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By Giles St. Pierre

"The purpose of this paper is to report in a general way on the use of the Portaspec X Ray Spectrograph.At Manitou Barvue, we are milling two types of ores, copper and zinc. The control assay practice was to take grab samples at 4 hour intervals. These samples were dried in the mill, then taken over to the Assay Office where two operators would process them. Three hours later results were available at almost the same time as the operator was ready to take his set of grabs again, leaving no time for adjustments, if any were needed.After a reduction of personnel, there were no assays available on night shift. This practice was slow and inadequate, and a new way of doing control assays was investigated.After investigation the Portaspec was found suitable for the type of operation that we had in mind. The Portaspec is a conventional dispersive type of X Ray spectrograph. The instrument consists of three parts:The Power Supply The Spectrographic Head The Digital ScalerIn our case, where dried powder samples are analyzed, the instrument was provided with a two sample holder using one for the standard and the other for the sample. The operation of the instrment does not require any degree of skill or knowledge of chemistry or spectrography.Previous to buying the instrument, six sets of six to ten samples were sent to the supplier along with the assay for each sample. These samples were Cu. HDS., Cu. Conc., Cu. tls, - Zn. HDS., Zn. Conc., Zn. tls. A definite pattern was observed. For example - six Cu. HDS. samples ranging from .40 to .90 gave 10400 counts for the lowest to 16.040 counts for the highest. The number of counts were then plotted to give percentages."

Jan 1, 1971

By A. E. M. Warner, P. J. Mackey

Copper metal is produced in large or small tonnages in almost all countries of the world—handling raw materials in the form of either as-mined or milled ores, custom concentrates, or other custom materials including scrap and recycled copper. The scale of operations and type of technologies used around the world varies widely. There is a certain concentration of both mining and smelter-refinery production as a total of ten countries produce some 80% of world mined copper, while ten countries—mostly different ones— produce about 80% of smelted and refined copper. As a result, international copper trade is significant. The present paper takes the reader on a virtual tour of the copper plants throughout the world with a focus on smelter facilities. Operations and technology employed at each plant visited are discussed including a brief historical sketch. Future trends identified during the world tour are also discussed. The present authors considered sufficient time was required for a thorough study tour and settled on eighty days—the same as that for the celebrated fictional story of world circumnavigation in the 1870s. INTRODUCTION The celebrated French writer Jules Verne published his book “Around the world in 80 days” in English in1873 and it is the story of Phileas Fogg and his French valet Passepartout circumnavigating the world in 80 days in the fall of 1872 on a £20,000 wager (equivalent to over 2 million pounds today) from the exclusive Reform club in London. This is an interesting period for copper as it started trading on the London metals Exchange in 1876 and the start of global copper production chains started to take off at this time with the rapidly increasing electrification of the world. The production chain includes mining, mineral processing, smelting, refining and fabrication. Since 1880 annual world copper production has increased by over 150 times from 154,000 tonnes in 1880 (nominally considered as smelted copper—essentially the only route at the time to marketable copper) to over 23 million tonnes today (including total refined copper of 19 million tonnes of smelted copper including scrap and 4 million tonnes by solvent extraction-electrowinning), in tandem with increased electricity usage, along with significant transportation usage and for manufactured products (Figure 1).

Jan 1, 2019

By M-A. Thibault, C. Gauthierand, J-P. Gagné, J-Y. Carrier, P. Rochette, G. Dufour

"Anodes consumed in the electrolytic process for the production of primary aluminium are considered consumables. They need to be replaced at regular intervals of approximately one month. The so-called anode butts which are removed from the cells contain the metal supports (rods), cast iron thimbles, crust and residual carbon material. Cleaning is required to remove the waste material before the rods are fitted with new anodes. An inspection is required to ascertain if repairs to the rods are necessary. Presently, this inspection is carried out visually. ST AS, in 2004 in collaboration with Alcoa Deschambault, initiated a project to develop an automated inspection system. The objectives were to find a technical solution to perform these functions with a very simple system. Such a system was designed around ""artificial vision"". The inspection system developed uses only one fixed camera and does not require a separate step in the process for the anode rod assembly to perform the inspection. This paper presents the initial steps of the work performed to develop the equipment and software as well as a summary of the results obtained."

