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By O. Zach, K. Gamweger

"The Process of gas purging in molten Aluminium has been an industrial practise for many years. The melting of alloying elements and their rapid distribution in the bath is very important. To improve the mixing and homogenisation process, at RHI NON FERROUS METALS ENGENEERING GMBH a lot of CFD calculations were done. The so developed new ""purging program"" was tested at Alumino Catalan S.A., Spain. The results of the testtrials were very satisfactory and corresponds very well with the calculated data."

Jan 1, 2004

By Z. Zhang, X. -G. Chen, F. Breton, A. Arici

"The microstructure of Al-10Si-0.3Mg-0.5Mn alloy with 0.27% Zr and 0.19% V addition was quantitatively analysed and compared to the base material. The addition of Zr and V in the AlSi10Mg alloy exhibit a beneficial effect on the Si modification, resulting in the reduction of the size of eutectic Si particles on both as-cast and T6 conditions. The quantitative image analysis results show that the Zr and V addition and T6 treatment can reduce the size of the intermetallic phases. In addition, the presence of Zr and V is favour to the partial dissolution of the intermetallic phases during the T6 treatment. Different heat treatment procedures were tested to optimize treatment parameters. The mechanical properties of the alloys were evaluated using hardness measurements and tensile tests. The results show that the addition of Zr and V can remarkably improve the mechanical properties on as-cast and T6-treated conditions. The correlation between the microstructure and mechanical properties of the alloys is discussed.INTRODUCTION Al-Si-Mg foundry alloys have been widely used in automotive and aerospace industries due to their high strength-to-weight ratio, heat-treatable capability and excellent castability. The alloying elements such as Cu, Mn, Fe are traditionally added into Al-Si-Mg alloys to improve their mechanical properties (Mohamed, Samuel, Samuel & Doty, 2009). In recent years, the attention has been paid to the effect of the transition elements such as Zr, V, Ti, etc, as minor alloying additives, on the properties of aluminum alloys (Elhadari, Patel, Chen, & Kasprzak, 2011; Kasprzak, Amirkhiz & Niewczas, 2014; Shaha, Czerwinski, Kasprzak, Friedman & Chen, 2015; Shaha, Czerwinski, Kasprzak & Chen, 2014; Mahmudi, Sepehrband, Ghasemi & 2006; Meng, Cui, Zhao & Zuo, 2013). Kasprzak et al., (2014) and Shaha et al., (2015) reported that additions of Zr, V, and Ti in Al-Si-Cu-Mg cast alloys can improve the alloy mechanical properties at high temperature by forming stable intermetallics and precipitates on as-cast and heat treatment conditions. On the other hand, the mechanical properties of near-eutectic and eutectic Al–Si cast alloys depend not only on the chemical composition but also, even more importantly, on microstructural features such as the morphology and size of eutectic silicon and intermetallic particles, which are present on both as-cast and heat treatment conditions (Mohamed et al., 2009). However, there is rather limited information on the effect of Zr and V on the microstructure features and mechanical properties of near-eutectic Al-Si-Mg cast alloys."

Jan 1, 2018

By M. DeLucia

"Over the past 15 years, technical innovations have improved the properties and performance of monolithic refractories. As these improvements have occurred, aluminum cast-house refractory selections have changed from brick to monolithic refractories supplied as either cast in place, or precast, ""Big-Block"" installations. A review of the properties of monolithic and brick refractories is presented, as well as the technical advantages of brick for highly demanding applications. Operating conditions and issues such as temperature, alloying, corundum growth and other variables are also reviewed."

Jan 1, 2004

By David Green

"This paper describes Outokumpu's Tank Cell concept using the unit reactor principle and operating experience gained in various applications. Presently the tank cells used range in size from 35 t pilot size to 100 m' (3500 cuft). The paper discusses operating experience and results from commercial installations in copper and zinc rougher and cleaner services.The key feature of the Tank Cell described is the effective control of the froth phase and resulting possibility to operate on an improved grade recovery curve by manipulating the control variables."

