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By M. Rudolph, A. D. Renno, H. Wu

In this study, synthetic pure cassiterite and cassiterite doped with Fe were successfully produced by sintering. Their crystal structure and chemical compositions are characterised by optical microscopy, X-ray powder diffraction (XRD) as well as scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDS) based chemical composition analysis. The electrostatic behaviour of synthetic and natural cassiterite was studied by electrophoretic measurements. Their floatability was studied by microflotation with two types of anionic collectors. Results show that the cassiterite floatability with these collectors behaves differently and lead to two opposite results: Natural cassiterite (enriched with Fe) > undoped pure SnO2 by using sulfosuccinamate (Aerosol® 22) Undoped pure SnO2 > Fe3+ doped > natural cassiterite (enriched with Fe) by using styrene phosphonic acid (SPA). Keywords: Synthetic cassiterite, lattice impurities, flotation, zeta potential, Aerosol® 22, styrene phosphonic acid

Jan 1, 2020

By D. F. Malan, D. Ile

This study explores the use of backfill in hard rock bord-and-pillar mines to increase the pillar strength and extraction ratio at depth. The use of backfill will also minimize the requirement for tailings storage on surface and the risk of environmental damage. A literature survey indicated that backfill is extensively used in coal mines, but rarely in hard rock bord-and-pillar mines. To simulate the effect of backfill confinement on pillar strength, an extension of the limit equilibrium model is proposed. Numerical modelling of an actual platinum mine layout is used to illustrate the beneficial effect of backfill on pillar stability at greater depths. The magnitude of confinement exerted by the backfill on the pillar sidewalls is unknown, however, and this needs to be quantified using experimental backfill mining sections equipped with suitable instrumentation.

May 3, 2023

By J. Petersen, A. E. Lewis, J. Chivavava

Rare earth elements (REEs) have special properties that prompted their extensive use in high-tech applications. The demand for REE has, therefore, increased over the past years, resulting in the supply risk of the materials. Extraction from non-conventional low-grade ores, like easy-to-mine ion adsorption clays (IACs), by hydrometallurgical methods is being explored to supplement the supply of REEs. The extraction of REEs from low tenor IAC leach solutions requires enrichment using cost-effective methods such as precipitation. Therefore, the aim of this study was to understand the recovery of REEs from IAC leach solutions using various reagents for precipitation. In the first part of the study, recoveries of REEs from IAC leach solutions through direct precipitation using H2C2O4 and NH4HCO3, as well as antisolvent crystallization using C2H5OH, were predicted via thermodynamic modelling using OLI Stream Analyzer. Verification experiments were then conducted through the use of an agitated reactor. Simulation results showed that high yields of REEs were possible using each of the reagents, but large quantities of C2H5OH were required. Experimental results confirmed the high yields predicted from simulations. Precipitation with H2C2O4 was found to selectively recover REEs while rejecting Al. However, utilization of NH4HCO3 and C2H5OH resulted in the co-precipitation of Al. Furthermore, the yield of Y from antisolvent crystallization was significantly lower than the theoretical value. The product recovered from antisolvent crystallization consisted of well faceted, large crystalline particles, which filtered faster than the fine, amorphous REE carbonates recovered using NH4HCO3. REE oxalates were crystalline, larger than the REE carbonates and, overall, showed the highest filtration rate.

Dec 11, 2024

By K. Barani, F. Moradpouri, M. Godarzi

A sampling campaign carried out on the lead flotation circuit at Lakan lead-zinc processing plant demonstrated that the Pb recovery was only about 68-69%. Characterization of the Pb flotation tailing showed that 61.4% of the Pb is in the –37 μm size fraction, which is difficult to recover by flotation. Batch flotation experiments were carried out on a plant sample of the lead flotation feed and high-intensity conditioning (HIC) was used to improve flotation recovery. The results showed that increasing the collector conditioning time from 1 to 3 minutes significantly increases the Pb recovery from 42.5% to 57.3%. Further increases in conditioning time to 5 to 7 minutes decreased the Pb recovery. With a collector conditioning time of more than 3 minutes, due to the surface cleaning effect, increasing collector and frother dosage improved the flotation selectivity and recovery, even at higher collector dosages. The Pb recovery increased from 69.1% to 79.8% with increasing impeller speed from 600 to 1250 r/min. HIC increases the flotation kinetics and greatly improves the flotation recovery and concentrate grade.

