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By R. L. Bruening, L. Navarro, Izatt. S. R., R. Adiga, R. M. Izatt, N. E. Izatt, A. Sharma, N. R. Patel, B. V. Rao

Bismuth is a notorious contaminant in the electrolytic refining of Cu that can cause cathodes to fail to meet ASTM International standards and not be suitable for use in Cu rod and other downstream products. Bismuth can significantly decrease electrical conductivity, decrease the mechanical strength of the annealed wire, retard recrystallization, and sometimes induce hot shortness during the hot rolling process in the production of rod. As a result, the control of Bi in the refinery tankhouse must be carefully managed. This paper describes how SuperLig® Molecular Recognition Technology (MRT) is being used for Bi removal at the Birla Copper Dahej Copper refinery. The operation of the SuperLig® MRT Bi removal plant is described and data on Bi removal efficiency are presented. INTRODUCTION Hindalco’s Cu division, Birla Copper, operates one of the largest Cu refineries in the world at Dahej, Gujarat; India. The main feed for this refinery is produced at the company’s smelter. Due to its massive production capacity, this operation mainly relies on imported Cu concentrates resulting in a variety of metals being carried out as impurities in the Cu anodes because pyrometallurgical technologies alone are not enough to remove them to the extent required. Metal impurities found in Cu ores include Fe, Zn, As, Pb, Bi, and Sb. During electrorefining, less noble metals dissolve in the electrolyte gradually increasing their concentrations creating the need for electrolyte control mechanisms that remove these impurities with varying degrees of success (Wang, 2004; Navarro et al., 2013.) Bismuth is one of the most significant impurities in a Cu refinery because it has the lowest ASTM product specification. This situation is critical because the Bi potential is very close to that of Cu making it possible to plate in the Cu cathode directly. Also, Bi can precipitate at high concentrations causing floating slimes and reduction of current efficiency (Ballinas, San Miguel, Munoz, & Gyves, 2003). Production of high purity cathodes from feed stock containing a diverse range of metal impurities becomes a major challenge in the refining of Cu (Izatt et al., 2015). In this work, the purification strategy followed by Birla Copper for the removal of Bi using a separation process based on MRT is presented, outlining the loading and stripping performance of SuperLig®83 and the benefits of using MRT over other lower selectivity methods where hazardous materials are produced instead of high purity products.

Jan 1, 2019

By W. M. Armstrong, John A. H Lund

The paper describes an investigation of some of the tensile properties of single crystal vanadium, poly-crystalline vanadium and polycrystal-line tantalum, in the range of: W°C to -196°C. Techniques employed in the preparation and testing of specimens are discussed in detail. Some results of determinations of the temperature dependence of yield stress and ductility are given, and discussed in terms of the Cottrell-Bilby Theory of yielding. At subnormal temperatures, all the body-centred cubic transition metals in the Periodic Table exhibit; a) the "yield phenomenon" in tension, b) a strong temperature and strain rate dependence of yield stress, and c) a large decrease or complete loss of ductility. The yield phenomenon (existence of an upper and lower yield point) has been explained by Cottrell and Bilby ( 1) in terms of the dislocation-locking effect

Jan 1, 1961

By R. H. McCorkell

"Sample drops were evaporated on Lexan disks on which fission tracks were etched and counted after neutron irradiation. [U] = 0.01 ppb could be measured. This method is rapid, cheap, simple and accurate when sufficient control and checking is possible, but several types of error were encountered in its use, the natures and sources of which were investigated but not always determined. The most troublesome were ""annealing"" processes which sometimes altered the fission tracks so that they were not fully revealed, or acquired varying appearances, after etching. Several different annealing processes seemed to exist and seemed to be produced by alteration of the Lexan surface by dissolved components in the solutions and, perhaps, by radiation and local heating during neutron irradiation. The appearances of the etched tracks varied with the natures of the droplet solutions even when annealing appeared to be absent, and for this reason, standards are best prepared by additions of known amounts of U to sample solutions. Contamination of sample droplets by U-containing dust from the air is best avoided by preparing the disks away from areas where other U-analysis is being carried out.IntroductionFission tracks are regions of radiation dam age produced in solids by the fission of atoms such as 235U. They can be enlarged to sizes visible through optical microscopes by etching surfaces through which they pass with solvents in which the solids are slightly soluble. A sample to be analyzed for U may be placed against a film of a solid of negligible uranium concentration (the track detector) and irradiated with thermal neutrons in a nuclear reactor to fission 235U. The track detector is then etched and the number of tracks per unit area, ?, which is proportional to the uranium concentration of the sample, c, and the neutron do se, n, is found by counting through a microscope. Uranium in solutions ha s been measured by evaporating drops on track detectors, irradiating, etching and determining the number of tracks per drop, T(2,3,4,5). Extensive test s of this method are reported here."