Jan 1, 2006

By Daniel Hodouin, Mélanie Proulx, Claude Bazin

"Collector and frother are commonly used to induce the floatability of valuable minerals in flotation plants. These reagents are usually distributed down a flotation bank or sometimes added in a single location at the top of the bank. A review of the literature and some experimental results obtained from laboratory and full scale trials indicate that the way flotation reagents are distributed down a flotation bank may influence the flotation response of coarse particles. The paper summarizes these observations which show that the distribution of reagents is a potential tuning variable for process optimization.IntroductionFlotation is in many cases the only way to concentrate sulphide and some oxide minerals. Flotation is a concentration process that uses particle surface composition to induce the selectivity by mean of hydrophobic reagents. The influence of particle size on flotation was firstly analyzed in the 50's1·2 and intensively investigated in the 70's, early 80's and 90's3-18. Most of the observed results show the existence of an optimum flotation size range9 whose recovery is not significantly influenced by a reduction of collector dosage""18. This result brought the idea of using a small portion of the total collector dosage at the top of a rougher bank and to distribute the remaining through the end of the bank to ensure sufficient collection of the coarse particles that need more hydrophobic coverage to attach to air bubbles and be lifted to the surface.This paper discusses the idea of using the distribution of reagents down a flotation bank to tune the operation of the process. Unlike the literature on the effect of reagents (collectors, frother...) dosage that is dense, little attention has been put on the distribution of reagents in a flotation bank. Although research on this subject has not been pushed very far, some operators have recognized the potential of a strategic addition of reagents down a flotation bank19. Except for a few exceptions, the proportions of the reagents to be distributed down a flotation bank are decided according to operator's experience instead of process analysis in relationships with particle size. This paper recalls observations made by different researchers that lead to the idea of using the distribution of reagents as a tuning variable for the flotation process. The paper does not present a detailed analysis or optimization scheme for tuning the distribution of reagents, but analyzes some plant and laboratory results with a view toward the development of a testing methodology and ultimately a validation or rejection of the idea."

Jan 1, 1998

By C. Pichler, J. Antrekowitsch

During the production process of steel and other metals a lot of different by products are generated in high amounts. Some of these residues are recycled to recover valuable metals like zinc, lead, copper and others. Especially the treatment of steel mill dust presents a great challenge. The need for new technologies can be seen in the wide range of available recycling concepts for steel mill dust treatment, however most of them have significant disadvantages. An example is the waelz process, which generates about 650 to 700 kg slag during the treatment of 1000 kg steel mill dust. This so called "waelz slag" must be dumped in the most cases. To avoid a landfilling all generated products must be able to get reused in another application. A so called "Zero Waste Process" can be reached with the "2SDR Process" (Two Step Dust Recycling Process), in which the dust is treated on an liquid iron bath generating cast iron, inert slag and zinc oxide. These products have a further usage and can also be sold. The paper focuses on the process development through trials in lab and technical scale up to planned pilot scales, with an accompanying characterisation of the generated products were done.

