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By H. H. Wang

Construction safety documents regulate significant safety actions and requirements by which construction workers or employees should abide in order to secure them from occupational hazard events. Therefore, facilitating faster identification of applicable safety requirements from the documents has become an important topic in the construction safety domain. To address the need in this regard, tools and techniques have been developed and research efforts have been made. One of the research efforts is to utilize ontology, a knowledge representation and reasoning approach, as the methodology to achieve the goal of identifying applicable safety requirements. In such ontology-based researches, the development and construction of the safety concept ontology is an essential task as the concepts and the relationships between the concepts both representing key safety knowledge need to be carefully identified. In this paper, the author focuses on the safety documents without predefined concept structure and aims to address the concept and relationship identification difficulties. Specifically, the author leverages the Formal Concept Analysis (FCA) methodology, a theory of data analysis that identifies conceptual structures among data sets, to mine and analyze the documents in order to discover safety concept structure and to further assist the development of the concept ontology for the construction safety documents. The author expects the application of FCA to construction safety domain can eventually benefit the ontology-based approaches for identification of applicable safety requirements.

Aug 1, 2013

By M. Brochu

In this paper, we present a computer-vision approach developed for wall-thickness measurements of corroded pipes inspected by double-wall radiography. The main objective of the work is to optimize data collection and film interpretation using computerized image analysis. To date, the system is able to identify the inner and outer contours of a pipe and perform wall thickness measurements at each pixel of a radiograph. This will be presented by analysing pipes having different dimensions. Another important feature of the system concerns the algorithms' adaptability to pipe wall texture. In other words, image analysis is automatically refined around rough or corroded areas. This allows more precise thickness measurements and shape identification in critical sections as will be demonstrated with examples. Finally a brief overview of results exploitation will be given and compared with human interpretation. It will show the reliability of automated image analysis and the many possibilities offered by complete output analysis.

Jan 1, 2005

By A. M. Bell

"The property of Gaspe Copper Mines, Limited, is in the Gaspe Peninsula some 60 miles west of the town of Gaspe and 20 miles in from the north coast. The Copper Mountain deposit was first discovered in 1921 and first optioned and drilled by Noranda in 1938. The Upper Needle Mountain showings a mile south were found in 1938, but it was not until after a delay of 10 years that the more important deep ore at Needle Mountain was located by drilling. Production started in 1955, and the smelter commenced operation in December. Mining is by open stope methods with first production coming from the Lower Needle Mountain orebody, of which only a small portion has been exposed in underground openings.Stratigraphy and AlterationThe country rock is composed of limy siltstones of Devonian age. Away from alteration these are dark and generally carbonaceous. Throughout the drilled area numerous narrow layers of tuffaceous fragmental material occur, and such beds are found to provide excellent horizon markers by virtue of their uniform thickness and wide lateral distribution. These markers are valuable for stope control in mining the bedded replacement deposits.Intruding the sediments at Copper Mountain are porphyry dykes, and one drill hole encountered granite 1,400 feet below the valley. Solutions responsible for the rock alteration and ore deposits seem to have emanated from this intrusive centre.On the mine claims strong hydrothermal alteration has completely obscured the original character of the sediments. The unaltered formations are all very similar in appearance, but following alteration rocks that are very dissimilar in physical characteristics are produced, and such differences have an important influence on ore deposition. The alteration effects are known to extend over a vertical range in excess of 3,000 feet and have a surface area of two square miles. All known ore bodies are within the zone of alteration. In this, rocks are strikingly bleached to a white colour in contrast to the normal dark-coloured sediments, and are much harder and more abrasive, with bedding often obscured. The first effect of alteration is driving off of carbonaceous matter, followed progressively by silicification in the acid rocks and by the formation of lime silicates in the lime rocks, with an accompanying gain in silica and a corresponding loss in lime. Extensive analysis has shown that there is an actual addition of silica involved in the alteration."