Apr 2, 2022

By Y. Qin, L. Han, P. Gao, Y. Han, Y. Lia

In the present study, an innovative comminution technology of high-voltage pulse discharge was proposed for galena to weaken the mechanical property. The results of pre-treatment experiments indicated that the optimal operating conditions of spherical gap spacing 25 mm, pulse numbers 120, and loading voltage 25 kV were obtained, where the relative grindability of pretreated products was improved significantly, although with the prolonging of grinding time, the superiority of high-voltage electric pulses was gradually weakened. The galena ores were subjected to a high-voltage pulse discharge, and then the crack generating along the boundary between galena and gangue was observed under an optical microscope, and the surface burning which appeared in the ores. The scanning electron microscope (SEM) results indicated that the pretreated products were in a state of melting and then condensation, accompanied by some pore formation. Pulsed discharge pre-treatment not only produced more micro-cracks and cracks in the sample but also extended the original crack. Keywords: High-voltage pulse discharge; galena; relative grindability; micro-crack

Jan 1, 2020

Ninth International Symposium TECHNIQUES FOR DECISION MAKING IN THE MINERAL INDUSTRY The Symposium which is to be held in Montreal during the week of 14th to 19th June, 1970, follows the Computer Symposium held in Salt Lake City in September, 1969. The purpose of the Symposium is to define the role of decision-making techniques within the mineral industry and to stimulate the development of specific applications. The subject of the Symposium-mathematics, operations research and computers as applied to the mineral industry-have permitted us to structure it in such a way that a complete picture of the mineral industry in its public policy, corporate, financial and technological environment emerges. Topics for the sessions are: . The Public Policy Environment;. The role of Decision Making Techniques in the Mining Company; . Information Storage and Retrieval; . Markets-Forecasting, Patterns and Strategies;. Search for Mineral Deposits;. Quantification of Geological Variables;. The Mine Development Decision; Production Systems;. Planning, Scheduling and Control Systems. The sessions will be directed energetically by chairmen who have been in continuous contact with the authors, providing them with information about related papers and sessions. This symposium is sponsored by the Canadian Institute of Mining and Metallurgy, McGill University and Ecole Polytechnique. Further information may be obtained from: The 9th International Symposium. W. H. Gauvin, General Chairman, J. Elbrond, Programme Chairman. Department of Mining Engineering, Ecole Poly technique, P.O. Box 501, Snowdon, Montreal 248, Quebec, Canada. ACHEMA 1970 The European meeting of Chemical Engineering and the Achema Congress 1970 is being held at Frankfurt/Maine, from 17th to 24th June, 1970. The programme includes some 110 plenary and specialised lectures, numerous technical films, excursions, and technical discussions in front of the exhibits which form the central feature of the Achema-Exhibition Congress. Further information may be obtained from the honorary representative of Achema in South Africa, Mr F. Schilling, P.O. Box 31274, Braamfontein, Johannesburg. NINTH COMMONWEALTH CONGRESS PROCEEDINGS Publication of the proceedings of the Ninth Commonwealth Mining and Metallurgical Congress, 1969, is being undertaken by the Institution of Mining and Metallurgy, London. There will be four volumes covering papers presented at the Congress together with the discussion and author's replies, and the addresses by Sir Duncan and Sir Ronald Prain. These will be available April-June 1970. Special pre-publication prices apply to orders received before 1st April, 1970. Order forms may be obtained from Secretary S.A.I.M.M., P.O. Box 1183, Johannesburg. 