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By M. D. Carver

The purpose of this investigation was to determine the effects of variations in content (near the residual level) of the impurities aluminum, nitrogen, manganese, and copper on the corrosion rate in pressurized hot water and in pressurized steam of zircaloy-3, a zirconium-base alloy of 0.25 percent tin and 0.25 percent iron. Thirty-five 10-pound ingots were cast with the appropriate additions of impurity elements, and these were converted to wrought sheets. These specimens were then tested both in water and in steam. The analysis of the resulting data showed that in environments of either pressurized hot water or superheated steam, corrosion rates increased with increasing content of aluminum, nitrogen, or manganese, but were not affected by variations of copper. The effects of aluminum and nitrogen were found to be greater than the effect of manganese. INTRODUCTION At the request of the Atomic Energy Commission (AEC) in August 1956, the Federal Bureau of Mines, in cooperation with Bettis Plant of Westinghouse Electric Corp., began investigating the effects of certain impurity elements on the corrosion rates of zircaloy-3 in pressurized hot water and in pressurized steam. It was necessary to know these effects in order to set control limits on residual impurity levels in zirnaloy-3, intended for heat transfer service in the nuclear reactor of the pressurized water type. A factorial expert it was designed by Westinghouse statisticians. The Atomic Energy Commission provided raw zirconium sponge purchased from Wah Chang Corp. The Bureau's laboratory at Albany, Oreg., made material of different combinations of impurity levels and subjected the material to corrosion tests. This report will describe the work done at the Bureau laboratory and will show, quantitatively the effects of different residual levels of aluminum or nitrogen, or manganese or copper on corrosion rates.

Jan 1, 1961

By A. S. Moore

The Bureau of Mines is doing research and development work on removing acid-gas impurities from synthesis gas made directly from coal. Since conventional gas scrubbers, packed towers and bubble-cap columns, are expensive to construct and difficult to operate with viscous solutions, one aspect of the work was developing a compact, agitated, gas-liquid contactor for use with concentrated absorbents. The efficacy of the agitated contactor for absorbing carbon dioxide in diethanolamine increased with increasing solution rate, turbine speed, diethanolamine concentration, and carbon dioxide concentration in feed gas, and with decreasing liquid-gas ratio. It was unaffected by pressure between 200 and 300 p.s.i.g. and little affected by temperature between 115 and 190° F.

Jan 1, 1961

By W. W. Adams, T. D. Lawrence, D. R. White

"This paper presents the results of the eleventh yearly accident-prevention contest, the National Safety Competition of 1935, conducted by the United States Bureau of Mines. Participating in the competition were 336 mines and Quarries in 37 States. Five mining or quarrying companies, each the leader in its group for having established the best safety record during the year, were awarded the national safety trophies 'Sentinels of Safety.Since these annual contests were begun 11 years ago the scope of the competition has been broadened materially, both as to the number of plants participating and as to the number of man-hours of exposure to accident hazards. Moreover, marked progress in the pre¬vention of accidents has been achieved, as is indicated by an almost constant downward course in the accident-frequency rates for the contest group as a whole during the past 11 years. On the other hand, the accident-severity rates for the group showed an upward trend during the first part of the period and a downward trend during the latter part, except in 1930 and 1934, when two disastrous explosions occurred with heavy loss of life, and in 1935, when there was an increase in the number of fatalities although no major disasters occurred. The accident rate for 1935, both as to frequency and severity, was higher than for 1934.The National Safety Competition is conducted by the Bureau of Mines in the interest of safety in the mining and quarrying industries. This object is accomplished directly through the efforts of the competing companies and their employees to win first place in the competition and thereupon receive well-merited and national recognition for their achievement. Indirectly the purpose of the contest is accomplished through studies by the Bureau of Mines of the fasts contained in the accident reports which the competing companies furnish to enable the Bureau to compute the accident rates that are the basis for determining the winners of the contest.The statistics that constitute the basis for determining the winning companies and the relative standing of all companies are prepared uniformly without regard to the States in which the companies operate, or to differences in classes of accidents covered by State laws relating to compensation for injuries resulting from industrial accidents."

