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By Regis Texeira, Leopoldo Gutierrez, Vicente Hernandez, Caludia Vidal, Lina Uribe

"Molybdenum is currently the most important by-product of Chile´s copper mining industry. This mineral has gained international relevance over the years, because of its price. At mining deposits in Chile, copper and molybdenum are extracted together and then separated in a concentration process consisting of several flotation steps using sodium hydrosulfide (NaHS) as copper depressant. However, there are environmental issues related to the potential emisions of toxic hydrosulfide gas and bad odours, which affects nearby communities and suppose a risk for operators. This problem has led to the need for development of new technologies to eliminate the use of NaHS in the process of selective flotation of Cu and Mo minerals. In this work, results of flotation tests in which lignin derivatives reagents are used to obtain the selective separation of Cu and Mo minerals by flotation are presented. In this technology molybdenite is depressed by the action of lignin derivatives (lignosulfonates), while copper sulfides remain hydrophobic and float. The use of lignin derivatives in the selective flotation of copper molybdenum minerals represents a non-toxic alternative to NaHS.INTRODUCTIONSeparation of copper sulfides from molybdenite is commonly achieved through a two-stage flotation process. In the first stage the collective flotation of copper sulfides and molybdenite is promoted to generate a collective concentrate which is then treated in a second stage with sodium hydrosulfide (2.5-3.0 kg/t NaSH) to depress copper sulfides flotation without affecting the flotation of molybdenite. As a result a copper concentrate with 30-35% Cu, and a molybdenum concentrate with 50-52% Mo are generated. Although this process is widely used at industrial level, environmental issues related to the risk of H2S generation and bad odors have always been a concern. Thus there is a need in the industry for a more environmentally friendly process to separate copper sulfides and molybdenite."

Jan 1, 2018

By S. Banisi, Seyyed Omid Mousavi, Alireza Ghasemi

Discrete Element Method (DEM) is extensively used to simulate the behaviour of particles in various processing units. This method is based on modelling the forces acting between particles in any contact and consequently calculating the new position of particles. The high number of elements and numerous equations needed have made the required computation time very long even using computers with very fast processors. The required computation time mainly depends on the time step. If the time step is chosen very short, the computation time will significantly increase. On the other hand, if the time step is chosen very long, the simulation will be in error due to not fully observing the contacts. In DEM calculations, the time step is chosen as a fraction of the collision time. In this research, a relationship was proposed between the contact time fraction and the error of simulation. In other words, to select the time step in addition to physical parameters, the accuracy of the simulation was also accommodated in the frequently-used relationships. The simulation error was defined as the relative difference between the initial restitution coefficient and the restitution coefficient obtained after simulation. The required time steps to arrive at the simulation error of 5% were calculated for two common contact force models namely, Hertz-Mindlin and linear spring-dashpot. The simulation was performed for two particles with radius of 3 cm, elasticity modulus of 210 GPa, Poisson's ratio of 0.3 and relative velocity of 0.5 m/s. The required time steps were found to be 2.3 and 0.19 µs for the Hertz-Mindlin and the linear spring-dashpot contact force models, respectively. Results showed that with a scaling-down the modulus from 210 GPa to 2.1 MPa, the required time steps for the Hertz-Mindlin and the linear spring-dashpot contact force models, with an equal simulation error, increased by 100 and 316 times, respectively.

Jan 1, 2014

By Crasta Jeason, T. Sreenivas, M. Narasimha

The subtle nature of the flow inside the hydrocyclone has encouraged development of mathematical models for predicting its performance, which are widely used in simulation of comminution circuits. But most of the models available are based on single average feed density. But the feed to hydrocyclone classifier is generally mixture of particles of different densities. This effect of varying density of feed particles on performance of hydrocyclone has been reported in literature. Further investigation of the effect of multi component feed on the performance of hydrocyclone is the objective of this work. This work involves experimental work to study multicomponent behaviour in various size cyclones. The performance of hydrocyclone for feed mixture of magnetite and quartz has been studied. The effect of presence of magnetite, a high density material on efficiency of separation of quartz has been analysed. It was observed that the effect of component interaction increases with feed solids concentration leading to an increased cut-size for a given optimum cyclone conditions. Based on the multi-component exiperiments available in literature, a concept for modeling the performance of hydrocyclones is proposed. A set of semi-empirical model equations for cut-size, sharpness of separation are presented. An attempt to validate the new hydrocyclone model on multi-component behaviour is made.

