Search Documents

"Since World War II, urban communities have expanded at an unprecedented rate. The industrial mineral industry supplies the sand, grave], limestone, crushed rock, cement, gyp-sum, etc. for urbanization. Most de-posits in use are close to or within communities. Pollution of water and air has become a matter of public concern. Waste disposal and the effects of noise and vibration are subjects of public debate. Need for the reclamation of land after operations such as strip mining is discussed in magazine articles and on TV pro-grams; i.e., the general public is educated in the unattractive features of mining.Legislation is on the books and being drafted to regulate mining operations and their side effects. To avoid over-regulation and restrictive legislation, it is necessary that the public be educated and legislators informed of problems peculiar to the mining industry. Our side of the story needs publicity."

Jan 1, 1968

By W. B. Morrey

"In recent years, the major effort in detonator development has been concentrated on ""non-electric"" systems. Existing types all involve some form of explosive reaction to transfer ignition energy from outside the borehole to the pyrotechnic delay element contained within the detonator. These may be based on low-energy detonating cords having grained or plasticized explosive cores, shock tube energy transmission principals and explosive gas ignition systems. Each has properties of internal and external effects not present in electric conductors.The MAGNADET System introduces transformer coupling into electric blasting circuits. Safety features with respect to current leakage, stray currents of AC or DC source, electrostatic energy and radio-frequency radiation are comparable to ""non-electric"" systems, with advantages in simplicity, speed of hook-up and range of application.The transformer device used is a small ferrite ring or toroid which is an integral part of each specialized detonator. The detonator legwires form the secondary side of the transformer winding. The primary side is a single wire loop common to all units within the circuit. Power is supplied from a frequency-tuned portable exploder with unique circuit-sensing features.The MAGNADET System is expected to have particular application to shaft sinking, raising and tunnelling where the protective features as well as speed and efficiency are critical factors. Applications of the 'MAGNA' booster in quarries, open pits and longhole deck charges offer control over vibration problems and elimination of surface noise.IntroductionFor many years, electric detonators and electric blasting systems dominated surface and underground applications where controlled delay times were required. Control over the instant of detonation by blasting machines or power-line switches is the major safety feature.Electrical energy exists in many forms. It may originate from many sources. Electrical energy can be difficult to contain. It may enter or escape through a variety of conductive paths. It may fluctuate, concentrate or dissipate to pose a most elusive potential hazard."

Jan 1, 1982

By P. C. McLeod

THE GECO OREBODY, located north of lake Superior in the Thunder Bay district of northern' Ontario, was discovered in 1953. Diamond drilling in the following year indicated a 15,000,000-ton ore-body, and production plans were made for the shipment of copper and zinc concentrates in three years. To accomplish this, the Geco Project was initiated. The property was in an undevdoped, inaccessible area, and the project involved the conversion and extension of a logging road to the property, the construction of two railways and seventy miles of hydro transmission line, the erection of a municipality, the building of a plant, and the development of an underground mine to produce 3,300 tons per day. This paper describes some of the methods used in the underground development phase of the Geco Project.

