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By Russell E. Griffin

Dielectric constants and dissipation factors were measured for six rocks over the 20-to 100-megahertz frequency range by means of the susceptance-variation method. Results for both dry and moist specimens are presented and compared with data reported by others. Loss factors calculated from the data presented are important to the Bureau's study of rock fragmentation by means of dielectric heating.

Jan 1, 1967

By Lon Santis, Scott Deitchman, John A. Decker

This report describes three cases of carbon monoxide (CO) poisoning in a manhole, including one fatality, from CO migrating through soil after nearby use of explosives. A municipal sewer project involved installation of new pipes and manholes. Work of the general construction contractor was interrupted when a subcontractor detonated 265 pounds of nitroglycerin-based explosive 40-60 feet south of the manhole to break up underlying rock. A construction worker who descended into the manhole 45 minutes after the explosion collapsed within minutes, and two co-workers descended into the manhole to rescue him. One rescuer retrieved the unconscious worker, and the other rescuer died in the manhole. All workers had elevated carboxyhemoglobin levels. In the subsequent NIOSH investigation, air monitoring was conducted with real-time instruments, and air samples were collected in Tedlar bags. Laboratory analyses of the bag samples collected near the bottom showed 1905 parts per million (ppm) CO, 19.5% oxygen, and 3% carbon dioxide. Direct reading instruments showed progressively higher concentrations as the sensor was lowered into the manhole. Subsequent chamber tests on sample explosive yielded 27 liters CO per kilogram detonated. Based on this value, the surface blast at the construction site may have produced about 3,250 liters (114.8 cubic feet) CO. The CO in this incident most likely was released from the nearby explosion and migrated through soil and fractured rock into the manhole. The blasting and construction industries should be made aware of this previously unrecognized CO exposure hazard associated with surface blasting. The extent of CO exposure from explosives used in construction is not known, and additional information on the extent of CO exposure must be collected. In addition, confined space entry procedures (including monitoring confined space atmospheres before entry) should be observed; CO monitoring of confined spaces in the presence of blasting can prevent future incidents such as this one.

Oct 30, 1997

By Robert F. Chaken

The National Institute of Occupational Safety and Health (NIOSH) is dedicated to achieving "safety and health at work for all people -- through research and prevention." An important procedure in pursuing this goal is the NIOSH surveillance studies where the number of injuries are monitored according to demographic, employment, and injury characteristics. These numeric data are then used to identify injury risk factors, develop safety programs, and monitor implemented remediation methods. In essence, ongoing surveillance data form the bases for directing the resources of NIOSH in setting of research and prevention priorities, and in evaluating safety procedures. This surveillance techmque, which is based on the Public Health Service approach to identification and control of disease (1, 2, has been used quite successfully in dealing with relatively high number injuries such as hearing loss, musculoskeletal disorder, respiratory disorder, falls, etc. (2). However a problem arises when extending this paradigm to lower frequency traumatic events; particularly those often referred to as disasters (i.e., high impact events like mine explosions, airplane crashes, etc.). One can ask the question - there hasn't been a coal mine fire fatality in the U.S. for over ten years, to what extent should we be concerned with mine fire safety (resource-wise)? - The National Traumatic Occupational Fatalities (NTOF) system (4J which NIOSH uses to survey occupational fatalities annually, would suggest that underground mine fires would not be a high priority item in occupational safety. Yet, miners' (i.e., the exposed workers) do consider mine fires and explosions to be major safety concerns. I believe that we need to rethink our evaluation of work place disasters, what is worker exposure, and what are the underlying assumptions (both explicit and implicit) as to the impact that economic, societal and degree of hazard factors make on risk evaluation. The answers to all these problems, will require much broader considerations than those in current surveillance safety and health models. This paper discusses some facets of those considerations.

By John J. Sammarco

Computer-related accidents have caused injuries and fatalities in mining as well as other industries. Normal accident theory (NAT) explains that some accidents are inevitable because of system complexity. NAT is a classic argument in organizational sociology although it has been criticized as having imprecise definitions and lacking criteria for quantifying complexity. These limitations are addressed by a unique approach that recasts this organizational theory into an engineering-based methodology to quantify NAT complexities of computer-based systems. In this approach complexity is categorized as external or internal. External complexity is defined by the external behavior of a system, and is quantified by these dependent variables: system predictability, observability, and usability. Dependent variable data contain the perceptions of 32 subjects running simulations of a system. The system?s internal complexity is characterized by modeling system-level requirements with the software cost reduction (SCR) formal method. Model attributes are quantified using 15 graph-theoretical metrics?the independent variables. Five of 15 metrics are correlated with the dependent variables as evidenced by structure correlations exceeding 0.25, with standard errors <0.10 and a 95% confidence interval. The results also show that the system predictability, observability, and usability decreased as NAT complexities increased. This research takes a step forward in operationalizing NAT for computerized systems. The research benefits mining and other industries as well.