Jan 1, 1949

By Paul E. Mather, Matthew J. M. Krane

Anode or fire refining is the final pyrometallurgical step in the production of copper anode. Part of this process purifies liquid copper by reducing its dissolved oxygen with a natural gas-steam mixture. Until now there have been no transient models of this process coupling the injected gas jet mass transport with its chemical reactions. A transient, 1D flow, chemical reaction model was made to estimate the time-dependent behavior of anode copper composition, soot formation, and the transient gas jet composition along its height. Model estimates were made for reduction rate, soot emission rate, and exergy loss and destruction distributions for two melt temperatures and a range of steam addition rates. It was found that increases to melt temperature and steam addition rate increased reduction rate and decreased soot emission, while having little effect on exergetic performance. Estimates for reduction histories were compared to industrial data. INTRODUCTION Anode/fire refining is the final pyrometallurgical step in the production of copper anodes; it is essential for removing dissolved gases which cause porosity in cast anodes. Despite its significance, the open literature appears devoid of any transient models of the entire process; furthermore, there are very little published process data with which to validate any models made. This dual dearth of modelling work and process data inhibits studies of the tradeoffs between process and performance changes, desirable for decreasing reduction time and soot formation as well as quantifying changes in the exergy losses and destructions of the process. This work introduces a reduced-order, transient model of reduction during fire refining, examines performance trends with operating conditions, and compares model estimates with industrial data. Overview of anode refining The purpose of anode refining is to produce liquid copper which can be cast with minimal gas porosity, which disrupts the downstream electrorefining process. Dissolved sulfur is removed first, then oxygen, by reactions with different injected gases. The removal of oxygen (the reduction step) is the subject of this proceeding and is effected by the bubbling of natural gas, typically mixed with steam, through the melt from tuyeres. A typical refining run reduces dissolved oxygen from 3000 ppm to 300 ppm in 2–3 hours (Schlesinger, King, Sole, & Davenport, 2011). The refined copper is then cast as anodes. Figure 1 shows a schematic of the furnace vessel.

Jan 1, 2019

By Prodipto Ghosh

This paper is prepared as a review of existing and traditional methods related to electrical maintenance strategy. Its primary focus is to explore newer ideas and how they point the way to a more efficient and effective manner of electrical maintenance. This discussion is primarily related to large electrical distribution assets typical of heavy industry such as mining.

Aug 1, 2013

By T. C. Chudy, C. C. Hamilton, G. R. Lane

The selection and provision of mineralogical services to assist in developing a GeoMetallurgical program for a Cu Porphyry Mine in South America is covered in this paper and presentation. The objectives of the study were to provide a rapid mineralogical scoping protocol to support and confirm results of sequential Cu leach data and to provide detailed mineralogical analysis of four composites and products on which locked cycle test-work were performed. Results showed good reconciliation was achieved between measured chalcopyrite and secondary Cu mineral contents with leach data using a linear intercept mineralogical procedure by TIMA (Tescan Integrated Mineral Analyser), as well as a generally positive correlation between pyrite and Cu-sulphide grain size. Size-by-size analysis of Composite feeds and test products was used to outline comparisons between feeds on a mineralogical basis and provide liberation and association data with which to diagnose and better explain performance. Identifying key mineralogical drivers to Cu recovery and concentrate grades using these results, a greater understanding of the role of chalcocite and pyrite on metallurgical performance was established. INTRODUCTION As a global supply of copper, porphyry copper deposits are typically very large, often in excess of a billion tons of ore (Keeney, Walters, & Kojovic, 2011; McMillan & Panteleyev, 1980) with grades typically between 0.2 and 1.2% Cu, and up to 2% Cu in places. They are also a source of gold. The complexity of copper porphyries arises from their classically zoned nature, the type of host rock, as well as whether or not they have been overprinted by oxidation, weathering and supergene enrichment (Sillitoe, 2011). Zones of alteration and other geological attributes give rise to varied mineralogy, ore mineral textures and material properties, all of which result in different processing characteristics. Due to the interdependencies of geological and processing characteristics, it is vital to study links between the geology at the macro-scale and mineralogical features down to millimeter and micrometer scale (mineral content and texture) and their influences on mineral processing behaviour (Cropp, Goodall, & Bradshaw, 2013). The growing field of GeoMetallurgy aims to provide an Orebody Knowledge framework by which to gather such information as it pertains to: (1) Understanding and predicting likely flotation response; (2) Guiding relevant test work to investigate and validate links, interdependencies, theories and data interpretation/evaluation; (3) Populate a block model with relevant information and; (4) Implement and refine the model for ongoing optimization and control. Specific questions addressed by using mineralogy often include flotation diagnostics as aids to interpretation, causes of dilution and losses to tailings, as well as guidance to sampling for test work (Cropp et al., 2013).