Jan 1, 1958

By S. N. Dixon

"Maximizing the value of each tonne of processed ore is the goal for all operations. Cyanidation processing of gold-copper ores has been challenging since its first use in 1889. The current practice treats a bleed or the total flow of mill solution to recover copper as copper sulfide (by sulfidization, acidification, recycling, and thickening), or to recover the cyanide (by acidification-volatilization neutralization). The process presented uses the adsorption of copper cyanide by carbon and the selective elution of copper from carbon to concentrate copper into a smaller stream. Copper contained in the smaller stream is precipitated as copper cyanide.RÉSUMÉ Toutes les exploitations ont pour objectif commun d’optimiser la valeur de chaque tonne de minerai traité. Depuis sa première utilisation en 1889, la méthode de traitement par cyanuration des minerais aurifère et cuprifère s’est révélée complexe. La pratique actuelle traite la saignée ou le débit total d’une solution de traitement du concentrateur pour récupérer le cuivre sous la forme de sulfure de cuivre (par sulfuration, acidification, recyclage et épaississement), ou pour récupérer le cyanure (par acidification, volatilisation et neutralisation). Le procédé présenté dans cet article utilise l’adsorption sur charbon actif de la solution de cyanure de cuivre et l’élution sélective du cuivre depuis le charbon pour concentrer le cuivre en un plus petit jet. Le cuivre contenu dans ce plus petit jet est précipité sous forme de cyanure de cuivre.INTRODUCTIONProcessing gold-copper ores by cyanidation has been a cost-control challenge since the cyanidation process was first used in 1889. Copper cyanide is stable only in the cuprous state, not the cupric. This factor results in the oxidation of a mole of cyanide per mole of nonchalcocite copper extracted. Each mole of copper extracted forms a cyanide complex with a minimum of 3 mol of cyanide. This cyanide-to-copper mole ratio is required to dissolve gold. The oxidation of cyanide and copper complexation with cyanide results in high cyanide consumption for copper-gold ores, which is a significant operating cost.One challenge in processing gold-copper ore is the cost of cyanide related to the extraction of copper. Processing 10,000 t/d of ore containing 1,000 mg/kg copper and 10% copper extraction yields 1,000 kg/d of copper. Currently, processes to remove copper from cyanide leach solution treat either the total flow of the barren or a bleed of the barren. The two processes used for copper-gold ores are sulfidization, acidification, recycling, and thickening (SART), which produces a copper sulfide product for sale; and acidification- volatilization-neutralization (AVR), which recovers the cyanide from a gas and produces a low–cyanide content solution. This low–cyanide content solution can be recycled to the process or might require additional treatment before being disposed from the operation."

Jan 1, 2017

By Ted J. Smith, Stephen E. Kesler

"Zonation patterns are welt developed in the mafic metavolcanic rocks that host epigenetic quartz-carbonate-gold vein mineralization at the Hollinger-McIntyre deposit. Carbonate alteration assemblages are strongly zoned about mineralization. Proceeding inward from background greenschist facies rocks to alteration envelopes enclosing individual veins, the following assemblages are observed:Assemblage I-quartz-albite-chlorite-epidote-actinolite-(calcite)Assemblage II-quartz-albite-chlorite-calcite-epidoteAssemblage III-quartz-ankerite-sericite-(chlorite-calcite)Assemblage IV-quartz-albite-ankerite-sericiteLithogeochemical zoning is equally well developed as variations in whole-rock abundances ofAs, Au, Ba, Rb, and Sb. As and Ba form the most useful zonation patterns, outlining individual ore zones as well as broader trends of mineralization.Gas chromatographic analyses of fluid inclusions in the quartz-carbonate veins indicate that the mineralizing fluid was an H20-C02 mixture. Locally, CH4-rich fluid inclusions are associated with graphitic and/or carbonaceous wallrocks. Fluid inclusions in ore-bearing veins have higher CO2 contents than those in non-ore veins. Extensive sampling and analyses of veins from the area surrounding the deposit reveals a well developed zonation of CO2 contents about the main zone of mineralization. Low CO2 levels (1-2 mole%) in veins are peripheral to the deposit and increase to over 12 mole% in mineralized zones.The observed zoning of the carbonate alteration assemblages is a result of the addition of CO2 to the wallrock, which is consistent with the zoning of CO2 in the fluid inclusions.The zoning patterns delineated in this study are useful in exploration both on a deposit scale and on the scale of individual ore zones."

