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By T. R. Skerry, H. P. Hudson, T. E. Warren

"ALTHOUGH coal is generally the cheapest fuel on the basis of heating value it has been at a disadvantage in competition with other fuels because means have not been available for efficient •Conversion of its thermal energy to mechanical work. Taking the •railway application •as an example, the cost of Diesel oil is about three times that of its thermal equivalent in coal, but the overall efficiency of a Diesel locomotive is about five times that of a coal-fired steam locomotive. Accordingly, the Canadian railways are replacing all coal-fired steam Locomotives, as they are retired from service, with Diesel units. This conversion in itself represents a major loss to the coal industry because the value of railway fuel is approximately 130 million dollars per year, and there are other applications in the medium power range where oil is displacing coal. There is, therefore, a strong incentive to attempt development of an efficient coal-burning engine.Coal has never been a promising fuel for reciprocating internal combustion engines because of the time required for its combustion in pulverized form . This is not less than one-tenth of a second so that the speed of such an engine would have to be very slow. There are also serious difficulties of a mechanical nature arising from the necessity for intermittent combustion and the use of close-fitting pistons."

Jan 1, 1952

By Ahmad Ghahremaninezhad, Denver H. Cowan

Much of today’s gold is locked within sulphide minerals. These sulphide minerals, including pyrite, need to be subjected to oxidative pre-treatment in order to leach the refractory-gold using traditional methods. Typically autoclaves employing high temperatures between 180?225 ºC, and extremely high pressures between 1,500?3,200 kPa, are used for the oxidative pre-treatment. However, the autoclaves themselves are very expensive, costly to operate and maintain, and produce excess sulphuric acid. This paper studies the atmospheric oxidation of pyrite in ferric sulphate solutions. In general, pyrite oxidation under atmospheric pressure can result in high elemental sulphur production, i.e. less acid generation. Activated carbon has displayed an ability to catalyze the process, achieving reasonable kinetics. The reaction kinetics were investigated by altering acidity of the leaching solution, temperature, catalyst ratio, sparged oxygen and agitation. A combination of X-ray diffraction, scanning electron microscopy, optical microscopy, X-ray fluorescence, inductively coupled plasma mass spectrometry (ICP-MS), and atomic absorption spectroscopy (AAS) were used to monitor the kinetics of the process and elemental sulphur yield. The purpose of this investigation was to determine optimal operating conditions that maximized kinetics of the atmospheric oxidation while maximizing elemental sulphur yield.

Jan 1, 2015

By R. W. Nice

Presently about 60% of the world's nickel resources are tied up with lateritic ores while about 25% of the world's nickel is produced from sulphides. Based on this the industry has to focus on improving lateritic nickel economics in order to maintain the high use of the metal worldwide. In 1997 three junior mining companies in Australia organised finance against all odds and commenced development of three separate nickel and cobalt extraction plants treating lateritic nickel ores. All three projects utilise similar pressure acid leaching (PAL) technologies while each has unique metal recovery technologies All projects have experienced numerous processing and maintenance related difficulties such that full ore throughput has been reached by only one operation after five years. This shortfall in performance has caused the owners considerable angst and financial pain. In 2000 Cawse went into receivership and was purchased by an international corporation. Recently, Bulong also went into receivership and has undergone an orderly shutdown, awaiting sale to a new buyer. Murrin Murrin has settled with its financiers and is in a position to operate as planned for many years forward. This paper will discuss a number of the technical difficulties that affect the ore preparation, PAL and solution treatment circuits of these plants. The objective is to identify the cause of some of the difficulties and propose possible solutions so that the next generation of lateritic operations can emerge as technically and, more importantly, economic successes. A number of these process improvements have been identified by the existing operators and in many instances have been or are being implemented into the existing operations.

Jan 1, 2004

By C. Cekerevac

The paper addresses some geotechnical issues related to the construction of the Deriner dam and HEPP. Design considerations and rock stabilization measures are presented for the excavations which took place in a highly fractured and weathered rock mass prevailing on site. Particularly, the shallow excavations for the overflow spillways tunnels are discussed. These present huge openings that are 12 m wide and 18 m high in portal areas, with an overburden of approximately 20 m, for which numerical finite element analysis and structural discontinuity analysis have been performed to ensure safe excavation process and future operation.