Jan 1, 2019

By Lo-Sun Jen

Introduction ? Canada is one of the largest miners and explorers in the world and is a world leader in the production and export of many key mineral commodities ? Canada has a stable political regime and a competitive investment and business climate ? Canada is endowed with mineral resources, advanced technology and management know-how ? Canadian stock exchanges are the world?s leading centres for raising equity financing for exploration and mining projects anywhere on the globe As with some other countries, Canada has experienced a recent decline in major mining developments

May 1, 2002

By H. Gharahbagheri, S. Shafiei Zadeh, H. Hassan Nejad

Waste Electrical and Electronic Equipment (WEEE) is one of the fastest growing types of solid waste in the world, and often contains precious metals, especially gold. Gold processing and recovery from secondary materials, especially WEEE, have been under investigation for more than a decade now; however, a comprehensive review that illuminates the future path is missing in the literature. The aim of this short paper is to discuss the recent advances in gold processing and recovery from secondary electronic materials and why it has not yet become practical. The role of pyrometallurgical and hydrometallurgical methods, as well as their advantages and disadvantages will be discussed; however, the focus will be on Biosorption and recent advances.

Jan 1, 2014

By H. Helmstaedt, P. Thurston, R. Harrap

"Evolution of the continental lithosphere over Earth’s 4.6 billion year history is one of the fundamental questions of geoscience. Much of the Earth’s present-day continental crust formed during the first 2 billion years, the Archean eon, of the planet’s lifetime and thus, Archean processes of lithospheric formation must be studied in order to address this question. Until recently, the processes of Archean lithospheric evolution were thought to be fundamentally different from present-day plate tectonic processes. However, subsequent evidence suggests that the growth of Archean continents may be explained in terms of modern tectonic accretionary tectonics similar to those presently operating in the southwest Pacific region. The evidence supporting this hypothesis was compiled largely by Canadian geoscientists working in the Superior Province of the Canadian Shield in northwestern Ontario, over the past 15 years. Study of Archean rocks is also economically important because the Archean rocks of the world, although comprising only a relatively small fraction of the exposed continental crust, contain much of the world’s mineral wealth, including more than half of the world’s gold, as well as significant base metal reserves. Furthermore, the vast majority of primary economic diamond deposits are derived from the lithospheric roots beneath Archean cratons.The LITHOPROBE Western Superior Transect is located within the western part of the Superior Province in northwestern Ontario (Fig. 1). The Superior Province is the largest and best exposed Archean crustal block in the world and forms the nucleus of the North American continent. The internal structure of the Superior Province records a history of the processes that formed the earliest lithospheric elements of the Earth into cratons, thus providing an ideal laboratory for investigating early crustal evolution. The Western Superior Province is characterized by a regional pattern of alternating, 100 km to 200 km wide geological belts (Fig. 2). The observed geologic relationships between and within these subprovinces have been explained in terms of a modern tectonic model of terrane accretion. Oceanic floor, volcanic island arcs, oceanic sediments and continental fragments were accreted successively from north to south against the southern margin of a cratonic nucleus (North Caribou terrane, Fig. 2) which grew steadily in size with the arrival of new terranes through geologic time. If this model is correct, it suggests that the tectonic processes operating today have been active without major variation over the past 3 billion years."

Jan 1, 1998

By David F. Machuca-Mory

Modelling the geometry of a vein is a crucial step in resources estimation. The resulting models are used as mineralization domain boundaries and have a direct impact on the tonnage of estimated resources. Deterministic models are often built using time consuming wireframing techniques usually based on hand interpretation of the drillhole intercepts. Another approach consists in coding the drillhole samples by a function of their distance to the veins contacts. The coding is subsequently used for modelling the vein contacts away from drillholes. This is a more efficient approach and is able to provide a measure of tonnage uncertainty. The use of location-dependent variograms improves the modelling by incorporating local changes in the anisotropy of the vein structure. This combined approach results in more realistic vein models, particularly when the geometry of the vein has been are altered by folding, shearing and other structural processes. The approach is illustrated on a realistic case study.

Oct 1, 2009

By Charles Tkaczuk

Key issues ? No business tool has greater potential to effect change and enhance profitability than process control. ? Successful businesses see process control as an integrated engineered system, designed and built into their business models from day one. ? The integration and use of process control sets the stage for years of compounded returns. ? Has been used for years to optimizing recoveries and minimizing waste. ? However, the mining/ore extraction sector has been slow to adopt integrated process control. What is the problem? ? Most executives and engineers do not clearly understand process control when applied to mining/extraction activities. ? Common approach has been to apply generic process control strategies as a blanket cure all and wait for it to pay off. ? No central focus which results in multiple group involvement, overlap and inconsistent application of questionable technology. ? Considered a low priority until production activities commence. ? Comfort in using brute force mining methods. ? An off-the-shelf integrated under ground mining process control architecture has not until recently been available.