Jan 1, 1985

By D. Ibarra, J. Jacob, A. G. Guezennec, P. d’Hugues, A. Archane

The lack of adequate gas mass transfer is a rate limiting step in many bacterial leaching processes. Oxygen often becomes a limiting factor because of its low solubility compared to the high demand induced by sulfide oxidation. One way of increasing the solubility of oxygen in water or in media solution is by increasing the driving force, i.e. raising the oxygen partial pressure in the gas stream supplied to the leach pulp. The use of oxygen is a well-known practice in high-temperature bioleaching reactors (above 70°C) whereas air is usually preferred in medium and low-temperature operations in order to avoid too high dissolved oxygen concentrations which could impact negatively the bacterial activity. The purpose of this study was to investigate the use of oxygen-enriched gas in bioleaching reactors at 40°C in order to improve the gas transfer in the system when operating at high solid load (20% and more). Bioleaching experiments were performed on a sulfide-rich tailing waste (pyrite 60%, copper 0.8%, cobalt 0.06 %, gold 1 g/t) using the “BRGM-KCC” bacterial consortia. The reactor used for the tests was designed on the basis of a new bioleaching reactor concept developed by Air Liquide, Milton Roy Mixing and the BRGM which uses floating agitators to inject gases and to mix and to suspend solids in the bioleaching solution. Two types of tests were carried out: with air injection and with oxygen enriched gas mix injection. The aim of this work was to confirm the capacity of bacteria to grow and to dissolve pyrite in this type of bioreactors in oxygenrich atmosphere, and to compare sulfides dissolution rates during both types of bioleaching tests. The results obtained show that the use of oxygen enriched gas mix does not decrease bioleaching performances compared to air injection. High metal extraction yields were achieved (above 80%). No deleterious effect due to oxygen use was observed on the bacteria despite the high level of dissolved oxygen reached in oxygen tests (up to 14 mg.L-1).

Jan 1, 2016

By G. J. Kipouros, P. W. Kingston, W. F. Caley

"Current practice in advanced materials processing has involved the dispersion of a second-phase, commonly SiC, glass, or other non-metallic fibres/whiskers/particulates to enhance physical characteristics of the matrix. These matrices may be either ceramic or metallic but in either case it is important that the physical and chemical properties of each phase be compatible. The dispersed, finely divided second phase is often both expensive and foreign-produced and may exhibit chemical instability at elevated temperatures. Thus, it would appear that certain naturally-occurring industrial mineral fibres/whiskers/particulates might offer an attractive and low-cost alternative. Suitable candidates, such as wollastonite and sillimanite, are available in Canada and may be milled to produce particles whose shape is appropriate for this application. It is suggested that wollastonite, in particular, may be a useful modifying agent in metal matrix composites utilizing AI, Al-Si, Zn-Al or other light metals and alloys. In addition, the possible use of these minerals in ceramic matrix materials is also addressed, with reference to a preliminary thermodynamic analysis of the systems involved.IntroductionBackgroundA composite material may be thought of as consisting of a matrix component, the properties of which are improved by the addition of a second component or dispersed phase which forms a distinct three-dimensional interface with the matrix. This matrix is commonly either metallic or ceramic, which leads to the two most popular types of composites: metal-matrix composites (MMC); and ceramic-matrix composites (CMC).Such materials are by no means new. Early composites include fiberglass, mixtures of plaster and horsehair in wall plastering, as well as use of natural materials such as bamboo in fishing rods. Some of the newer applications include high strength, low-weight bicycle rims, as well as the more familiar role in aircraft and automobile engine components."

Jan 1, 1993

By Jehan Rondot

Les bancs de quartzite inhabituellement purs et epais decouverts lors de la cartographie geologique de la region de Charlevoix sont maintenant entres au stade de !'exploitation et se revelent etre une richesse naturelle durable pour cette region. Les etudes stratigraphiques effectuees dans cette partie (Quebecia) du bouclier canadien indiquent que la succession: lo. complexe a amphibolite et leptynite a la base, 2o. quartzite et gneiss a sillimanite, muscovite et gneiss calcosilicate et conglomeratique au sommet est constante sur de grandes distances (de Charlevoix a la Basse Cote Nord) et represente une sedimentation continentale et de plateforme, peu epaisse, du proterozotque inferieur. La purete et la grande epaisseur du quartzite s'expliqueraient par un processus de sedimentation continentale complexe ou se succedent climat tropical-humide et glaciaire-aride et transport fluviatile et eolien. Parmi la multitude de depots de quartzite qui existent dans le monde, peu sont de qualite superieure. Or, de par sa composition chimique, le quartzite de La Galette se compare avantageusement a ceux des meilleurs gisements des Etats-U ni s, de l'Europe de l'Ouest et de I' Afrique du Sud. D'acces facile pour l'exploitation, les gisements ne sont qu'a une quarantaine de kilometres de Baie Saint-Paul ou de La Malbaie, sur le SaintLaurent. L'utilisation en metallurgie du quartzite de La Galette comprend la production de silicium, de ferro-silicium et d'autres alliages de silicium . La composition du quartzite est en outre appropriee pour la production de carbure de silicium et de silicate de sodium. Les fines peuvent etre utilisees pour la fabrication du verre et comme matiere de charge.