Jan 1, 2014

By P. Erskine

"Hyperaccumulator plants can be utilized as ‘metal crops’ in agromining operations. This emerging technology produces ‘bio-ore’ by growing ‘metal crops’ on sub-economic ore materials, such as natural ultramafic soils. In a typical application plant material is periodically harvested, followed by air-drying and incineration to produce the bio-ore intermediate. The bio-ore is of very high grade (>15 wt. % nickel), and of high purity, and may be processed into a number of different products (including nickel metal, nickelbased catalysts and pure nickel salts). Current research efforts from our team focus on Mediterranean climate field trials (Albania, Spain) and tropical climate field trials (Malaysia, Indonesia). Field-scale demonstrations are required to provide evidence of real-life performance and of economic viability. If the trials are successful, agromining may in the near future support local livelihoods with income opportunities as an alternative type of agriculture: to farm nickel.INTRODUCTION AND BACKGROUNDHyperaccumulators, plants with the exceptional ability to uptake and concentrate trace elements in their shoots, can be utilized as ‘metal crops’ in agromining operations (Van der Ent et al., 2013a; Chaney et al., 1998; 2007; Baker et al., 2010). Agromining produces ‘bio-ore’ from harvested ‘metal crops’ grown on unconventional resources such as natural ultramafic soils (Van der Ent et al., 2015a). The bio-ore is a high purity and very high-grade (>15 wt. % nickel) product intermediate that may be turned into a range of different nickel products (nickel metal, nickel-based catalysts and pure nickel salts). The potential for agromining is greatest in tropical regions (Asia-Pacific Region: Indonesia, Malaysia, Philippines, Papua New Guinea and New Caledonia) where very large expanses of ultramafic soils exist (Van der Ent et al., 2013b). Agromine operations may replace existing marginal agriculture on poor ultramafic soils, for example oil palm plantations that require high fertilizer inputs to be profitable, or take place under a cocropping regime. The ability of ‘metal crops’ to achieve high nickel concentrations in biomass (and hence in harvested bio-ore) from soils with just <0.5 wt. % nickel, makes it possible to access non-conventional resources, not accessible by traditional mining techniques. For example, agromining could be implemented both on the large ‘halo’ around the mine leases, and as part of the progressive rehabilitation process after conventional resource extraction. As with all methods for resource extraction, agromining will be finite due to the diminishing concentrations of nickel in the zone accessible by plant roots (Chaney et al., 2014). Nevertheless, considering soil materials with 0.2 wt. % nickel and ‘metal crops’ with a yield of 100 kg nickel ha-1 the agromining venture may be sustainable for decades (Van der Ent et al., 2015a)."

Jan 1, 2016

By S. V. Burr

"IntroductionOne of the more puzzling geological enigmas, in the writer&apos;s opinion, is how rock can move sideways with respect to other rock. In the writer&apos;s study of regional northwest-southeast folding in North America (Burr, 1980), he may have found the answer to horizontal offset.Horizontal OffsetSideways movement or horizontal offset does not mean that the movement was, or is, horizontal. As indicated below, the actual movement may be at a high angle from the horizontal. However, it is the horizontal VECTOR, or offset, which is measured on surface by geologists. Vertical movements (thrust, normal, reverse) can be understood, as they involve blocks of rock , generally separated on four to six sides, which have been pushed up or subsided. Vertical faulting across dipping strata can produce APPARENT horizontal offsets. However, this thesis deals only with ACTUAL offsets.The ProblemFigure 1 is a plan view of a simple hypothetical horizontal offset. Three vertical dykes are intersected by a fault lineament. Two dykes exhibit no movement; the middle dyke has been offset a distance (a). Vertical faulting would have produced no horizontal offset. How can a horizontal distance (a) disappear or appear? Rock expands or contracts in infinitesimal amounts.SolutionThe map (Burr, 1980) shows the writer&apos;s interpretation of regional northwest-trending folds in Ontario. The writer made two observations about horizontal offsets during his thirty year study of these folds:1) All major horizontal fault lineaments strike at a high angle to the northwest fold axes. Many of the northwest-trending lineaments are fault s, but their movement is essentially vertical.2) Close to many of the known horizontal offsets (and several lineaments), there are areas where plunge reversals are so frequent and close together it is impossible to draw in all the fold axes at a scale of 1 inch = 4 miles, and, in the highly faulted Espanola area southwest of Sudbury, Ontario, all the indicated folds cannot be easily separated at a scale of 1 inch = 1 mile. The writer has observed folds less than 30 feet apart next to the strong Puskitamica-Chibougamau fault in northern Quebec."