Jan 1, 1983

By J. Janzen

The cost to supply ventilation may exceed 40% of the total mine energy cost for underground mines and is often higher for deeper mines. The goal of Ventilation-on-Demand (VOD) is to ensure that the required quantity and quality of air is supplied to underground mining crews and diesel equipment at the least energy expenditure (minimum cost). A VOD system may include control of surface fans (Supply & Exhaust), underground booster fans, auxiliary fans and automated regulators/dampers to regulate the flow of air with more control elements providing more value. Strategically located Air monitoring stations measure air quantity and quality and provide feed-back enabling control. The modular design involving controls, intelligent instrument and intelligent motor control centres coupled with a communication network allows the quick installation, commissioning and expansion of the system as the mine develops. The result is a very robust, flexible system while reducing maintenance costs and spare parts. This paper discusses the impact of sensors, installation and commissioning on advanced controls and provides solutions for in-field applications.

Aug 1, 2013

By R. K. Carnochan

MANY improvements have been made in recent years in the milling of industrial minerals and it is the purpose of this paper to review some of the more important innovations that are now being used in the preparation of these products. Some of the observations which will be made have been prompted by what was seen on a recent trip to industrial mineral milling plants in the north and central sections of the eastern United States. The flotation plants visited were those of the Valley Forge Cement Company at West Conshohocken, Pa., the International Agricultural Corporation at Mount Pleasant, Tenn., and the Aluminum Ore Company at Rosiclare, Ill. Besides these, sand plants in Pennsylvania, West Virginia, and Ohio, coal-cleaning plants in Pennsylvania, pyrophyllite, mica, feldspar, clay, and kyanite plants in North Carolina, and a zinc mill and the Tennessee Valley Authority ceramic laboratory in Tennessee were visited. The milling of industrial minerals can be considered under three broad headings, namely, crushing, grinding, and purification. Usually there is both a separation and grinding problem in treating an industrial mineral, but the problems are distinct, although sometimes a separation is made while grinding, as in the case of a Raymond throw-out mill, which grinds and at the same time throws out most of any hard material present in its feed.

Jan 1, 1939

By M. P. Brameld, R. H. McCorkell

"Overburden covering bedrock uranium deposits was sampled to depths of 29 m and Rn concentrations measured at the same depths. Total-alpha activities, V concentrations and Rn emanation (J) of the samples were measured. The U-flux into the overburden was greater in the past: oxidation and dissolution has since removed most U, leaving decay products which indicate the presence of U deposits when U itself does not. Distributions of U and decay products and their ratios to each other reflect U-migration and degrees of U-removal. Rn distribution in overburden is related to the J of overburden samples and the presence and movement of groundwater. Simple, rapid methods of total-alpha and J measurement are described.IntroductionThe overburden drilling apparatus developed by Bondar-Clegg and Company makes possible sampling and radon measurement in overburden from the surface down to about 50 metres. This apparatus was used here to study the diffusion of uranium and its decay products from ore deposits into over lying overburden at the N deposit of the Amok Ltd. property (Cluff Lake, Saskatchewan) and on the Imperial Minerals Ltd. property at Gooderham, Ontario. These ores are enclosed in bedrock; the overburdens were deposited by glaciers or streams. The migration of uranium and its decay products in such situations and the factors which affect it have been little studied in the past, as readily usable techniques for mapping it in three dimensions have not been available. The results reported here are somewhat sketchy and preliminary, but they indicate the value of the methods used and some of the patterns to be expected. Surface and subsurface sampling and measurements were carried out on 3-line grids crossing known zones of mineralization. The lines were 60 metres apart at Gooderham and 40 metres apart at Cluff Lake."

