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By Haibin Wang, Zhiwei Huang, Zhixiang Cui, Wenzhao Cui, Zhi Wang

Fangyuan Two-Step copper smelting process was commercialized in October, 2015 and has been operating for 3 years and 5 months. As the unique continuous copper smelting process with simplified flow in the world, production parameters have been significantly improved after three years. In the first half of 2018, the feed rate was above 200t/h, availability reached 97.5%, operation cost was about 20% lower than the conventional three-step processes showing obvious economic advantages. The Two-Step process in Fangyuan is composed of 1 Submerged Lance Smelting furnace (SLS) and 2 Submerged Lance Converting& Refining furnaces (SLCR). Two SLCRs work alternatively to ensure continuous production. High grade and liquid matte from the SLS is introduced to the SLCR by sealed launder to complete converting and refining. The SLCR is an original and independent innovation of Fangyuan, for which Fangyuan completed lots of development and improvement. This paper will introduce the process and experience. INTRODUCTION China is the largest producer and consumer of refined copper. Most of the processes adopted in China are conventional "Three-Step" copper smelting processes, which are comprised of smelting, converting and refining. There exists some problems in the conventional processes, such as high energy consumption, large heat loss, low altitude emission of SO2, etc. To deal with these problems, Fangyuan developed the new copper smelting process with simplified flow, low cost, clean and high efficiency. The SLCR that combines converting and the refining process was also developed, which shortens the process flow from conventional three steps to two steps. The SLCR is of great significance in promoting the development of the copper industry. Development and industrialization of SLCR At present, copper concentrates are treated in three steps: smelting, converting and refining. Anodes are also produced by continuous converting processes such as the Mitsubishi process and the Double Flash process. Problems like matte transportation by ladle, capacity limitation, and low altitude pollution exist.

Jan 1, 2019

By Abdelhak Bentriou

The choice of tool for the first well of an oilfield or gasfield is an important factor, given that we will be drilling with the same type of tool for the entire phase and explains why we need to have another type for comparison based on the efficiency of the tool and its ability to crush the rock, and the wear of different types of tools. Development of theoretical and practical tests to determine the optimal regime for drilling is required to take into account the characteristics of rock layers crossed. Classification of boring tools is based on the geometry of the teeth and depends on the hardness, the abrasiveness of rocks as well as their hydraulic system, but it is better to classify them according to the working conditions with a coefficient designating a discriminant. This is called physical characteristic of the drilling tool. The goal is to designate each element of the tool by a coefficient. Results were obtained from laboratory tests. Modeling the initial rate of progress by different types of tools allowed us to determine an adequate mathematical model of the speed initial progress in clean conditions. Using experimental data and statistics we have established the mathematical model of the average speed of progress as a function of time. With these equations we can determine the wear evaluation and analysis of these factors as an approach to classification according to their characteristics. The main equations for the selection of drilling tools will be based on the optimization of drilling parameters for each type of tool. After analysis, we choose the tool that gives a better forward speed with an optimal load and axial rotation.

Aug 1, 2013

By J. Huh

Recently, there is growing trend to build the high-rise and install curtain walls. Following this trend, we developed robot for building wall cleaning work, which moves along Built-in guide rail of building. Because it moves attached at building wall for cleaning work, it can be seriously affected by potential threats, like earthquake, strong wind, malfunction, and construction error of built-in guide rail. In order to cope with those threats actively, this paper presents the Fail-Safety system. The building wall cleaning robot consists of two moving system: The Horizontal Moving System which mainly do maintenance work, and The Vertical Climbing System which transport the horizontal moving system floor by floor. We apply the Fail-Safety system to these systems. The Fail-Safety system consists of sensors to detect external situation, and, with information of sensors, give instruction for what to do. This robot system is installed with four kinds of sensors: shock sensor, infrared ray sensor, laser sensor, magnetic sensor. First, shock sensor detects external shock during cleaning work. When shock sensor detects big shock, the robot returns to starting point to inspect how damaged it is. Second, infrared ray sensor detects damage of built-in guide rail. It is to prevent destruction of robot caused by moving along damaged rail. Third, laser sensor gives notice about where obstacle is. It is for robot to avoid crash with obstacle and decrease damage. Fourth, magnetic sensor detects magnetic points, which are installed in rail at regular intervals, and helps robot to find its position, based on location of magnetic points detected. If robot is damaged by external shock and its encoder, which gives information of location to it, is not working, magnetic sensor will give information of robot?s location to robot. And then, robot regulates its velocity depending on position of it, and safely returns to starting point. The Fail-Safety system in this paper is for building wall cleaning robot to sense external threats, and prevent getting worse. Applied to this active protection system, making safe environment of maintenance work is possible for robot system.