6th World Congress on the Prevention of Occupational Risks This Congress, dealing with industrial accidents and occupational diseases, will be held in Vienna from 10th to 15th May, 1971. Further information may be obtained from: VI Weltkongress für Unfallverhütung, Postfach 745, A-1015 Wien, ÖSTERREICH. International Vacuum Metallurgy Conference 1970 The Vacuum Metallurgy Division of the American Vacuum Society is organizing an international meeting that will be held at the Convention Center in Aanaheim, California from 15th to 19th June, 1970. Enquiries should be directed to the Arrangement's Chairman, L. M. Bianchi, TRW Inc., 23555 Euclid Avenue, Cleveland, Ohio 44117, Tel. No. (216) 383-2111. AIME WORLD LEAD-ZINC SYMPOSIUM This symposium is being held from 21st to 23rd October, 1970, in St. Louis, Missouri, U.S.A., in conjunction with the Fall Meeting of the Society of Mining Engineers, and a Rapid Excavation Conference. In addition to local field trips to smelter and refinery operations there will be a number of extended trips of six to eight days. Information may be obtained from: Mr. John C. Fox, Secretary, Society of Mining Engineers of AI.M.E., 354 East 47th Street, New York, N.Y. 10017, U.S.A. NEW SUBSCRIPTION RATE TO THE JOURNAL As from 1st JANUARY, 1970, the subscription rate for the Journal has been increased from R12.00 to R18.00 per annum, i.e. R1.50 per issue instead of R1.00. The discount to booksellers is 15 per cent. COURSEOF THE THEORYOF THE UNIT OPERATION OF GRINDING The South African Institute of Chemical Engineers is arranging for Prof. L. G. Austen to conduct a course on the above subject in September, 1970. Interested persons should contact Dr G. S. Harrison, S.A. Institution of Chemical Engineers, A.E. & C.I., 15 Anderson Street, Johannesburg. METRICATION The S.A. Bureau of Standards has published a document entitled "Metric Scales and Units for use in the Building and Construction Industry." It has been compiled by the Metrication Committee of the National Building and Construction Advisory Council and is the first of the series of informatory documents relating to the programme for the metrication of the Building Act Construction Industry. This document is obtainable from the South African Bureau of Standards, Private Bag 191, Pretoria at 50c per copy.

By F. Nakhaei, A. Noury, S. Ghodrati

To achieve maximum efficiency in any purification stage, the flotation should be continued until the concentrate grade reaches the feed grade. During sampling from rougher cells of the Iranian Sarcheshmeh copper concentrator plant 1, it was revealed that the concentrate grade of the last five cells of rougher circuit was close to feed grade. Therefore, it was suggested that the concentrate of the aforementioned cells be mixed with rougher feed. In this study, one of eight rougher circuit rows was selected and evaluated. The floatability tests were performed to compare the flotation behaviour of rougher feed and mixture of concentrate of the last five cells with rougher feed in the laboratory scale by a tree analysis process. The results showed that mixing of rougher last five cell concentrate with feed has a detrimental effect on flotation efficiency that leads to a 3% decrease in recovery. It was also observed that with grinding of this concentrate, recovery can be improved. Keywords: Efficiency, flotation, rougher, tree analysis, floatability, concentrate, mixing