Jan 1, 2005

By G. W. Birge

The Bureau of Mines investigated the effect of temperature on the mechanical strength of cokes of the type normally used in blast furnace operations. Eight samples of industrially produced cokes were subjected to ASTM tumbler tests at temperatures as high as 1,100° C (2,012° F); these temperatures had no significant effect on tumbler results for cokes with stability indexes of 40.6 to 59.9. Two foundry cokes which were tested at only one elevated temperature (900° C) decreased slightly in tumbler stability. Iron are pellets made from a variety of ores and by various industrial methods were not significantly affected by temperature when tested in an oxidizing atmosphere at 1,000° C (1,832° F) by the tentative standard ASTM method.

Jan 1, 1966

By Irving Hartmann

Modern mechanized mining with high-speed machines, multiple-entry systems, multiple blasting, high-velocity air currents, and rapid haulage has brought many economic benefits and has on the whole enhanced safety in the coal-mining industry. It has, however, also introduced some added hazards, the control of which requires concerted effort and ingenuity. Mechanized mining has greatly increased the production and dissemination of fine coal seam or in mine entries. Use of high-speed machines has increased the probability of formation of incendive sparks, which are produced by frictional contact between moving metals and certain mineral substances in the coal seam or in the adjoining rock strata. In gassy seams rapid extraction of coal has increased the rate of gas evolution. These facts have made more urgent the need of preventing the ignition of coal dust and the development of widespread mine explosions. The ignition hazard can be controlled best by eliminating all potential igniting sources and by careful attention to ventilation designed to prevent accumulation of gas capable of triggering a coal-dust explosion. Frictional spark ignition by mining machines and suggested safeguards are discussed in a recent publication. Extensive research and long experience have shown conclusively that the propagation of coal-dust flames can be arrested and the development of widespread explosions prevented by properly applied, generalized rock dusting.

Jan 1, 1956

By Sidney Katell

This report is an economic evaluation of the production of hydrogen in a continuous system by the steam oxidation of partially reduced iron oxide in a fluidized bed at 7 atmospheres using producer gas to reduce the iron oxide. The oxidation-reduction step is based on experimental data obtained by the Bureau of Mines at the Pittsburgh Coal Research Center. The estimated capital requirement for a plant producing 30 million std. c.f.d.3 of 99.8 percent purity hydrogen at a discharge pressure of 450 p.s.i.g. is $13,100,000, using January 1961 equipment cost data. Based on a 330-day operating year, the operating cost before profit and taxes with coal price as a variable is estimated to be:

Jan 1, 1962

By Leslie H. Sharp, Martin J. Gavin

Those of the oil-shale operators in this country who are sincerely attempting to make a real industry out of oil-shale developments, are anxious to obtain fundamental data on the retorting of oil-shale; particularly as regards the effect of certain variable factors in the process of retorting on the quantity and quality of products yielded from oil shales when they are subjected to destructive distillation. From careful examination of a con siderable number of suggested processes for treating oil shales and the con flicting ideas on which they are designed, it seems probable that accurate information of a fundamental nature is highly essential to the successful establishment of an oil-shale industry in this country. . Accordingly, the United States Bureau of Mines, in cooperation with the State of Colorado, is undertaking to furnish some definite and impartial information of this type through investigations now under way at the University of Colorado, Boulder, Colo. A retort for the distillation of oil from oil shale has been designed and installed, together with the necessary auxiliary equipment for controlling and determining variable factors of distillation, and for recovering and de termining the quantity and quality of the products yielded from the shales. The retort is of such a nature that conditions of retorting can be accurately . and completely controlled, and varied at will. It is not designed as a com mercial retort, but only for research purposes. A testing laboratory with equipment necessary for the examination of the shales, physically and chemic ally, and the products yielded by them, has also been fitted up . The material used in the investigations is oil shale obtained from the DeBeque, Colorado, shale field. It yields on distillation in the Bureau of Mines testing apparatus, about 42 gallons of oil to the ton, and is there fore a fairly representative sample of the shales that probably will be first worked in Colorado. The shale used will be as uniform as possible in character and oil yield and will all be obtained from the same seam at the same point, in order to avoid the introduction of unnecessary variable factors in the tests and to render results strictly comparable •