Jul 1, 1936

By R. L. Grant

The Bureau of Mines developed two new gap-sensitivity methods for explosives, and especially permissible explosives, to overcome certain disadvantages of the present routine half-cartridge method. The revised methods are based on the statistical up-and-down method and give more useful measurements of the 50-percent' gap values than the nonstatistical routine method. The new methods use full cartridges and incorporate certain physical improvements such as the use of cardboard tubes for containing the explosives and coal dust gaps to simulate actual mining conditions. A total of 60 samples of permissible explosives were evaluated simultaneously with the 2 improved methods and with the half-cartridge method

Jan 1, 1967

By Robert F. Chaiken

More than 500 fires are now burning in abandoned coal waste banks and coal deposits in the United States. Once established, such fires can burn for decades, and extinguishing them by conventional methods such as surface sealing to exclude air, excavation to remove fuel, or flushing to cool the fire zone is usually difficult and always expensive. Burnout Control, a technique developed by the Bureau of Mines for the control of abandoned coal fires, involves the accelerated combustion of coal in place with total management of the heat and fumes produced. A burning waste bank or mine is placed under negative pressure relative to the atmosphere, and heat and combustion products are drawn from the combustion zone through an exhaust ventilation system. Heat produced appears as sensible heat in the exhaust, at temperatures as high as 1,000° C (1,832° F), and could be recovered for the production of steam, hot water, process heat, or electricity. The Bureau's first field demonstration of Burnout Control was at Calamity Hollow in Allegheny County, PA (near Pittsburgh). Calamity Hollow was the site of an underground mine in the. 1900's and was surface mined in the 1940's. In the winter of 1961~62, a fire of undetermined origin was discovered in the exposed coal. In 1963, the Bureau constructed a trench barrier around the fire and a surface seal over the affected area. The fire was isolated but, not completely extinguished. In 1979, when the Bureau began work on the Calamity Hollow Mine Fire Project to demonstrate controlled burnout, the fire was still smoldering on the hot side of the trench barrier. The project, which was begun in December 1979 and ended in July 1982, consisted of the design, construction, operation, and subsequent dismantling of a Burnout Control ventilation system. This report, although considered part 2, is actually the last of a five-part series that describes the Calamity Hollow Mine Fire Project. It was written last because it involved the analysis of a substantial body of data describing in detail the results of a continuous 4-month burnout operation. The first report, part 1, describes the design and construction of the field installation. Part 3 describes the instrumentation used to control and monitor the progress of the burnout operation. Parts 4 and 5 deal with the closeout phase of the field demonstration. Part 4 describes the procedure used to quench the fire, and part 5 describes the final excavation and backfilling of the heated zones. The reports in this series document the Calamity Hollow controlled burnout demonstration, which showed that (1) controlled in situ combustion is a feasible method for controlling underground fires in abandoned mines, (2) the resultant thermal exhaust output is suffIcient for energy utilization, and (3) water injection-fume exhaustion is a potentially effective method for cooling large underground fire zones. Further investigations of both Burnout Control and the water injection-fume exhaustion quenching procedure are planned.