Jan 1, 1982

By W. E. Uren

The Dominion Coal Board was created by Statute passed on July 17th, 1947, and was brought into effect by proclamation on October 21st, 1947. It is, consequently, a comparatively young body, having been in existence for only eighteen months. Before dealing with the constitution and duties of the Board, it may be well to answer the unspoken question of why it has been considered necessary to single out coal as one specific mineral requiring the continuous attention of a specially created permanent Board. In Canada, coal has been the neglected sister of the more spectacular minerals and it comes as a surprise co many to note that in 1948 the value of the coal produced in Canada was higher than that of any other mineral with the one exception of gold. Coal touches upon our daily lives in many different places of which the public are not generally conscious. As household fuel, it is a necessity of life in this northern climate; as a source of steam, it provides the heat for most of our industries; it is the food of the 'iron horse' chat shuttles our persons and our goods across the land; it is the source of power in many parts of the country; it is the chemical reducing agent chat, in our furnaces, transmutes the metallic oxides to the virgin metal. Coal is, in fact, the indispensable mineral chat forms the corner-stone of our present structure of industrial civilization. Is it, then, such an odd thing that the provision of an adequate supply of coal should be a matter of national interest or that measures should have been taken by government co provide for a constant watch, by a permanent Board, on the supply of co al? ? The Board is the result of the recommendations of the Royal Commission on coal which made a long and detailed study of the Canadian coal problem. It is composed of a permanent Chairman and six part-time members, most of whom have had intimate contact with various phases of the industry.

Jan 1, 1949

By J. G. Kim, B. G. Chae, D. S. Cheon, E. S. Park

The underground structures such as high-level radioactive waste disposal thermal energy storage should be designed and constructed considering thermal-mechanical characterization because of long term and/or cyclic thermal stress. High temperature changes in these structures can extend the existing cracks and generate new cracks in surrounding rock mass. In case of long term and/or cyclic thermal stress conditions, it is possible to lose the function of structures caused by the significant cracks and fracture growth in the rock mass. In this study, the critical thermal crack temperature of the granite, limestone and thermal Kaiser effect were evaluated. Experiments were carried out with the heating speed of 1.5?/min. To avoid thermal shock and target temperatures were set at 150? and 250?. In order to verify the thermal Kaiser effect, the samples were heated by 150 ? after 2-3 repetition to 250?. The generation and growth of cracks were observed through an acoustic emission measuring system. The variation of the physical rock properties was measured before and after thermal experiments. After compared with the thermal experiments using PFC2D, numerical simulations were carried out at higher temperatures (400?). The experiments showed that the initial thermal crack temperature of granite and limestone is about 35?, 32? and the critical thermal crack temperature were about 69? , and 49? , respectively. The experiments confirmed the thermal Kaiser effect of experimented granite and limestone due to thermal cyclic loading. From the numerical analysis, the critical crack temperature showed the same tendency as the thermal experiments. The P and S wave velocity of the sample after the experiment were reduced. Therefore, when heat is applied in long-term and repetitive conditions, these cracks may affect the function and stability of the underground structure. Therefore, further studies of thermal stress effects should be performed.

Jan 1, 2015

By J. Paquin, P. Doiron, G. Proulx, P. Champoux

After nine years on a 36 hour schedule and two programs of creeping, the Alcoa Deschambault Potroom of faced the necessity of changing its organization for many reasons: the anodes butts were too small, the anode schedule was unbalanced, the iron content in the metal trends had increased, the metal tapping volume did not convene with crucible capacity and the liquid measurement task was delayed by tapping activities. A kaizen activity inspired the Potroom department to improve the organization. A team of 15 people including the process engineer, the process technician, team supervisors and Potroom operators developed a scenario, which would permit flexibility to creep pots if energy is available and an increase of added value production.This paper will describe the systematic approach, the communication method, the trials, the changes, and our success, along with the problems experienced by the team during the adaptation of Alcoa Deschambault Potroom organization over a 20 month period. Aluminium 2006 45th Annual Conference of Metallurgists ofCIM Montreal, Quebec, Canada Edited by

