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By Tobias Hens, Andrew Frierdich, Barbara Etschmann, Joël Brugger, Barrie Bolton

"Advancing our knowledge about trace metal distribution and abundance provides insight into formation, alteration, and trace element enrichment processes of ferromanganese nodules and crusts. A fundamental understanding of these mechanisms, in turn, has implications for the selective recovery of critical metals and the development of sustainable hydrometallurgical techniques. Synchrotron-based X-ray Fluorescence (SXRF) is a powerful, state-of-the-art analytical tool that can examine geochemical features of Fe-Mn nodules and crusts, such as abundance and distribution of trace elements, in an integrated and efficient manner. By correlating trace element composition and Mn oxidation states in these highly complex samples, it can be determined whether these parameters are related to the Mn oxide mineralogy (vacancy content of crystal lattice) and chemistry.In this study, eleven Fe-Mn nodule and crust samples from three circum-Australian locations – the South Tasman Rise, Lord Howe Rise, and Coral Sea – were analyzed at the Australian Synchrotron, Victoria, Australia. Micrometer-scale spatial resolution of geochemical features, such as concentric growth structures and element distribution, was achieved with high sensitivity (Fig. 1). For instance, Ni could be detected at 10's of ppm to 1 wt% levels. Information on other redox-sensitive trace elements, which are present at 10-1000 ppm levels (e.g., Cu, Co, Ti), were gained by means of fully quantitative elemental composition maps."

Jan 1, 2017

By Tap Pryor

A very small nation with large seabed resources requires a strategy. The simplest approach is to duplicate every step taken by the United Nations (UN), in its own leasing programme. In addition, the smaller nations must sell itself and its competitive offering. It is one thing just to await applicants and/ or tenders, another to work to make the leasing seem like a very good idea. This cap be achieved through publications, correspondence, meetings (such as the Underwater Mining Institute, but especially through pro-active planning, seeking the ideal technologies in both harvesting and processing. The ideal would be some combination that could begin quickly and on a small scale. It must be within the UN environmental guidelines. To meet the "quick and small criteria," simple harvesting and physical processing methods must be given the highest priority. Once these are satisfied, then marketing studies can be completed. There is, of course, a market for every element but only careful engineering and cost analysis will determine accessibility. What is required is a stepwise approach, gaining greater and greater credibility at each step. In fact, much planning can be done for very low cost. In the Cook Islands, the first crucial step was the East-West Center publication which pulled together all facts in one volume and which found the local resource to be richer in significant ways than Clarion-Clipperton. Most seem to believe that it could be many years before full production is possible, but this has been conventional wisdom for so long that it has taken on the suspicious aura of myth. Is it real? Have all possible recent technologies such as robotics and physical processing been taken into account? Either way, it is essential that a comprehensive approach be taken so that all factors from resource to market are considered as inter-related until a single business plan emerges. When that is in hand and when its profitability and risk levels are found to be credible, adequate investment funds are available.

Jan 1, 1994

By Gary J. Massoth

Are hydrothermal emissions from subduction-related volcanic arcs important to the total hydrothermal burden of the oceans? While historical observations of hydrothermal venting of fluids at mid-ocean ridgecrests, intra-plate hotspots, and backarc spreading centers are numerous, we remain poorly informed regarding the contributions from hydrothermal systems associated with oceanic submarine arcs. Here we report the chemical results from the first systematic assessment for hydrothermal activity at an intra-oceanic arc front. We discovered that 7 of the 13 submarine volcanoes that define a 260-km-long segment of the southern Kermadec arc north of New Zealand are hydrothermally active. Most significant here is that the chemical compositions of the various hydrothermal systems, inferred from back-extrapolation of observations of hydrothermal plumes, are diverse, and in many instances enriched in the concentrations of gases (e.g., CO2 and H2S) and metals (e.g., Fe and Mn) compared to effluents commonly discharged from mid-ocean ridges. If our results are generally representative of submarine arcs, whose global extent may equal one-third that of ridgecrests, the answer to our leading question could be a resounding yes in terms of both volume and chemical composition.