Jan 1, 1984

By Neil Schofield

"The estimation of recoverable ore reserves for feasibility in precious metal deposits such as Pine Creek must account not only f or the extreme variability of the ore grade but also for the complexity of the geology. Compatible models f or both must be adopted. Further, very selective mining demands reserve estimates be based on small selection units whose individual grades cannot be estimated reliably from the exploration drilling data.Multigaussian kriging is one method based on a multivariate normal model for estimating recoverable reserves under such conditions. In this paper, a non-mathematical description of the multigaussian model is presented together with its application to the Pine Creek Gold Deposit. The results, when compared to the first year of production, are encouraging for the model but not without surprises.Together, Part 1 and Part 2 of this study combine a detailed and geologically conditioned variogram analysis with an appropriate estimation method for a highly variable low-grade gold deposit. This and other studies of gold deposits familiar to the author show convincingly both that while the appropriate geostatistical skills and techniques are necessary to tackle the question of reserves, equally important but often discounted is the need for an appropriate and compatible geological model. IntroductionThe Pine Creek gold mineralization is associated with saddle reefs, and quartz and quartz- sulphide veining within the Enterprise Anti cline. The anticlinal structure is complex and, prior to mining, the mineralization was considered to be mainly strata controlled. Grades vary up to 160 grams in l .5rn core samples with coefficients of variation in excess of three.The estimation of the recoverable reserves for such a depo sit must account for both the geological complexity and the extreme variability of the gold grade.Part 1 of this work presented the geological model for the deposit and summary statistics 0 f the gold data. A detailed structural and variogram analysis considered both gold grades and the normal score (or gaussian transform) of these gold grades for different composite sizes."

Jan 1, 1988

By B. E. Jones

"The area of uranium deposition is situated within the Churchill Province on the western edge of the Wollaston Iithostructural domain where it underlies the eastern edge of the Helikian Athabasca Formation. The Collins Bay deposit is 6 miles north-northeast of the Rabbit Lake mine. Two principal zones of uranium mineralization are described.The ""A"" zone is a partly eroded, high-grade pod of metal oxide and arsenides sheathed by clay-like minerals. It trends north-northeast and lies under 25 to 40feet of water. Uranium mineralization is localized at or adjacent to the unconformity between the Athabasca Formation and the basement rocks. The basement comprises a granitoid Archean terrain overlain by paragneisses of the Aphebian Wollaston Group. ""A "" zone ore contains phyllosilicates, quartz, pitchblende, rammelsbergite, pararammelsbergite, carbonaceous material, galena, gersdorffite, niccolite, carbonate and a trace of sphalerite.The ""B "" zone lies 6,000 ft south of the ""A "", and subcrops under till cover. It is a partly eroded zone composed of metal oxide and arsenides which occur within variably altered Athabasca Formation. Minerals recognized are phyllosilicates, pitchblende, niccotite, gersdorffite, millerite, carbonaceous material, pyrrhotite, skutterudite and a trace of galena. The Athabasca Formation varies from 90 to 160ft thick. Granitoid gneisses of probable Archean age and paragneisses of the Wollaston Group underlie the deposit. An easterly dipping thrust fault transects its length.The deposit is typical of the ""unconformity-type"" uraniumnickel deposits of the Athabasca Basin. Observed features fit well with the ""diagenetic-hydrothermal"" model for such deposits, as envisioned by Hoeve and Sibbald (/978)."

