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By S. P. Kinney, A. C. Fieldner, S. H. Katz

"1 Introduction The regrettable death of James S. Cunningham, Foreman Miner, attached to Bureau of Mines Rescue Car No. 2, while wearing a half-hour type oxygen breathing apparatus in a gasoline storage tank at Trinidad, Colorado, raised the question as to the possibility of gasoline vapors permeating the rubberized fabric of the breathing bags of such apparatus.It is known that most gases and especially certain organic vapors permeate rubber, by solution or a similar process. The rubber becomes saturated with the gas and if a concentration of gas is maintained on one side of the rubber sheet it slowly gives off gas from the other side. It of course takes some time for the gas to diffuse through the rubber and the length of time before it reaches the other side is proportional to the thickness of the rubber. The amount of gas that passes through per unit of area in unit time increases with the concentration of gas and also varies with the structure and composition of the rubber.It has been suggested that the gasoline vapor could not have penetrated into the interior of an oxygen breathing bag because the pressure is greater on the inside, but this is not true as the process of permeation by solution in the rubber is affected only by the difference in the partial pressures of gasoline vapor on the inside and outside of the bag. The positive oxygen pressure on the inside can only prevent the entrance of gasoline vapor through measurable holes, and has no effect on permeation by diffusion through the rubber."

Dec 1, 1919

By W. Bruce Montgomery

Manganese oxides occur, with some iron oxides, in small scattered lenses on property controlled by the Columbia Manganese Co. (1943) near Evington, Campbell County, Va. The company mined some manganese ore during 1917 and 1918. A preliminary examination in May 1942 indicated the possibility of finding additional ore. On August 21, 1942, the Bureau of Mines began prospecting to verify the continuity of the ore exposures. Work on this project continued until February 5, 1943. Prospecting and development work included shaft sinking, crosscutting, drifting, trenching, and test-pitting in six separate areas indicating two types of deposits. The most predominant type is a wide brecciated area in which occur lenses or pockets of nodular manganese oxides. The other type is characterized by more of a vein structure, including thin layers of manganese oxides.

Jan 1, 1949

By Frank Pilotte

Proper design characteristics for a seismic system to locate miners during a mine disaster are considered in terms of a total system concept. Field hardware, processing equipment, operating personnel, deployment, training, and supportive R and D are necessary elements of the total system. Each of these elements is discussed and an indication given as to the requirements necessitated by each one. Hardware must be portable, rugged, and fieldworthy. Processing equipment must be simple to operate, expandable for future processing improvements, and ruggedized for field use. A small well-trained team must be available for quick response in times of emergency. Alternative deployment procedures are necessary to allow for a variety of situations including both ground and air delivery. Supportive R and D is used to support training and upgrading of the system.

Jan 1, 1974

By G. L. Oldright

This paper is the first of a series that is to appear on smelting in the lead blast furnace. The objects of this investigation are to determine the conditions obtaining within the blast furnace by direct experimentation, and to correlate the behavior of the furnace at various times with the main factors governing the operation of the blast furnace, and metallurgical losses. ACKNOWLEDGMENTS The writers wish to express their appreciation to the management of the International Smelting Co. at Tooele, Utah, to Mr. J. O. Elton, the general manager, and to Mr. A. B. Young, his assistant, for their broad-gauge policy that has made possible the securing and publishing of these data. For the staff at Tooele, acknowledgments are made to Messrs. B. L. Sackett, general superintendent, Carlos Bardwell, assistant general superintendent, S. Jacobsen, blast-furnace superintendent, H. M. Rockwell, assistant blast furnace superintendent, and J. O. Welsh, superintendent of the general research, for the spirit of cooperation they manifested in carrying out this work. Mr. C. Reish, a member of the research department, was detailed by, the company to assist in this' work and his whole-hearted assistance has been found invaluable.

