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A study was conducted by the Bureau of Mines to evaluate natural gas as an automotive fuel and to provide guidelines for optimum engine adjustments for low exhaust emissions. The study was conducted using a single-cylinder engine, a multicylinder engine, and a total of eight vehicles. Results from single-cylinder engine tests showed that the light-load, lean-limit misfire region for natural gas begins at an air-fuel ratio between 150 and 160 pct of stoichiometric. Changes in ignition timing significantly influenced emissions of nitrogen oxides and hydrocarbons, but had little effect on carbon monoxide emission. Low emissions can be achieved with current-design engines by adjustment of engine parameters, but only with heavy penalty to engine performance. Emissions from vehicles fueled with natural gas are virtually unaffected by ambient temperature change within the range 20° to 100° F. The organic emissions from engines fueled with natural gas were estimated to be 22 to 25 pct as reactive as the emissions produced using gasoline. Levels of exhaust emissions from vehicles fueled with natural gas were unchanged over 10,000 miles of normal driving.

Jan 1, 1973

By Kenneth J. Miller

The Federal Bureau of Mines coal-pyrite flotation process has been modi¬fied to produce a concentrated final clean coal slurry underflow that could be dewatered more effectively by filtration or centrifugation. This change was accomplished by redesigning the Bureau's two-stage flotation pilot plant facility and running the second-stage flotation step with undiluted or only partially diluted first stage coal froth concentrate. Results of the pilot plant flotation tests showed that substantial sulfur reduction could be achieved by flotation with undiluted pulp but some dilution is recommended for maximum selectivity. For example, coal-pyrite flotation in slurry of 25 percent solids yielded clean coal products analyzing as low as 0.7 percent pyritic sulfur and froth reject products containing slightly over 3.0 percent pyritic sulfur. In comparison, coal-pyrite flotation with pulp diluted to about 12.5 percent solids yielded clean coal containing as low as 0.4 percent pyritic sulfur and froth reject of 5.6 to 6.7 percent pyritic sulfur. Despite the need for some dilution, it was concluded that excellent coal-¬pyrite flotation selectivity could be achieved without diluting to 6 or 7 per¬cent solids as done in the earlier work. Thus the economics of coal-pyrite flotation would be improved by easing clean coal dewatering problems and by reducing second-stage flotation cell volume requirements.

Jan 1, 1977

By Jr. Karr

The Bureau of Mines studied the influence of carbonization method, temperature, and carrier gas on the composition of eight different low-temperature tars produced from a Colorado subbituminous coal. A fluidized bed was compared with an entrained bed, temperature was varied from 500° C to 650° C, and external heating using recycle gas as the carrier gas was compared with internal heating using oxygen-containing gas. The entrained bed yielded significantly more m-cresol and m-ethylphenol, indicating that thermodynamic equilibrium was more nearly approached in the system. Increasing the temperature greatly increased the yield of benzenes and naphthalenes, while paraffins, olefins, and total tar acids were reduced. Using oxygen in the carrier gas decreased the yield of low-boiling phenols and increased that of paraffins and olefins at 650° C.

Jan 1, 1966

By Carlton E. Brown

Impinger dust-counting methods are used by industrial hygienists for determining the number concentration of unhygienic siliceous dusts in industrial atmospheres. Various statements have been made regarding the size of the smallest particles revealed by the microscopic employed in such determinations. Published data on the subject are quite limited. This report presents information on the size of the smallest particles revealed by light-field and dark-field techniques applied to impinger and electric precipitator samples collected from experimentally established aerosols of silica dust and bituminous-coal dust. Size distribution and number concentration of particles of the various sizes in the aerosols were determined from samples collected by thermal precipitation simultaneously with the impinger and electric precipitator samples. The size of the smallest silica and bituminous-coal dust particles determined in the light-field counting method used was about 1./1, . There was relatively little variation in the values from 8 impinger and 33 A.-C. precipitator samples of silica dust and 13 impinger and 13 A.-C. precipitator samples of coal dust. The coefficients of variation of the values from the four sets of determinations were low, ranging from ± 7.7 to t 10 percent. This size of 1,14 is close to the limit of resolution of the microscopic method used and to various previously suggested values. The size of the particles determined in the dark-field counting method used was smaller than the size (about 0.28A ) of the smallest particles determined in the light-field, oil-immersion method used for the thermal precipitator samples.

Jan 1, 1951

By H. Stuart Auvil

Twelve samples of run-of-oven coke were taken at coke plants in the United States and Canada. Sampling procedure was directed toward obtaining the highest possible degree of uniformity in the gross samples, so that variations in results caused by sampling variations were at a practical minimum. Under these conditions the standard deviation of the screen analysis test on 500-pound samples is found to range from 1.2 percent for the 1-inch screen to 4.5 percent for the 5-inch screen. At present, the A.S.T.H. standard method of test requires that results be reported to the nearest 0.1 percent. This implies a higher than actual degree of precision, and revision of the report required by the method is suggested. Much larger Samples than are generally tested are required to reduce normal testing errors to a point where they are not appreciable fractions of the total variations found in a smoothly operating plant. For example, it is deduced that over 100,000 pounds of coke must be screened to determine if ordinary day-to-day variations in screen analysis have appreciable effects on the performance of a blast furnace.

