (LTR) into the heading. The amount of air available to ventilate the face of the empty heading depends on the heading dimension, settings of the LB, and velocity of air in the LTR. LBs are commonly installed by underground supervisory staff based on work experience, which may result in ineffective ventilation. The correct installationof LBs remains a challenge. In this study, a validated computational fluid dynamics (CFD) model has been used to analyse the effect of the LB ventilation system variables on the air flow rates close to the face of the empty heading. Full-scale three-dimensional models with various heading heights, heading depths, LB settings, and LTR velocities were simulated. The air flow rates and patterns at various locations inside the heading were analysed. A comparative study was carried out to quantify the effect of each of these system variables on the flow rates close to the face of the heading. Based on the findings, a user-friendly numerical model was formulated that can be used to estimate the flow rate close to the face of an empty heading for different practical settings of the system variables. This model can help the supervisory staff to swiftly implement the ventilation plan according to the regulations and the mine standards. The model can also serve as part of the curriculum for educating future mining engineers."

Jan 1, 2017