Jan 1, 1982

By S. Timbillah, R. LaDouceur, C. A. Young

A low carbon-chain trithiocarbonate ((NaOOC)CH2SCSSNa), known as Orfom® D8, was tested as an organic depressant in the differential flotation separation of chalcopyrite and molybdenite in the presence of sodium isopropyl xanthate (SIPX) or potassium ethyl xanthate (KEX). Flotation studies show that Orfom® D8 depressed chalcopyrite while molybdenite remained floatable. A study of the mechanism of adsorption indicated that Orfom® D8 adsorbs on chalcopyrite through its trithiol (CS -) functional group via both chemisorption and Orfom® D8-metal complexation. The Orfom® D8 depressant is selective and does not form any Orfom® D8-molybdenite bonds. Thus, the combination of the depressant in the presence of either collectors depressed the chalcopyrite and floated the molybdenite. Fundamental parameters of the Orfom® D8 including pKa determination as well as possible decomposition products of the depressant are reported. This study includes an economic case illustrating why using Orfom® D8 can be beneficial. INTRODUCTION Depressants are incorporated in mineral flotation units in the minerals processing industry to make or keep certain minerals selectively hydrophilic. Most reagents used are inorganic and include, for instance, sodium hydrosulphide (NaHS) which is the major reagent used for depressing sulphide minerals, particularly those containing copper, iron and lead. However, the issues with its use include high toxicity, tendency to explode, strong odour, and high consumption due to required high dosages as well as its tendency to oxidise in air. The latter can be overcome by conducting flotation in inert atmosphere such as nitrogen and recycling of the flotation process water. The use of more novel depressants that are essentially organic including homopolar reagents with hydrophilic functional groups on both ends of its structure adsorb onto a target mineral surface with one polar end, the other polar end orients into the bulk solution making the surface hydrophilic and thus, ensuring that the desired mineral does not float. The stringent environmental and safety regulations being implemented in recent times mean that the search for more environmentally friendly chemical reagents is a must have. The use of organic depressants for flotation systems such as Cu-Mo sulfide bulk concentrates has become increasingly important because of the health, safety and environmental issues surrounding the use of inorganic depressants. Nagaraj et al. (1983) investigated the Cu-Mo sulphide flotation system using a structure-activity study of depressants. They found that a major advantage of organic depressants is the ability to tailor-make organic molecules to suit many requirements and thus, eliminate the guess work approach that was predominant in the industry.

Jan 1, 2019

By J. Mirza, E. Nicol, J. Lipkowski

Gold passivation in thiosulfate leaching media is a major barrier to its implementation. Addition of Cu (II) into the leaching solution has shown to aid in gold dissolution, but the mechanism by which it acts, and its role in the passive layer, remains unknown. Surface Enhanced Raman Spectroscopy (SERS), in tandem with linear sweep voltammetry, were employed to determine the dependence of leaching currents on mass transport and for fingerprint identification of sulfur species on the surface of gold. SERS leaching experiments were performed using gold nanorod electrodes that showed increased stability compared to other SERS active surfaces.

Jan 1, 2011

By F. Parada L

Two copper concentrate with medium and high enargite content were leached in a 3 L autoclave reactor under conditions based on the CESL process. Copper, arsenic, sulfur and iron were checked in all the experiments and antimony, zinc and molybdenum were evaluated in selected tests. The 98% of the obtained copper extraction is agree with others authors, but the behavior of arsenic, iron an sulfur have some differences. The solid residue was characterized by chemical analysis, DRX and QEMSCAN®. Finally a comparative analysis with neutral roasting as an option for the treatment of this concentrate is done.

Jan 1, 2014

By Qing-hua Tian, Xue-yi Guo, Fei Li

A novel process for the preparation of a-Al2O3 from secondary aluminum dross was studied. Factors including alkali dross ratio, salt dross ratio, smelting temperature, smelting time, leaching temperature, leaching time, and the solid-liquid ratio, which possibly influence the transfer of Al into water were studied, and the feasibility of using seed precipitation as a treatment technology of the leachate was discussed. The optimum condition of the process was determined as: alkali dross ratio 1.3, salt dross ratio 0.7, smelting temperature 500°C, smelting time 60min, leaching temperature 60°C, leaching time 30min, solid-liquid ratio 1:4. The results show that using the seed precipitation method, the leaching of aluminum reaches 92.71%, demonstrating the technique as a feasible and effective treatment technology of the leachate.

