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By A. T. Adema

The cohesive zone, where the ore fed into the blast furnace softens and melts, is critical to the blast furnace performance and stability due to its influence on the gas and solid flow. This paper de-scribes a project for the development of a process model to predict the cohesive zone properties and the results of its first step; the solid flow model. The process model is expected to describe a realistic solid burden flow and the formation of the cohesive zone, its shape, location, structure, permeability, and in particular the mineralogical changes within the cohesive zone. This will be achieved using various simulation and computing tools: a combination of the Discrete Element Method (DEM) and Computational Fluid Dynamics (CFD), the DEM?CFD hybrid approach, together with models for the thermodynamics and reaction kinetics. The key benefits of the hybrid approach lie in the coupling of the continuous phase and the discrete particles, and the possibility of introducing thermodynamics and reaction kinetics into the system in a more realistic manner. Two DEM simulations are presented for a small scale blast furnace to investigate the influence of non-spherical particles on the solid flow. This influence can be observed from a more even solid flow pattern and a reduced deadman size. The results indicate the requirement to include non- spherical particles in a blast furnace simulation to achieve a realistic solid flow.

Jan 1, 2014

By Duong Huu Hoang, Nathalie Kupka, Urs A. Peuker, Martin Rudolph

"The froth ability, froth stability and the froth structure are strong influences in flotation process i.e. on water recovery, bubble size, entrainment of gangue particle, flotation rate constants, grade and recovery. The labscale flotation of rich apatite ore with a high mass pull leads to significant changes in pulp and froth properties over time. The froth stability decreases with increasing the flotation time. These changes can be related to different solid contents, reagent concentration, froth heights and bubble size distributions. This study presents the results from froth studies and discussions on the particle size of fully liberated silicates and degree of entrainment based on automated mineralogy size-by-size analysis. The change of entrainment in a rich apatite ore batch flotation with time will describe more precisely by measuring froth properties using a Dynamic Foam Analyzer. It is concluded that the degree of entrainment is not only dependent on particle size but also the pulp density due to its effect on particle settling and also froth properties in varying resistance to particle drainage. Furthermore, entrainment models are applied to predict the effect of size, flotation time on entrainmentINTRODUCTIONFroth flotation belongs to the group of heterocoagulation separation techniques. Froth flotation is classically divided into two active zones, the pulp zone (where particle collection occurs) and the froth zone. A schematics drawing of the interaction between both zones is plotted in Figure 18 (Yianatos and Contreras, 2010). In froth flotation, the collision probability in the collection zone is governed by the physics of the process or hydrodynamics (Wills and Finch, 2016). The true flotation event in the pulp occurs when the hydrophobic valuable mineral particles collide with bubbles and formation of a stable particle-bubble aggregates moving upwards against gravity to the froth phase (Yianatos et al., 2009)."

Jan 1, 2018

By J. Quinteros-Riquelme

Despite increasing demand, the supply of silver is limited by its inadequate recovery from ores. Due to its scarcity in nature, its high ore variability and complex mineralogy of current silver deposits, its recovery by mineral froth flotation presents a real challenge for process engineers. A silver ore often contains significant amounts of five to ten different silver minerals and knowledge of the mineralogy is a necessary precursor to flotation testing. In this work, a complex silver ore was treated by using batch laboratory flotation, in an effort to find the best experimental conditions to obtain the optimal silver recovery. Mineralogical characterization of feed samples was conducted using a combination of tools, namely the mineral liberation analyzer (MLA) and inductively-coupled plasma mass spectrometry (LA-ICP-MS), which indicated that most of the silver occurred as ?invisible? silver in pyrite. The pyrite assay of the ore was approximately 4%. The ore was processed in two flotation stages. The first stage, sulphide flotation, aimed to collect a sulphide mineral rich concentrate; then a non-sulphide flotation stage was performed by adding sodium sulphide and collectors to the remaining material in the cell, with the objective of obtaining a pyrite rich concentrate. To reach the target recovery of silver from this ore, various variables were altered. In the first stage: mixed collectors, activators, dispersants, and mainstream inert grinding were assessed. In the second stage, the conditions for sulphidization and subsequent flotation were both investigated. From the grade recovery curves for silver and sulphur it was possible to observe a similar metallurgical behavior for both elements, supporting the results given by the mineralogical characterization. Keywords: silver oxide, froth flotation, sulphidization, mig