Jan 1, 1929

By L. A. Neumeier

Sound experimental ingots of zinc alloys for use as rolling slabs were cast with a specially constructed, semicontinuous casting machine. Nominal alloy compositions of Zn-1.0 percent Cu, Zn-0.12 and 0.36 percent Ti, and Zn-1.0 percent Cu-0.03 to 0.36 percent Ti were cast. This Bureau of Mines study was conducted to evaluate the suitability of the casting procedure for providing stock for rolling into sheet. Microscopic examination of ingot sections revealed structures in which grain size varied from the outer to center ingot zones. Columnar grains present in the center zone of the Zn-1.0 percent Cu ingot were absent in the titanium-containing ingots. The ingots with titanium displayed a finer grain size and eutectic structure in the center ingot zone than in the outer zone; the transition in grain size between the two zones was quite abrupt in some ingots. The overall grain size of the titanium-containing ingots was finer than that of alloys cast by more conventional methods. Chemical analysis revealed that compositional segregation is not a significant factor in the formation of the ingot structure. Microstructural studies of small ingots of similar alloys solidified at slow, fast, and intermediate rates confirmed that the ingot structure in the semicontinuous-cast ingots is related to cooling rate, which is, in turn, related to the particular casting machine design and the influx of cooling water on the withdrawing ingots. Microstructures of thin sheet hot-rolled from slabs of the semicontinuous-cast ingots demonstrated that the ingot structure does not preclude the rolling of sheet having a uniform microstructure. Results of hardness surveys of the semicontinuous-cast ingots demonstrated that copper and titanium exert essentially additive hardening effects in these cast alloys.

Jan 1, 1968

By H. W. Wainwright

One phase of the research and development work on synthetic liquid fuels conducted by the Bureau of Mines at Morgantown, W. Va. in cooperation with West Virginia University deals with the purification of synthesis gas.2/ Most of the experimental studies on gas purification have been directed toward the removal of organic sulfur from gas, either catalytically or by adsorption with activated carbon. An important part of the purification program has been the development of suitable analytical methods for determining organic sulfur compounds. As the total sulfur content, organic and inorganic, of purified synthesis gas should not exceed 0.1 grain per 100 cubic feet, the need for accurate analytical methods is apparent. It is also apparent that such methods must be rapid if one wishes to evaluate various processes for removing sulfur from gas. The organic sulfur found in most gas produced from coal is usually present as carbon disulfide, carbon oxysulfide, methyl and ethyl mercaptans, and thiophene, with the exception of thiophene, the remaining organic sulfur compounds respond similarly to catalytic treatment and can be removed effectively. Not only does thiophene resist most catalytic treatment, but it poisons some catalysts, rendering them ineffective in removing the other forms of organic sulfur.