Jan 1, 1980

By Bo R. Arvidson

"New permanent magnetic alloys have recently opened up possibilities for development of unique mineral separators. These are now making several new applications feasible. In many cases where conventional electromagnetic-induced roll separators have traditionally been used, the new permanent magnetic roll separators may reduce both over-all capital costs and operation costs.The development of the next generation of extremely powerful permanent magnets, i.e. neodymium-iron alloys, is progressing rapidly and will affect the roll separator as well as another type of magnetic separator. Permanent Magnet Roll SeparatorDesign and FeaturesDiscs of permanent magnets interleaved with soft iron discs constitute the basic magnetic roll design (Fig. I). By enveloping the magnetic roll with a thin abrasive resistant belt (Fig. 2), even highly magnetic particles are removed.The first prototype roll utilizing the new magnets was shown to have approximately equal strength as induced magnetic roll (IMR) separators. Since the initial test roll, the new separator, called the PERMROLL® , has been made twice as strong with regard to magnetic force, that is, the magnetic flux density is determined to exceed 1.7 tesla (17 kilogauss), while the magnetic field gradient is more than twice the gradient than can be practically achieved with IMR."

Jan 1, 1985

By D. R. Winchester

"I wish to thank you and your organizers for inviting me to address you at this point in time when we are all concerned for the future of the mineral industry in Canada.My topic ""Some Initiatives of Government Assistance to Industry Applicable to Mineral Processing"" is purposely limited in scope. To cover the entire range of initiatives in detail would take me all day, and at best, would be a mere recital of program titles, and a one sentence summary of the contents of the program. As you know, OREE or Regional Economic Expansion, is in the process of being amalgamated with elements of the Department of Industry, Trade and Commerce. We will become Regional Industrial Expansion or ORIE. If the name Canada Dry becomes popular, I don't think we will object as we hope to become a good mixer. The entire departmental thrust has been re-evaluated, and is in the process of being re-constituted to better serve the nation, and industry as a whole. Amalgamation of the industrial, trade promotion and marketing support skills of IT&C, with the regional development orientation and decentralization program delivery mechanisms of DREE, will, it is believed, provide better support to industry on a national and regional basis."

Jan 1, 1983

By Brian W. Mackenzie

"This paper briefly outlines the characteristics which should be considered in assessing the economics of mineral exploration, and illustrates such an assessment by using data from the Canadian base metal sector. Implications for the sector are found to include the following:(1) base metal exploration has the potential to create a substantial amount of new wealth;(2) investment incentive for exploration under current conditions is not unattractive over-all;(3) because of existing taxation policies, there is much more incentive for large companies to explore than for smaller enterprises;(4) succesful exploration is sensitive to the size, financial resources and organizational structure of the exploration entity;(5) the general level of recent exploration expenditures should be adequate to maintain the current rate of production and perhaps to support very modest growth; and(6) there is an important opportunity for growth in the sector.The findings of the study suggest that government policies should be made more flexible, in order to take into account the risks associated with exploration and with price fluctuations in the base metal sector. Recommendations are also made concerning improvements in provincial regulations for disclosure of exploration information."

Jan 1, 1981

By P. A. Distin, Jr. da Silva

The history of commercial processes for zirconium/hafnium production and separation is reviewed. A new technology is then proposed as a potential alternative for zirconium/ hafnium separation in a simpler, cleaner way than achieved with current processes. Primary sources of zirconium always contain small amounts of hafnium that must be removed during production of zirconium metal for nuclear applications. This separation is usually carried out by a solvent extraction process, developed in the 1950s, that selectively extracts hafnium, as a thiocyanate complex, using methyl isobutyl ketone (MIBK). Environmental problems inherent to this process are the high aqueous solubility and low flash point of MIBK, and possible gaseous contaminants formation generated by the decomposition of the thiocyanic complexes in hydrochloric acid medium (H2S, HCN, mercaptan’s formation). The present work shows how these problems could be avoided by using organophosphorous extractants that were unavailable when the MIBK process was developed.