Aug 1, 2013

By C. Caners

One of the main uses of fossil fuels is in the transportation sector, leading to environmental consequences such as climate change. In order to move towards a more sustainable energy infrastructure, a transition must begin from fossil fuels to renewable fuels, derived from e.g. biomass. One means of facilitating this transition is to develop reforming technology that can extract hydrogen from a suitable fuel that is either fossil fuel or renewable in origin. The hydrogen would be feed to a 'fuel cell' engine that would power the car, truck or bus. One reforming technology that is attractive for automotive applications is autothermal reforming (ATR). Autothermal reforming is the combination of steam reforming and partial oxidation, whereby a portion of the fuel is combusted using a sub-stoichiometric amount of air, and the resulting thermal energy drives the more desirable steam reforming reaction. ATR is attractive for fast start-up, rapid load following and ease of control. ATR also has the benefit of smaller volume and fewer peripheral requirements as compared to other reforming technologies. Recently, a bench-scale gasoline autothermal reformer (ATR) was constructed and tested. This ATR employs a novel design, consisting of three concentric annuli in order to promote heat transfer from the partial oxidation reaction to the steam reforming reaction. Concurrently, a CFD based model (FLUENT) of the ATR that considers the geometric complexity of the reformer was validated. In spite of the use of simplified kinetics, the model predicted well the observed trends in temperature and overall performance. This paper will discuss the use of the model to improve the design of the ATR. The impact of various system parameters upon performance will be investigated along with alterations in the geometry of the ATR. The various tradeoffs in performance and system volume/size will be highlighted in the context of a fuel cell power system.

Jan 1, 2005

By S. M. Moon

Today, underground exploration is spotlighted as an infinitely developable area. For this purpose, many tunneling technologies were created. And until this very day, many techniques are being developed for more efficient underground movement. Although previous technologies have been developed and now being used in various forms like TMB, struck propulsion method and hydraulic propulsion method, it is hard to find a robot type exploring in small scale. But development of small scale underground exploration robot is a promising research subject for its usage in examination of soil, mineral, and subterranean resources, investigation of hazardous regions, and the military. So we developed a robot that can dig and move underground, inspired from the motion of earthworm and mole cricket. Earthworm and mole cricket dig the soil in the front and draw it off backward, so that they can move forward. We developed a mechanism that uses 2 rotating solid of revolution (bits) for pulverizing the firmly united soil in the front and put it inside the body. The bits rotate in the opposite direction of each other. While moving forward, the soil in the front moves along the spiral on the bit and is saved inside the body. The soil saved inside is taken out through an outlet in the back by a ventilation system. The ventilation system on the ground blows through a hosepipe connected to inner part of the robot and the air blows off the soil. The moving mechanism of exploring underground can be classified into 2 parts. One is to fix the blade link on the soil in a form of 4-bar link. The other one is to move forward rotating the whole link. When the blade link system for movement rotates a certain degree, one blade link is fixed, while the other one is folded in. When 2 blade links of different length rotate as it is, different torque is applied on each link. By the law of action and reaction, the link that has larger torque leads the rotation and movement.

Aug 1, 2013

By C. L. Reichardt

Pressure exerted on gold producers by regulators, project financiers and civil society in the wake of the Baia Mare tailings spill in Romania during 2000 prompted most responsible gold companies to sign up to the International Cyanide Management Code for the Manufacture, Transport and Use of Cyanide in the Production of Gold (the Code). The Code stipulates a ?cradle to grave? approach more comprehensive than that applied to any other mining reagent and poses particular challenges for operators who use cyanide-bearing tailings for backfill. This paper examine some of the challenges for Code compliance facing deep underground gold mines that employ backfill technology, most particularly the requirement to demonstrate that the potential migration of cyanide (and its degradation products) from emplaced backfill will not have an unacceptable impact on worker health and safety or the receiving environment, either during mine life or after closure. Although the Code only contains a single reference to backfill, more careful consideration confirms that most sections of the Code that deal with tailings management are potentially applicable to mines where tailings material is used for backfill, as are certain principles pertaining to aspects of operations, worker safety, emergency response, training and dialogue with stakeholders. For gold mines of the Far West Rand, the most significant cyanide-related risks associated with backfill operations relate to worker exposure to cyanide-bearing seepage and HCN gas. There is potential for seepage of cyanide-bearing water from backfill to compromise the beneficial use of surface and groundwater, and thus impact on downstream users and ecosystems. However, the extreme depth of mining and the specific geological and hydrological controls on the Far West Rand suggest that the potential environmental risks associated with backfill are likely to be considerably less significant than the cyanide-related risks to the workforce.