Jan 1, 2020

By B. M. V. Baloyi, D. Mchabe, D. Chetty

South Africa accounts for the largest global manganese ore production share, primarily from its Kalahari Manganese Field deposit. Despite this, domestic smelting is beset by energy constraints, resulting in most ore being exported for smelting. Mintek is investigating energyefficient pathways for ore reduction, specifically undertaking prereduction tests to reduce energy consumption for manganese smelting. The present contribution considers the effect of methane, anthracite, and holding time, at a fixed temperature, on the extent of reduction of Mamatwan-type ore, primarily from a mineralogical perspective. In particular, the aim was to carburise the monoxide Mn phase to Mn carbide, as this is less energy intensive than producing metallic Mn from the monoxide. Based on thermogravimetric test results, the ore and products from three experiment sets were analysed using X-ray diffraction and scanning electron microscopy to assess the phases and textures present. The findings show that carburisation of manganese monoxide and its equivalents is most advanced under conditions of 8% anthracite, 10% methane, and 60 minutes of holding time, thus confirming with the thermogravimetric data. These results show promise for reducing energy consumption for Mn smelting in ferromanganese production.

Mar 4, 2025

By J. D. T. Steyl, G. B. Grobbelaar

Two examples are presented to show how first-principles – physical-dynamic, here termed behavioural modelling, is used to build digital twins of unit processes or plant sections. A digital twin equips the metallurgist, engineer, or manager with a powerful tool to conduct model-based design, solve process problems and improve operations. It is particularly relevant in the metallurgical industry where plant behaviour is highly integrated, rates respond to particle dynamics in complicated ways and mineral flows across flowsheet boundaries are variable. The two examples used to illustrate the behavioural modelling methodology are 1) a flotation column unit block and 2) a multi-compartment pressure oxidation (POX) autoclave. It simultaneously accounts for the causality of material and heat flow, takes care of mineral particle dynamics, physical and chemical reaction rates, the plant control system behaviour and operating heuristics. The basic modelling building blocks are briefly reviewed to show how the behavioural modelling attributes constrain the mass and heat flow dynamics to physically realistic values. This is the key aspect that allows project value to be created with minimal input data. Behavioural modelling is especially valuable where the process dynamics are poorly understood or controlled, where data-driven models fail to cope with complex and highly integrated plant behaviour, where quality data is lacking or limited funds are available to generate the data required to fill all the knowledge gaps. The paper uses the flotation column example to show how behavioural modelling and simulation can be used to optimise plant performance, while the multi-compartment POX autoclave model shows how it can be used to diagnose process problems. It also provides a solid basis to add a data-driven component – in other words, it makes a strong case for a hybrid first-principle– data-driven approach to solve process problems, especially where microscopic-level understanding is poor. Keywords: Digital twin, behavioural modelling, simulation, flotation column, pressure oxidation

Jan 1, 2020

By L. Dison

This technical note is issued in two parts as follows. Part I, which appeared in the January issue of this Journal, after a brief introduction, discusses the value of patents and the law of patents, including patent applications and the exploitation of inventions. This is followed by some comments for the benefit of would-be inventors and potential users of patents. Part I focuses on the mining industry and then discusses views on patents that were quoted in Part I. The last section makes recommendations as to how inventors and users (including mining authorities) should handle patents.

Jan 1, 1992

By B. M. Wainstein

An extension of lognormal theory and its application to risk analysis models for new mining ventures by B. M. WAINSTEIN*, B.Sc., M.B.A. (Witwatersrand) (Visitor) The lognormal distribution, which remains the most popular distribution model for ore values, is investigated. The T-distribution, an integral part of this theory, is dependent on the sample size, n, and the unknown population parameter, o2, which cannot be integrated out. Hence, o2constitutes a nuisance parameter. In this study, the robustness of the T-distribution to changes in o2 is examined. It is found that the T-distribution is robust for 0,1 <= o2 >= 2,5, a domain covering most practical applications of the lognormal theory. By the use of o2 = 0,7, multiplier factors, which facilitate the computation of the confidence limits, are derived for a comprehensive set of confidence levels.