Jan 1, 2014

By Alexander E. Sobolev

The kinetics of oxidative dissolution of lead sulfide in solutions of nitric acid and sodium hypochlorite was studied using the rotating disk method and the factor experiment design. The dependences of the PbS dissolution rate on concentration of oxidant (HNO3 or NaOCl), temperature, disk rotation frequency, and duration of interaction were determined. The adequate kinetic models allowing calculating the specific dissolution rate at any combination of values of the influencing factors were obtained. As a result of the complex analysis of kinetic parameters, the modes of the each process proceeding were established, their macromechanisms were determined, and the limiting stages of the oxidative dissolution processes were revealed. The dissolution kinetics of lead sulfide in solutions of nitric acid was found to have several regimes. At HNO3 concentrations below 0.5 mol/L, the process proceeds in a mixed mode close to a diffusion-controlled. It is caused by low oxidative activity of HNO3 and considerable diffusional diffuculties at this acid concentration range. At the nitric acid concentrations more than 0.5 mol/L and less than 6.0 mol/L, the process was found to be kinetically controlled. The limiting stage of the interaction is the surface chemical reaction. The observed relatively high order of the dissolution rate with respect to the concentration of HNO3 was explained by the autocatalytic action of the acid reduction products. At nitric acid concentrations exceeding 6 mol/L, the process proceeds in a mixed mode close to a diffusion-controlled, and the dissolution rate sharply decreased that was explained by a decrease in the solubility of reaction products. When lead sulfide is dissolved in sodium hypochlorite solutions, at first time the amount of PbS transferred into solution remains close to zero. Gradually, as time goes, this amount begins to increase sharply. The dissolution rate rises and reaches the maximum value, further remaining constant. At the steady-state regime, the dissolution rate is independent of the duration of interaction and disk rotation frequency. The process was found to be kinetically controlled. The limiting stage is likely to be chemical reaction on the surface of solid lead sulfide. The obtained kinetic characteristics enlarge the database on hydrochemical oxidation kinetics of sulfides and can be used for the elaboration of the recommendations for the effective comprehensive exploitation of lead-bearing ores and concentrates. Keywords: lead sulfide, nitric acid, sodium hypochlorite, hydrochemical oxidation, dissolution kinetics

Sep 1, 2012

By Sanja Miskovic, Manjunath Basavarajappa

Numerical investigation of fluid flow characteristics and mixing efficiency of different impeller designs, based on the mixing characteristics of a passive scalar/tracer, is conducted using CFD for lab scale flotation cells of diameter D and height H equal to 300 mm. Fine computational mesh containing close to 1.6 million cells is used to obtain fully resolved steady state flow field close to the impeller. Unsteady scalar mixing simulations are performed on a relative coarse grid consisting of approximately 450,000 cells. Based on detailed numerical simulations, flows are fully characterized for four impeller designs at two off-bottom clearances C of 50 and 25 mm (D/6 and D/12). Passive scalar is injected from the cell bottom and the time required to attain uniform concentration distribution inside the cell volume is taken as the mixing time by monitoring scalar concentration at four discrete locations. The effect of varying agitation speed and off-bottom clearance on mean flow characteristics is also investigated. The scalar mixing results reveal regions of low mixing efficiency and are used to understand mixing process in greater detail. Through the previous research work, it was found that the main flow pattern undergoes transition from double-loop to single-loop configuration with decrease in off-bottom clearance below a certain critical height for stirred tanks using flotation impellers in the absence of stator. The inclusion of stator is found to alter the mean flow behaviour by preventing the jet from transitioning to axial type flow for lower clearance. Power numbers for different impeller designs are calculated based on the torque generated on impeller blades, and also from the total turbulent kinetic energy dissipation in the overall fluid volume. Power number is found to exhibit a significant dependence on off-bottom clearance based on the CFD results.

Jan 1, 2014

By P. Saha, D. M. Chakrabarti, J. P. Srivastavam, P. Bhattacharyya, B. R. Sarkhel, Banerjeem B.