Jan 1, 1950

By G. W. Jones

[As a part of its investigations pertaining to the promotion of safety, the Bureau of Mines is investigating various means, useful for the elimination or mitigation of the explosion hazards of combustible gases encountered in mining and industry. Information has been obtained and a procedure developed whereby the explosibility of many complex, gaseous, combustible atmosphere may be calculated in a simple manner without the necessity of performing laborious laboratory experiment. In a previous publication4/ data were given and a method described whereby the limits of inflammability of gaseous mixtures, including methane, hydrogen, carbon monoxide, nitrogen, carbon dioxide, and oxygen, could be determined by calculation. The information published in that retort enables one to calculate the limits of inflammability of such gases are liberated by mine fires, gases from explosives, automobile exhaust gas, gases present after mine explosions, blast-furnace gas, and other gases containing part of or all of the above-listed constituents.]

Jan 1, 1938

By G. W. Jones

As a part of it investigations pertaining to the promotion of safety, the Bureau of Mines is investigating various means, useful for the elimination or mitigation of the explosion hazards of combustible gases encountered in mining and industry. Information has been obtained and a procedure developed whereby the explocibility of many complex, gaseous, combustible atmospheres may be calculated in a simple manner without the necessity of performing laborious laboratory experiments. In a previous publication4/ data were given and a method described whereby the limits of inflammability of gaseous mixtures, including methane, hydrogen, carbon monoxide, nitrogen, carbon dioxide, and oxygen, could be determined by calculation. The information published in that report enables one to calculate the limits of inflammability of such gases as are liberated by mine fires, gases from explosives, automobile exhaust ran, uses present after mine explosions, blast-furnace gas, and other gases containing part of or all of the above-listed constituents.

Jan 1, 1938

By G. T. Fisher

The U.S. Bureau of Mines conducted research on calcium ferrite slags to determine the distribution of Pb and minor elements (Ag, Cd, Zn, and Co) between Pb bullion and slag. These fundamental data are required to evaluate nonferrous smelting with calcium ferrite slags as a substitute for conventional iron silicate slags. Determinations were made in 25-cm3-capacity MgO crucibles at 1,250° C for 2 h in a CO-CO2 atmosphere with an O2 potential that would retard the formation of magnetite. Calcium ferrite slag composition variables studied were from 16 to 32 wt pct CaO in 2-pct increments and Si02 ranging from 1 to 5 wt pct in 1-pct increments with equal additions of MgO. For all compositions studied, the retention of Pb in the calcium ferrite slag was less than 1 wt pct, which compares favorably to about 6 wt pct Pb in conventional iron silicate slags used in smelting of Pb concentrates. Minor element distribution was insensitive to changes in slag composition in the range studied. However, slag composition had significant impact on the melting and fluidity of the slag.

Jan 1, 2010

By L. T. MCELVENNY, Robert B. McElwaine, M. Clair Smith

Production of mercury from the cinnabar deposits of the southwestern Arkansas mercury district began in 1931 , reached its peak in 1942 , and ended in 1944. The mines are now idle . Virtually all the cinnabar was obtained from deposits in a belt , about a mile wide , of steeply dipping sandstone beds in the overriding blocks of three thrust faults . The belt was productive for a length of about 27 miles eastward from eastern Howard County, through Pike County, into Clark County . During the early life of the district, Federal agencies watched and recorded its progress as a contributor of a strategic metal, and later, during the war, conducted investigations designed to advance its development . In 1941 , the Bureau of Mines and the U. S. Geological Survey cooperated in investigations on eight mineralized areas in the western part of the district , to wit : Hales mine , U. S. mine , Lulu Bell property, Hopkins Hill , East Gap Ridge , Gap Ridge , Parnell Hill , and Section 17 mine area . U. S. Geological Survey prepared both surface and mine maps and designated the areas to be investigated ; the Bureau did the drilling , trenching, and sampling involved in the investigations . Twelve holes , aggregating 3,539 feet of bore , were diamond drilled on six properties ; 5,309 linear feet of surface trenches were bulldozed in six areas and 19 samples taken from them ; and 86 underground channel samples were cut in two adits on one property . In 1944 , the Bureau of Mines measured mine dumps and calcine dumps in the district in an investigation of their mercury content . Two mine dumps and one calcine dump were sampled . The data pertinent to the work done by the Bureau are included in this report .