Jan 1, 1989

By R. Hogg, T. F. Dumm

"There is a considerable need for standardized respirable dusts with consistent, reproducible characteristics which simulate those of actual mine dust. The availability of such materials should be a significant factor in promoting coordinated research into dust characterization and mine monitoring, dust control, and the biomedical aspects of dust toxicology. The use of an opposed-jet, fluid-energy grinding system in closed circuit with a cross-flow, centrifugal air classifier for preparing bulk quantities of respirable-size dust has been investigated, and appropriate, standardized procedures have been established. By stage-crushing, screening, and fine-grinding with a Donaldson Acucut classifier/mini-grinder system, it is possible to produce bulk quantities of respirable dust at relatively high rates. Using minor modifications to the system, broader or narrower size distributions can be prepared within the respirable range. The system has been shown to reach steady-state with respect to product size distribution very rapidly. However, preferential grinding/classification effects appear to lead to a slow build-up of mineral matter in the circulating load with a corresponding slow change in product composition with time. In those applications where the dust composition is required to match that of the feed coal, it may be necessary to allow considerable time for a true steady-state to be established.Standard respirable dust samples have been prepared from coals representing the western (high volitile A bituminous), central (medium volatile bituminous) and eastern (anthracite) mining areas of Pennsylvania. Quartz and kaolin clay samples, representing important mineral constituents of coal dust have also been prepared. Extensive characterization studies have been performed on the samples to evaluate chemical and mineralogical composition and the distributions of particle size and specific gravity. Detailed information on the original coals is available from the Penn State Coal Data Base. The standard coal dust samples appear to simulate actual mine dust very well with respect to particle size and shape, but generally have somewhat lower ash content. Samples of these standard dusts have been made available to research groups concerned with respirable dust in mines."

Mar 1, 1989

By J. D. Ramsdell

The study described in this report was undertaken to obtain information on the character and effect of antimony additions to titanium. The availability of high-purity, low-hardness titanium metal, resulting from fused-salt electrorefining techniques, permitted a reassessment and evaluation of the physical behavior of titanium-antimony alloys. Alloys, based on several grades of titanium containing up to 10 percent antimony, were arc-melted and processed to sheet by hot and cold rolling. Properties and characteristics were evaluated by hardness tests, hot and cold rollability, annealing treatments, metallographic examination, and tensile tests.

Jan 1, 1960

By D. B. Taliaferro

Information regarding the pores or voids in reservoir rocks is vitally important in the scientific extraction of petroleum from natural underground reservoirs, and petroleum technologists concerned, with subsurface, conditions have devised various methods that give reasonably accurate information as to the porosities of oil and gas-bearing sands.5/ In this, work, several investigators have made use of the experience of the ceramic and other industries. The method of determining the effective porosity of oil sands described in this report falls within the general classification of gas-expansion methods. It was devised and developed at the United States Bureau of Mines Petroleum Experiment Station, Bartlesville, Okla., as a part of the research dealing with fluid and energy relations in reservoirs and improved oil-recovery methods. The apparatus and procedure are well adapted to the requirements of the Bureau, and the following detailed description has been prepared so that others may make use of the information. A tabulation at the end of the report gives the results of several hundred porosity determinations for oil sands in fields of 11 States.

Jan 1, 1937

By D. B. Taliaferro

Information regarding the pores or voids in reservoir rocks is vitally important in the scientific extraction of petroleum from natural underground reservoirs, and petroleum technologists concerned. with subsurface conditions have devised various methods that give reasonably accurate information as to the porosities of oil and gas-bearing sands.5/ In this work, several investigators have made use of the experience of the ceramic and other industries. The method of determining the effective porosity of oil sands described in this report falls within the general classification of gas-expansion methods. It was devised and developed at the United States Bureau of Mines Petroleum Experiment Station, Bartlesville, Okla., as a part of the research dealing with fluid and energy relations in reservoirs and improved oil-recovery methods. The apparatus and procedure are well adapted to the requirements of the Bureau, and the following detailed description has been prepared so that others may make use of the information. A tabulation at the end of the report gives the results of several hundred porosity determinations for oil sands in fields of 11 States.