The phosphatic soil deposit at the Sukulu hills region of Uganda contains 10-12% P2O5. The ore occurs as a naturally degraded soil deposit containing a very sticky slime composed of earthy lateritic minerals. Desliming of the ore, which is imperative for its further beneficiation, is an extremely difficult hurdle to overcome for its commercial utilisation. Earlier studies on samples of the same ore at the National Metallurgical Laboratory (NML) and abroad established that it was necessary to pass the ore through a series of three stages of desliming, each consisting of a step of vigorous attrition scrubbing followed by hydrocycloning, for effective elimination of the sticky slime. In the present paper an innovative use of the very strong shear-fields created inside a hydrocyclone has been discussed, that could effectively eliminate the stubborn slime from the ore. The standard design of the hydrocyclone was suitably modified to increase the shearing effect on the slurry. It was possible, through the application of this modified hydrocyclone, to not only totally eliminate all the stages of attrition scrubbing, but also to reduce the subsequent stages of hydrocycloning. The modified technique yielded a concentrate of grade comparable to that obtained by employing the earlier more complex flow sheet, with about 25% higher P2O5 recovery.

Jan 1, 2003

By Aubrey Mainza, Malcolm S. Powell

"A hydrocyclone with two vortex finders, named the three-product cyclone, has been successfully tested in the Platinum industry for dealing with the dense chromite found in UG2 ores. This dense component preferentially reports to the cyclone underflow, resulting in an over-ground fine chromite component in the final product. The dense media effect caused by a high chromite concentration in the cyclone feed produces a coarsening of the cyclone overflow, which results in loss of recovery through over-size material in the float feed. The fine barren particles of chromite that report to the overflow are recovered through entrainment in the flotation process, resulting in detrimental contamination of the slag produced from the concentrate.With the three-product cyclone a middlings product has been extracted that has a higher concentration of fine chromite. This volumetric stream flow represents a small percentage of the total cyclone feed and it is thus possible to treat it separately via fine screening to remove the fine chromite from the system and recover coarse silica."

Jan 1, 2003

By Rintaro Hayashi

The enrichment of useful components from ores and/or wastes has become important with increasing recent worldwide resources demand and the amount of wastes generated from the urban mines, in order to establish real ?sound resource-cycle society? including the activity of resource exploitation. The first stage of the treatment in the process must be comminution and it is important to make good liberation among compositional phases in the targeted resources. Electrical disintegration (ED) is well known to make a selective breakage at phase boundary. However, the detailed mechanism of the phenomena is not clarified yet, in especial, on the influence of electrical properties of compositional materials on the liberation. This paper made a comparison between the liberation degrees of ED products and the results of electromagnetic field analysis using finite element method (FEM). In the experiments, we used several synthetic cement paste based samples in which mineral particles were dispersed to apply the ED, and in the electromagnetic field analysis, we calculated the charge density accumulated and the Maxwell stress at phase boundary. It was found, for highly insulating mineral samples, that higher breakdown voltage was necessary because electric charge was not easily accumulated at phase boundary but that higher liberation degree was obtained after the breakdown (ED). It was also found the tendency that higher liberation was observed for the samples which had higher maximum Maxwell stress calculated by the electromagnetic field analysis. From the results, the electrical charge and Maxwell stress induced at phase boundary could be driving forces of selective breakage. In addition, we also applied the ED to the printed circuit boards (PCBs) in order to concentrate miner rare metals, which were essential for producing electronic devices. It could be demonstrated that the devices installed on the PCB were easily detached from the board and that most of metal elements in the devices was exposed and liberated from the insulating plastic covers, which were broken in the ED, then, it is considered that the subsequent solid phase separation could be effective for concentrating such metal elements. Keywords: liberation, electromagnetic field analysis, printed circuit board, miner rare metal