May 1, 2004

By P. Coulombe, J-F. Riverin, A. Gaboury

Cavity cleaning during anode change generates a material that consists of anode cover material and cryolite melts. This material is scooped and placed in bins for transport and further processing and recycling as fresh anode cover material. Typical processing methods in use involve cooling of the hot cavity bath in bins, with or without emission treatment systems, until it is adequate to be processed and grinded to the required particle size distribution. Handling of the hot and cooled cavity bath material can be labour intensive. It also generates significant air emissions which contain particulate and gaseous fluorides. With the advent of the Aluminerie Alouette smelter Phase II expansion, the hot cavity bath tonnage to be processed increased to 700 t/day and maintaining existing practices was not satisfactory. This article presents a novel process implemented at the Alouette smelter where cavity bath is processed as a hot material directly from the potlines ( 600-800°C range), sized, cooled and then processed in the existing cold bath treatment plant. The system is designed to process 36 t/h, is fully automated and requires limited monitoring from operations. Implementing this new system in a Browrifield environment imposed numerous constraints for space, interfaces with existing operations, commissioning and ramp-up. It is presently operating at approximately 80% availability and is easily meeting the requirements of the potlines. This system has significantly improved the workplace environment in the bath treatment area and reduced the overall particulate and gaseous fluorides emissions at Alouette. Aluminium 2006 45th Annual Conference of Metallurgists ofCIM Montreal, Quebec, Canada Edited by

Jan 1, 2006

By D. G. Sediako

Chemical composition and the casting/rolling production routes determine the cost and properties of the wrought material. For example, the coarse-grained structure frequently associated with DC casting requires complex rolling schedules to refine the grain size. Hot forming (rolling/forging/extrusion) results in a strong crystallographic texture, which is responsible for the tension-compression strength asymmetry frequently exhibited by magnesium alloys. Understanding the influence of alloy composition on texture evolution during forming provides useful practical information to optimize industrial hot-forming technologies for magnesium alloys. In this study, a series of Mg-based alloys containing varying combinations of Al, Rare Earths, Zn, Ca, and Sr were subjected to identical casting and extrusion processes in order to isolate the effects of alloy composition on texture evolution. Textures were measured by neutron diffraction at the NRC Canadian Neutron Beam Centre. The ability of neutrons to penetrate deeply into materials allowed information to be retrieved from all regions of the bulk specimens without destructive and time-consuming sectioning operations, thereby providing true bulk texture data. {1010} , (0002), {1011}, and {1012} pole figures were generated for all of the as-processed alloys, from which Orientation Density Functions were obtained. The were then used to reconstruct the pole figures and to extract semi-quantitative texture data showing how the (0002) and {1010} planes align themselves with respect to the extrusion axis. It was found that varying the concentration of aluminum (3-4 wt%) and Rare Earths (2-3 wt%) in AE alloys had a weak effect on texture development. All of the alloys showed similar magnesium extrusion textures, in which the (0002) poles align themselves preferentially with the extrusion axis. The substitution of Sr for Rare Earths also did not have a significant impact on texture development. On the other hand, while the presence of small amounts of Zn and Rare Earths did not have a strong effect on texture development, alloys with higher concentrations of these alloying additions (in combination) showed an enhanced tendency for the {1010} poles to align themselves with the extrusion axis. The addition of Ca also enhanced the alignment of the {1010} poles with the extrusion axis. These textures can complicate further processing and introduce a significant anisotropy that could influence creep properties.

Jan 1, 2007

By D. Mark Richards

Highland Valley Copper is a large open pit copper mine in the southern interior of British Columbia. Machine guidance technology using the Global Positioning System (GPS), was first implemented at the mine in late 1996 for blast hole drill navigation. The purchase of a third BE49R drill in 1998 completed the change to GPS navigation for all the mine?s drilling. The acceptance of this technology was almost immediate at both the operator and management levels. With the purchase of a new P&H 2800 shovel in 1997, the opportunity was taken to extend GPS navigation to a shovel. Due to communication restrictions, this was not as successful as envisaged. In late 1999, following a cost benefit analysis, a three-shovel trial of Caterpillar?s Computer Aided Earthmoving System (CAES), was initiated. The trial was successfully concluded in June 2000 and a further two shovels were equipped. Acceptance of this system has been very good at all levels, which has undoubtedly contributed to its success. In September 2000, CAES was extended to the dozer fleet with the purchase of a new track dozer. The CAES equipped dozer is used for pit production and project work. It is planned to extend CAES to the rest of the shovel fleet in 2001, along with a production front-end loader and one or two more track dozers.