Jan 1, 2011

By Ling Wu

The development of pyrometallurgical technologies has been focused on new smelting reactors, but the proposal for new converting reactors has been substantially lower. Up to today about 80% of copper matte is treated by the traditional P-S converters which have the weakness of pollutant fugitive emissions. Therefore, the continuously converting processes for treating molten matte have been studied and developed. In July 2017 the "oxygen-rich side blowing smelting + multi-lances top converting & fire refining" continuous copper treating process was commissioned. This process was designed by ENFI and YanTai GuoRun Copper Smelter. In this process, oxygen rich side blow technology is adopted for smelting, which is a new type of side blowing smelting furnace to produce high-grade copper matte. The converting adopts the horizontal multi-lances top-blowing continuously converting process, which eliminates the transportation of molten melt and the SO2 fugitive emission. The intermediate products of this process, copper matte and blister copper is fed into the furnaces respectively through launders. This new process is more advanced, more reliable and more environmentally friendly. Until now, this process in the GuoRun copper smelter is operating smoothly. An increasing number of projects which use this process are under design and construction in China. INTRODUCTION At present, there are many advanced smelting technologies for copper concentrate, such as oxygen bottom blowing smelting, flash smelting, top lance smelting (including ISA and Ausmelt furnaces smelting), side blowing smelting, Mitsubishi smelting, etc. At the same time, there are many copper matte converting technologies such as oxygen bottom blowing continuous converting, flash converting, Ausmelt top lance converting, horizontal multi-lances top blowing converting, Mitsubishi converting, P-S converter converting, etc. The final blister copper fire refining technology mostly adopts rotary anode furnace. Therefore, in the process of processing and extracting the copper from concentrate to produce anodes, there are dozens of technology combinations. Among them, the non-continuous converting technologies for molten or cold matte are often adopted in the converting process. The traditional P-S converting technology had been utilized for over one hundred years, with a mature, reliable and simple operation, also has advantages in the secondary scrap smelting of a wide range of quality. However, due to its batch operation, frequent roll in and out, poor sealing, considerable air infiltration, needs for ladles for molten phases transportation and other characteristics, the technology has a serious pollution problem due to fugitive SO2. At the same time, in the cold matte converting technology, the molten matte needs to be cooled and then processed. The sensible heat of the molten matte cannot be recovered, and the preparation process is needed in the process. Therefore, both energy consumption and investment are relatively higher.

Jan 1, 2019

By Edouard Masengo

A long dyke will be constructed in a lake with rockfill placed by end dumping method. Its crest will be at elevation 521.5 m compared to the nominal lake level at 520 m. In the first portion, its height will vary from 1.5 m on a 35.1 m thick tailings layer to 18.3 m on about 0.5 m of tailings. In the second portion, the dyke will be built on native silty clay and will vary from 18.3 to 15.2 m in height. The tailings consist in stratified layers of fine-grained soils showing lateral and vertical segregation. The tailings are compressible and may develop excess pore water pressure on loading. The tailings overlie a thin layer of relatively soft native silty clay. The till beneath the silty clay is considered incompressible compared to the material above. After construction, as the tailings and silty clay consolidate, pore water pressures will dissipate and dyke stability will improve. Since dyke stability will increase with time, the primary concern is its stability during construction. As a result of construction activities, three potential modes of failure were identified and recommendations were provided regarding the measures that should be undertaken to increase dyke stability during construction.