Jan 4, 1975

By T. F. Cho, B .. O. You, K. S. Yoon, K. S. Won

Discontinuity Orientation Measurement (DOM) drilling system capable of retrieving the reference line-marked core log, which can be used for determining the relative positions and orientations of discontinuity planes along the borehole axis, has been developed. Accuracy of the borehole joints data measured from the reference-lined core and, eventually, the significance and applicability of DOM drilling system for site exploration are verified by comparing with the spatial characteristics of joints investigated by implementing borehole image-taking instruments in the same borehole. Enhancement of boring efficiency has been also confirmed by performing twin drilling operations, one with DOM drilling system and the other with a conventional drilling machine equipped with D-3 core barrel, on two neighbouring sites of 5 m apart. Ein DOM(Diskontinuitätsorientierungsmessung)-Bohrsystem, das durch Grundlinien markierte Bohrprobelog extrahieren kann und die relativen Lagen und die Orientierungen der sich im Bohrloch verbreitenden Flächen bestimmen kann, ist entwickelt worden. Die Wichtigkeit des DOM-Bohrsystems und dessen Anwendbarkeit auf die Erforschung auf dem Bohrplatz werden dadurch bewiesen, dass man die Genauigkeit der Daten der Bohrlochsspalte, die durch die die Grundlinie zeichnende Bohrprobe gemessen werden, mit dem räumlichen Eigenschaften der Spalte vergleicht, die durch die Bildaufnahme des gleichen Bohrlochs nachgeforscht werden. Un system de sondage, Discontinuity Orientation Measurement (DOM), capable de récupérer des carottes markés en une ligne de référence a été dévelopé. Il peux être utilisé pour déterminer les positions relatives et les orientations des plans de discontinuité le long de l’axe de trou de sonde. Leur signification et applicabilité pour une caractérisation de site est verifiée par une comparaison de la précision des données a propos des joints mesurés a partir des carottes markés et les carac-téristigues spatiales des joints enquêtés par le camera de sondage

Jan 1, 2003

By K. R. Vost

"In situ" measurements of the surface heat transfer coefficient in underground airways by K. R. VeST,* B.Se. (Glas.), M.Se. (N.S.W.) (Visitor) Few "in situ" measurements have been made of the surface heat transfer coefficient in mine airways despite the importance of this coefficient in determining the heat flow into the ventilating air. In this paper, the values obtained at various air velocities and the comparisons of these values with theoretical values are given. Examples are also given ofthe errors which would result if rock surface temperatures were obtained by extrapolation from temperatures further into the rock without taking into account the time delay which occurs before a given change in air temperature reaches the points from which extrapolation is carried out.

By P. Kitobo, T. Nduba, D. Mbay, J. B. Vangu, R. Ciband

The flotation plant tailings at Kamoa Copper Mine concentrator were found to contain a high proportion of extremely fine particles. The potential issues with settling these fine solids were resolved by the use of a poly-di-allyl-di-methyl ammonium chloride (DADMAC) coagulant, Flobead DB 45 VHM, in conjunction with a standard anionic polyacrylamide flocculant. This paper outlines some of the issues encountered and how they were resolved at the Kamoa concentrator. The potential to use this process and technology at other sites is also considered

Jan 1, 2023

By F. M. Ramadhan, M. R. Pratama

Monitoring open-pit mine road conditions has become very critical nowadays. There are several benefits to in conducting research on this field such as opportunity to improve truck’s speed which directly influences truck’s productivity. This research aims to provide a semi real-time, and sensors-based automatic road damage detector that predicts the road quality through road damage exact location tracing, road damages auto-classification, and real-time instruction in the form of work order format to mining road maintenance, and repair authorities through mobile apps and maintenance unit’s in-cabin display. It will also provide the maintenance/repair activity performance evaluation via integrated dashboards. The artificial neural network algorithm is applied during the process of data training regarding classifying road damages and severities which resulted in a valid model. The road damage classification model has a precision level of 80.5% in predicting whether the road is damaged or not. Using this approach, we are expecting to visualise a road quality map of all active roads on mine site.