Jan 1, 1950

By S. P. Kinney, A. C. Fieldner, S. H. Katz

"The regrettable death of James S. Cunningham, Foreman Miner, attached to Bureau of Mines Rescue Car No. 2, while wearing a half-hour type oxygen breathing apparatus in a gasoline storage tank at Trinidad, Colorado, raised the question as to the possibility of gasoline vapors permeating the rubberized fabric of the breathing bags of such apparatus.It is known that most gases and especially certain organic vapors permeate rubber, by solution or a similar process. The rubber becomes saturated with the gas and if a concentration of gas is maintained on one side of the rubber sheet it slowly gives off gas from the other side. It of course takes some time for the gas to diffuse through the rubber and the length of time before it reaches the other side is proportional to the thickness of the rubber. The amount of gas that passes through per unit of area in unit time increases with the concentration of gas and also varies with the structure and composition of the rubber.It has been suggested that the gasoline vapor could not have penetrated into the interior of an oxygen breathing bag because the pressure is greater on the inside, but this is not true as the process of permeation by solution in the rub¬ber is affected only by the difference in the partial pressures of gasoline vapor on the inside and outside of the bag. The positive oxygen pressure on the inside can only prevent the entrance of gasoline vapor through measurable holes, and has no effect on permeation by diffusion through the rubber.A sample of gasoline was obtained from the tank in which Cunningham met his death. Examination by Dr. E. W. Dean of the Petroleum Division of the Bureau of Mines gave the following results.This shows the gasoline to be heavy and typical of the gasolines sold throughout Colorado for motor fuel A. Salvus half hour oxygen apparatus was arranged with the breathing bag only in a gas tight box in which the space was kept saturated with the vapor of this gasoline. The main part of the apparatus was outside the box. Oxygen from the apparatus was breathed by a man in the usual manner. Gas samples were taken from the box at intervals to determine the concentration of gasoline vapor, also samples of the oxygen breathed were taken from a side tube in the mouthpiece. The room temperature was 75°F. The concentration of gasoline vapor in the box at the beginning of the test was 4.3%. The man breathing from the apparatus thought he detected gasoline in his oxygen in two minutes after starting the test. Analysis of the inspired oxygen at this time showed 0.03% gasoline vapor. The same man remained on the apparatus for 18 1/2 minutes without suffering any ill effects. His place vas then taken by another man who wore the apparatus until the oxygen was exhausted without noticing more than a trace of gasoline at any time. At the end of the test the inspired oxygen contained 0.07% gasoline vapor. The total time of test was 38 minutes."

Dec 1, 1919

By J. H. Perkins

The Bureau of Mines has conducted desorption work on fine coal particles at near atmospheric pressure. An apparatus Iris been developed that uses a capacitance manometer to measure desorption of methane from coal particles up to, 2 inches in diameter and pressures up to 1,000 psi. This will make it possible to duplicate the desorption process as it occurs in its natural underground environment.

Jan 1, 1969

By F. A. Rutledge

The Rainy Creek deposits lie at the western base of the Kilbuck Mountains, about So miles southeast of Bethel, in southwestern Alaska. The deposits were brought to the attention of the Bureau of Mines by placer miners on Rainy Creek after cinnabar concentrates were recovered by their gold-mining operations. In August 1947 the Bureau excavated 1,500 feet of dozer trenches totaling 2,547 cubic yards. Further hand trenching in the bottoms of the dozer trenches on the surface totaled 1,440 linear feet, or 40 cubic yards. Nineteen samples were taken for analyses.

Jan 1, 1948

By Mark I. Copeland

The formation of A1203 dispersoids 0,14 and less in size in dilute iron-aluminum alloys by internal oxidation in wet hydrogen and dispersion strengthening of iron by application of the technique to iron powder were found to be feasible by the Bureau of Mines. In flowing H2-1.5 H20 gas, A1203 dispersoids 0.1w and less in size formed (at 650° to 750° C) in Fe-l and 2 Al sheet material but not in Fe-3 or 4 Al alloys. With higher temperatures and/or higher H2O/H2 volume-ratio gases, A1203 and FeA1204 dispersoids >0.14 in size formed in all the sheet materials- Minus 100-mesh Fe 2 Al powders were internally oxidized under conditions that promoted formation of fine A1203 particles in sheet material, and then the oxidized powders were hydrogen reduced, sintered, extruded, and evaluated. During internal oxidation, fine A1203 dispersoids formed within the powder grains, and coarse FeA1204 particles formed on the powder surfaces and grain boundaries. The FeA1204 content was essentially eliminated during sintering by reacting with the unoxidized aluminum that remained in the center of the larger internally oxidized powders. The tensile strength at 800° C depended upon the aluminum-oxygen weight ratio of these elements in the extrusions and reached a maximum of 17,000 psi. The stress-rupture strengths at 800° C of the better alloys were comparable with those of type 310 stainless steel.