Sep 1, 2012

By Brian Loveday, Sandile Nkwanyana, Indresan Govender

"Recent batch experiments by the authors in a pilot scale ball mill (Ø = 0.6m) have demonstrated that a partial replacement of the ball charge by pebbles (25 % pebbles; 75 % steel balls) optimally reduces the ball and power consumption without altering the rate of production of fine material (passing 75 microns). At higher pebble volumes, the production rate of fines was reduced progressively. With the 25/75 composite charge a saving of 13 % in power consumption was achieved, and a saving of 25 % in steel ball consumption is implied. A partial replacement of steel balls by pebbles reduces the overall density of the grinding media in the charge. Taking into consideration that the production rate of fines is usually proportional to the bulk density of the charge in the mill, it would be expected that a composite charge (e.g. 25/75) would coarsen the grind and consequently reduce the rate of production of fines. Pebble wear contributes a small proportion of fines and it doesn’t provide a full explanation of why the 25/75 composite charge has no (or minimal) adverse effects on the rate of production of fines. Clearly, the production of fines across the mill is directly related to the shear and compressive power dissipation density. Accordingly, we hypothesise that the spatial power dissipation distribution meeting the minimum requirements for fines production— at the so-called active regions—are equivalent, or minimally comparable, for both the 25/75 composite and 100 % ball charge operating conditions. To test the hypothesis, we performed DEM simulations to analyse power dissipation in the active regions. 1. INTRODUCTION Comminution remains to be the most expensive process in mining operations, particularly because the energy consumed in this process accounts for 30-70 % of the total cost of a mining operation (Nadolski et al, 2014). Optimization of comminution circuits has been focussed on reducing capital and operating costs and maximising throughput capacity. For existing operations, it is often a challenge if the optimization process recommends retrofitting new ‘major’ equipment. The challenge arises from new capital cost and the difficulty of retrofitting in an existing circuit, while maintaining production (Major et al, 2001). Thus, for existing mining operations, optimization of comminution (cost and throughput) is often limited to operating conditions and/or addition of auxiliary equipment (such as pebble crushers, additional screens and high pressure grinding rolls (HPGR)) (McIvor and Greenwood, 1996; Hart et al, 2001; Powell et al, 2015b)."

Jan 1, 2018

By E. R. Bobicki

"Low-grade ultramafic nickel ores, while representing a large potential nickel resource, are difficult to process due to their serpentine content. Microwave treatment is proposed as a technique to improve the beneficiation of ultramafic nickel ores by converting the constituent serpentine to olivine. The present paper reviews the microwave heating response of ultramafic nickel ores and resultant changes in mineralogy, as well as effects on grinding and slurry rheology. Beyond nickel extraction, microwave treatment improves the mineral carbon storage capacity of ultramafic ore tailings, providing a potential source of additional revenue via the sale of carbon credits. The combined positive effects, considered in the context of the whole operation, suggest an economically viable process is possible.INTRODUCTIONAs high-grade deposits become depleted, the processing of low-grade ores has become increasingly important. One such resource is low-grade ultramafic nickel ores. While representing a large source of nickel, these ores are difficult to process due to their serpentine content. Serpentine is a phyllosilicate mineral consisting of 1:1 stacked sheets of silica tetrahedra and magnesium hydroxide octahedra. There are three primary polymorphs: lizardite (platy), antigorite (corrugated) and chrysotile (coiled, fibrous). The anisotropic nature and non-spherical morphology of serpentine particles leads to complex rheology. Suspensions of serpentine minerals, especially those of chrysotile, exhibit high viscosity and yield stress, which can have a negative effect on comminution, flotation and dewatering operations. In flotation, serpentine is known to slime-coat pentlandite, a valuable nickel mineral, and form bubble-fibre aggregates that report to the froth, reducing nickel concentrate grade and recovery. Methods used to counteract the effects of serpentine in processing include desliming, the addition of chemical dispersants, salts or acid, and dilution (Bobicki et al., 2014a). Microwave pre-treatment has been proposed as an alternative way to eliminate the deleterious effects of serpentine in ultramafic nickel ore processing by converting the serpentine to olivine via dehydroxylation, which occurs at 600-700oC (Reaction 1). Olivine is isotropic, consisting of isolated silica tetrahedra linked by octahedrally coordinated magnesium ions, and has the same surface potential as pentlandite at the pH of flotation (~pH 9). Furthermore, since olivine is more reactive to CO2 than serpentine, microwave pre-treatment creates an opportunity to store more CO2 in tailings, an attractive option for mining operations looking to increase their bottom line where carbon pricing exists."