Jul 1, 1920

By R. V. Ramani, P. M. T. White, D. Sutton

4.1 Introduction Using methods outlined in previous sections of this report, programs were written and/or obtained to: i) select best combinations of "a" and "k" for up to 8 different value parameters, ii) calculate available and unavailable ore tonnages and other statistics, and iii) produce contour maps of various parameter characteristics and available tonnages on a line printer. All the above programs are written in Fortran IV for execu¬tion on IBM 360/370 computers. 4.2 Calculation of Coal Reserves The Ore Reserve program suite consists of the following sections: (a) UNIT 1: This unit is a subroutine called by Unit 2 to determine values for "a" and "k" from the given data. (b) UNIT 2: These programs calculate ore reserves and are composed of a main program and several sub¬routines. In the following, their functions are abbreviated: i) MAIN - calls subroutines, reads run parameter variables, reads borehole data and interpolates grid node values for the area of investigation

Jan 1, 1974

By Richard J. Mainiero, Sapko, Marcia L. Harris

Since 1988, there have been thirteen documented incidents in the United States and Canada in which carbon monoxide (CO) is suspected to have migrated through near surface strata into structures or other enclosed spaces as a result of nearby trench blasting or surface mine blasting. From these incidents, there are thirty suspected or medically verified CO poisonings and one fatality associated with these incidents. To better understand the variables contributing to this hazard, the National Institute for Occupational Safety and Health (NIOSH) carried out a small-scale field study to identify key factors that may contribute to the migration of CO through the ground. NIOSH conducted single-hole heavily confined experimental test shots to measure the radial pressure pulse as it propagated through surrounding monitoring holes to determine if a relationship existed between the pressure pulse and resulting CO measurements afterwards. NIOSH also monitored blasts at an airport construction site. Following the detonations, the concentrations of CO, nitric oxide (NO), and nitrogen dioxide (NO2) were monitored for several days in the surrounding satellite holes. The peak CO measurements relative to distances from the shots were compared. Pressure histories and peak particle velocities (PPV) were measured at monitoring boreholes. It was found that the differential pressures recorded within the boreholes give some indication as to the likelihood of CO appearing, whereas the PPV measurements do not seem to be as good an indicator for potential CO migration. In this limited study, changes in barometric pressure had very little influence on removing the trapped detonation products, whereas applying a vacuum to the monitoring holes was effective in reducing the entrapped CO concentration.

By Ruth F. Brinkley

This report is the 17th of a series originally issued annually, and more recently bienially, to acquaint the reader with the work of the Division of Explosives Technology, Federal Bureau of Mines. It differs from preceding reports in that its material is presented in two parts: Part I reviews briefly the overall activities of the Division during fiscal years 1955 and 1956;4/ part II presents in abstract form, the publications of the Division during that period. As it is not unusual for research completed in the course of one report period to be published only in the following period, the Bureau believes that the present approach will give a more accurate presentation of its work for the period considered. The Bureau hopes too, that the somewhat more concise presentation will prove convenient to the reader.5/ PART I -RESEARCH AND TECHNOLOGIC ACTIVITIES The activities of the Division during fiscal years 1955 and 1956 reflected the steadily growing preoccupation with factors affecting the safety of permissible explosives and those affecting the tests used for approval of these explosives. Findings by a team of French investigators prompted a study of the influence of atmospheric moisture on the ignition of firedamp by

Jan 1, 1961

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Jan 1, 1997

By Wing G. Agnew, John A. Johnson, McHenry Mosier

"INTRODUCTION AND CONCLUSIONSThe first three reports of investigations 5/ in this series, pertaining to the investigation of stemming at the Mount Weather Testing Adit dealt with the dust produced by blasting, the effect of stemming on gases generated by blasting, and the relative advantages and disadvantages of different types of stemming and no stemming when used with 60-percent ammonia gelatin dynamite.This report covers an investigation of the length of stemming material through which a primer will fire and detonate a charge of dynamite, such as a missed hole.The practice of drilling a new hole a foot from a missed hole to blast out the missed hole should be prohibited. It is dangerous, as is evidenced by the number of miners killed through drilling into missed holes. It is even more hazardous in a mine on a multiple-shift basis, in which the same miners do not drill succeeding rounds."