Jan 1, 1937

By R. V. Ramani, J. Qin

"In this paper, the results of a research study on airborne dust transport in a full scale simulated longwall face are presented. The simulated longwall face was set up in the Lake Lynn Laboratory mine of the U.S. Bureau of Mines to conduct experiments under controlled conditions. The controlled parameters in the experiments were the dust dispersion rate, dust size distribution, density of the dust, air velocity, and the rate of travel of the dust generating source. The analyses of the experimental results on mass concentrations, particle size distributions, and real-time respirable dust concentrations are discussed. There are definite spatio-temporal trends between the location of the shearer, the concentration at any location in the face, and the dust generation rates. The size-consist and density characteristics of the source dust, the air velocity in the face, and the air leakage into the gobs all affect the concentration. INTRODUCTIONA detailed experimental study on the characteristics of longwall dust cloud in operating longwall faces has been reported by Ramani, Qin, and Jankowski (1991). The study indicated that there are several important factors whose effects on dust transport in longwall faces need to be further investigated. In an operating longwall face, the effect of these parameters could not be easily isolated as control over the affecting parameters is not readily possible. In a simulated longwall face, however, these parameters can be controlled. Therefore, as a follow-up to the field study, a series of controlled experiments were conducted in a full scale simulated longwall face in the Lake Lynn Laboratory mine of the U.S. Bureau of Mines [Qin, 1992]. Specific aspects which were addressed during the experimental design phase included determining the types of samples to be collected, selecting proper instruments to collect these samples, and developing detailed sampling and time-study plans to correlate the dust concentrations with face activities. Two types of dust--anthracite and bituminous--were used. Dust dispersion rate into the air as well as the source dust particle size distribution were documented. Control was exercised over both air velocity at the face and air leakage along the longwall face. During experiments, the dust source was moved to simulate the shearer movement at operating longwall faces. Detailed descriptions of the design of experiments, experimental results, and data analyses follow in the subsequent sections."

Dec 1, 1996

By E. B. Kester

Of the many angles from which coal can be studied it is evident that some have a direct and others have only an indirect bearing on its physical or chemical nature . The more drastic the treatment employed in an investigation , the more inferential become the conclusions permissible from the experimental evidence obtained . Thus , ultimate and proximate analyses tell something concerning age , behavior on carbonization , and possible industrial usefulness , but nothing regarding structure or composition in the larger sense . Strong oxidation reveals the fact that benzenoid , pyrrol , and furane rings are prevalent in the chemical substances present , and milder oxidation indicates that the mass of coal , as in the case of the peats and lignites , is humic in character . But beyond such points of information , very little additional can be gained by the use of these more or less vigorous measures . To gain wider knowledge of the actual constituents of coal substance as found investigators have worked out systems of separation by means of solvents , of which a large number have been employed at various times both singly and in combination . The list of solvents includes petroleum ether , benzene , toluene , xylene , ethyl ether , alcohol , acetone , carbon bisulphide , pyridine , quinoline , aniline , phenol , tetralin , glycol ethyl ether glycol ethylether acetate , glycol methyl ether , glycol diethyl ether , pine oil , mesityl oxide furfural , benzaldehyde , ethylene oxide , rosin , caustic potash in solvents , amyl alcohol plus pyridine , chloroform , carbon tetrachloride , acetylene tetrachloride , naphthalene , and others . Once a coal has been extracted it has become common practice to subdivide the extract by means of partial solution in other and weaker solvents . Thus , we find the oily and solid bitumens of Fischer ( 1 ) , 3 Bone ( 2 ) and others ; the alpha , beta and gamma constituents of Wheeler ( 3 ) ; the classification of Novak and Hubacek ( 4 ) embracing oils , resins A , resins B , bitumens An , bitumens Bn , and bitumens Cn ; Crussard's ( 5 ) malthenes , asphaltenes , and carbenes , borrowed from asphalt terminology; and the 40 or more subdivisions of the phenol extract of coal worked out by Frazer and Hoffman ( 6 ) . Perhaps the primary object of interest in these many researches has been to find the coking principle of coal , and to study it and to learn why certain coals form hard , wellfused cokes , and others merely fall to pieces during carbonization . The origin of the various constituents of the gas and tar , the temperature at which each forms , and something of the mechanism of their synthesis have also been sought , as well as new bases for adjudging rank .