Jan 1, 1998

By A. Plugatyr, C. P. Baxter

"Bessemer matte iron content is a critical process parameter that needs to be closely monitored and controlled in order to achieve optimal Ni/Cu smelter returns. Current process control practices during Ni/Cu converting often rely on visual observations and typically involve matte sampling to confirm that target composition was reached. A high-level techno-economic analysis study was carried out to evaluate potential direct benefits of advanced process control during the final stages of Ni/Cu matte converting. The results indicate that the magnitude of direct benefits will largely depend on matte iron control practices already implemented as well as matte iron set point. Preliminary assessment suggests that under the assumptions used in this study, implementation of advanced process control can potentially result in additional revenues ranging from several hundreds of thousands to tens of millions of US dollars per year per converter producing about 200 tonnes of Bessemer matte per day based on Ni, Cu, and Co metal recoveries alone.INTRODUCTION Real-time measurement of molten metal elemental composition, arguably, remains one of the key unresolved issues impeding full automation and real-time optimization of pyrometallurgical operations in different industrial areas, including non-ferrous metals and ferro-alloys. In particular, current process control practices during Ni/Cu matte converting often rely on visual observations and typically involve matte sampling in order to confirm target matte composition. In addition to being time consuming, this approach relies heavily on operator experience and diligence, and, therefore, requires continuous performance and quality control efforts. For instance, the need to improve quality of the Bessemer matte (BM) at the Copper Cliff smelter has prompted an impressive staff engagement and training campaign that was carried out by Vale’s team in the late 2000’s (Zanini, Wong, & Cooke, 2012). This training exercise was executed to address the compounded effect of several operational challenges, namely demand for higher throughputs, changes in the feed concentrate composition, increased feed variability, loss of process knowledge and expertise due to retirement, as well as lack of a comprehensive approach to improving the overall performance of the flowsheet rather than meeting production targets for intermediate products. Although the campaign was very successful and has resulted in significant improvements in the Bessemer matte quality, it has also highlighted the need to move away from “the-art-of-converting” and develop analytical tools that would enable real-time process monitoring."

Jan 1, 2018

By Alexandre Desbarats, Michel David

"All optimum pit design studies start from the geological are reserves inventory, the estimated grades of all blocks of potential are within the interpreted limits of the deposit. The actual optimization procedure is then carried out on block valuations based on these estimated grades. Thus, the relevance of any pit design can be seen to depend directly on the ore reserve estimation . To insure a proper pit design, a first step would be to use a geostatistical reserve estimation technique such as kriging, however, this is not enough. A frequently neglected fact is that the blocks of ore estimated during the planning stage of the mine are usually considerably larger than those on which the ore-waste selection will be made at the time of mining. Experience in the exploitation of large low-grade deposits has shown that large blocks, estimated to be are, when mined selectively in smaller blocks, often yield significant amounts of waste material. This phenomenon, known as internal waste, is a function of the variability of the grades, the size of mining unit and the amount of sampling information on which ore-waste decisions are made.In this study, it was proposed to consider the effect of internal waste caused by selective mining, on. pit design, using geostatistical methods to predict the tonnage and grade of recoverable reserves within large blocks.Optimum pits obtained using a block valuation formula taking into account the recoverable reserves within large blocks were compared with optimum pits obtained using a conventional block valuation formula. It was found that the optimum pits obtained by the proposed method had the highest total valuations and thus were, in fact, ""more optimum”. These pits were characterized by greater are tonnages at a lower average grade, the additional ore more than compensating for the drop in grade. It was also found that the consideration of internal waste in pit design could considerably alter pit limits in marginal areas of the deposit.It was concluded that selective mining had a significant, potentially critical, impact on the design of optimum pits especially in the case of large low-grade deposits."