Sep 1, 2012

By C. Dorfling, P. Albertyn

"Hydrometallurgical recovery of metals from printed circuit board waste typically involves multiple leaching stages; conventionally, base metals dissolution by mineral acids is followed by leaching of gold using cyanide or halide based lixiviants. Alternative lixiviants for gold leaching can reduce the potential hazardous nature of operation. The aim of this study was to investigate the feasibility of using thiosulfate as lixiviant for gold leaching from waste printed circuit boards. Batch leaching tests were performed to investigate the effects of thiosulfate concentration (0.1 – 0.2 M), ammonium concentration (0.2 – 0.4 M), pH (9 – 10.5), solids content (25 – 50 g/L), and copper content of the feed material on the gold leaching behavior. The concentrations of metals in liquid samples were determined by means of inductively coupled plasma atomic emission spectroscopy, and high pressure liquid chromatography was used to evaluate thiosulfate degradation/consumption. The ratio of thiosulfate to ammonia was found to have the most significant effect on the extent of gold leaching, with the best gold extraction observed at a ratio of 0.5 mole thiosulfate per mole ammonia. The lower pH range of 9 – 9.5 generally produced better Au leaching, while low copper extraction during the first stage base metal leaching stages has proven to be detrimental to gold leaching from the residue. Thiosulfate degradation/consumption increased and gold extraction decreased with higher residual copper in the feed. An optimum gold extraction of 78.5 % from base metal leach residue was achieved with 0.2 M thiosulfate, 0.4 M ammonia, and 0.02 M cupric ions at 25°C in the pH range 9 – 9.5.INTRODUCTION Background and Aim The recycling of e-waste is becoming increasingly important as it provides certain economic benefits apart from the obvious environmental benefits. Printed circuit boards (PCBs) are found in most forms of e-waste and contain especially high concentrations of base and precious metals. Hydrometallurgical processes are often considered for the recovery of valuable metals from PCBs; these processes normally implement several leaching stages to selectively recover certain metals."

Jan 1, 2018

By Y. H. Hu, X. X. Zhang, Z. F. Dai, H. J. Huang, Q. S. Huang

"In order to get a more comprehensive understanding of the interaction of fine fluorite particles and bubbles, the electro-flotation was conducted, a high speed CCD was used to determine the bubble size distribution, and the results were analyzed using the models of collision and attachment. The electro-flotation was performed in a modified Hallimond tube. The results show that for different fluorite with size of 0 -10µm, 10 -38µm, 38-74um, there is a matching range between the different particle sizes and cathode aperture size (38um, 38um, 74um) to reach highest recovery. In addition, improving the concentration of collector is benefit for the flotation recovery due to the ability of collector to decrease the bubble size and prevent the merger of bubbles. Furthermore, theoretical calculation of collision, adhesion probability and collection probability is in agreement with the experimental data for electro-flotation recovery of fluorite.INTRODUCTIONFluorite is widely distributed, and has been found in more than 40 countries around the world. As fluorite minerals are easy to float, flotation is used as the best method of the current recovery of fluorite (Yang and Ai, 2016; Chen et al., 2017). In the field of mineral processing, the flotation of fine particles is particularly difficult, caused by the small quality and large surface (Sun et al., 2006). Flotation is now considered to contain three subprocesses, including the collision, attachment and detachment between the particles and bubbles (Sun et al., 2011). The collision of particles with bubbles is related to factors such as particle size and density, bubble size, bubble rise rate (Qin et al., 2012). Zongfu Dai et al. (2000) summarized the particle-bubble collisions models in detail and compared the experiment results with the model predictions. However, particle-bubble interactions occur in complex and turbulent flotation environments (Xing et al., 2017). Both thermodynamics and dynamic factors affect the adhesion of particles on bubbles surface (Schulze, 1989; Shahbazi et al., 2010). Scheludko et al. (1976) believes that the necessary condition for successful adhesion of particles on bubbles is that the contact time is greater than the induction time. The probability of adhesion between particles and bubbles increases with the increase of bubble size, but if the particle size is too small, the probability of adhesion decreases instead (Ren, et al. 2014; Norori- McCormac et al., 2017). After the particles adhere to the bubble surface, the particles will slide down to the bottom of the bubble due to gravity. At this point, the gravity, inertial centrifugal force and fluid force promote the desorption of particles from the bubble surface, while the surface tension, surface hydrophobic force maintain the stability of particles-bubble combination (Ralston et al.,2017). In addition, in the process of rising to the foam layer, desorption can also occurs. The purpose of this study is to observe the flotation behavior of fine fluorite with different size and to get a more comprehensive understanding of the interaction of fine fluorite particles and bubbles."