Jan 1, 2001

By Lu Jun

Up to now, much data on marine minerals, as well as on marine geochemistry, have been accumulated. Modem computer databases provide optimum flexibility and power for manipulating these data. The best worldwide marine mineral database is currently the Marine Minerals Bibliography and Geochemical Data Base created by Carla Moore et al. at the National Geophysical Data Center in the United States. In fact, in the course of studying marine minerals and geochemistry we may collect not only digital-character type data but also graph and image (black-white, grey and color image) data types. For instance, correlation diagram between chemical compositions of minerals, spectroscopic graphs, (e.g. infrared spectra, Mossbauer spectra, etc.), grey or color images from both optical and electron micro- scopes (scanning or transmission electron microscopes) as well as seabed photographs. Charles L. Morgan et al. (1993) reported that 10,000 photographs and some video images of the seabed in the Clarion-Clipperton region of the northeastern tropical Pacific have been collected by the Ocean Minerals Company. If both graphic and analytical information were stored in a database, it would be very useful and convenient to marine geologists. This system would not only be able to search for all the data based on one parameter, but also for both size and composition distributions. If possible, geostatistical methods could be combined with fractal dimensional methods. Of course, this would require enormous efforts. Before multimedia technology emerged, it was very difficult to create image databases. The emergence of large-capacity compact discs, high-speed central processing units, and high-speed digital signal processing techniques makes it possible to establish multimedia database management systems (DBMS), image-text DBMS, that involves graphs, text, images, and sound. In order to store image fields in a DBMS, we have to take into account two problems: (1) image access format and (2) image compression code standard.

Jan 1, 1994

By L. B. Khershberg

According to geochemical specialization, cobalt-manganese crusts (CMC) of the Magellan Seamounts are rich in cobalt and manganese and are complex in composition. Besides cobalt, manganese, and nickel, they contain such components, as platinum, copper, molybdenum, and rare earth elements, which enhance the value of this material. Factors and conditions responsible for Co-Mn ore-genesis and processes of cobalt-manganese crust formation are described in a number of Russian and foreign geological papers. The study of ore-concentrating processes in the Magellan Seamounts helped to solve an important applied problem, namely to reduce the time needed to reveal the factors of CMC formation mechanism. The authors of this research found seawater over the described area of Magellan Seamounts to be stratified and to contain high concentrations of manganese, iron, cobalt, nickel, copper, lead, and zinc. Diagrams of suspended Co, Mn, Ni, and other components in seawater (0-5500 m), as well as medium concentrations of basic elements (Co, Mn, and Ni) in ore deposits of metallogenic levels of Magellan Seamounts, were found to coincide both on guyots and abyssal plains. Detailed geological study of guyots in the Magellan Seamounts (Dalmorgeo, IOAN, Roskomnedra, and others) revealed that medium Co-Mn crusts cover bedrock rocks in narrow ribbon-like bodies along the edges of bathymetric intervals 1300-1600 m, 1400-2000 m, 2000-2500 m, and 2500-3000 m.

Jan 1, 2004

By Anthony T. Jones

Deep seabed mining requires technology to collect materials and transport them to the surface. An international patent search was conducted to define the state of the art in seabed mining technology. Over 350 patents were identified from 12 patent systems. The majority was from the United States, Japan, and the former USSR. Patent activity in this field peaked in 1983 when 34 patents were issued. Since 1984, on average 6 patents have been issued annually. The technology represents ten major classifications. With the exception of Deepsea Ventures, Kawasaki and International Nickel, it appears that much of the technology developed and tested in the 1970s by consortia active in seabed mining was never patented. Over the past two decades, identifiable trends in marine technology could influence seabed mining application such as more sophisticated communication systems, advances in hydraulic manipulators, improved computational technology in navigation, modeling of vessel ? ocean interactions, and improved materials. The most significant recent activity has been in European applications, which disclose remotely controlled subsea vehicles for mining diamonds.