Jan 1, 1984

By Maurice Hall Haycock

ONE result of the higher price of gold has been the exploitation of many low-grade deposits, the successful treatment of which depends upon obtaining high recovery of the contained gold. Modern methods have made it possible to recover gold from many ores formerly regarded as impossible to treat economically, but in order to apply these methods efficiently it has become desirable, and indeed in many cases indispensable, to gain precise information concerning their mineralogical and physical character. The most successful means of doing this is the use of the reflecting microscope. Reflecting microscopes had long been employed by metallurgists for studying polished surfaces of iron and steel when, thirty years ago, Dr. W. Campbell, of Columbia University, advanced the idea of using similar methods for studying opaque minerals (1). The immediate result was the completion of two microscopic studies, the first on Cobalt silver ores (2) and the second on Sudbury nickel ores (3). The idea was surprisingly slow in being adopted, and not until 1911 did it begin to spread through the universities of this continent. From then on, ore microscopy, or 'mineragraphy', made rapid progress, and, during the next fifteen years, research in universities of North America and Europe led to the development of somewhat specialized apparatus and technique. This phase of development, which resulted largely in contributions of a descriptive nature, furnished a mass of data from which the possibility of economic applications was soon recognized. Ore microscopy became an aid to the mining geologist in solving many problems of ore deposition. This soon led to its application in the study of ores and mill products in connection with their treatment. Its usefulness in this latter field has been very marked and has led to its widespread adoption by the mining industry.

Jan 1, 1937

By T. H. Chuang, Y. Y. Shiue

"Rapid whisker growth was significantly alleviated in a Sn-58Bi alloy doped with 0.5 wt.% La. Experimental results showed that many thin, plate-form intermetallic phases appeared in the solder matrix. The absence of tin whiskers was correlated to the shape effect of RE-containing intermetallic plates. After reflowing, Cu6Sn5 intermetallic compounds appeared at the solder/pad interfaces of Sn-58Bi and Sn-58Bi- 0.5La packages with OSP pads, which grow linearly during the aging at 75 and 100? for various times ranging from 100 to 1000 h. In addition, the interfacial intermetallics layers in Sn-58Bi-0.5La solder joints were also observed thinner than those in undoped Sn-58Bi joints. However, RE-containing interfacial intermetallic compounds in Sn-58Bi-0.5La solder joints led to lower bonding strengths in both ball shear tests (0.4 mm/s) and high speed ball shear tests (2000 mm/s). All the reflowed and aged solder joints of both packages were ruptured through the solder balls indicating brittle characteristic INTRODUCTIONIt has been widely reported that solder alloys doped with rare earth (RE) elements reveal many beneficial effects, such as higher strength, lower melting point, improved wettability, and longer creep life (Wu et al., 2004; Ma et al., 2002; Chen et al., 2002). In addition, Dudek et al. reported that the alloying with 0.5 wt.% La in Sn-3.8Ag-0.7Cu solders resulted in an increase of rupture strain, up to 150% over undoped solders (Dudek et al., 2006). However, Chuang and Yen observed that a large amount of long, fiber-shaped tin whiskers were extruded out of the oxidized CeSn3 intermetallic clusters in the matrix of a Sn-3Ag-0.5Cu-0.5Ce solder air-stored at room temperature for several days (Chuang & Yen, 2006). Furthermore, many coarse hillocks appeared around the CeSn3 clusters in the RE-doped alloy after storage in an air furnace at 150? for several minutes. Chuang proposed a mechanism for the phenomenon of rapid whisker growth, which the predominate oxidation of CeSn3 intermetallics in Sn-3Ag-0.5Cu-0.5Ce solders induced compressive stress and extruded the tin atoms out of the specimen in the form of tin whiskers (Chuang, 2007). However, further investigation showed that Sn-9Zn-0.5Ce solders, after long term exposure at room temperature and 150?, were immune to the whisker growth; the immunity was attributed to the refining of the CeSn3 intermetallic phase in the alloy (Chuang & Lin, 2008). The inhibition of tin whiskers through the refining of rare earth containing intermetallics was further observed in Sn-3Ag- 0.5Cu-0.5Ce solders doped with 0.5 wt. Zn (Chuang & Lin, 2009). In addition to the size effect, the thin plate shape of intermetallic compounds was also shown in this study to inhibit the whisker growth on the surface of Sn-58Bi-0.5La solders."