Oct 1, 1950

By Murray Jacobson

Data obtained by the Federal Bureau of Mines on the dust explosion hazard in air are presented for 220 samples of agricultural products. Information is given on ignition temperature of dust clouds and layers, minimum explosive concentration, minimum electrical energy for ignition, explosion pressure and rates of pressure rise, amount of inert dust required to prevent flame propagation, and, in a few instances, the permissible oxygen concentration in an atmosphere to prevent ignition by spark and by heated surface. The effects of particle size and source of sample on explosibility are shown. The relative ignition sensitivity, severity of explosion, and overall explosibility of the materials are characterized by empirical indexes. This report contains Ma obtained by the Bureau in laboratory studies on the explosion hazards of agricultural dusts. Recognition of the dangers will encourage adoption of adequate measures to prevent ignition and explosion during preparation, processing, and utilization of the materials. Agricultural products constitute one of the largest groups of materials used in America. More than 260 million tons of various grains, much of which now exists in dust form, was grown in 1958.6/ Over 600,000 tons of the annual production of 200

Jan 1, 1961

By R. F. Stevens

A laboratory method for examining crude shale oil is described. The method uses only about 500 ml. of sample and a limited number of analytical determinations. Results provide information on the general characteristics and composition of an oil and serve as a basis for comparing different oils. However, the method does not provide for direct estimates of yields of commercial products. Analyses of 10 oils produced in the United States by different methods of retorting and of 10 shale oils from commercial-scale operations in 6 foreign countries are given. The shale-oil-analysis method presented in this paper is based on and employs the same equipment as the Bureau of Mines routine method for analyzing crude petroleum. As shale oil contains groups of compounds not generally found in petroleum, several modifications of the petroleum method that might increase its suitability for application to shale oil were investigated. The modifications included in the present method take into account the apparent poor heat stability of shale oil and the presence of large quantities of olefins and nitrogen compounds.

Jan 1, 1952

By B. E. Davis

Over 80 pct of domestic phosphate rock, which is the starting material for phosphorus-containing fertilizers, comes from central Florida deposits. As K-her grade deposits are depleted, lower grade phosphate ores containing 'Mg0 in the form of dolomite are encountered. Treating high MgO ores with present beneficiation technology will not yield a concentrate meeting specifications for acidulation. The Bureau of Mines conducted research on three high-MgO phosphate samples from south Florida. The sales contained, in percent, 5.4 to 10.2 P205, 1.9 to 7.6 MgO, and 35.3 to 60.1 acid insolubles. A technique of sizing, grinding, desliming, scrubbing, and redesliming was used to produce a feed suitable for continuous flotation studies, A conventional fatty acid-fuel oil rougher flotation followed by two to three cleaner stages resulted in concentrates containing, in percent, 30.7 to 31.3 P205, 0.6 to 1.3 MgO, and 2.5 to 4.8 acid insolubles. The P205 recovery from the flotation feed ranged from 55.1 to 89.7 pct.

Jan 1, 1984

By E. L. Garton

The Bureau of Mines for a number of years has been conducting an investigation of crude petroleum from producing fields in the United States and the Western Hemisphere and has published a series of reports on these fields. Analyses of crude-oil samples from many oil fields of Oklahoma are given in Bulletin 2913. Analyses of 21 representative crude oils from various producing zones of the Oklahoma City field are given in this report. A close study of the analyses reveals very few differences in the general characteristics and chemical properties of these oils.

Jan 1, 1932

By O. C. Blade

"INTRODUCTION This report on the properties of aviation gasolines and aviation jet fuels produced in the United States during 1952 was mode under a co¬operative agreement between the American Petroleum Institute and the Bureau of Mines of the United States Department of the Interior.Analytical data are presented for 94 samples of aviation gasoline which include for the first time in this series of reports, data on five samples of grade 108/135 aviation fuel. Data also are given for 34 samples of aviation jet fuel. The analyses were made on samples typical of the manufacturers' production in their laboratories and the results sub¬mitted to the Bureau of Mines for compilation. The products of 20 manufacturers of aviation gasolines and of 16 producers of aviation jet fuels are represented.SUMMARYA comparison of certain properties of the commercial aviation gasolines produced in the United States during 1950, 1951, and 1952 is presented in table 1, the 1952 data being average values from tables 3 through 7 of the present report. Trends in certain characteristics of these fuels may be seen in figures 1 through 5 which also indicate the minimum and maximum values. As may be observed, the properties of commercial aviation gasolines have not varied greatly during recent years. A list of aviation-fuel survey reports published by the Bureau of Mines is given on page 7.Table 2 presents a summary of data from table 8 and compares properties of aviation jet fuels of 1952 with summarized data on jet fuels of October 1951."