Jan 1, 2018

By A. An. Mushketov, A. Al. Mushketov, N. A. Sopina

"INTRIDUCTION At present, more and more metallized raw materials with a metallization degree of not less than 80% are used in the smelting of steel. The main quantity of this raw material is produced in furnaces of mine type. Advantages of this type of raw materials for metallurgical processing are low levels of harmful and slag-forming impurities and a high content of metallic iron. At the same time, the cost of smelting raw materials and obtaining high-quality steels are reduced. In addition to the undoubted merits of metallized raw materials, there are high requirements for the quality of iron concentrates, which are the starting material for metallization: the mass fraction of acidic oxides should not exceed 3%; The mass fraction of iron should not be less than 69%, mass fractions of harmful impurities (phosphorus, arsenic, sulfur, copper, etc.) should not exceed 0.02%. These requirements are dictated by the fact that the recovery of burned pellets is carried out by gas in a solid phase. In this case, the empty rock and harmful impurities from the metal are not separated and sent to the steelmaking unit, increasing the heat consumption for heating and worsening the quality of the steel. The combined production of high-quality concentrate and metallized raw materials requires a large capital outlay from the enterprise, which in the future can be compensated for by increased profit from the sale of more expensive marketable products. At present, in the territory of Russia and the CIS countries Lebedinsky mining-and-processing integrated works is the only enterprise that carries out the entire chain of operations for the production of metallized raw materials, starting with the production of high-quality magnetite concentrate with a mass fraction of iron of 69.5% and ending with the production of a metallized product in the form of hot briquetted gland. JSC «SSGPO» is the largest iron-processing enterprise in Kazakhstan, which processes about 40 million tons of ore per year and receives 16 million tons of concentrate per year with a mass fraction of iron 66.0-66.5%. The technological scheme existing at the concentrator of JSC ""SSGPO"" includes the crushing of the feed ore to the size of 20-0 mm; dry magnetic separation operation; three reduction stages to a fineness of 90-95% kl-0.071 mm; operation of desliming, wet magnetic separation and filtration of the concentrate. Dry magnetic separation of the feed ore makes it possible to remove from the process of 19.6% of the tailings with a mass fraction of the total iron 12.5%, of magnetite 2.2%. The first reduction stage is carried out in rod mills with the volume of 40 m3 to a size of -1.6 + 0.0 mm. The first stage of wet magnetic separation is carried out in counterflow magnetic separators PBM-P-150/200L. The magnetic product of the first stage of WMS is classified in hydrocyclones; sands enter the second reduction stage into central discharge ball mill 3600 × 5000. Runoff of mills enter on the second enrichment stage in counterflow magnetic separators PBM-P-150/200L. The magnetic product enters the classification of the second stage, forming a closed cycle. Mass fraction of the class -0.071 + 0 mm in classifications runoff of the second stage is 70-75%. The second stage classifications runoff is transported toWMS-III operation in semi-counter separators PBM-PP-120/300. The magnetic product of the third stage enters the classification of the third stage. Granular residue are transported to the reduction of the third stage into central discharge ball mill 3600 × 5000. The mill runoff enters the third stage of classification, forming a closed cycle. Classifications runoff of the third stage enters on deslimation. Deslimed product is sent for fine screening to the crasher «Derrick» 2SG48-60W-5STK with a cell size of 0.1 mm. Top size of crasher is sent to regrinding. Undersize with a mass fraction of the class -0.071 + 0 mm 90-95% is fed to the wet magnetic separation of WMS-"