Jan 1, 2018

By T. B. M. Himawan

In this study, effect of thiosulphate and oxidation using oxygen were studied in arseno copper ore flotation. Single mineral study of chalcopyrite and tennantite in regard to the aforementioned techniques was also studied. Zeta potential, XPS, contact angle and floatability of single minerals were conducted for each treatment to understand the mechanism. It was revealed that the separation is best conducted in alkaline condition at where there will be interaction between thiosulphate and the mineral surface as well as the formation of hydroxide species in the oxidation using oxygen. From zeta potential of both thiosulphate and oxidation conditioning, it can be found that the reactivity of tennantite is much higher rather than chalcopyrite resulting higher rate of depression on both techniques as shown from contact angle and floatability of each mineral after treatment. XPS spectra confirmed qualitatively and quantitatively the existence of species responsible for the depression of each conditioning techniques. As for the copper ore flotation test, it is the oxidation using oxygen provides best performance after 60 minutes of oxidation. Keywords: tennantite, chalcopyrite, arseno copper ore A, thiosulphate, oxidation using oxygen

Sep 1, 2012

By Fedotov Pavel

"Today the main objective of improving the process of ore dressing is to reduce energy consumption and performance of the basic rule of auxiliary enrichment processes. One of the modern means of ore destruction with a minimum of energy consumption is the interparticle fracturing, for example in the roller press. There still remain the unsolved problems of the energy consumption determination and the particle size distribution of the crushing product .Existing methods for determining these parameters are empirical and require considerable expenses and time. The improved finite element was developed to solve these problems using finite element contact interaction of the rock. Also it was developed to clarify the stress-strain and the rock fracture energy in a layer. These elements are used to study ore destruction in the layer and allows to create a model taking into account the interaction of crushing particles surfaces. The same algorithm was developed determining crushing product particle size distribution in the layer on the base of the Bond’s theory of crushing. The presented finite element model allows to determine the quantity of strain energy and particle size distribution of crushed product during the destruction processes of the material in the roller press with fair accuracy."

Jan 1, 2014

By Vladimir Vigdergauz, Elena Belogub, Dmitriy Makarov

The influence of supergene oxidation on physicochemical and technological properties of polysulfide ores was studied. Modeling and analysis of oxidation pyrite copper-zinc ore samples from the Valentorskoye deposit show that sulfide floatability is decreased by the longer-term oxidation. The treatment of oxidized samples by sulfuric acid in oxidative conditions and its impact on the elemental sulfur composition on the surface of sulfides was discussed. It is shown that an enhancement of the floatability of sulfides of oxidized polysulfide ores after leaching by sulfuric acid could be perspective for the developing of combining floatation-hydrometallurgical technology of the nonferrous metals recovery.

Jan 1, 2014

The multiphase reactive flow in process equipments, e.g., fluidized beds, involves complex coupling among flow, heat/mass transfer and reaction kinetics over scales ranging from molecules, sub-particle eddies up to equipments. Conventional two-fluid model (TFM) ignores the effects of meso-scale structures, and hence is not suitable for describing the intrinsically multi-scale heterogeneity within multiphase systems. To be consistent with the meso-scale structures, we proposed a structure-dependent multi-fluid model (SFM), and closed its drag force by invoking the stability condition defined in the energy-minimization multi-scale (EMMS) model. The SFM reduces to the conventional TFM if homogeneous distribution is assumed within each grid, and reverts to the original EMMS model if it is used to describe steady state, global behavior of a fluidized bed. The multi-scale computational fluid dynamics (CFD), which is characterized by coupling of TFM and EMMS drag coefficient, can then be viewed as a simplified solution of the SFM. We demonstrate that the SFM significantly improves the accuracy and at the same time enables higher efficiency by allowing for much coarser grid used than in TFM. Recent application of it in 3D, full-loop, transient simulation of industrial processes, e.g., fluid catalytic cracking, coal combustion, gasification, kaolinite clay calcinations, shows its advantages in helping design and troubleshoot multiphase process equipments. Keywords: meso-scale, SFM, multiscale, CFD, simulation, structure, EMMS, multiphase

Sep 1, 2012

By Lev O. Filippov, Inna V. Filippova

"Flotation of metal-organic precipitate in column is sensible to the hydrodynamic conditions determined by the diameter and the dispersion of rising bubbles. Thus, the dissipation energy in the system resulting of ratio between superficial fluid velocities (gas and feed) in the column is the main parameter for precipitate flotation in pilot or industrial scales. The suggested limiting factor is the aggregate stability under the turbulence created by the rising bubbles. The stability of precipitate is related to the structural organisation of aggregates, which determines the size distribution of particles during precipitation and flotation stages.Structural evolution of Mo precipitate and the destruction phenomenon were described by using of the various fractal dimensions. The fractal studies allow the detection of a structural scaled organisation of the precipitate flocs. The fractal dimension of the particle mass distribution Dm=1.94+/-0.15 suggests, for the floc structure, a cluster-cluster aggregation process either with restructuring or breakage phases.The destruction process, which occurs for the lowest values of the dissipation energy E (0.02 . 0.05 W/kg) was characterised by a fractal dimension Dg of size distribution. Besides, the destruction of floc produces very fine particles, and thus induces the difficulties of bubble-particle collision during the precipitate flotation in column."