May 1, 2007

By Terry Bachynski

_ Regulatory Process _ Approval Timelines _ Trends _ Stakeholder Consultation Expectation _ Challenges _ Initiatives for Regulatory Process Reform _ A Better Way? Alberta Regulatory Process _ Regulatory Approval of a major capital development requires multiple approvals from several regulatory authorities: ? EUB ? Decision Report approves development scheme and recommends conditions for other regulatory agencies ? AEnv ? approvals to construct, operate and reclaim required prior to any in field construction activity ? Federal - approvals for federally regulated activities ? Municipal ? Development Permit

May 1, 2004

By A. E. Gillis

"Some or all of the following benefits can be expected following application of automatic control to a grinding circuit:1. Maintenance of Optimum Mill Load Level2. Improved Uniformity of Grind3. Increased Productivity4. Decreased Power Costs per Unit of Product5, Reduced Ball Wear per Unit of Product6. Reduced Labour Costs per Unit of Product7. Reduced Operator SupervisionTo establish an indication of the benefits that could be expected through automation of the grinding circuit at East Malartic Mines Ltd. it was agreed that the Department of Mines and Milltronics Limited should jointly conduct a survey of the existing grinding circuit and operation.Aside from establishing feasibility, an important purpose of this survey was to determine costs of a suggested control system that East Malartic Mines Ltd. management might be in a position to assess the economics of the proposal and justification of the investment.The survey involved the taking of sound recordings of rod and ball mills during manual operations, locating circuit bottlenecks, establishing time constants and determining the number and location of sensors for good automatic control."

Jan 1, 1966

By Palaniappan Chidambaram

Despite the advances in processing technologies, construction techniques, inspection methods, and materials, the number of process safety incidents are still increasing, and often the same types of incidents are being repeated. While regulators are enforcing stringent requirements in regards to safety management systems, process safety incident statistics reflect a failure in effective implementation. Upon closer look at the implementation of safety management systems, it becomes evident that the systems were not built on robust risk recognition. The risk-based implementation approach enables facilities to develop systems focused on managing specific risks and quickly gain momentum and confidence to take next steps towards implementing comprehensive systems. This paper will cover the importance of risk recognition and governance, risk based implementation and the role of Process Hazard Analysis in managing operational risks through the lifecycle.

Jan 1, 2014

By L. Sun

Recently, micro-tubular solid oxide fuel cells (SOFCs) have attracted the attention of many researchers because of their numerous advantages over larger tubular and planar SOFCs. These include excellent thermal shock properties giving rapid startup/shutdown capability, a high volumetric power density compared to larger tubular SOFCs, and reduced sealing problem compared to planar SOFCs. In order to screen cathode materials for micro-tubular SOFCs, the perovskite cathodes were deposited, using a variety of methods, on 10.5 mol % yttria-stabilized zirconia (YSZ) tubes. Their electrochemical properties were then evaluated by using electrochemical impedance spectroscopy and steady-state polarization methods, based on a three electrode configuration, and with the reference electrode position carefully optimized. The oxygen reduction reaction kinetics at the cathode/electrolyte half cell were then investigated in detail.

Jan 1, 2005

By Y. P. Wu

Steeply dipping seam refers to the coal seam with dipping angle in the range of 35?55°, which is well recognized to be very hard to mine by the mining industry all the world. In the last two decades, some fundamental researches were focused on the strata behavior of long-wall panel, complicated rock mass breaking process of the steeply dipping seam, overburden stress field developing and evolution, rock strata breaking and moving process, rock structure stability mechanism and control. Results show that it?s presenting macro stress arch-shell (MSAS) of the stress distribution of the overlying rock in steeply dipping seam. The MSAS is the spatial distribution of intensity envelope line under the strength criterion and has the geometry shape asymmetry as well as the stress distribution heterogeneity. The arch- shell base will forward as the working face mine forward and the shell roof will extend to higher overlying strata above the gob. In this paper, the stress arch-shell analysis model and coordinate system were established and analyzed the inclined masonry structure at different zone. Analysis results show that the rock damage at the key part of the arch-shell is the main factor which causes whole overlying rock structure failure. The rock structure instability modes have tension instability of the shell roof, compression-shear instability of the shell shoulder and composite instability of the shell base, meantime, instability coefficient is proposed to determine instability condition. The above research results enrich the complex coal seams mining theory and provide a theoretical basis for mining safely and efficiently in steeply dipping seam.