Jan 1, 2018

By A. Akcil, O. Celep, C. Erust, E. Y. Yazici1, H. Deveci1

"Recycling of WEEE has already gain prime importance from both environmental and economic point of view. For the recovery of metals from e-waste, many conventional physical, bio/hydrometallurgical and pyrometallurgical processes are proposed. Economic potential of e-waste is mainly driven by its precious metal content. Physical separation methods (e.g. electrostatic, magnetic, eddy current and gravity separation) exploit the differences in the physical properties of metals and non-metals. Physical separation methods are simple and economically sound but they suffer from metal losses and ineffectiveness at fine sizes. Hydrometallurgical processes are promising owing to their relatively low cost, reduced environmental impact, potential for high metal recoveries and suitability for small scale applications. Hydrometallurgical processes can be developed for selective extraction of base/precious metals using suitable reagent systems. Sulphate-based leaching with a suitable oxidant (e.g. H2O2, O2, Fe3+) is effective for copper and other base metals. After removal/recovery of base metals, precious metals can be easily extracted using various lixiviants including thiosulphate, thiourea, cyanide and chloride. However, further research is required to develop new, cost effective and environmentally friendly processes and/or refine existing ones for leaching and, in particular, downstream processes. INTRODUCTION Electrical and electronic equipments are indispensable to modern societies with numerous applications in the field of medicine, transport, communication, education, security and environmental protection. With technological developments and innovations, the replacement of old equipment leads to ever fast accumulation of waste materials such as waste electrical and electronic equipment (WEEE or e-waste). People are upgrading their mobile phones, computers, televisions, audio equipment and printers more frequently than ever before (Babu et al., 2007; Lee et al., 2007). With the rapid growth in technology today, the life span and utilisation period of most electronic and electrical equipment has been reduced considerably with concomitant generation of huge amounts of WEEE over the past several decades. According to statistics presented by Balde et al. (2015), total WEEE produced around the world was 41.8 million tonnes in 2014 and expected to rise to approximately 50 million tonnes by 2018. Kumar et al. (2017) estimated that annual growth rate for the WEEE stream is 3–5% (Singh et al., 2016). The aim of this paper is to provide an overview of physical separation and hydrometallurgical methods available for the treatment of WEEE."

Jan 1, 2018

By M. M. Kulkarni1

Kaolin clay is used as a filler and pigment in various applications such as paper, paint, rubber, plastics, adhesives, ink and ceramics etc. Major mineral content in crude kaolin clay is kaolinite along with some accessory minerals as quartz, hematite, mica, feldspar, anatase, rutile, illemnite etc. The Fe and Ti bearing minerals play very important role in determining quality of the kaolin, as these minerals impart yellow, pink or darker color to the white kaolin. Conventional beneficiation methods used in kaolin processing are de-gritting, classification and sodium dithionite bleaching, which improves the optical properties of kaolin, wherein reduction of color imparting constituents such as Fe2O3 and TiO2 is marginal. In the present study, these coloring impurities are separated using selective adsorption of water-soluble polymers. Degritted kaolin samples after passing through 45 micron sieve is used in the study for selective flocculation by polyacrylamide based polymers. The effect of pH, zeta potential, and polymer dose on the reduction of impurities is studied. Analytical tools such as XRF, XRD, SEM, and TEM techniques are utilized and results are discussed in detail.