May 1, 2001

By Mitchell Gordon

"In almost all thickener applications the highest possible solid/liquid separation efficiency is what is desired by the user. There is a trend in the industry due to monetary restraints and environmental pressures to look at ways to extract this maximum performance by either retrofitting existing thickeners or installing the most cost effective new thickener. This paper looks at some of the common problem areas and presents a range of solutions developed by Outokumpu Mintec in North America and outokumpu's subsidiary Supaflo Technologies Pty. Ltd.The Emerging PictureAfter many hours of discussions with a large number of plant personnel over the last two years a picture began to emerge regarding current thickening operations in the industry. Initially, it seemed that everybody had their own unique process problems and therefore needed a correspondingly unique solution. Looking more closely at all the cases and the ideas that we had either implemented or suggested, it gradually became apparent that the majority of operators all had one and the same process need ....""Better Separation Efficiency""The range of operational problems that were uncovered in the survey were much more varied than expected and often were not even considered initially to be thickener problems. Often, it was only after the rejection of many solutions to the problem, generally due to capital cost, that the actual cause of the problem was looked at and found to be a thick-ener.A summary of the problems that have so far been identified is presented in Table 1. They are subdivided under three major categories of environmental, process and paste fill to highlight the wide range of mining activities that can be affected by poor thickener performance. These seem to be the major areas where the need for better separation efficiency is rooted."

Jan 1, 1995

By Edward Rybinski, Serkan Dikmen, Walter Valery, Jorge Ghersi, Roberto Valle, Alex Jankovic, Javier Linares, Frank Davila

Compañía Minera Antamina is a polymetallic mining complex that produces copper and zinc concentrates as primary products and molybdenum and lead/bismuth/silver concentrates as by-products. In 2007, Metso Process Technology and Innovation (PTI) was contracted to increase SAG mill throughput by integrating and optimising blast fragmentation, crushing and grinding for the harder M4/M4A (CuZn) ores. Following the implementation of recommendations provided by Metso PTI, the SAG mill throughput increased from 2750tph to reach an average of 3600tph for the remainder of 2007. Due to continued application of mine to mill integration and optimisation philosophy, by 2010, the concentrator consistently exceeded the target of 4400tph while processing harder CuZn ores.

Jan 1, 2012

Flotation of a mineral bearing particle is the result of successful completion of a chain of events, such as, producing particles with sufficient exposure of the valuable mineral on the surface, reagent adsorption, suspension of the particle in the pulp, collision of particle with air bubbles and subsequent attachment, ascending to the froth column and transport to the concentrate stream, among others. These sub-processes in turn are affected by the feed properties such as size and density, and process variables such as size of air bubbles, degree of turbulence in the cell, particle/particle interactions etc.. Thus, inefficiencies occurring in any one or more of the above processes will result in inefficient flotation performance. In spite of its dependency on a wide variety of sub-processes, flotation performance is commonly modelled based on first order kinetics using two or three parameter models. As the model parameters may be affected by several of the sub-processes mentioned above, interpretation of their variations and identifying the specific causes is extremely difficult. Of the many factors that influence the flotation performance, liberation information of the particles such as the grade distribution and surface exposure are considered vitally important. In this paper, it has been demonstrated a) how a predictive liberation model may be derived and used in quantifying the liberation information of the particles produced at various grind sizes and b) how the flotation process may be modelled by explicitly incorporating the liberation information, thereby improving the accuracy of the model. Comparisons of the observed data with the proposed model and those of published liberation/flotation models have also been made.