Aug 1, 2013

By Patrick Chabot

Ce document présente une méthode hybride de long trou favorisant une méthode de minage initiale par chambre-magasin et complétée par une méthode de minage long trou. Cette méthode a été adaptée suite à plusieurs facteurs tels qu?une géologie complexe, une rareté de mineur d?expérience et un haut taux de roulement de main d?oeuvre spécialisée. Cette méthode a permis d'excellents résultats par rapport à la dilution. De plus, la récupération de pilier à haute teneur par forage long trou sera expliquée. Cette méthode permet aussi de récupérer le minerai qui est resté accroché dans les chantiers chambre-magasins. Introduction : La mine Géant Dormant est une mine filonienne d?or située à environ 80km au nord de la ville d?Amos au Québec. Elle est en opération depuis 1988 et à la fin de 2007, elle a produit près de 885 000 onces d?or à partir d?environ 2 400 000 tonnes de minerai pour une teneur moyenne d?environ 11,5g /t Au. Cette mine est la propriété d?IAMGOLD Corporation depuis l?acquisition de Cambior par cette dernière au mois de novembre 2006. Elle emploie 151 employés permanents et environ 41 entrepreneurs.

Feb 1, 2008

By J. Someehneshin

Nowadays along with population growth, industry development, consumption of mineral resources and the fact that the reserves on hand are running out, the depth of surface and underground mines for further exploitation are increasing. During recent years, in underground mining, the block caving method for low-grade and large-scale deposits has shown a growing rate of application. This method is very cost effective and economically affordable. The dimensions of blocks are one of the most important parameters which should be taken into account since it has been proved to have a great deal of effect on technical issues such as commencement of caving and mine design. Proper calculation of the length and width for a block in this method leads to proper caving and discharging which are the most important stages. Therefore, in this method, the calculation of the optimized dimensions (length and width) of blocks is not only important but also directly helps the productivity of extraction. In this study, firstly for the purpose of facilitation, some assumptions were considered and having used these assumptions for estimation of optimized length and width of block, a relationship based on rock mechanics and physics was explored. Furthermore, some necessary details were added to the said relationship and finally, it was transformed into an inequality. Solving this inequality provides us with the optimized length and width of the block. The explored relationship was analyzed with MATLAB software and the graphs thereof were drawn. In these graphs, each time one of the input parameters has been drawn up in a logical range so that it could be compared with previous states.

Aug 1, 2013

By M. Takebayashi, K. Takenaka, S. Matsubara, T. Yoneyama

The cathode production of Toyo Smelter and Refinery, owned by Sumitomo Metal Mining Co., Ltd. reached 450,000 tons per year in 2016 with three tank houses. Niihama tank house commenced operations in 1919 with conventional sheet cathode technology. Approximately 100 years of operation experience and the technical development enabled that the current density of Niihama tank house and the Toyo tank house #1 increased to 320 A/m2. These operation techniques were utilized at the Toyo tank house #2 which started in 2005, and its current density reached up to 350 A/m2 with permanent cathode technology. In order to achieve high current efficiency under condition of 350 A/m2 operation at Toyo tank house #2, continued efforts had been made to verticality of anodes and permanent cathodes. To improve verticality of anodes and cathodes, reduction of short circuit ratio by changing the shape of the anode, optimizing the anode pressing machine and off-line process for rectifying the distortion of permanent cathodes was carried out. In addition, concentration control of electrolyte and expansion of Ni removing ability from the electrolyte prevented passivation. Finally, more than 96% of the current efficiency was stably confirmed. INTRODUCTION Today, Toyo Smelter and Refinery of Sumitomo Metal Mining operates three tank houses in Japan, namely, Toyo tank house #1, Toyo tank house #2, and Niihama tank house with a total capacity of 450,000 metric tons of copper cathodes. Figure 1 shows the trend of cathode copper production and the current density at three tank houses over the last 10 years. Cathode production by Toyo Smelter and Refinery reached 450,000 tons per year in 2016 with three tank houses.