Jan 1, 2003

By T. Kalliomäki, B. P. Wilson, M. Lundström, J. Aromaa

"The diffusion rate of cupric ions and limiting current density are important factors that determine the rate of copper mass transport in electrolytes proximal to the electrodes used in electrorefining. As a result, diffusion can critically affect both the rate and morphology of cathodic copper deposition thus it is crucial that it be optimized to improve production. The diffusion coefficient of cupric ion (DCu(II)) in copper electrolytes has been previously researched but the values detailed in the literature show significant variations and moreover arsenic - a common impurity - is generally excluded. Furthermore, in previous studies the models have only been validated with model solutions rather than real industrial electrolytes. In this study, the limiting current density and diffusion coefficient of cupric ion were defined for synthetic electrolytes containing copper (40–60 g/dm3), nickel (0–20 g/dm3), sulfuric acid (130–220 g/dm3) and arsenic (0–45 g/dm3). The cathodic limiting current densities were measured at three temperatures (50, 60, 70 °C) with linear sweep voltammetry using the rotating disc electrode (RDE) as the cathode. By utilizing the limiting current density, models for the DCu(II) were constructed using Levich equation. The validity of the DCu(II) model for technical use was confirmed through their application to industrial electrorefining electrolytes with known element concentrations. Consequently, this study provides improved models for limiting current density and diffusion coefficient of cupric ion that can be utilized for industrial process optimization.INTRODUCTION For an efficient copper electrolysis process, the mass transport of copper ions has to be effective. The main mass transport types of copper ions in copper electrorefining are diffusion and convection while the effect of migration is negligible. In order to maintain good mass transport, it is beneficial to keep both diffusion and convection high to maximize the limiting current density (jlim) (Bard and Faulkner, 2001). jlim is the highest current density that can flow in the cell, thus by maximizing jlim the deposition time can be minimized and the good quality of cathodic copper can be ensured. Thus, it is important to research possibilities that increase and optimize diffusion since slow diffusion in the electrolyte limits the rate of the process (Levich, 1947; Moats et al., 2000; Subbaiah and Das, 1989)."

Jan 1, 2018

By P. Basarova

The attachment of bubbles onto a collecting surface is an ubiquitous natural phenomenon, playing a critical role in numerous practical processes. The goal of the project is to broaden the knowledge about hydrodynamic interactions between small bubbles and large solids that occur in nature and industrial processes. Focusing on collision processes between a single rising bubble (Db<1 mm) and a larger falling spherical particle in stagnant liquid, the theoretical model describing the bubble trajectory is given here. The model is based on analysis of forces acting on the bubble, and utilizes equation for the bubble motion. Mobile and immobile type of bubble surface mobility are considered. The calculated results are compared with the experimental data; here a high-speed video camera was used to capture the bubble motion and bubble-particle interaction. Very good agreement between experimental and calculated data was found. For both types of surface mobilities, the bubble deviation in the horizontal direction is nearly linear. The proportion constant is bigger for immobile bubble surface and increases with the bubble size. Furthermore, particular forces acting on bubble were studied. A similar course of relative bubble velocity and force impact was observed for identical bubble position. For cases when the bubble centre is close to the particle axis, only deflection in one direction is observed. When the bubble is reaching the maximum trajectory, the force ratio is changed. The bubble is firstly pushed away from the particle, but when it is within close distance from the particle, the bubble is pushed towards the particle.