Jan 1, 1972

By Edward D. Thimons

Several types of inflatable stoppings, developed under Bureau of Mines contract for use as mine air barriers during underground production, have been tested by the Bureau. All of the stoppings tested showed significant internal leakage initially but, in all but one stopping, the leaks were sealed with limited effort The stoppings were tested underground in two western noncoal mines under production conditions. The results from the Colorado molybdenum mine showed the stoppings to be generally unsatisfactory for daily mine usage if they are deployed near blasting areas or in locations where near-perfect air seals are required. They were very susceptible to blast damage and seldom were better than 90 percent efficient as air barriers. However, stoppings tested in the New Mexico uranium mine were located substantially distant from any blasting. Because slight leakage past the stoppings was acceptable, they proved very satisfactory in that application.

Jan 1, 1976

This report summarizes the work performed by the Bureau of Mines on the development of analytical procedures for determining metallic and interstitial impurities in high-purity tungsten. Fourteen published methods and seven unpublished methods are briefly described. Carbon, hydrogen, nitrogen, and oxygen, in microgram to higher quantity levels, can be determined by several methods. Trace levels of 29 metallic impurity elements can be determined by optical spectrography, X-ray spectrography, and other instrumental methods.

Jan 1, 1968

By V. F. Parry

Under the present emergency every consumer should store as much coal as he can. Although there is no shortage of coal, there is likely to be a shortage of labor to mine excessive quantities in the fall, and railroads cannot be expected to deliver coal promptly on account of the need for transporting war materials. Some miners must join the armed forces, and those who are left may be unable to mine coal as rapidly as you will need it when winter comes. When the first cold days arrive, there may be a shortage of trucks to deliver coal. Deliveries may be planned in advance, and your turn might not come until it is too late.

Jan 1, 1942

By Donald O. Capstick

In 1481, U.S. Bureau of Mines personnel conducted a survey of mines, prospects, and mineral resources in the Table Mountain RARE II area. There are no mines or active prospects in the study area. One prospect in the study area, the Waterfall Prospect, is estimated to contain 480 tons (440 t) of indicated subeconomic tungsten resources averaging about 0.18 percent tungsten trioxide (W03). Other tungsten occurrences are at the Stevens Prospect, just northwest of the area. Stone and sand and gravel deposits in the area are not considered to be resources because equal or better quality material is available closer to major markets. INTRODUCTION The 4,400-acre Table Mountain study area is 13 mi (21 km) southwest of Bishop, California, on the eastern flank of the Sierra Nevada range. The John Muir wilderness adjoins the study area on the southwest (fig. 1).

Jan 1, 1982

Flexible hoses with rated working pressures up to 40,000 psi are used when high-pressure water jets are employed to cut rock or improve the performance of mining machines. Hose failures at such high pressures can result in serious injuries to workers. The Bureau of Mines used fatigue and burst tests to investigate the failure modes of high-pressure hoses at their rated working and burst pressures. Fatigue failure, at rated working pressures, occurred when the inner liner of the high-pressure hose broke, allowing water to seep through the wire wrapping, although the reinforcement wires did not break. At the burst pressure, all hoses failed catastrophically when the reinforcement wires broke. Low-pressure hoses placed over the high- pressure hoses for safety failed to contain water released by catastrophic failure.

Jan 1, 1987

By H. Kenneth Sacks

The Bureau of Mines has developed hardware for electromagnetic (EM) detection and location of miners trapped in underground coal mines. This report describes a technique for using the developed equipment for locating uncased boreholes underground. Results of several field and laboratory experiments are described.

Jan 1, 1978

By H. C. Loesche

The problem of signaling to the hoisting engineer from the cage in a shaft mine has been given considerable thought and attention by engineers and mine operators seeking to Increase the safety and efficiency of hoisting. HISTORY R. L. Rutherford,3/ an employee of the Magma Copper Co., Superior Ariz., realizing the need for a simple and practical moving-cage signaling system, began a serious of experiments early in 1937, Available electrical moving-cage signal in operation at this date required that signal wires be installed in the shaft to make a simple, positive signal without wires, the first experiments used the pipe lines in the shaft for carrying the signal current, but these experiments were not successful.