Jan 1, 2019

By T. L. Lee, D. Y. Tan, J. Mi

Considerable progress has been made in studying the mechanism and effectiveness of using ultrasound waves to manipulate alloy solidification microstructure, However, uncertainties remain in both the underlying physics of how microstructure evolve under ultrasonic waves, and the best technological approach to control the final microstructure and properties. We used the ultrafast synchrotron X-ray phase contrast imaging facility housed at the Advanced Photon Source, Argonne National Laboratory, USA to study in-situ the highly transient and dynamic interactions between the liquid metal and ultrasonic waves/bubbles. The dynamics of ultrasonic bubbles in liquid metal and their interactions with the solidifying phases were captured in-situ for the first time. The experiments were complemented by the simulations of the acoustic pressure field, the pulsing of the bubbles and the associated forces acting onto the solidifying phases, providing more quantitative understanding for using ultrasound to control the growth of dendritic grains and to enhance grain multiplication effects for grain refinement.

Jan 1, 2014

"HPGRs operate in a wide array of applications in mining and minerals. These range from relatively coarse crushing of copper and gold ores at one end of the spectrum to the processing of fine iron ore pellet feed and fine industrial mineral products at the other. Traditionally these circuits involve the treatment of relatively moist materials in pre-grinding circuits; using single stage HPGRs in open circuit or as a closed circuit operation with screening or partial product recycle. More recently, HPGR is increasingly deployed in dry grinding in combination with air classification. The high throughput demonstrated by larger HPGRs has stretched the application towards coarser size reduction duties for a number of new projects. At the same time, the basic principle of inter-particle crushing for generating a product with a high fines proportion gives ground to investigate applying the technology further towards finished product duties. The advantages that HPGR brings are clear. Multi Stage grinding enables energy efficient size reduction across more of the comminution circuit. Primary HPGR serves for a coarse grinding duty, whereas a secondary HPGR is geared towards generating a fine product for downstream processing or even a finished product. This publication summarizes some of the features of staged HPGR circuits and discusses some examples of operating and projected applications.INTRODUCTION In most HPGR applications, the grinding units are used as a single process stage, either in open circuit, such as for pebble crushing [Rose 2002, Westermeyer 2000, Van der Meer 2015] or in closed circuit with classification [Van der Meer 2009, 2012] or product recycling [Van der Meer 2010]. Where a higher plant capacity is required, the HPGRs are commonly installed in multiple lines in a parallel arrangement [Parker 2005, Koski 201, Vanderbeek 2006]. HPGRs can take a wide range of feed size distributions, and grind this down to a product with a high fines content. In general view, there is a limit on the size reduction range that even an HPGR can provide. Grinding down from a very coarse ore (e.g. 70-100 mm) to a very fine product (e.g. 100 microns range) is stretching the ability of a single stage HPGR circuit. Fine grinding generally requires a classification stage that returns the classifier oversize to the head of the HPGR circuit. From one point of view, it can be demonstrated that when recycling a large proportion of fines and middlings back to the HPGR feed results in an effective feed with an overrepresentation of middlings and fines, which will eventually reduce the grinding efficiency and consequently result in an increased recirculation mass flow [Van der Meer 2014]. From another point of view the large recycling mass puts a strain or even a limit on the capacity of present-day conveyor capacity."

Jan 1, 2018

By D. A. MacLeod

DURING the past fourteen months, dust surveys have been made at thirty-six mines in the Province. These surveys are made to determine the concentration of dust in the mine atmosphere, the flow of air through the mine, the methods adopted to prevent the generation of dust, and the measures taken for its elimination. When high concentrations of dust are encountered, suggestions are given for its prevention ?and elimination wherever possible. Dust sampling is absolutely necessary to determine the effectiveness of any measure taken in the prevention and elimination of dust in the mine workings. Consequently, more time has been spent on this phase of the work than on any other. The apparatus used is the Devers circular konimeter and Zeiss microscope. At various mines, the Zeiss konimeter is used, and the dust counts taken by the two instruments have given results that are closely comparable; so much so that either instrument can be used with confidence and the results obtained will compare in accuracy with those obtained by the methods used in Ontario and South Africa. Before the Workmen's Compensation Act Amendment Act was passed in November, 1936, most of the mine operators were already keenly interested in the prevention of silicosis. This interest has been intensified at all the mines, and measures have been adopted to decrease the amount of dust in the mine atmosphere. Several operators have spent a large amount of time and money in bettering these conditions, and have met with decided success. Practically all others are adopting the known methods of prevention, suppression, and elimination of dust, that apply to their ?particular mines. To prevent the production of dust in underground workings should be the first, as it is the most important, aim, especially during the time the men are underground. An atmosphere free of dust cannot be obtained, but measures can be adopted to lower the concentration that is found? in the average mine.