Jan 1, 2001

By Porter Hoagland

There has been a recent surge of interest in existing and proposed institutional mechanisms that would govern the exploration and disposal of nonfuel minerals within the U.S. ocean jurisdiction. The Minerals Management service, a bureau of the Interior Department, has begun to promulgate regulations to allow the exploration and leasing of lands for nonfuel mineral development on the outer Continental Shelf of the united States. At the same time, a bill has been introduced in the U.S. Congress that would create a new ?national seabed? and authorize the allocation of exploration licenses for marine nonfuel minerals. Because only limited efforts have been devoted to the discovery of marine nonfuels in areas beyond the territorial sea of the United States (and no production has occurred), exploration and the generation of resource information are two primary foci of these regulatory and legislative efforts. Generally, minerals exploration activities (and associated R&D on exploration and production technologies) are eligible for the same institutional incentives available for other industrial efforts, including tax preferences for research and experimentation, patent protection, small business innovation research grants, and even the new leniency in antitrust rules

Jan 1, 1988

By Walter L. O?Niell

The Continental Shelf Division of the Marine Minerals Technology Center has recently completed field tests of the percussion- waterlift drill and the vibracore/vibralift convertible drill. The two systems have been modified from existing drills to increase their effectiveness and flexibility for nearshore minerals exploration. Originally the percussion-waterlift drill was designed for iand based operations, but it has been modified for use in protected shallow water areas. This drill is easily maintained, inexpensive to construct and operate, and is able to accurately recover representative samples from a variety of sedimentary deposits. Sampling is accomplished using either a reverse circulation method for the recovery of a slurry of sediment cuttings and water or employing a thin walled "Shelby tube" to core zones of interest. The vibracore/vibralift convertible drill is a modification of the remote placer drill (RPD). By combining these drills into one convertible system, it is possible to recover continuous cores of unconsolidated fine-grained sediments (vibracore), a slurry of clay to gravel size sediments over 1.0 meter intervals (vibralift), and to sample sedimentary material in environments where indurated

Jan 1, 1991

By Akira Usui

Platinum is one of the most rare elements in the earth?s crust, but it is significantly enriched in some hydrogenetic ferromanganese crusts in the ocean. The element is essential to the electric industry and is believed to be of importance as a raw material a future fuel-cell industry. The earlier reliable chemical analysis of platinum-group elements (PGE) of ferromanganese crusts have indicated a variety of concentrations of Pt in the range of 100 ppb to a maximum of about 1 ppm, but little is known about the elemental abundance in ferromanganese crusts on fine-scale, or the geochemical behavior and form of the element. The chemical and mineralogical forms of platinum and its group are important in planning the methods of mineral exploration and extraction of the elements from of ferromanganese crusts. We attempted to characterize the distribution pattern within a cobalt-rich crust on the fine to microscopic scales by using reflecting microscope, scanning electron microscope/energy-dispersive spectroscopy, electron microprobe X-ray analysis (EPMA), ICP-mass spectroscopy, X-ray absorption near edge structure (XANES), small-focus XRF, and X-ray diffraction (XRD). These data indicated a wide range of Pt concentration from 150 to 700 ppb within a crust, though we found no distinct inter-element correlation or mineralogical control. Under the reflecting and electron microscope, no distinct Pt-bearing minerals or particles were identified. Small-focus XRF indicated no uneven distribution in any particulate matter, but all areas are less in abundance than the detection limit of about 10 ppm. Our tentative conclusion is that zero valence Pt0 (as suggested by XANES) is dispersed in the form of submicroscopic material most probably within ferromanganese minerals, and therefore, Pt-rich mineral particles may not be a major carrying phase.