Jan 1, 1995

By F. Habashi

In the period 1970-1995, a number of hydro metallurgical processes to treat copper concentrates to overcome the pollution problem due to S02 emission in smelters were developed. Pilot and commercial scale plants were built and operated for some time, but eventually all were abandoned a few years later. It is constructive to examine why these processes were abandoned after so much expenditure of funds and effort, so that errors should not be repeated in the future and lessons from the past are learned.

Jan 1, 2007

By R. M. Kalanchey

The application of pressure oxidation processes to copper feed materials has gained increased exposure in recent years and some of these processes have made commercial inroads, although rather limited to date. Among the hydrometallurgical processes with significant commercial potential, Dynatec's copper pressure leaching process has been applied to arsenic-bearing copper materials and has shown, through a number of batch and continuous test programs, that pressure oxidation is a technically feasible option for the recovery of copper with coincident sequestration of arsenic in an environmentally benign residue.

Jan 1, 2007

By Q. Jia, M. Rigaud, F. Ye, X. Zhong

In this work, the rheological behavior of ultra-low cement alumina-based castables with addition of flake graphite and extruded graphite pellets has been investigated. Emphasis has been laid on the influence of the type and amount of carbon additions and the results are compared with corresponding alumina castable samples without any carbon addition. It is found that alumina-based castables with extruded graphite pellets have good rheological behavior and flowability with lower water demand (< 6.3%), and no segregation during the shearing of castable.

Jan 1, 2004

By M. Uszko

Methane drainage and ventilation methods of methane hazard mitigation are used in the coal mines of Kompania Weglowa S.A. Over 22% of methane released during mining activities is captured by methane drainage systems and transported to the surface. In this article we present development plans for utilization of methane captured and transported to the surface by methane drainage systems. The results of research on the possibility of economic utilization of methane concentrated in ventilation air that leaves the mine through fan diffusers are also described.

Aug 1, 2013

By T. H. Etsell, P. C. Holloway

Vanadium is concentrated in the fly ash which is produced as a solid waste from oil sands operations in northern Alberta. Although a process flowsheet using sodium chloride as a roasting reagent has been developed at the University of Alberta, recent studies examine the p otential o f p otassium o r c alcium s alts a s alternative reagents for roasting Suncor fly ash to recover vanadium. Suncor fly ash was roasted with CaO, Ca(OH)2, CaCO3, CaSO4.2H2O and KC1 at 750, 850 and 950°C. Water leach extractions for the calcium compounds were low (<45%); leaching with 100 g/L Na2CO3 gave maximum extractions of 56 to 69% at 950°C. Ash roasted with KCI behaved similarly to ash roasted with NaCl. These tests indicate that similar roasting conditions (25 to 30% KCI, 850°C, and 2 to 4h) could be used to achieve similar water leach extractions (75 to 85%). However, the lower solubility of KVO3 in solution, compared to NaVO3, would make the use of KCI instead of NaCl less attractive from a process and economic standpoint. Mineralogically, leucite (KAlSi3O8) was the predominant phase in ash roasted with KCl while, in crystalline samples of ash roasted with calcium compounds, anorthite (CaAl2Si2O8) and pseudobrookite (Fe2TiO5) were identified. Ash roasted below 950°C with the calcium compounds remained poorly crystalline.