Jan 1, 1939

By Michael Jerome Wallace

"This paper refers to the wet open circuit ball mil ls in operation at Sidbec-Normines'5 pelletizing plant at Port-Cartier, Quebec, which commenced operations in late November· 1977. Prior to detailing our experiences in the grinding area at Port-Cartier, a general description of the total Sidbec-Normines project is outlined.HI STORYSidbec-Normines was incorporated in 1976 to develop the Fire-Lake - Port-Cartier iron ore mining, concentrating and pelletizing project. The primary objective of Sidbec-Normines is to produce 6mi11 ion tons per year of oxide pellets, of which 3 mi 11 ion tons per year are of a low silica grade suitable for direct reduction purposes. The participants in the project are Sidbec, the Quebec Government steel producer, British Steel Corporation (lnt'l) and the Quebec Cartier Mining Company. Equity interest is held in the company by the participants in the proportions of 50.1%, 41.6:7% and 8.23%, respectively."

Jan 1, 1979

By M. R. MacIver, M. P. Pawlik

"An image analysis method based on chord length distributions is applied to the batch settling of polyacrylamide flocculated kaolin suspensions. Two features of the interaggregate void space, the void chord length distribution mean and the white-to-black distribution ratio are extracted from an image series obtained over the two hour settling experiments. This approach produces three signal values, from two different probability distributions that can be measured as an indication of underlying sediment bed density and aggregation state. Further work is required on the physical interpretation of the signal, the image acquisition conditions, and the parameter selection methods. It is suggested that this chord length based feature extraction technique may be a useful signal to monitor during batch settling or thickening.INTRODUCTIONFew in situ techniques are available that can be used to directly measure aggregate properties within sediment beds in thickeners or secondary settlers. Typical process variables monitored include rake torque and height, bed level and pressure, feed rate and density, underflow rate and density, settling rate, and overflow turbidity; yet these process variables are only weakly related to process dynamics (Concha et al. 2014). Additional process monitoring signals, based on the direct measurement of aggregate properties could improve solid-liquid separation control and allow the extraction of more detailed information from batch settling experiments.Several optical methods exist for measurement of moving suspensions of aggregated solids in the dilute concentration regime, such as focused beam reflectance measurement (Peng and Williams 1994), and the turbidity fluctuation method (Gregory 1985). In the more concentrated region of a thickener, acoustic backscatter penetration and attenuation measured with an acoustic probe and changes in the underlying solid concentration in the highly concentrated, near-bed region of a thickener as a function of height and time (Hunter et al. 2012). While machine vision for froth monitoring has been thoroughly studied with at least five commercialized technologies (Aldrich et al. 2010), its’ application to the study of thickening has been limited."

Jan 1, 2016

By Hasini Wijayaratne

Anode cover material, a mixture of crushed electrolyte and alumina, is a crucial part of an aluminium reduction cell because of its important role in maintaining overall heat balance. However, until recently little attention has been given to understanding or controlling its composition and quality. The thermal conductivity of anode cover material determines the extent of the heat loss from the top of the cell. This will change as a function of the granulometry and composition of the applied cover as well as over time as the cover material consolidates on top of the cell. The ability to measure or predict the thermal conductivity of fresh and ageing cover is an important tool for managing cell heat balance. Recent studies have shown that granulometry or more correctly, voidage is likely to be the predominant determinant of thermal conductivity of anode cover materials. We have developed equipment to measure the thermal conductivity of granular cover material and tested the relative importance of composition (ratio of alumina to crushed electrolyte) and granulometry/voidage on cover thermal conductivity. In general, our results confirm that granulometry is the dominating factor. Generally, high voidages contribute to lowering the thermal conductivity especially when particles are mostly fine. However the relationships between granulometry, voidage and thermal conductivity are complex due to the varying nature of heat transfer between particles. Aging of granular cover material occur during cell operation forming a consolidated crust due to exposure to heat and fumes over time. Structure and thermal behaviour of this consolidated crust is also important in understanding the overall properties of cover. This paper presents the outcomes of laboratory studies conducted in order to understand the thermochemical behaviour of anode cover material and in particular, the role of fines in anode covers mixtures.

Jan 1, 2011