Jan 1, 2016

By D. E. M. Plaumann, B. S. Fee, R. D. Hansen, R. R. Klimpel

"This paper briefly summaries the status of a recent program aimed at identifying new chemistry for use as sulfide mineral frothers and collectors. The background motivation and planning behind this work is given along with the general families of chemical structures synthesied and studied in detail followed by typical flotation application results in various laboratory and plant scale tests. Flotation testing to date has been very encouraging with often improved recoveries of certain minerals and improved pyrite selectivity being observed over commercially available reagents. In addition, in some cases, the dosage and lime requirements of these new collectors are significantly less than that associated with standard sulfide mineral collectors. INTRODUCTIONFroth flotation is one of the most widely used and economic means of concentrating metal sulfide ores. There are numerous reference books that have been published on the chemical aspects of flotation [e.g., ref. 1-7] which are based on studying the influence on selected minerals of chemical structures that have been used commercially for many years. In fact, almost 98% of the volume of flotation collector and frother reagents used at the industrial level today were known and manufactured in some form 25 years ago [8]. There are many reasons for this lack of significant new flotation reagent development [9] including the general utility and relative cheapness of existing collectors such as xanthates and existing frothers such as the alcohols and glycol ethers. Another reason is the inherent complexity of the flotation process itself coupled with highly variable and difficult to standardize feed materials. This environment makes reliable reagent comparisons difficult and seriously limits the use of theoretically based chemical structure studies to predict new or optimal reagents. In addition, the higher cost of specialty flotation reagents demands that their performance attributes be significantly greater than that achieved with existing all-purpose commercial reagents - something often difficult to prove in practice."

Jan 1, 1988

By Nirmal Weerasekara, Jochen Franke, Malcolm Powell, John Favier

Mill liners serve the dual purpose of protecting the shell from wear and transferring the rotary motion of the mill to an effective grinding action. As the liners wear, the efficiency of energy transfer changes, so there is balance between liner profile for wear and for milling efficiency. A tool that can simultaneously predict the evolution of the liner profile and the associated change in milling efficiency should prove most useful in optimal liner design. This paper presents such an approach, based on measured 3D liner profile data informing 3D DEM simulations of charge motion and liner wear modelling.

Jan 1, 2012

By Aleksandar N. Nikoloski, Tendekayi Tapera, Glen P. O’Malley

Chalcopyrite (CuFeS2) and enargite (Cu3AsS4) are among the most important copper sulfides. At present, many known deposits of these minerals are uneconomic to process because they are of too low grade, insufficient size or too remote to be cost effectively treated with conventional technologies that can deal with their refractory nature. Therefore, developing an effective, low cost extraction process for recovery of copper from them is important. The research presented in this paper will deal with potentially cost effective strategies involving catalysed processing, studied under conditions relevant to recycle heap leach conditions. The present account summarises some of the main findings from the research program carried out at Murdoch University between 2014 and 2018 that has investigated the effects of the common leaching parameters, major and minor species present in the leach system and additives on the rate and extent of copper extraction from low-grade ores, in which primary copper sulfide minerals such as chalcopyrite and enargite were the dominant copper minerals. The study involved batch leaching tests, detailed structural and mineralogical characterisation and thermochemical modelling under conditions relevant to heap leaching. The results have demonstrated that silver in particular has a strong catalysing effect on the extraction of copper from ore under the leach recycle conditions and, at an adequate dosage, can effectively overcome surface passivation, enabling almost complete extraction of copper from chalcopyrite as well as enargite. The aim of this paper is to present the effect of the studied additives and to briefly elaborate on the mechanism of the silver catalysed leaching process. In addition, the presence of certain secondary agents was shown to lower the critical dosage of silver and promote extraction. The data from the study allowed the development of a theory for the silver catalysed reaction mechanism, which enables further optimisation and cost-effective application of this strategy in practice. INTRODUCTION Researching the extraction of copper from chalcopyrite is important as it is the most abundant copper mineral in the earth’s crust. The majority of ores containing this mineral are processed by flotation to produce a concentrate, followed by smelting and electrorefining. However, most reserves available nowadays are of low grade or limited in size, and therefore not suitable for this conventional approach. Hydrometallurgical processing via heap leaching with or without the aid of bacteria has been shown to be potentially economical. Chalcopyrite is refractory though and suffers from slow leaching kinetics and poor overall extraction, so understanding the mechanism of how it leaches has received significant attention by researchers working in this field over the past 50 years. The refractoriness, which is the main issue with the hydrometallurgical approach, is generally described as passivation of the chalcopyrite surface whereby a surface coating is formed that blocks the reaction interface or wetting of the chalcopyrite, limiting the copper extraction. Exactly what this layer is made of or how the issue could be overcome has been the subject of intense study and debate for many years. One of the limitations of the work to date is that much of the research focus has been on typical initial leaching conditions, while there has been relatively little research into how the leaching is affected under recycle solution conditions where certain metal ions (Fe, Mg, Al) have often accumulated in the liquor. This occurs because the leach solution exiting a heap contains many species from the dissolution of gangue minerals and typically this solution is returned to irrigate the heap, once the copper has been removed, leading to an accumulation of these species.

Jan 1, 2019