Jan 1, 2005

By Benjamin W. Haynes

The Federal government has a lengthy history in supporting and conducting research in the ocean mining and minerals field. The Federal effort has been and is currently focused primarily in four agencies: the National Oceanic and Atmospheric Administration (NOAA) within the Department of Commerce, and the Geological Survey (USGS), the Bureau of Mines (BuMines), and more recently the Minerals Management Service (MMS) within the Department of the Interior. While NOAA and the USGS have played dominant roles in mapping and geologic studies, and the MMS has recently provided funding for several task force studies within the Exclusive Economic Zone (EEZ) , the Bureau of Mines has conducted research in mining technology, minerals processing, resource definition, and economic evaluation of minerals from the seabed for over 20 years. These studies have yielded considerable minerals information regarding manganese nodules and crusts, placers, mineral sands, phosphorites, and sulfides. This paper reviews the past achievements in ocean mining and minerals programs starting in the late 1960's, describes current research and information efforts, and presents an outlook for Bureau of Mines research and information gathering efforts. Specific topics

Jan 1, 1989

By D. S. Cronan

Studies on polymetallic manganese nodules and Co-rich crusts in the EEZ's of the Cook, Line, Ellice and Phoenix Islands between 0-20°S show that Ni and Cu reach their greatest combined abundances of over 2% between 2-8°S on the southern margin of the equatorial zone of high biological productivity, as a result of biological fluxing of Ni and Cu to the nodules at and just below the CCD. By contrast, Co reaches it greatest abundance of 0.6% south of 8°S in nodules on non-biogenic clays well below the CCD where little biological Co supply is likely. Nodule abundances are greatest (up to 30kg/m2) in the Co-rich area in part due to AABW flow, giving highest overall metal quantities per sq meter in the nodules there, particularly of Co. There are approximately 110 x 106 tonnnes of combined Ni plus Cu plus Co expressed as Ni equivalent in Cook Islands EEZ nodules, approximately 12 x 106t. in Phoenix Islands ones, and approximately 1.4 x 106 t. in Ellice Islands ones, in areas of greater than 5kg/m2 nodule abundance. In the Co-rich crusts, Co averages about 0.7% and crust thickness about 1.6cm, both related to metal fluxes in and adjacent to the 02 minimum zone in association with which both maximum thicknesses and Co grades occur. Within the Cook Islands permissive area there are about 930 x 103 t. of Co and 630 x 103 t. of Ni in crusts, in Phoenix Islands crusts there are about 69 x 103 t. of Co and 55 x 103 t. of Ni, and in Ellice Islands crusts there are about

Jan 1, 1989

By Chris Castle

Following the recent award of a prospecting license by the New Zealand Government, Widespread Energy Ltd. (Widespread) is focused on the acceleration of its exploration program in order to bring a potential phosphorite deposit to market in the near future. Rock phosphate is the primary constituent of most fertilizers that are manufactured and distributed in New Zealand. Field trials in the 1980s demonstrated that direct application of rock phosphate can result in a more effective fertilizer (than super-phosphate) with less environmental damage from run-off. At present virtually all of the rock phosphate used by the New Zealand fertilizer industry (approximately 1 million tonnes a year) is imported from Morocco. In recent years price increases of up to 12 fold (peak of $500/t) with massive increases in freight costs have bought to the forefront the economic opportunity to in part replace foreign imports with a local source of phosphate. The Chatham Rise phosphate deposits are relatively well understood, having being discovered during the 1950?s and it is estimated that approximately 100 years supply (at current requirements) is present at shallow depths. An estimated 100 million tonnes of rock phosphate is present within the license area based on previous private and publicly funded research. Widespread has engaged several parties to assist in the exploration planning to confirm the resource potential. Widespread has commenced investigating the feasibility of recovering the phosphorite nodules off the sea floor, and presently has several conceptual technical solutions under consideration and will advance the discussions with potential contractors during the exploration phases. Widespread is acutely aware of its responsibilities to conduct both the exploration program and extraction of the rock phosphate, in a manner that causes minimal disruption to the marine environment. To this end, the National Institute of Water and Atmosphere (NIWA) ? a New Zealand Crown Research Institute has been engaged to assist in designing sampling and extraction methods that will minimize disruption to the seabed. All sampling and extraction activities are planned to be conducted with reference to the environmental guidelines published by the International Marine Minerals Society ?Code for Environmental Management of Marine Mining.? Widespread is conducting its project with a background of changing regimes to both the allocation and environmental management of its activities.