May 1, 1942

By R. H. Lien

The Bureau of Mines, U.S. Department of the Interior, has developed a flue gas desulfurization process as part of its goal of minimizing the undesirable environmental impacts associated with energy and mineral-processing plants. This process, known as the citrate process, involves absorption of sulfur dioxide (SO2) in a buffered solution of citric acid. The S02-loaded solution is regenerated by reaction of the S02 with hydrogen sulfide (H2S) to form elemental sulfur. As an adjunct to the citrate process, bench-scale research has shown that S02-loaded citrate or glycolate solutions can be regenerated by countercurrent contact with steam (stripping) in packed towers. Concentrated S02 is produced by condensing the steam from the stripper product. Thus, steam stripping provides strong S02 gas for liquefaction, sulfuric acid production, or reduction to elemental sulfur. Stripping steam requirements were determined for treatment of 0.25-, 0.50-3 1.0-, and 2.0-pct-S02 waste gases. Steam requirements decreased with increasing S02 concentration n the simulated waste gases. For example, 5 grams of steam per gram o S02 was required to remove 90 pct of the S02 from a simulated copper smelter gas (2.0 pct S02), while 30 grams of steam per gram of S02 was needed for 90 pct S02 removal from a simulated coal-fired powerplant gas (0.25 pct S02).

Jan 1, 1979

By Richard J. Mainiero

The U.S. Bureau of Mines in cooperation with Jim Walter Resources, Inc. (JWR), Brookwood, AL, evaluated the use of sheathed explosive charges in breaking up large stones that can jam the feeder¬breaker or pan conveyor on longwalls and halt operations. Use of the sheathed charge reduced the downtime of the longwall panel to 15 to 30 min as compared with the 1 to 2 h required to drill and shoot the stone. Firing the sheathed charge at the face caused no significant damage to Iongwall equipment. Use of the sheathed charge also represented an improvement in safety by eliminating the exposure of miners to the inherent hazards of the face for extended periods of time. Another benefit, which is difficult to quantify, is the elimination of the temptation to shoot mudcaps or adobes, which is illegal in U.S. underground coal mines.

Jan 1, 1990

By C. J. Thompson

In the course of the work currently conducted by the Bureau of Mines in cooperation with the American Petroleum Institute Research Project 48 on identifying sulfur compounds in petroleum, a micromethod was developed (12)5 for catalytically removing the sulfur atom from sulfur compounds. The product is the residual portion of the molecule; the structure otherwise was unaltered except for hydrogenation of any unsaturated bonds that were present in the original compound. Positive identification of sulfur compounds isolated from crude oils is a difficult problem. Direct comparison of properties of the unknown with those of reference compounds is often impossible because of the limited number of reference sulfur compounds available. However, a relatively large number of pure hydrocarbons is available, and the conversion of the sulfur compound to a hydrocarbon enhances the possibility of identification. The technique also can be used to prepare microquantities of scarce hydrocarbons by hydrogenating compounds that are readily available.

Jan 1, 1962

By John P. Powell, J. L. Eakin

"INTRODUCTION AND SUMMARYNowata County, in the northeast corner of Oklahoma, is one of the principal oil-producing counties of this stripper area. Many fields in the county were opened and much oil was produced before statehood. The location of the major fields, as defined by the Oklahoma Corporation Commission, 2/ the outline of the areas of water-flooding activity, and the location of the several projects described in detail in this report are shown in figure 1.There was some drilling in the county earlier; but it was not until after 1904, when the Secretary of the Interior confirmed as valid the leases granted by the Cherokee Nation, that the major drilling activity began. Initial development in this part of Oklahoma was in the Chelsea field in Rogers County, which adjoins Novata County on the south. The activity spread rapidly northward to the Alluwe and Coody's Bluff fields, and then to the Nowata-Claggett field. Continued exploration resulted in discovery of the Delaware-Childers field, where some wells having an initial production of 1,000 barrels daily were completed. Fields discovered and developed during the next few years included the Lenepah (Elliott), Adair, California Creek, Curl Creek, Woody, and South Coffeyville. The oil-production history of Nowata County is shown in figure 2. In assembling the data for a production curve, it was found that the combined production records for Nowata and Rogers Counties were available for 1914 to 1951, inclusive, and that records for the individual counties were available only from 1926 to 1951, inclusive. The early production figures for the counties from 1905 to 1914, inclusive, except for 1909, were calculated from the initial production statistics of the Federal Geological Survey mineral resources bulletins and production data assembled by C. H. Beal. 3/ The production values for 1905 to 1926 for Nowata County were obtained by dividing the total production for the two counties by a percentage factor derived from known facts regarding the oil industry in the area. Production figures for the individual counties from 1926 to 1933, inclusive, were obtained from the files of the Oil and Gas Journal, and the figures from 1933 through 1951 were obtained from monthly reports of the Oklahoma Corporation Commission."