Sep 1, 2021

By M. Rudolph, A. van Hall, G. Öktem, S. G. Özkan, A. Hassanzadeh

Despite the four-decade study on ultrasound’s (US) impact on mineral’s floatabilities, there is still not clarity regarding its role in mineral surface wettability. For this purpose, the present investigation endeavours ……the hydrophobicity and floatability characteristics of a chalcopyrite-pyrite-quartz (Cp- Py-Qtz) system in the presence and absence of an ultrasonic pre-treatment. The ultrasonic process was carried out by a sonopuls at a constant frequency of 20 kHz with an adjustable power level from 30 to 200 W. Initially, the impact of sonication time (15, 30, 45, 60 and 90 s as well as 10, 20 and 30 min) and power magnitude (30, 60, 90, 120 and 180 W) were evaluated while the dissolved oxygen, temperature, conductivity and pH were also monitored. Collector-less micro-flotation tests were carried out on the non-pre-treated and the US pre-treated samples at 60 W and 15 s. The samples’ hydrophobicities were determined by the drop shape analysis approach. The dissolved-oxygen level was varied using a mini bench pressurised water reactor to study the effect of O2(aq) concentration on the chalcopyrite and pyrite wettability characteristics. The results showed that the minerals’ hydrophilicities were relatively more sensitive to the sonication’s time than its power that resulted in reducing all three minerals’ hydrophobicities. In addition, it was found that the dissolved-oxygen content and creation of sub-micron sized bubbles led to an improvement on chalcopyrite and pyrite hydrophobicities. Finally, we proved that the Cp’s floatability increased and Qtz’s recovery reduced while being subjected to the ultrasonic irradiation (15 s at 60 W); however, Py’s recovery remained constant. This conclusion confirmed the possibility of a selective separation in ultrasound-assisted copper ore flotation. We recommend that further advanced investigations be conducted, using an X-ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM) to thoroughly understand the surface modifications induced by the ultrasonication

Jan 1, 2020

By K. C. Corin, M. S. Manono

The drive to reduce water usage globally has led to the mining industry reassessing its water usage - owing to past environmental degradation due to effluent discharge, tailings disposal and process water seepage into the water-table (Haggard et al., 2015). Factors such as water scarcity and environmental restrictions have created the necessity for recycling of process water in mining and other industries. Water recycling, however, causes an accumulation of ions in the process water, which may affect the strength of reagent action on the target mineral and in turn critical aspects of flotation may be impacted. Prior studies have shown that certain ions have specific effects on flotation: for example, calcium and copper have been found to enhance the adsorption of depressant onto gangue (Feng et al., 2013, Wang et al., 2016). Calcium and sulfate ions have been seen to give a higher concentrate grade than other ions present in process water (Manono et al., 2012). An increase in ion concentration will increase the mineral grade due to a decrease in entrainment (Corin et al., 2011). This study considers the impact of ion accumulation on reagent action and flotation response. Keywords: Flotation chemistry, water quality, ionic strength

Jan 1, 2020

By J. C. Vreugdenburg, B. A. Dippenaar, J. Muller, T. L. de Vries

Iron ore fines are agglomerated in the sintering process to produce sinter: an important feed material for blast furnaces worldwide. A model of the iron ore sintering process has been developed with the objective of being representative of the sinter pot test, the standard laboratory process in which the behaviour of specific sinter feed mixtures is evaluated. The model aims to predict sinter quality, including chemical quality and physical strength, as well as key sinter process performance parameters such as production rate and fuel consumption rate. The model uses the finite difference method (FDM) to solve heat and mass distributions within the sinter pot over the sinter bed height and time dimensions. This method can further be used for establishing empirical relationships with measured sinter properties. Inputs into the model include the feed material physical properties, chemical compositions, and boundary conditions that vary over time. Sub-models describe relationships between applied pressure differential and gas flow rate through the bed of granulated fine ore particles, combustion of carbonaceous material, calcination of fluxes, evaporation and condensation of water, and melting and solidification. Four sinter pot tests were performed and the model predictions validated against temperatures measured at depths of 100, 230, and 420 mm. Differences between predicted and measured temperatures indicated the need for optimization of some model parameters that are uncertain. Optimization resulted in an improvement in the correlation between the predicted and measured temperatures for all tests, although an acceptable level of agreement was not achieved in all cases. Using these parameter values, reasonable agreement was found in terms of typical performance parameters for three out of the four tests.