Sep 1, 2012

By Z. Cheng, Y. Han

"For non-sulphide minerals such as oxidized minerals, fluoride minerals, and oxysalt minerals, there are generality in the molecular structure of their floating collectors, and similarity in crystal structure of the minerals. In the paper, adsorbing mechanism of these collectors on the surface of these mineral particles in different pH pulp was investigated by means of Pauling's rules & valence bond theory, Valence-shell electron pair repulsion theory (VSEPR) theory, Crystal and ligand field theory, and quantum chemistry simulation by DMol3 and CASTEP modules of Material Studio software. Besides, the role and status of hydrogen bond in the floating adsorption mechanism were studied emphatically, and the confirmation and characterization of hydrogen bond were explored also based on the test results. What is more, the conclusion “the effect of hydrogen bond can not be overlooked in adsorbing mechanism of flotation collectors on the minerals” and a new viewpoint of multi-polarity collaboration and hydrogen bond coupling were summarized eventually based on analysis of the measurements. Finally, a novel collector 2-Amino-3-Methyl Heptyloxy-Propylamine (AMHP) was developed based on the new viewpoint of molecular structure design, and its collecting performance was exhibited.INTRODUCTIONWhen it comes to the recovery of flotation, it is necessary for researchers to investigate the flotation mechanism of collectors. In traditional theory, when collectors were used to collect minerals, the attractions between collectors and minerals were divided into chemical, electrostatic and physical attractions (Wills, B.A., 2006). Especially, because of the reaction between sulphide minerals and sulphydryl collectors is complex and various mechanism has been proposed (Yoon and Basilio, 1993), when collectors were used to collect non-sulfide minerals, it can be classified into oxyhydryl anionic collectors and cationic collectors. In traditional theory, the adsorption of oxyhydryl anionic collectors were due to water-repulsion, and the adsorption of cationic collectors were due to electrostatic attraction between the polar head of the collector and the charged electrical double layer on the mineral surface (Wills, B.A., 2006)."

Jan 1, 2018

By Y. Foucaud, I. Filippova, L. Filippov

Flotation is the most common beneficiation route for tungsten ores, but the predominance of minerals with similar surface properties poses a real challenge. This study investigates the use of Falcon centrifugal separators for gangue minerals removal and desliming prior to flotation. A typical tungsten-bearing skarn ore (Tabuaço, Portugal) is used, containing scheelite (CaWO4) associated with dense calcium-bearing silicates (vesuvianite), fluorite, apatite and light silicates (feldspars) as gangue minerals. Two types of Falcon bowls (Falcon UF and Falcon SB) were used, prior to flotation tests with fatty acids as collectors and a combination of sodium carbonate and sodium silicate as gangue minerals depressants. This flowsheet was compared with a reverse configuration, using flotation prior to Falcon concentrator, and with a classical flowsheet, using hydrocyclone and flotation. Gravity pre-concentration and desliming with the Falcon concentrator were optimized through the design of experiments (DoE) methodology. The influences of pulp density, rotational speed, feed flowrate and fluidisation pressure (for the Falcon SB) were studied for both bowls. Results showed that the Falcon can be used as a desliming and pre-concentrating apparatus. Separation performances depend mainly on rotary speed and pulp density for the Falcon UF, whereas rotary speed and fluidisation pressure are the main parameters for the Falcon SB. With only one stage of Falcon SB, an enrichment ratio of 7.9 is obtained with a 65% WO3 recovery while 89% of apatite and fluorite are rejected, which constitutes a very good selectivity. In comparison, Falcon UF shows lower enrichment ratios, around 2.7. In terms of desliming, Falcon UF is as efficient as the hydrocyclone, while the Falcon SB is significantly more efficient. Hence, the use of Falcon SB prior to flotation improves the overall performance of the tungsten flotation route by desliming the flotation feed while pre-concentrating the scheelite. It impacts very advantageously the flotation, as most of the calcium-bearing minerals are eliminated. A Falcon SB stage prior to flotation yields a final concentrate grade of 29.7% WO3 with a recovery of only 36.8 % that should be optimized as the reagents dosages were not adapted to the pre-concentrated feed.