Jun 1, 1952

By Alice V. Peter

Meerschaum or sepiolite is employed principally in tobacco pipes and cigar and cigarette holders, although a few other uses of minor importance are Down. The unique value of a meerschaum pipe is derived from the owner&apos;s pleasure in watching the color deepen with smoking and in having the color "set" at the desired shade. The name "meerschaum" (German for "sea foam") is applied because the material, when pure and dry, will float on water. Owing to its resemblance to the porous, bonelike structure of the cuttlefish, or septa, it is also known as sepiolite. There are a few scattered deposits of meerschaum in. the United States which have yielded a small product ion, but the world&apos;s supply of the&apos; material is obtained fined principally from Asia Minor, Meerschaum deposits near Eski-Shehir, Turkey, are said to have been worked 2,000 years ago, but commercial exploitation is a development of the last hundred years DESCRIPTION AND PROPERTIES Meerschaum is a hydrous magnesium silicate (H4Mg2Si3010) having the following theoretical analysis: Si02, 60.8 percent; MgO, 27.1 percent; H20, 12.1 percent. It is a soft. (H.2 - 2.5), fine-grained, earthy, white, gray, or yellow material. It is very light weight when pure (specific gravity, 1 to 2) and is highly absorbent. Because of its porosity the proportion of water present in the mineral is affected by the humidity&apos;of the atmosphere. In a moist atmosphere the water content may be as much as 21.7 percent. Then wet the material is soft and somewhat plastic. When dried again it becomes lard and tough. The toughness is especially apparent in some forms that have a fibrous or leathery texture.

Jan 1, 1934

By M. G. Zabetakis

Amyl nitrite (C5H11NO2) is a pale-yellow liquid with an ethereal fruity odor and a pungent aromatic taste. Its use in first-aid treatment of cyanide poisoning has been suggested by Chen and his coworkers. Although not the most effective treatment, it is the only one that does not require intravenous injections and is, therefore, very suitable as a preliminary measure, which only involves breaking a capsule near the patient&apos;s nose until intravenous injections can be given. In the case of the sodium nitrite -sodium thiosulfate treatment, for instance, such injections require about 15 minutes. As amyl nitrite "Pearls" (small capsules containing liquid amyl nitrite) are placed in many first-aid kits by various companies that handle, store, or use hydrogen cyanide gas, it appeared advisable to investigate the explosion hazards of this material in air and oxygen. Accordingly, tests were made to determine the limits of flammability, temperature range of flammability of amyl nitrite saturated with air and with oxygen, and minimum ignition temperatures of this material in air and in oxygen.

Jan 1, 1952

By Jr. Driscoll

The thermoelectric properties of yttrium monoarsenide, yttrium monoanti-monide) and ternary materials from the Y-As-Se and Y-Sb-Te systems were investigated by the Bureau of Mines from room temperature to 1,000° C. The maximum calculated figure of merit for yttrium monoarsenide and yttrium monoantimonide was 2 x 10-5 ° C-1. YAs and YSb were semimetallic conductors with low Seebeck coefficients and electrical resistivities. The values of the Seebeck coefficient and electrical resistivity of the Y-As-Se and Y-Sb-Te materials were between those of the yttrium selenides and tellurides and of YAs and YSb, respectively. The maximum power factor calculated for the Y-As-Se materials was 2 X 10-5 watt/cm ° C2 which yielded an estimated figure of merit of 6 X 10-4 0 C-1. Most of the Y-As-Se compounds had high Seebeck coefficients and moderately low electrical resistivities. The Y-Sb-Te materials were degenerate semiconductors with power factors of 6 X 10-8 watt/cm ° C2.

Jan 1, 1967