Jan 1, 2004

By C. Allen, M. Gangal, J. Stachulak

"Most underground diesel equipment is equipped with diesel oxidization catalysts (DOCs) to reduce carbon monoxide and hydrocarbon emissions. DOCs do not alter nitrogen oxides concentrations but can promote the oxidization of nitric oxide (NO) to the more toxic nitrogen dioxide (NO2). Vale and CanmetMINING have been researching how to reduce worker exposure to diesel emissions by testing mining equipment DOCs. Results indicate a > 77% decrease in carbon monoxide concentration but a 46–315% increase in NO2 concentration for 8-mode test cycles. It is recommended that DOCs that increase NO2 emissions be evaluated regarding their continued use in underground operations.RÉSUMÉ La plupart des équipements miniers souterrains sont équipés de catalyseurs d’oxydation diesel (DOC) afin de réduire les émissions de monoxyde de carbone et d’hydrocarbures. Les DOC ne modifient pas les concentrations des oxydes d’azote mais ils peuvent faciliter l’oxydation du monoxide d’azote (NO) en dioxyde d’azote (NO2), plus toxique. Vale et CanmetMINING effectuent des recherches pour réduire l’exposition des travailleurs aux émissions de diesel en analysant les DOC des équipements miniers. Selon les résultats, une diminution > 77 % dans la concentration de monoxyde de carbone est atteinte mais elle est accompagnée d’une augmentation de 46 à 315 % de la concentration en NO2 pour des cycles d’essais à 8 modes. Il est recommandé d’évaluer les DOC qui augmentent les émissions de NO2 pour décider de la poursuite de leur utilisation dans les opérations souterraines."

Jan 1, 2016

By Y. Qi

A cell-level nonlinear dynamic model of solid oxide fuel cell (SOFC) based on physical diffusion principles is built in this note. It demonstrates that reactant diffusion processes from gas flow bulks to triple phase boundaries (tpbs) play an important role in the dynamic behaviors of SOFC. The simulation shows that under certain condition, the effect of the double layer capacitance may be neglected. The phenomenon of slow rise of voltage in current interrupt experiment may be explained by the dynamic behaviors of partial pressures in the vicinity immediately above tpbs.

Jan 1, 2005

By X. Zhong

Thermal shock resistant properties of reaction sintered bauxite-based ß -Sialon bonded corundum have been investigated, and the results are compared with those of Al2O3 based counterpart. It is found they all have very good thermal shock resistance. Their residual strength ratios after one thermal shock cycle at ? T=1200°C and A T=1350°C are 61-73% and 53-65% respectively. TSR parameters are calculated based on thermal expansion, modulus of elasticity, and fracture toughness determined. The reasons for improved TSR of these composite materials are discussed.

Jan 1, 2004

By M. Spreij, M. Hogenboom

Refractory lining performance of aluminium melting and holding furnaces and downtime due to refractory re-linings, are important parameters for increasing the aluminium output of a cast house and decreasing costs. The importance of refractory materials testing is illustrated by examples of improvements made in refractory lining concepts, quality control and introduction of alternative and newly developed materials. These examples also show that the information given by product definitions of refractory suppliers will in many cases be insufficient to judge the risks and benefits of using alternative materials.

Jan 1, 2004

By H. P{ops

This paper summarizes important developments that have occurred in the mining and subsequent production of copper into rod and wire from 9000 B.C. until the present time. Principles and practices associated with continuous rod production are discussed from a metallurgical perspective, and include the effects of oxygen content and impurities. A brief historical review is also given of important wire drawing events dating back thousands of years. Finally, predictions concerning the future of the wire and cable industry are presented with particular emphasis upon copper wire, technology in this market, and competitive materials.

Jan 1, 2007

By Michael Schindler

Uranyl mineral dissolution appears to be complex, affected by factors such as solution pH and the presence of various cations in solution, and sometimes involving formation of secondary surface precipitates. Such secondary precipitates potentially could armor the underlying uranyl mineral surfaces from further dissolution. A detailed understanding on the formation of secondary precipitate is therefore essential for predictive modeling of radionuclide fate and transport in the subsurface. Several types of secondary precipitates on the surface of uranyl minerals were examined using Atomic Force Microscopy, Scanning Electron Microscopy, and, Xray Photoelectron Spectroscopy.