Jan 1, 2018

By Susanna A. C. Stadler, Chris Aldrich, Jacques J. Eksteen

Slag foaming occurs in several pyrometallurgical processes. These processes include steelmaking in basic oxygen steelmaking furnaces and electric arc furnaces as well as various non-ferrous operations like sulphide smelting/converting and base metal slag cleaning. Although slag foaming in steelmaking processes has been extensively researched, little attention has been given to slag foaming in non-ferrous operations. Slag foaming phenomena are complex because often the system consists of three or more phases. With this in mind, factors previously identified as influencing slag foaming were investigated. These include the slag basicity, physical properties of the slag, namely viscosity, surface tension and density, the formation of particles due to undercooling of the slag and the FexO concentration in the slag. The effect of increasing FexO concentration was found to decrease the foam index due to lower viscosities, but higher surface tension depression appears to have led to increased foam index values at high FexO concentrations. The foaming index decreases with increasing basicity, until precipitation of solids occurs. After this point, the foaming index was found to increase with increasing basicity due to increased solids precipitation. In general, increasing amounts of slag-wettable solids led to higher foam indices, but the precise nature of the effect on slag foaming was dependant on the nature of the solid precipitate.

Jan 1, 2003

By S. J. Lui

Sodium oleate was an effective diaspore collector, whereas chelate collector OL2 showed certain collecting power over diaspore and nonionic surfactant OL3 showed little collecting ability. Then experiments were carried out using sodium oleate as the main collector with the addition of OL2,OL3 to study the influences on diaspore flotation, it could be seen from the experiments that accelerants had a marked influence on the recovery of diaspore, which could be raised by 10%, and the addition sequence also affected the flotation behavior: the best results could be gained when the accelerants were mixed thoroughly before adding and the best ratio of collector OL1 and accelerant OL2, OL3 stood at 30:2:1. Based on the calculation of the ingredients in the sodium oleate solution, sodium oleate reacted with surface of the mineral and formed the acid-soap polymer [HOl?Ol-] when pH was about 9. Zeta potential test showed the accelerant promoted the absorption of collector on the mineral surface, which lowered zeta potential. As could be seen from surface tension experi-ments, the addition of accelerant OL3 lowered the CMC value of OL1 solution, which was equiva-lent to raise the power of the agents. Further Infrared Ray experiments showed the co-absorption of OL1 and OL2 make aluminum oleate on the mineral surface more stable. Up till now, the mixed reagents with sodium oleate as the main collector, combined with other two accelerants had been used in the Zhongzhou concentration plant, which is the first diaspore flotation plant in China.

Jan 1, 2014

By Alban Lynch, Benigno Aquino, Hakan Dündar, Alexander Kalugin, Marco Delgado, Alberto Palomino, Ali Türkistanli

Dynamic separators are efficient dry classifiers because new designs during the last 50 years have reduced the by-pass and improved the partition curve. By contrast cyclones have been used as classifiers in wet grinding circuits for 50 years but without serious change and the early problems which were caused by high and variable by-pass, and different mineral specific gravities, still exist. High frequency screens are now used for wet separation and the operating characteristics of closed grinding circuits using cyclones or screens are discussed. Data come from circuits at the Condestable, Cerro Lindo, El Brocal and Catalina Huanca mines in Peru, the Eczacibasi mine in Turkey, and the Apatit mine in central Kola Peninsula in Russia. All classifier data are described by their partition curves and all mill data by their breakage rates. With cyclones the by-pass, d50, and sharpness of the partition curve change as operating conditions change but with high frequency screens the values vary little because the by-pass is low, the sharpness is high, and d50 depends on the aperture size. Data from all plants indicate that lower by-pass and sharper separation improve breakage rates and throughputs. An initial model of the screen is proposed.

Jan 1, 2014

By Dmitriy Makarov

The paper presents the modeling and analysis of oxidation of pyrite copper-zinc ore samples from the Letnee, Yaman-Kasy and Valentorskoye deposits. It is found, that the oxidized samples contain copper and zinc sulfates that are leached under the sample and water contact. It is shown, that sulfide floatability is decreased by the longer-term oxidation.We advise to improve nonferrous metals recovery by joint leaching and ultrasonic treatment of oxidized compounds. Study of the geotechnological processes of non-ferrous metal extraction, on the basis of two copper-zinc ore deposits shows, that heap leaching is of little use for the ores of the Letnee deposit. Leaching results for the Yaman-Kasy ore showed more promise.