Jan 1, 2010

By Natsumi Kamiya

The Metal Mining Agency of Japan (MMAJ) has started the project in the fiscal year of 1989 under the administration of the Ministry of International Trade and Industry '(MITI). The purpose of this study is to assess the impact on the ocean environment caused by manganese nodules mining. Summary of research and survey of MMAJ is as follows: 1. Evaluation of environment impact The aim of this study is to assess impact for ocean environment by manganese nodules mining. It is studied by using three-dimensional hydrodynamic prediction model and by carrying out cultural experiment of surface fauna with adding deepsea water and sediment. Development of hydrodynamic prediction model for discharged water at ocean surface has started in 1989. On board cultural experiment was carried out in the Japanese application area in the eastern Pacific in May 1991 and in May 1992.

Jan 1, 1993

In the western Woodlark Basin, propagation of seafloor spreading is occurring directly into the continental crust of Papua new Guinea. The spreading is not strictly in a back-arc tectonic setting, rather it appears associated with microplate rotations related to the complex convergence of the Indo-Australian and Pacific plates in the southeastern Pacific region. Volcanic rocks along the western Woodlark spreading axis range from normal mid- ocean ridge basalts to basaltic andesites with back-arc geochemical affinities. Rare peralkaline rhyolites also occur. Hydrothermal deposits occur at a basaltic andesite volcano located on the neovolcanic zone near its westernmost propagating tip. Franklin Seamount is a 250m-high cone constructed largely of pillow lavas and talus which sits astride a 450m-high ridge of similar lavas oriented subnormal to the spreading direction. At its crest, 2150m below sea level, there is a 100m-deep caldera.

Jan 1, 1993

By Chul H. Jo

The functions of miner mainly include the pick-up manganese nodules laying on the surface of the seafloor, the separation them from sediments, the crushing the nodules and the covey to the inlet of the flexible hose. The miner is connected with umbilical cable that can supply power, instrument signal, communication data, etc. The major concerns of the system is to monitor and control the launching and retrieval operation, the landing, maneuvering and track keeping, to monitor the pick-up operation and to monitor the hydraulic system. Also as per the seafloor profile the track and pick-up processes need to be controlled. The recent research and development of deep sea miner is mainly focused on the efficient performance and workability in deep water. To communicate and control the miner, navigation and positioning system have been applied. As the miner is being deployed or retrieved, it is very critical to avoid any damage to the device that would be caused by the dynamic behavior of surface vessel or the minor itself with wave and current motion. The fast deployment and retrieve should be considered very important to minimize the possible damage. The paper introduces the various type of deployment devices and recommend the possible system to the miner developed by KRISO.

Jan 1, 2003

By Fredrik Søreide

Several potential marine mineral deposits of various types have been identified within the Norwegian EEZ. The Norwegian University of Science and Technology has recently designed and built a new remotely operated vehicle (ROV) system for scientific investigations of the deep-ocean and seafloor. A program to locate and investigate the most interesting of the identified marine mineral deposits using the new ROV system is underway. The ROV has been designed for detailed survey and sampling tasks. Although initially built for a major marine archaeology project, the design is equally suited to locate and investigate marine mineral deposits. The ROV is equipped with a high precision multi-sensory package that consists of various high quality cameras and lighting systems (together with state-of-the-art video and photo mosaic systems), several sonar systems, magnetometer and various other sensors. The ROV is also equipped with a 7-function manipulator arm and an excavation system. Internal collection baskets are used to store material for retrieval to the surface. A closed-loop control dynamic positioning system is used for detailed positioning of the ROV. Position data and other information are stored in a digital data management system. The ROV will also be used together with a specially developed remotely operated tool (ROT). The size and shape of this benthic lander can be adjusted before it is carefully lowered to the seafloor. The ROV can be docked on a moving platform on the ROT, to do detailed scientific investigations. The ROT can also be equipped with a separate sensor and system package, including drilling, excavation and coring units. This paper will present the new remotely operated system and the planned projects in Norway.