Jan 1, 2006

By Floyd B. Bowen

Pumping methods are used, almost exclusively, to transport materials in the mining, beneficiation and chemical processing of phosphate rock in the Florida phosphate pebble field. Matrix pumping systems capable of pumping 15,000 g.p.m., transporting 15,000 long tons (dry) per hour, are now in use. They utilize 16-by 48 Yz -in. pumps, driven by 1.250-h.p. motors, discharging into pipelines 20 inches .in diameter .and sometimes several miles in length. As an average, it is necessary to pump 3 tons of matrix to the beneficiation plants, and to dispose of 2 tons of sand tailings and clay as waste, in order to produce 1 ton of shipping-grade rock. The washers and flotation plants, where the clay and phosphate and silica particles are separated, require the movement of large volumes of slurries with densities ranging from 2-3 per cent to 45 per cent solids, by weight. Extensive waste disposal systems require the pumping of dilute clay slurries in quantities of up to 50,000 g.p.m.,

Jan 1, 1963

By R. Walker

This paper deals with the selection and design of a belt conveyor handling steam coal between a mine and a barge loading terminal, and extending for some 5 ¼ miles over some of the most rugged terrain in the state of West Virginia, U.S.A. After a thorough analysis by consulting engineers and the owner's engineers, a single-flight cablebelt conveyor was chosen as representing the alternative of greatest reliability and lowest over-all cost. The value analysis and design features of the system are covered in this paper along with an updated report on the performance of the system since its start-up in the spring of 1969.

Jan 1, 1971

By Q. B. Li, B. Gonçalves da Silva, J. T. Germaine, H. H. Einstein, Z. Moradian

"Shale gas and oil production has grown rapidly in recent years, and consequently there are increasing demands to understand the mechanical and microseismic properties of shale. Acoustic emission (AE) monitoring provides useful information on the fracture mechanisms of shale rocks, and provides a basis for interpreting field seismic observations. While there have been attempts for microseismic monitoring of conventional hydrocarbon reservoirs, shale presents a large number of issues that require further investigation. For this purpose, experiments were conducted to understand the characteristics of the AE waveforms propagated through Opalinus shale rock in the time and frequency domains. Frequency range, arrival time, first arrival amplitude and other parameters such as counts, duration and energy of the waves generated from artificial and natural sources in the shale specimens were detected and compared with AE characteristics of granite, a brittle rock that has been extensively investigated. The experimental tests showed that there are some important factors that influence the analyses and interpretations of seismic surveys and microseismic monitoring of shale compared to granite. One of these factors is the anisotropic behavior of shale that causes the wave to propagate with different velocities in different directions. Also bedding planes and micro-discontinuities in the shale cause attenuation of the waves. Thus the AE waveforms that arrive at the sensor are a distorted and attenuated versions of the source waveform.INTRODUCTIONMonitoring microseismic activity from hydraulic fracturing of shale provides vital information for mapping injection paths and fluid migration in order to check the effectiveness of the hydraulic fracture stimulation. Analysis of microseismic source locations can be used to identify fracture networks induced or mobilized during the hydraulic fracturing operation (Rotherd and Shapiro, 2003). On the other hand, by monitoring and assessing detected signals from hydraulic fracturing one can evaluate the induced seismic impact of the stimulation operation.While there have been attempts to monitor microseismic events in conventional hydrocarbon reservoirs, shale presents a large number of issues that require further investigation. For this purpose, experiments were conducted on Opalinus shale to understand its acoustic emission (AE) characteristics in the time and frequency domains."