Sep 1, 2012

By A. V. Kurkov

The secondary action reagents (SAR) are organic diphilic compounds capable of altering ac-id-base and donor-acceptor properties of the main collector and consequently the energy of collector interaction with the mineral?s surface, its hardness and fixation forms ratio through associates formation via the hydrogen bonds. When the basic flotation conditions are being established, convergence of the electronic structure of the collector and the mineral being extracted due to minerals surface preconditioning with modifiers and the most efficient collector choice. At the next stage of the selective flotation condition establishment SAR is selected for a more precise adjustment of the energy of the collector fixation on the mineral. Such an approach makes it possible to solve efficiently various issues of flotation separation of non-sulfide minerals. In particular neutral organic substances containing groupings C==O, S==O, P==O (ethers of carboxylic and phosphonic acids, amides of carboxylic, phosphonic and sulfonic acids) were proposed as SAR. In order to enhance the flotation process selectivity in the conditions of water recycling including the selectivity of carboxylic collectors especially in the environment of high hardness water flotation, it was proposed to use SAR with long hydrocarbonic radical and groups with enhanced electronic density within the molecule: N-methylolamides of alkylphosphoric acids and ethers of methylphosphonic acid. Introduction of small amounts of these compounds alongside with the main fatty-acid collector enhance the performance of fatty-acid flotation of fluorite, beryl, columbite etc., lowers the collector consumption, and completely compensates the depressive effect of recycled water. Di-2-ethylhexyl ether of methylphosphonic acid?CH3P(O)(OC8H17-i)2 (hexarane) was more thoroughly researched as such an agent within fatty-acid flotation process. Following aspects of the flotation system were studied: interaction of oleic acid and sodium oleate with hexarane in the liquid phase (infrared spectroscopy); heat emission under the interaction of hexarane-oleic acid ? sodium oleate ? calcium salts (isoperiboric diathermic colorimeter); colloid-disperse state of the collector influenced by hexarane (nephelometric analysis); dynamics of the mineral surface hydration due to the agents (method of indicator negative adsorption); hexarane effect upon the interaction of fat-ty-acid collector with calcium salts (complexometric method with Trilon-B); floatability of pure minerals (quartz, microcline, beryl, columbite) in Hallimond tube; hexarane effect upon oleic acid (sodium oleate) adsorption (nephelometric method for identification of the residual content of oleic acid and its forms within the solution). Upon the research it can be definitely concluded that the adjusting effect of such compounds as hexarane within the non-sulfide minerals flotation process is mainly determined by their interaction with the main collector both within the pulp and at the mineral surface with associates formation due to the hydrogen bond. The consequence is calcium oleates destruction with the release of the most active collector under flotation in hard water environment which determines the efficiency of hexarane joint application with fatty-acid collector under recycled water supply. Therefore the introduction of the class of secondary action reagents is supported by their operation mechanisms and flotation process function and determines a new approach to the development of efficient conditions of selective flotation separation of non-sulfide minerals.

Jan 1, 2014

By H. R. Manouchehri

The importance of the grinding environment and its effect on sulphide minerals flotation behavior has been known for many years. The grinding environment may play a role in controlling fine and coarse particle flotation along with dissociation of different chemical species in grinding environment. Dissociation of different chemical species and ions within the process water may result from changing the grinding environment. The mining and mineral processing industry undertakes activities that may impact on water resources. These include use and storage of chemical storm-water management, process water management, mine dewatering and management of tailings. In mineral flotation understanding and controlling water quality is paramount important not only because of its effect on flotation but also with respect to control the quality of the water which is released to the environment. Releasing of different anionic and/or cationic chemical species in the process water results from the interactions among different mineral within the ore, process water, and the milling environment. In fact grinding mill acts as an electrochemical reactor which affects the flotation performances of different value minerals as well as the quality of the tailing products. An increasing in antimony content in process/discharge water at Boliden?s Tara processing plant in Ireland to above limitation level was reported in April 2010 which needed to be controlled. An increase up to 6 times of the permitted level was reported which needed an immediate action to control due to environmental considerations. Therefore attempts were made to detect why this higher amount of Sb is released and how to control and minimize its release to the process/reclaim water. This paper discusses how/why Sb content in process/reclaim water was increased by changing the mill electrochemistry and the strategies were taken into considerations to control it. Different strategies, including electrochemical controlling of the milling section, Fenton process, using Bauxsol in treating the process water, etc., have been considered and tested which are described herein. All strategies taken into consideration for solving the problem were successful which indicated good understanding of the issue and good decision making. Furthermore, for each solution the capital and operational costs were roughly estimated. Accordingly, the Sb content in process/discharge water was controlled to a value lower than allowed limitation, i.e., 1 ppm. Keywords: antimony, water contamination, mill electrochemistry, ag milling, grinding media, eh-ph, sulfide minerals, fenton process, bauxsol, lime addition