Jan 1, 2004

By Tetsuo Yamazaki

The importance of cobalt-rich manganese crusts on the Pacific seamounts for possible future rare metal sources has currently been recognized. The thin layer-type deposit characteristics affect not only the excavation efficiency but also the economy of mining venture. Considering the thin layer-type distribution and the utilization of some rare metals in cobalt-rich manganese crusts, a preliminary economic feasibility of the mining venture is evaluated. Under some preliminary technical assumptions, the possibility of cobalt-rich manganese crusts for future rare metal sources for Japan is examined. The important role of utilization of rare metals in the crusts is highlighted.

Jan 1, 2010

By Steven D. Scott

Stephen D. Scott Steven Scott is a Professor of Geology, Director of the Marine Geology Research Laboratory and, until May 1997, was Chairman for 9 years of Geological and Mining Engineering, all at the University of Toronto. Steve also holds a cross appointment at the University of Western Brittany's European University Institute of the Sea in Brest, France. He was educated at the University of Western Ontario (B.Sc. and M.Sc.) and at Penn State (Ph.D.). Steve is a geologist/oceanographer specializing in base and precious metal massive sulfide deposits which he and his students have studied on five continents and on the bottom of three oceans. He was the first ore deposits geologist and first Canadian to witness "black smokers" on the ocean floor. Since 1982, he has participated on 21 oceanographic surface and submersible expeditions, many of them as Chief Scientist. His research team is currently carrying out projects in the W and NE Pacific Ocean. Steve has published more than 150 research papers and lectured in more than a dozen counties. Popularized accounts of his work have appeared in various media.. He has been honored by several awards and distinguished lectureships. Steve is President of the Canadian Scientific Submersible Facility, which operates the Canadian ROPOS robotic submersible, and is President of the International Marine Minerals Society.

Jan 1, 1998

By Marco Figoni

The increased interest on deep water minerals resources is a challenge for both mining and oil industry. The exploration and production of oceans minerals require a synergy between of different technologies. While mining industry is leading the dredging and processing part of the system, oil industry is contributing through development of ore lifting technology based on existing subsea knowledge. The paper presents an overview, based on published projects around the world, of different approaches to marine mining. Several exploration techniques and offshore production systems were already designed and assessed, all of them with apparently positive results. Exploration phase is well advanced and in continuous expansion allowing the discovery of increasing resources around the world of different nature but production can be considered to be in an early stage. Different from onshore mining, subsea operations require a closer cooperation with international and local authorities to preserve as much as possible the environment. There are still many uncertainties at respect and all the exploration process must be carefully evaluated to allow subsea mining to develop in a sustainable manner. Technically, mining at seabed was already demonstrated and the process is based on three main components, namely seafloor mining tools, riser and lifting system and production vessel support. This layout is based on the concept that ore must be disaggregated at seafloor first, transported to surface in form of slurry that must be dewatered before loading to be transported to processing plants onshore. The challenges are rising because the environment and safety must be taken into consideration as a priority when evaluating the efficiency of the system. The most critical challenges regarding the production operations, especially in deep water are the deep-sea excavation process, the transport of large slurry volumes, the slurry abrasivity, the power supply management and the subsea

Sep 14, 2011

By John W. Padan

The 1982 United Nations Convention on the Law of the Sea contains major provisions that U.S. negotiators have sought for over two decades. The internationally recognized right to the mineral resources of a broad continental margin is of potentially enormous future importance to the United States. Although water depths reach 10,000 feet in some of the deeper areas of the margin, technology is rapidly making those depths economically accessible. In 1997, production in the Gulf of Mexico will reach a world record water depth of 5400 feet. Of perhaps even greater importance to the oil and gas industry is the broadly acknowledged right for tanker transport of oil to take place throughout all parts of the world's oceans.

Jan 1, 1996