Jan 1, 2014

By A. C. Lawrence

A new approach to the -study of human factors in stope productivity by A. C. LAWRENCE B. Econ., D. Com. (S.A.) (Member) The extent of the improvement in mean performance which could be achieved by reducing the variance between stoping gangs is examined, and it is shown that a worthwhile gain would result if variance were reduced by as little as 5 to 15 per cent. The problem of identifying human factors which contributed towards variance in gang performance was examined in one gold mine. A total of 342 &apos;observations&apos; on 49 stoping gangs were gathered, each observation consisting of a set of figures for 36 variables for one gang for one week. The variables included &apos;stope factors&apos; such as face length, &apos;gang factors&apos; such as the ethnic composition of the gang, and &apos;supervisory factors&apos; such as the experience of the miner. These variables were related to &apos;tons trammed per week&apos; as a measure of work performance. The findings showed that certain of the predictor variables accounted for 66 per cent of the variance in gang performance and about two thirds of this could be attributed to gang and supervisory factors, that is to the &apos;human factors&apos;. The method suggests a basis for a new approach to the identification of human factors and is a promising step towards optimizing gang performance.

By P. R. Jochens, D. D. Howat, C. W. Wolhuter

Prof D. D. Howat (Member): I am a man with a grievance this afternoon. The other authors of the paper entered into a conspiracy to ensure that I presented the paper, and finally even had the audacity to say that this was the least that could be expected from me as I had done so little of the other work. Looking at the distinguished audience here that includes some figures who have forgotten more about cement that some of us have ever learned, I realise how right the other authors were. I feel very much cast in the role of the fool who was pushed in where angels fear to tread. I hesitate to say, Sir, that I would not use the word angels in any definition of the authors of this paper. In presenting the paper, may I try to put forward a few simple points about cement that are probably as little known to the majority of the audience as they were to me-at least until very recently. Concrete, made by mixing Portland cement, sand, crushed rock and water is the most widely used constructional material in the world. Generally the production of actual Portland Cement is about two-thirds that of steel and by the time this is formed into concrete the total is about five times the world tonnage of steel produced. A very rough approximation suggests that world consumption of concrete is about one ton per person per annum. Apart from fresh water mankind consumes no other material in such quantities. What mankind originally required was a mortar to be used for joining blocks of stone or bricks. Such mortar was originally made from limestone burned in a kiln and then mixed with water. Production of mortar of this type began over 5,000 years ago. Some samples from pyramids in Egypt have shown this mortar to be in good condition although over 4,500 years old. The progress of technological development was very slow until 1824 when an English bricklayer, Joseph Aspidin, patented a new mortar material which he made by burning limestone and clay together in his kitchen stove. Aspdin called his product &apos;Portland Cement&apos; because, in colour, it resembled a well-known building stone quarried in the Isle of Portland on the south coast of England. Aspid&apos;s same types of raw materials are used today in modern cement production and the product is still referred to as Portland cement. A lime-containing material such as chalk or shell and a clay-type material such as shale, slate or clay itself, are mixed in the required proportions, ground and fed to a kiln where the minimum burning temperature is about 1,500°C. The raw materials react to form hard chunks of a material known as &apos;clinker&apos;. About 5 per cent of gypsum is added to the clinker and the mixture is then ground to a very fine powder, the function of the gypsum being to control the rate of setting of the concrete. The key oxides in cement production are lime, silica, alumina and iron oxide. The possible reactions occurring during and the products of the burning process are shown in Table I.

Jan 12, 1968