Sep 1, 2012

By X. Q. Ma

The beneficiation test on low grade phosphate ore from a state of Russia is carried out. The rougher-cleaner ? re-cleaner system is used in the flotation process, The fineness of grind is 39.07% minus 200 mesh. The result indicates that concentrate containing 31.25% P2O5 can be obtained from the flotation feed assaying 6.18% P2O5, with 93.54% P2O5 recovery. The test result is also a guideline for further development of some currently operated phosphate beneficiation plants.

Jan 1, 2014

By A. P. Liu

Semi-industrial test on fine products of Meishan dressing plant was carried out with type RP80/25 high pressure roller mill produced by Homburg Corporation of Germany, and the influences of such factors as energy consumption, water containing, throughput and circulating load on rolling effect were investigated. Closed circuit experiment result showed that Meishan iron ore could be suitable for powder grinding with high pressure roller mill, and energy consumption of the operation was declined by 25%~30%, which was favorable for energy-saving, increasing production efficiency and improving grinding effects. According to above experimental results, this paper put forward the technical proposal of application of high pressure roller mill in Meishan, and pointed out some technical problems which needed to be settled urgently in technology disposal.

Jan 1, 2014

By Jyotirmoy Sarma

The surface-active agent, like sodium humate, in the present systems produces a very stable suspension. Saline water up to 15% is used as a flocculating agent for recovery of water from the dispersed phase containing 1% solid. The recovered water in the presence of humate at different concentrations (0.05-0.2%) and at pH 8 also produces a stable dispersed phase of iron ore fines and tailings. The beneficiation techniques adopted in the present systems can increase ~ 2-3% iron value in the concentrate of iron ore fine, however, for tailings the increase in iron value is not observed. Keywords: beneficiation, flocculation, iron ore fines, tailings, saline water, surface-active agent

Sep 1, 2012

By P. S. Dash

With implementation of stringent environmental regulations, ultra clean coal technology development programs have gained significant importance worldwide. As far as Indian scenario is concerned, most of the coals present in India are of drift origin and low grade, containing high mineral matter varying from 15% to greater than 50%. The inorganic or ash constituents of Indian coals are finely disseminated through the organic or carbonaceous constituents so, that commonly used physical beneficiation techniques are of only limited value in affecting separation. Chemical processes involve addition of chemicals, which react with the mineral matter and allow its easy removal. The present study envisages the effect of aqueous alkali leaching followed by acid washing on the removal of mineral matter from two different captive coals of Tata Steel at elevated temperature and pressure. The experiments are conducted at desired conditions using a bench scale pressure reactor set up having proper data acquisition and control system. The research study revealed, that it is possible to reduce the ash content up to 70% by this method. The alkali content of the product clean coal does not increase whereas the silica and alumina content reduces by nearly 58% and 62% respectively. Significant reduction in the phosphorus content is observed after the acid treatment. The crucible swelling number of the feed coal improves after the treatment. The mechanism of demineralisation was evaluated by analyzing the coal samples before and after the alkali and acid treatment using scanning electron microscope (SEM). Because of the acidic nature of the silicates and aluminates, they dissolve into the NaOH solution and form sodalite. Sodalite is partially soluble in the alkali solution. The hydrates formed during alkali treatment are partially removed due to acid wash. This study in overall provides an insight into possible alternative methods of beneficiation for removal of ash from high ash Indian coals.

Sep 1, 2012