Aug 1, 2010

By Kevin Azocar, Jim Hazzard

"Slope stability analysis is performed most commonly using limit equilibrium calculations or numerical models assuming a two-dimensional slice through an infinitely long slope surface. In areas such as open pit mining, where most slope surfaces are not planar, the importance of curvature becomes important due to the economic gains associated with creating a steeper slope. With advances in computing capabilities within the last decade, three-dimensional slope analysis can be performed within reasonable time frames. Some work has been done on the potential importance of curvature on slope stability, mainly assuming homogenous materials with a circular shear-failure mechanism. However, many open pit mines are excavated in jointed rock mass where a completely different set of failure mechanisms can be seen. Depending on the geometry and radius of the pit, the curved geometry may influence the factor of safety and failure behaviour compared to a two-dimensional slice.A series of numerical analyses were performed to investigate the effect of curvature on jointed rock slope stability compared to an equivalent two-dimensional slope analysis. By using discrete element method models, the influence of joint planes and interaction between distinct blocks can be seen. With a three-dimensional model, the effect of curvature can be combined with multiple joint sets at any orientation, which cannot be seen in a single slice. Numerous three-dimensional models are created, along with an equivalent unit-thick slice. The effect of curvature on a variety of different types of failure mechanisms is observed, and graphical relationships are created to quantify the difference between the three-dimensional factor of safety and the two-dimensional factor of safety based on the degree of curvature."

Jan 1, 2015

By Greg Gosson

"Early efforts to develop formal reporting systems to quantify and classify mineral deposits date back over 100 years. (e.g. Hoover 1909: “Proved, Probable, Prospective Ore”). This was at first driven by mine operators’ need for reliable estimates of what their mines could produce. Disruption of transportation routes by world wars prompted western governments to recognize the need for assessments of strategic sources of metals and minerals that could support domestic industry during times of crisis. Categories were created to quantify mineral potential which were additional to those of mine reserves. Terms such as hypothetical and undiscovered resources entered the lexicon. Capital markets serving the mining industry were traumatized during the latter part of the 20th century by undisciplined and fraudulent disclosure by exploration companies of mineral deposit potential. Government securities regulators pressed for the development of credible reporting codes (e.g. SEC Industry Guide 7: 1981; JORC 1989; SAMREC 1994, CIM 2000). Representative organizations from the major western mining countries generally agreed that there should only be three categories of mineral resources (measured, indicated, and inferred) and two categories of mineral reserves (proven and probable). This was formalized in 1997 with the “Denver Accord”. Acceptance of the standard terminology may have been the easy part, because the challenge for the 21st century is to get general industry acceptance and agreement of the principles behind the definitions of each category. There has been noticeable movement towards this objective in the last few years. This is reflected in part in the updated reporting codes by JORC 2004, CIM 2005; SAMREC 2007; SME 2007; and PERC 2008, and the development of the CRIRSCO International Reporting Template 2007."

Jan 1, 2003

By W. Haibei, Lei. Z., Z. Bangsheng, W. Yufang, J. Kaixi

In 2007 output of zinc was more than 3.71 million tons in China. Some new projects have finished FS and several new zinc plants are building now. In recent ten years it happened great changes in zinc industry. For zinc concentrates one pressure leaching plant was built with capacity 10,000t/a and at least four companies are carrying out FS or engineering design now. Direct atmospheric leaching will put into used in China in 2008 with capacity 100,000t/a. It is estimated that until 2010 the output of direct leaching will be 400,000t/a.

Jan 1, 2008

Recently, renewed interest in the recovery of uranium from leach solutions has necessitated a re-examination of the hydrometallurgy methods used for uranium in the 1960?s to 1970?s. A synthesizing overview of the lessons learned in those decades together with examination of recent developments in this area is warranted. This paper considers uranium recovery chemistry from acid and alkali leach solutions using solvent extraction and resin ion exchange, and provides information on circuit selection and configuration, equipment selection and design, as well as operational considerations. The unique thermodynamics of uranium solvent extraction are also presented and discussed.

Aug 1, 2010

By J. Koike

Mg alloys for structural application have attracted much attention. However, high process cost and poor mechanical reliability are major concerns upon expanding the application to a wider area. In order to break through these barriers, better ductility is desired at lower temperature. Plastic anisotropy and peculiar twin formation appear to play key roles in the deformation and fracture mechanisms of Mg alloys. In the paper, dislocation slip and twin formation are reviewed. The effects of crystallographic texture and grain size are discussed. The results suggest that a good control of microstructure and texture can improve ductility and mechanical reliability of Mg alloys.

Jan 1, 2006