May 1, 1931

By R. E. Heithecker, Van A. Mills

"Crude oils are capable of dissolving quantities of gas under pressure. This fact has been known for some time, but questions have arisen as to the effects of gas in solution upon the characteristics of the oil. Previous investigations4 show that gas in solution in an oil affects the viscosity and surface tension of the oil, but the effects on the volume and A. P. I. gravity of the oil have not been known. The results given in this report show that there is a decided change both in volume and in the A. P. I. gravity of the oil due to the solution of the gas in the oil under pressure. As gas is dissolved, the volume of the oil and the A. P. I. gravity increase. The converse of this phenomenon is also true: if the gas is released from a saturated oil, there is a shrinkage in volume and a decrease in A.P.I. gravity due to the release of gas from solution. However, various oils show marked tendencies to retain a portion of the dissolved gas upon releasing the pressure to that of the atmosphere. This retained gas has an appreciable effect on the volume and A. P. I. gravity of the oil because the oil does not resume its initial volume or gravity while it retains dissolved gas. In a sense the oil has been ""freshened"" and will not return to its original or weathered volume until it loses some of the lighter fractions. Wiggins5 has shown that a fresh oil decreases both in volume and in gravity because of the weathering of the lighter fractions while the oil is standing in storage tanks.This paper includes data attained during the determination of volume and gravity correction factors to be applied in the oil recovery investigations of the Bureau of Mines. Three oils having a wide range in gravity were used in determining the correction factors. These oils were from the Bartlesville-Dewey field, Oklahoma, the Seminole field, Oklahoma, and the Inglewood field, California. The same gas that was used in the oil recovery experiments was used throughout this investigation. Determinations were made of the volume and A.P.I. gravity increases resulting from the gas going into solution at 200, 400, 600, 800, and 1,000 pounds pressure; also the increases in the volume and gravity of the oil due to retained gas were determined after the dissolved gas was liberated from solution by releasing the pressure to that of the atmosphere.Samples of residual and liberated gas were taken throughout the investigation in order to study the selective absorption and selective retention by the oil of the various constituents of the gas. The analyses of these gas samples showed that there was selective absorption and selective retention of the constituents of the gas. The tests on Inglewood crude gave the most pronounced example of selective absorption and selective retention of the gas.All of the tests were conducted at a constant temperature of 709F."

Oct 1, 1928

By J. E. Doo1ey

To process and use the heavy ends of petroleum effectively, the development of suitable separation and characterization procedures not currently available was required. A systematic procedure was developed by the Bureau of Mines using such techniques as isothermal and molecular distillation, chemical treatment, silica-alumina gel chromatography, gel permeation chromatography, and spectrometry. Using these techniques, the Bureau achieved a detailed separation and characterization of a 370° to 535° C distillate from Gach Saran, Iran, crude oil. Such a systematic procedure and the semiquantitative data resulting therefrom should be of value in selecting feedstocks and in optimizing petroleum processing operations.

Jan 1, 1973

By Jack C. White

The purpose of this Bureau of Mines research was to determine the technical feasibility of direct sulfuric acid digestion of Florida land-pebble phosphate matrix. Preliminary tests in a continuous digestion circuit showed that 92 to 96 percent of the P2O5 contained in the matrix was extracted, while the P.05 concentration in the product acid ranged from 21 to 30 percent. The waste filter cake contained about 1 percent P205 and up to 18 percent water. These sandy compact filter cakes, comprised mostly of quartz and gypsum, appeared to be suitable for backfilling and reclamation of mined lands.

Jan 1, 1975

By Christopher H. Roe

This Bureau of Mines report reviews the various methods of removing the liquid from tailings slurries that contain very fine grained solids. Gravitational settlement, centrifugation, filtration, and thermal drying methods are discussed in detail. Chemical additives, electrokinetic dewatering, and the rotary trommel screen are also mentioned. Lists of dewatering equipment and suppliers are given in the appendixes to assist the planner who must choose the most efficient, economic, and practical method of dewatering very fine grained mill tailings.