Jan 1, 2012

By J. L. Nebreda, Z. Fan, J. B. Patel

"A380 alloy has been widely employed to produce thin-wall components via high pressure die casting (HPDC). During HPDC processing, there is a significant problem of property variation even with the very stable and precision automated casting procedure. The enlarged variation lowers the component performance and affects the steady and uniform property distribution along the whole component. In this study, high shear melt conditioning technology was developed and applied to the melt prior to pouring into the shot sleeve. Experimental results show that with application of intensive melt shearing, the variation of elongation was decreased from 21.8to 13.9%, and yield strength variation was reduced from5.5to 3.6%. The improved property variation is attributed to enhanced nucleation both in shot sleeve and the die-cavity, and to the improved distribution of porosity and secondary phases as a benefit of high shear induced grain refinement. With application of high shear, large number of the Spinel phase (MgAl2O4) particles with double size distribution in average diameter of 80and 300nm were formed. Due to the good orientation relationship and small misfit between alpha Al and MgAl2O4, the particles act as the effective nuclei in shot sleeve and die cavity, respectively.INTRODUCTIONA380 alloy had been widely used for produce automotive components by cold chamber high pressure die casting(HPDC) processing, due to its relative good mechanical properties and cast ability performance, and more important most of A380 ingots were produced by recycled Al alloys. Therefore, to promote utility of A380 will contribute to reducing emission of CO2and to the lightweight of automotive industry as well. When cold chamber HPDC was employed to produce the components, the mechanical properties of A380 alloy always have a distribution range (named variation herein), or in other words the properties were not stable. The reason was ascribed to the typical solidification characteristics occurred in HPDC processing. During HPDC processing, there are three steps of melt movement. The first step is that the melt was poured into shot sleeve at temperature of about 680°C, in which shot sleeve was preheated by few shots of melt filling, or by heater. During step one, the first solidification of melt was happened in shot sleeve and about 20% solid made of coarse a-Al grains was formed(Li, Xiong, & Guo, 2016).Such kind of grains will retain in the final products and deteriorate the properties variation. The second step is that the melt was forced moving forward slowly by plunger at about 0.2–0.3m/s until the liquid melt front to the inner gate of mold. The third step is that the melt moved very fast to complete the filling of die cavity and refilling the solidification shrinkage by fast movement of plunger about 2–3m/s. The second solidification was occurred in die cavity and fine a-Al grains will be formed by high cooling rate at about 500–1000°C/s. From the solidification point of view, the grain size was dominated by nucleation and growth. When HPDC was employed to produce components, the melt quality becomes the priority factor to control the solidification process as the other casting parameters were kept at the same."

Jan 1, 2018

By Craig H. B. Leitch

"In describing the alteration of porphyry systems, the term ""secondary K-feldspar"" appears to be an oversimplification. A better term would be ""alkali feldspar"" alteration, because in actual fact the replacement feldspars show gradational changes from an albite, which is important in some systems, to an alkali feldspar containing minor orthoclase molecule, to true orthoclase.There are several textural varieties of secondary alkali feldspar present in the porphyry systems studied from British Columbia, Australia and New Zealand. These include, in apparent increasing order of alteration intensity: clear albite (An10); patchwork albite (An5-10); chessboard albite (An0-10); ""irregular albite "" (An0Ab100 to Ab90Or10); untwinned ""anoralbite"" (Ab90Or10 – Ab70Or30); and orthoclase (Ab40Or60 - Or100)·The exploration significance of these varieties of alkali feldspar is that their gradation in composition, from sodic to potassic, may be linked to a corresponding increase in intensity of alteration. Thus, there is a tendency for more sodic alteration feldspars to characterize weak, sub-economic deposits, or the fringe zones of stronger deposits; the more potassic alteration feldspars may provide an exploration vector toward more highly mineralized zones."

Jan 1, 1981