Jan 1, 2015

By P. O. Parfitt

At the McIntyre mine, there are two distinct operations: a gold mine with narrow veins, mined by cut-and-fill methods, and a copper mine with large, open, long-hole stopes. The application of the Critical Path Method to scheduling work in the copper mine, where it has been used successfully for several years, is de-scribed briefly. This application is relatively simple. Use of C.P.M. has now been extended to the gold mine. To replace the former method of scheduling from bar-charts, a procedure was developed for scheduling automatically. To handle an operation of this size and complexity, a computer was essential. Improved schedules are now being produced, with a saving in time.

Jan 1, 1967

By J. Budac, R. Kofluk, S. Mankasingh

Stainless steels such as 316L or 304 are normally relatively resistant to attack by nitric acid. However research at Sherritt International’s Fort Saskatchewan Operation reveals that when the stainless steel is immersed in an aqueous system in which nitric acid is used to dissolve metals such as cobalt or nickel, the steel can be seriously corroded. Sherritt is patenting a simple process for arresting the corrosion via the use of copper. This process is expected to substantially eliminate corrosion in processes where nitric acid is used to dissolve metals attached to a stainless steel substrate.

Jan 1, 2014

By William H. Emling

With profitability pressures in heavy industry increasing, many producers are turning to predictive maintenance as a means of harvesting untapped value from their production assets. Corporations are losing their maintenance and processing core competencies through attrition. As capital budgets are being trimmed, manufacturers are consolidating operating units into fewer, more profitable routes. Maintenance functions, however, typically receive low priority when investment is made, since many companies consider maintenance costs as ?overhead?. Condition-based monitoring, integrated to Level I and Level II process inputs, is seen as the most cost-effective solution to the implementation of predictive maintenance strategies. This paper will review the evolution of preventive and predictive maintenance programs, highlighting examples of successful application of integrated condition monitoring.

May 1, 2001

By Yvon Trudeau, Deni Raymond

"The Orion gold mine, located 7 Ian northeast of the town of Malartic, Quebec, was discovered in mid-1985. Underground exploration was undertaken in 1986 leading to commercial production in 1988. The upper part of the orebody was exploited above the 125 m level and a total of 131 090 t at an average grade of 5.31 g/t gold were extracted.This paper describes the authors' current knowledge and interpretation of the geology, gold distribution, and structure of the Orion No.8 ore zone deposit. The deposit is an epigenetic lode gold occurrence somewhat unique in that both quartz-vein type and pyritic type of gold ore occur side-by-side. It is located within the Marban-Noriartic Deformation Corridor (MNDC) formed during a first deformation stage (D1) The MNDC is a well-defined regional structural feature in the Val d'Or - Malartic mining camp. Primary gold mineralization is associated with the D1 event and is represented by pyritized, silicified and brecciated basaltic lavas enclosed by ultramafic flow units. The ore zone is concordant with the MNDC. Felsic intrusions are spatially related with the ore zone, but their role in the genesis of the ore has yet to be dermed.A second deformation event (D2) resulted in local folding, a second schistosity (S2) and reverse faulting. Gold remobilization, the formation of the gold-bearing quartz breccia and the emplacement of the main quartz vein at the No. 8 zone deposit were associated with this event."

Jan 1, 1992

By D. W. Li

Due to the ultrasonic testing and mechanical wind speed sensor have high requirement for the environmental of the coal mine, the charge induction wind speed detection method based on wavelet analysis is proposed. The same wavelet disturbance detection method is used at a fixed distance to obtain an induction signal to obtain a pass time, and then calculate the magnitude and speed of the wind. Simulation and verification experiments show that the method has application across a wide range of test speeds (up to 60 m/s). The metal probe causes little pipeline flow field interference. The method is particularly well-suited to dusty environment, and does not cause dust deposition through long-term operation. It can be widely used in coal mines for point wind speed continuous online testing.