Jan 1, 1945

By Richard L. Sayrs

"The Stiner zinc prospect near the north boundary of Union Tennessee, and the Bunch Hollow property 5 miles northeast in Claiborne County, Tennessee, were diamond-drilled by the Bureau of Mines during the period .September 1, 1944, to February 22, 1945. Seventeen holes totaling 5,687 feet were completed, 13 of which, totaling, 5.083 feet, were on the Stiner property and the remainder, totaling 604 feet, at Bunch Hollow.The Stiner prospect is about 1 mile east of the old workings known as ""New Prospect"" or ""Lead Mine Bend."" The Federal Geological Survey made a study' of the area early in 1944. The prospect was first visited in August 1944 by Bureau of' Mines engineers3/ accompanied by members of the Federal Geological Survey.4/ The locality is reached by traveling State Road 33 north-about 9 miles from Maynardsville, Tenn., thence northwest about 7 miles by an improved county road that leads to the mine (fig. 1). The tract comprises an area of about 181 acres held by G. S. Stiner of Sharps Chapel, Tenn.; it is now under option to the Universal-Exploration Co. of Jefferson City, Tenn.The Bunch Hollow property, about 5 miles northeast of the Stiller prospect, was also studied by the Federal Geological Survey previous to being;Visited by Bureau of Mines engineers in August 1944. It is reached by traveling north from Maynardsville, Tenn., on State Road 33 about 13 miles, thence northwest by county road 6 miles to the property (fig. 1). The last 3 miles of the county road are in poor repair but are passable during the entire year. The property comprises an area of approximately 300 acres and is held by the imperial Mining Co., Pressman's Home, Tenn.Few reliable data are available as to the history of the Stiner prospects themselves. However, the New Prospect mine, 1 mile west, has had a colorful past, This mine was opened in 1883 and was worked intermittently until 1918, by which time more than 65,000 tons of concentrates had been shipped. No further work was done until 1942, when the mine pillars were robbed and 1,900 tons of ore averaging 25 percent zinc was shipped to the New Jersey Zinc Co., Austinville, Va."

Apr 1, 1946

By David F. Smith

The American Society for Testing Materials4 has recommended that the melting temperature of potassium chromate be used-for indicating the temperature to which a coal sample should be heated in the standard method of analysis to determine its volatile matter content. The specified temperature is 950± 20° C., the melting point of potassium chromate being noted as 940° C. Le Chatelier5 originally found the melting point to be 975°; later6 he found 9400. According to Shemtschushny7 the melting point is 984°; he also found a transition at 679°. Groschuff8 found the melting point to be 971° and the transition temperature 679°. Amadori9 reports a melting point of 9.78° and a transition point of 666°. The International Critical Tables10 take the melting point as 975°, which is estimated to be correct to two significant figures. In view of the apparent uncertainty existing, it has been though worthwhile to make a careful redetermination of this datum. It is of interest not only to determine the melting point of the pure salt, but also of the commercial product, in order to test its suitability for use as a temperature indicator. The work was suggested by A. C. Fieldner, chief engineer, experiment stations division, U. S. Bureau of Mines.

Jan 1, 1929

By R. L. Schmidt

Research conducted over the past 20 years in France, Great Britain, and the United States on the use of the large-hole burn cut has established cer¬tain advantages for this system. Advantages include longer pull and more complete fragmentation from blast rounds. However, research is needed to establish a set of parameters for optimum performance. As part of the Bureau of Mines Advancing Mining Technology for Marginal Resources program, the Twin Cities Mining Research Center, Twin Cities, Minn., acquired a horizontal rotary drill capable of boring holes up to 24 in. in diameter. This was used for a series of underground experiments at White Pine mine, White Pine, Mich., during 1973. Exceptional results were obtained with a 12-1/4-in void hole that yielded up to 18 ft of pull in a 10- by 20-ft drift, Fragmentation was excellent, and the compactness of the muck pile facilitated loading.

Jan 1, 1975