Jan 1, 1984

By Floyd D. Everett

The Cougar Spar property is in southwestern Beaver County, Utah, approximately 35 miles by road northwest of Lund, a station on the mainline of the Union Pacific Railroad (fig. 1). Original fluorspar discoveries on the property were made a. short time before 1941. During 1941 lessees produced approximately 600 tons of ores averaging 40 percent CaF2. Bureau of Mines engineers examined the property in 1942 and recommended development. Work was begun in December 1942 and completed in October 1943. The area was mapped by members of the Federal Geological Survey during the project period. Development included surface trenching; drifting, and crosscutting, a short distance below the outcrop. The surface work comprised a total of 440 linear feet of bulldozer and hand trenches. A total of 550 feet of workings was driven on the 100-foot level. Samples were taken for assay from the trench exposures and from the underground workings as work progressed. Pocks in the area of the Cougar Spar property are igneous and consist mainly of fine-grained tuff and quartz monzonite porphyry. The fluorspar mineralization occurs in a northwest fault zone.

Jan 1, 1951

By Donald E. Redmon

This Bureau of Mines report reviews injury experience in the nonmetallic mineral industries (except stone and coal) for 1968-69. For each of the years, 23 tables summarize disabling work injuries by department, source of injury, extent of disability, part of body injured, and nature of injury. Correlative information on employment, worktime, and operating activity is also presented.

Jan 1, 1973

By Edwin B. Cook

This report presents the results of calculations of the equilibrium composition of the products of combustion with air of six different mixtures of octane CgH18, plus PbEt4 and halogen-bearing scavengers at three air-fuel ratios, at pressures of 5 and 30 atm., and at temperatures of 350°, 1,000°, 1,800°, and 2,000° K. The air-fuel weight ratio has the values 12, 15:12, and 18. The concentration of PbEt4, M, in milliliters per gallon of iso-octane, has the value 1 or 3. The word "case" is used to designate the halogen concentration. Three cases have been considered [ ]

Jan 1, 1953

By M. W. Pullen

It is recognized that the determination of electrical resistivity of the earth within a given area may furnish information concerning the location of certain mineralized strata of economic importance. Present knowledge of the electrical resistivity of the various rock formations is almost nil, and the geophysicist who is detailed to make a survey of an area without any data as to the relative resistivity of the underlying rocks is greatly handicapped. Such surveys are usually made within areas known to contain mineral deposits to aid in locating desirable points for drilling. Usually these areas have been prospected by diamond drilling, and drill cores of the various rocks and ores are usually obtainable. Were it possible to make resistivity tests in a laboratory of the drill cores or from pieces of the rocks and ore within an area before attempting a field survey, this would indicate not only the advisability for such a survey but would aid considerably in the interpretation of the results of such a survey. To be of most value a definite method should be used for all such tests, and as yet such a method has not been established.

Jan 1, 1929

By Floyd D. Everett

The J. B. fluorite deposit is in the Washington mining district, southwestern Beaver County, Utah (fig. 1). Fluorite outcrops were found during 1942, and three lode claims wore located. Little work was done on the property until October 1943, at which time the Bureau of Mines started development to determine the subsurface extent of the fluorite mineralization exposed at the surface. The most prominent rocks in the J. B. mine area are porphyries, which vary considerably in composition. Dacite porphyry appears to be the most common host rock for the fluorite-quartz-calcite lenticular masses. The dacite porphyry in the area is highly brecciated over a strike length of more than 1 mile. Fluorite deposits in the brecciated zone cover a strike length of approximately 400 foot. The fluorite lenses range in length from 40 to 200 feet and in width from 4 to 10 feet (fig. 2). The Bureau of Mines work on the J. B. property was started in October 1943 and completed in October a year later. The work consisted of surface trenching by bulldozer and hand methods, shaft sinking, drifting, and crosscutting. Eleven trenches totaling 1,800 linear feet were excavated. An inclined shaft was sunk to a depth of 105 feet, and from thin shaft 577 feet of drifts and crosscuts were driven to outline the extent of the mineral deposit (fig. 3). Two hundred ninety-seven samples were taken in the surface trenches and underground workings. The locations of the samples and analyses arc shown in accompanying figures and tables. Results of metallurgical tests comprise the concluding section of this report.

Jan 1, 1950