May 1, 2003

By S. Markstrom

The Boliden AITIK copper mine is located 100 kilometres north of the Arctic Circle in northern Sweden. A pre-feasibility study was conducted in 2005 with the aim of increasing the capacity of the existing processing plant. After analysis, options to upgrade the existing plant were abandoned in favour of building a new processing plant, with higher capacity and therefore greater profitability. A new plant could be designed with greater flexibility to make potential future expansions easier. A feasibility study for a new 36 Mt/y processing plant including fully AG grinding circuits and flotation was completed in 2006. The project was approved by the Boliden board shortly thereafter. Construction started in the beginning of 2007 and was completed during 2009. Commissioning of the new plant was undertaken in the first half of 2010. The grinding circuit consists of two lines with each line consisting of a 22.5 MW AG mill and a 10 MW Pebble mill in closed circuit with a spiral classifier. The nominal production level is 2 200 t/h for each grinding line. This paper presents the start-up and operation of the grinding circuit.

Jan 1, 2012

By Joseph B. de Hart

Two papers recently published on the subject of mine ventilation: "The Theory of Ventilation," by Douglas Hay. and "The True Effect of Natural Ventilation in Deep Mines," by Robert Clive, form the first and second reports respectively of the committee on the Ventilation of Mines appointed by the Midland Institute of Mining Engineers. The purpose of the present paper is to draw attention to these two papers and the discussion thereon. The theory of ventilation as taught in our schools is based on Atkinson&apos;s formula, which is a variation of Chezy&apos;s formula for the flow of water in pipes. The formula depends on two assumptions : 1. That air is an incompressible fluid within the limits ordinarily encountered, and; 2. That the pressure required to produce ventilation varies as the square of the rate of flow. The Atkinson formula has been assumed to hold good over the entire range of conditions met with in mines.

Jan 1, 1924

By T. G. Joseph, R. K. Soni, M. Curley

"Rapid dampening suspension is a proposed suspension design for ultra-class haulers that is intended to avoid metal-to-metal contact inside a strut and under shock loading, thus improving ride quality and ameliorating fatigue loading issues on a hauler structure. Laboratory testing has shown the ability of the proposed design to reduce the opportunity for bottoming out, that is, metal-to-metal contact between the colliding ends of oleo-pneumatic, two-piece suspension struts during the compression cycle. This paper predicts the performance of a full-size rapid dampening suspension strut by applying scaling rules to test the proposed design based on a set of field data from a Caterpillar 797B ultra-class haul truck operating in the oil sands region of the province of Alberta, Canada. The predicted performance of the suspension strut is compared to that of the original equipment manufacturer model, which was monitored on board the truck during field data collection. ¦ KEYWORDS Haul truck, Original equipment manufacturer (OEM), Rapid dampening, Strut, Suspension RÉSUMÉ La suspension à amortissement rapide est une conception de suspension proposée pour des camions de transport de catégorie ultra-class (des engins dont la charge utile dépasse les 320 tonnes métriques), visant à empêcher un contact métal sur métal à l’intérieur d’une jambe de suspension et dans des conditions de choc au chargement. Elle améliore la qualité du roulement et les problèmes de charge de fatigue sur la structure d’un camion de transport. Les essais en laboratoire ont confirmé que la concep¬tion proposée évitera au cylindre interne de heurter le cylindre externe, autrement dit empêchera le contact métal sur métal des jambes de suspension oléopneumatique en deux parties pendant le cycle de compres¬sion. Cet article prévoit la performance d’une jambe de suspension à amortissement rapide à taille réelle en appliquant les lois d’échelle afin de mettre à l’essai la conception proposée, sur la base d’une série de données de terrain relatives à un camion de transport 797B de catégorie ultra-class de Caterpillar (aujourd’hui remplacé par le nouveau modèle 797F) utilisé dans la région des sables bitumineux de la pro¬vince de l’Alberta, Canada. On compare la performance prévue de la jambe de suspension à celle du modèle du fabricant d’équipement d’origine (FEO), qui a été contrôlée à bord du tombereau pendant la collecte des données de terrain. ¦ MOTS CLÉS amortissement rapide, camion de transport, fabricant d’équipement d’origine (FEO), jambe de suspension, suspensionINTRODUCTION Research basis for the paper This paper is based on the unpublished MSc thesis work of El-Sayed (2003), Santos (2007), and Soni (2009) under the direction of Dr. Tim Joseph within the oil sands–equipment interactions program (OsEIP). OsEIP is part of the Alberta equipment–ground interactions syndicate (AEGIS) surface mining research group, School of Mining and Petroleum Engineering, University of Alberta. The aforementioned work spanned a decade of progressive studies into rapid dampening suspension systems, leading to the scale performance indications highlighted here. Although this paper uses a specific Caterpillar 797B suspension strut for field monitoring and as a basis for scale prediction of a modified rapid dampening suspension strut design, the design scaling principles used here could be applicable to any such design change consideration for an oleo-pneumatic suspension system."