Aug 1, 2013

By N. Moelans, I. Bellemans, K. Verbeken

In this work, we present a phase field model to simulate the facetted crystallization of Fe3O4 in a quaternary FeO-Fe2O3-Cu2O-SiO2 melt under different partial pressures of oxygen. An important focus in creating more realistic phase field models is the incorporation of the thermodynamic driving forces in multicomponent multiphase-field models by coupling to thermodynamic databases. The diffusion of FeO, Fe2O3 and Cu2O is considered. The ratio of FeO/Fe2O3 at the upper boundary is in equilibrium with the oxygen fugacity of the atmosphere, while conserving Fe. Two-dimensional simulations are performed with different varying oxygen fugacity in the atmosphere. For the considered composition range, the growth velocities of the spinel crystals increase with decreasing oxygen fugacity. INTRODUCTION Crystallization of silicate melts has its applications in geology, pyrometallurgy and glass making. In pyrometallurgy, the solidification of slags influences the freeze lining behaviour (Campforts et al., 2007) and the cooling of slag after tapping (Durinck, Jones, Blanpain, & Wollants, 2008). Modeling of silicate melt crystallization is frequently done on the macroscopic level, using thermodynamic equilibrium calculations to determine the fractions of all phases as a function of temperature. The Factsage software and database package (Bale et al., 2016, 2009, 2002) already proved its usefulness in pyrometallurgical applications, for example to model the phase mixture after solidification of a stainless steel slag (Durinck et al., 2008). Crystallization of phases typically results in complex morphologies on the mesoscale, e.g. dendrites or facetted growth. On this mesoscale, the phase field concept has proved to be a very powerful tool (Moelans, Blanpain, & Wollants, 2008) for modeling crystallizing microstructures, because it can treat arbitrarily complex interface shapes with minimal mathematical complexity. In contrast to macroscopic models, the diffusion profiles and crystallization kinetics can be described as well as the morphology of individual crystals. First, Kobayashi (Kobayashi, 1993) simulated a growing dendrite in a pure undercooled metallic liquid. Then, Warren and Boettinger (1995) simulated a dendrite in an isothermal system considering a binary alloy. The extension to multi-phase systems was done by Steinbach et al. (1996). This was further extended by Tiaden, Nestler, Diepers, and Steinbach (1998) to a framework with coupled diffusion and phase field equations in multi-component systems.

Jan 1, 2019

By T. V. Lord

Minerals containing uranium have been successfully pre-concentrated by flotation at Queen's University, Kingston. In particular, uraninite, uranothorite, euxenite, and fergusonite, have responded to flotation to yield grades of 0.2 to 6.0 .per cent U .o. with recoveries of 85 to 98 per cent, from heads analysing approximately 0.10 per cent U3Os. Of the ten or so radioactive samples examined to date, two distinct groups were recognizable, firstly, those samples in which uranium was the sole constituent of economic interest, and, secondly, those in which Columbium (with minor amount of tantalum) was present in addition to uranium. For the purpose of this paper, the results of investigation on two samples of each of the above groups have been selected as typical.

Jan 1, 1945

By D. Houghton

"I am very pleased to be a member on this panel today because abrasion and wear in mills has been part of my life over the past forty years. My presentation will deal with the role Ni-Hard has played in combating wear and abrasion in mills. Before Ni-Hard came along, unalloyed white iron was used in ball mills and one of the most popular types of white iron liners was the pocket liner. Slide #1 illustrates the design of the pocket liner used at Dome Mines in their 5' x 22' pebble mills. The pockets filled with grinding media and it was on this that the wear took place. The concept is not unlike the new magnetic liner which utilizes the ore and grinding media to form the wearing surface. In this slide please note the tapered pocket type of cored bolt holes. If cored bolt holes do not fill with grinding media there could be excessive grooving or wear at that area. Therefore all cored bolt holes should be tapered in this manner.Before Inco patented the name Ni-Hard several foundries were making the alloy iron under different brand names such as Diamond Alloy, Mitchelloy and Specialloy. In the early days some of the Ni-Hard was poor quality. Inco provided foundries with technical knowhow and provided assistance to licence them to sell under the name of Ni-Hard. This was in the late 1920's. The material we are discussing is Ni-Hard type I with the following analysis (slide #2). It is a martensitic white iron with BHN of 550 - 600 and is a relatively easy alloy to produce in either a cupola or electric furnace. The annual average production of Ni-Hard in North America is 90,000 tons with mill liners making up 25,000 tons and grinding media 30,000 tons, according to Warren Spear of Inco."

Jan 1, 1983