May 1, 1953

By Foster Fraas

Almost all minerals show irreversible changes in electrical conductivity after heating in the temperature range 100° to 800° C. This effect can be detected with only a limited number of minerals with the standard ionizing-electrode-type separator, which differentiates between nonconductors and conductors in the single-particle resistivity range of 1011 to 1013 ohms. Tests outside this range with other type separators, such as the static field type, increase the number of minerals with which the effect can be detected to almost all that were tested. Irreversibility may be the result of an alteration of adsorption layers, volatilization of surface cations or anions, or an oxidation or reduction. One example is limonite, which decomposes to hematite and passes through two minima and two maxima in conductivity in the temperature range 100° to 900° C.

Jan 1, 1959

By M. H. Chetrick

Since 1945, a commercial-scale pilot plant for the gasification of lignite has been operated by the Bureau of Mines at Grand Forks, N. Dak. The description, operation, and objectives of this pilot plant have already been described in previous reports (6, 7, 8). Although the experimental data obtained from the operation of the externally heated retort have been tabulated and summarized (1, 7), few studies have been made in the correlation of these data. The purpose of the present investigation was to review the data taken in tests of the lignite-gasification pilot plant and to correlate the gas-composition data in terms of their basic factors.

Jan 1, 1950

By J. E. Hamak

This publication contains analyses and related source data for 162 natural gas samples from 15 states and 4 foreign countries. Of the total samples, 154 were collected during calendar year 1992. The remainder were collected earlier, but releases granting permission to publish were not received until 1992. None of the analyses have been previously published in annual reports. All samples were obtained and analyzed as part of U.S. Department of the Interior, U.S. Bureau of Mines investigations of the occurrences of helium in natural gases of countries with free-market economies. This survey has been conducted since 1917. The analyses published herein were made by mass spectrometer and chromatograph.

Jan 1, 1993

By R. K. Franklin, S. T. Reese, J. J. Forbes

"INTRODUCTION It is a recognized fact that in the coal-mining industry coal dust must be allayed to promote the safety and health of underground workers. The Bureau of Mines has been cognizant of the hazards of coal dust for many years, and the necessity of controlling such dust was acknowledged when the Federal Mine Safety Code was formulated. Accumulations of coal dust increase the explosion hazard in a bituminous-coal mine and facilitate the propagation of an explosion. Some of the coal dust produced in mining is inhaled by the workers and contributes to respiratory infection. Impairment of vision and personal discomfort resulting from working in dense clouds of coal dust reflect unfavorably on the efficiency of workmen. Considerable coal dust, originating at the working face, is carried in the ventilating current and deposited elsewhere in the mine, thereby increasing the explosion hazard. It is apparent, therefore, that if coal dust could be allayed effectively at its points of origin, the dust-explosion hazard in bituminous-coal mines would be reduced greatly.Although dust control is practiced in many bituminous-coal and lignite mines, the extent and effectiveness of control for the, entire industry-is not generally known. The purpose of this circular is to present such information clearly, and to encourage coal-mine operators to install dust- allaying equipment.Factual data on dust-allaying practices at working faces in a large number of the bituminous-coal and lignite mines in the United States were .compiled from reports on recent Federal inspections of these mines, The information is presented in tabular form to permit review of the dust-allaying practices of a substantial part of the industry, by States, and also according to employment, and loading practice."

May 1, 1950

By B. J. Moore

This publication contains analyses and related source data for 191 natural gas samples from 22 states and 1 foreign country. Of the total samples, 182 were collected during calendar year 1987. The remainder were collected earlier, but releases granting permission to publish were not received before 1987. All samples were obtained and analyzed as part of Bureau of Mines investigations of the occurrences of helium in natural gases of countries with free market economies. This survey has been conducted since 1917. The analyses published herein were made by mass spectrometer and chromatograph.

Jan 1, 1988

By D. Bienstock

A high-B.t.u, gas can be synthesized by the catalytic methanation of a mixture of 2.5 to 3 parts of hydrogen to 1 part of carbon monoxide, obtained in the gasification of coal, using a steel catalyst followed by Raney nickel in a hot-gas-recycle system. Conversion of 99 percent of the H2+CO yields a fuel gas with a heating value of 983 to 1130 B.t.u. per cubic foot containing 78 to 96 percent methane, no carbon monoxide, and very small amounts of unsaturated hydrocarbons. With the steel catalyst alone, conversions were 85 to 90 percent, giving a fuel gas of 810 to 868 B.t.u, per cubic foot, or 847 to 975 B.t.u. on a C02-free basis. INTRODUCTION In 1948 the U.S, marketed production of natural gas was 5.15 trillion cubic feet; by 1958 it had reached 11.0 trillion cubic feet, a rate of growth of 8 percent annually. 4 5 Although demand is expected to increase less rapidly, by 1966 it may reach 16 trillion cubic feet, based on an estimated 4.7 percent annual increase.6

Jan 1, 1961