Jan 1, 2019

By G. T. Lapidus, O. J. Solis-Marcial

Currently, ores with high-grades of copper oxides and secondary sulfides have become increasingly scarce, which has encouraged industry to look for alternative raw materials to obtain copper. The problem is that primary sulfides are difficult to dissolve at near ambient conditions. Proposed hydrometallurgical processes have not been implemented beyond a pilot or demonstration scale. One of the principal disadvantages is that the majority of these processes are not viable with ores that contain less than 4% copper. One of the more recently proposed techniques involves the use of organic solvents in the dissolution of copper concentrates with a chalcopyrite content of between 20 and 30%, which has shown high efficiency. The present research explores the ability of this process to leach copper from low grade chalcopyritic ores (<4% Cu) at different temperatures ranging from 20 to 50°C. It was found that depending on the temperature, high percentages of copper were extracted in 40 to 100 minutes, using different oxidants. Additionally, distinct leaching behavior was observed with each oxidizing agent. In some cases, the extraction kinetics adjusted to the diffusion controlled shrinking core model.

Jan 1, 2014

By Patrick R. Taylor, T. A. R. Putra

A review of various methods to treat high arsenic copper concentrates through pyrometallurgical processing is presented. Examples are drawn from various past and current operations and research. Various aspects of the engineering alternatives for treatment methods are discussed. Some of the methods discussed include: controlled oxidation roasting, adaptation of some smelter technology to accept higher amounts of arsenic, complete oxidation with arsenic fixation; sulfation roasting; acid baking, soda ash roasting, and others methods. Other topics include: a short discussion of other problematic impurities; the effects of arsenic on copper electro-refining and product purity; and methods for the ultimate disposal, or marketing, of the arsenic. The latest work being done at the Colorado School of Mines on soda ash roasting is also presented.

Jan 1, 2014

By J. J. Jonas

The categories of interpass time encountered in hot rolling are characterized. These are shown to fall into three broad categories: short (in rod rolling); intermediate (in strip processing); and long (in plate schedules). The effects of interpass time on recrystallization and carbonitride precipitation are described, and particularly on the interaction between these two mechanisms. The interactions, in turn, determine the final microstructure produced as well as the mechanical properties.

Jan 1, 2005

By Yufeng Yao, Robert P. Lowell

Abstract - Conductive heat flow anomalies associated with hydrothermal sulfide mounds on the seafloor have been studied. Sulfide mounds tend to focus conductive heat flow because sulfide minerals have a greater thermal conductivity than country rock. The topography of the mound above the seafloor, however, leads to a reduction of heat flow, particularly near the center of the mound. Because the focusing effect is constant, whereas the topographic effect decreases with distance away from the center, the focusing effect dominates toward the edges of the mound. The magnitude of these effects depends upon the conductivity contrast and the height/radius aspect ratio of the mound. Conductive heat flow anomalies at sulfide mounds also result from fluid circulation within the edifice. For the active and relict mounds at the TAG hydrothermal field, which have an aspect ratio of approximately 0.3 and a conductivity contrast of 3, the heat flux through the center of the mound should be roughly 70% of the background heat flux. The maximum effect of heat flow focusing is to increase the heat flux by about 30% above background. By comparing these effects with conductive heat flow data at TAG, we find that advective processes dominate conductive heat flow at both the active and relict mounds. Advective circulation can also give rise to much larger lateral and vertical temperature gradients than would result from conduction alone.

Jan 1, 1999