Sep 1, 2012

By M. Morales, J. Yianatos

"In this work, an alternative approach to evaluate the flotation performance along a flotation rougher row is presented. The collection zone as well as the froth zone performances were separately evaluated. For this purpose, sampling for metallurgical balances along with sampling of top-of-froth (TOF) grades in each cell of a flotation row were employed. The modelling of the rougher circuit consisted of using TOF grades for evaluating the collection zone recovery, because they are a good representation of the bubble loading, which identifies the true flotation process, as shown in previous studies for shallow froths. In addition, the feed characterization, size-by-liberation, allowed the identification of the mineral distribution and its evolution along the circuit. The latter result was obtained by fitting the recovery profiles as well as the TOF grades down the flotation bank. The flotation rates and the maximum recoveries in terms of size-by-liberation (size classes: -45 µm, +45-150 µm, +150 µm, and liberation classes: -20%, +20%-80%, +80%) were then estimated. The results were in good agreement with those reported in literature by other authors and showed the new approach allows flotation kinetics to be characterized in industrial circuits.INTRODUCTIONMineral recovery in industrial flotation circuits is a function of the mineral characteristics, such as particle size distribution and liberation (Trahar, 1981, Jameson, 2012), and operating conditions such as air flowrate, pulp flowrate, solids percent and reagent conditioning (Jameson 1977; Klimpel, 1980; Mehrotra and Kapur, 1974). The cell type and size (self-aerated or forced air) and the circuit arrangement (single cells or banks of cells in series) are also relevant factors. Sampling of circuits (e.g. rougher, cleaner or scavenger) are commonly carried out using standard automatic samplers for metallurgical balance assessment. However, the flotation plants are generally not provided with proper accesses for local streams, which hinders the recovery estimations and the flotation rate characterization."

Jan 1, 2018

By Igor P. Solozhenkin, Peter M. Solozhenkin, Sanda Krausz

"In this work, authors will show the efficiency of computer technology and chemical programs at studying collectors for flotation of minerals of elements of platinum group (EPG). Clusters various minerals EPG (flotation reagents) are created, named us clusters minerals (reagents) as their structure corresponds to the chemical formula, and the distance between separate atoms corresponds to the known tabulated data. By molecular modeling are investigated clusters sperrylite PtAs2, stumpfilyte PtSb, sadberryte PdSb, sobolevskite PdBi, palladoarsenyte Pd2As, paolovyte Pd2Sn, rustenburgyte (Pt3Sn, Pt6Sn2) and their computer parameters (absolute rigidity, electronegativity, transfer factors of carry, charges of the atoms) are determined. Tellurides of palladium (IV, II) merenskyite PdTl2 and kotulskyte PdTe and platinum clusters are investigated: PtFe4, Pt3Fe, PtFe (Pt2Fe2), Pt2Fe (Cu) Ni. The technique of attachment of the collector (composites) to cluster atoms EPG is offered. For the first time, it is established that at linkage of flotation collectors on monodentate, bidentate and bridged to circuits with atoms clusters the minerals containing atoms As, Sb, Bi, Pb, Sn, reaction of connection with change of a degree of oxidation of these atoms and occurrence of a proton operates. It is executed virtual skirling organic compounds connections by the developed criteria from accessible libraries of a database. The principle of an estimation of interaction energy for flotation reagents with mineral clusters is offered. It is developed the prognosis of collector activity evaluation (P?AE) and his values for candidates in collectors for flotation of minerals EPG are calculated. For flotation of ores containing Pt and Pd minerals, a number of reagents, including compounds on basis P (III), for innovational technology of Pt, Pd mineral flotation are recommended. Key words: flotation, minerals, flotation reagents on the basis of phosphorus (III), molecular modelling, chemical programs, program ????? , electronic energy."

Jan 1, 2014

By M. Evertsson, E. Hulthén

"In aggregate production and mining the operators are responsible for controlling and monitoring the process to maintain high plant throughput and safe operation. Operators have to make different decisions to control the process due to changed demand on the operation from both management and conditions of the process. The quality of the response and the time it takes for an operator to respond to altered demand relies on what information is available and the experience of the operator. In this work a dynamic simulation platform has been developed to be used for operator training. Models for representing production units and process control for plant simulations have been developed and implemented in MATLAB/SIMULINK to simulate time-dependent plant behavior. Stochastic and scheduled events are included using the discrete events simulation toolbox SimEvents. The human-machine interface was developed using the human-machine interface software ICONICS. The operators’ cognitive process, in interpreting the plants semantic, has been studied by observations and with informal interviews with operators. This was done to get information about the daily operation and the problems that occur in the process. By interacting with operators that experience different physical interactions with the process; more qualitative e-learning software for supporting operator training in a dynamic operator environment could be developed. The quality of the operator training environment was evaluated with a usability study that was performed with operators and others within the production."

Jan 1, 2014