May 1, 2009

By G. Kachaniwsky, M. Bédard

"The Noranda Continuous Smelting Process at the Home smelter was commissioned in March 1973. The ability of the process to handle a wide variety of feed materials and a steady stream of technical innovations in recent decades has served to maintain the Home as an efficient and versatile custom smelter. This paper reviews recent technological development and capabilities in areas such as sampling and preparation of secondary and complex materials, as well as the smelting and related environmental control issues. Future trends and improvements are also addressed.IntroductionThe Noranda Home smelter commenced operations in 1927. It was originally designed to treat 910 tonnes per day of copper concentrates and ores coming from the new Home mine site. In the 19305, the company opened its doors to other mines in northwestern Quebec. Treatment of feed materials on a custom basis has, therefore, always been an important factor in the operation of the Home smelter. Throughout the years, the Home gradually increased its custom smelting capacity, while maintaining its production from the Home mine. By the early 1950s, 65% of the materials processed was from outside customers, and by 1974, this figure had increased to more than 85% . With the closure of the Home mine in 1976, the company extended its smelting operations beyond ore and concentrate, and began to treat more scrap metals and residues rich in copper and precious metal content.Corresponding with the ever-changing pattern of feed sources, the Home smelter has adopted technological improvements to meet new and challenging business conditions. The technology of the original smelter of 1927has been completely replaced over the years in the quest for improvement. One of these major changes occurred in 1973 with the start-up of the Noranda Process Reactor. This extremely efficient smelting system has been exploited to treat a wide variety of copper and precious metal (PM) containing custom materials. This paper reviews recent developments and improvements achieved at the Home smelter, in the receiving, sampling and treatments of copper and PM scrap and secondaries, with particular emphasis on the development of new technology and equipment in complex feed materials treatment."

Jan 1, 1991

By E. E. N. Smith

"Uranium exploration by Eldorado prospectors north of Lake Athabasca began in late 1944 and resulted in initial discoveries in 1946 in the Beaverlodge region with mill production starting in early 1953. The operation was closed in mid-1982 having produced 21,457,947 kilograms U30 8 from the Eldorado FayVerna mine, Eldorado satellite operations and from other district producers on a custom basis.The Fay- Verna mine consists of pitchblende-brannerite orebodies spatially associated with both sides of a regional eastwest structure, the St. Louis Fault. The orebodies in the footwall (Fay) are elongate deposits of two types raking steeply to the southwest along the 50 degree south dip of the fault.One type consists of networks of fractures and veins filled with pitchblende, calcite and quartz in chlorite, epidote-altered mylonitized mica schists and amphibolites of the Middle Aphebian Tazin Group. The other type is comprised of fragments of mylonitized metasomatic quartz-feldspar granite of Late Middle Aphebian age cemented with a matrix of pitchblende, brannerite, calcite and some quartz. The vein networks lie en echelon in the footwall of the breccia ore bodies which, in part, are capped by the mud gouge of the St. Louis Fault; in other places, the breccia orebodies are overlain by basal conglomerates, grits and arkoses of the late Aphebian Martin Formation which itself immediately underlies the plane of the fault.Orebodies in the hanging wall (Verna) are a series of irregular, tabular deposits lying within a tightly overturned syncline of Tazin mica schists, amphibolites and siliceous mylonites. They consist of pitchblende, calcite-filled fractures grouped into zones and deposits displaying stratabound habits within individual rock types.Also described are several Eldorado satellite properties which were significant producers of uranium and which display complementary geology to that in the Fay- Verna mine.In general, uranium deposits in the Eldorado Beaverlodge region are closely related to minor structures associated with major faults. Uranium appears to be best concentrated where the rocks are well mylonitized and brecciated. Pitchblende fills networks of veins and fractures in metasediments and metavolcanics as well as matrix material cementing brecciated, mylonitized granite. All deposits in the Beaverlodge region lie in close proximity to the unconformity between the Martin Formation and the underlying Tazin Group."

Jan 1, 1986

By Robert A. Bosschart, Harold O. Seigel

"Most electromagnetic methods presently used in mining exploration are of the moving source type; i.e., the primary field source is moved simultaneously and in a fixed configuration with the receiver. Of the fixed-source methods, which employ a stationary primary field and a moving receiver, the Turam method is the most effective and has marked advantages over alternative electromagnetic methods. The results are little affected by topographic relief, and a high degree of resolution can be obtained because of the constant relation between source field and investigation area. Another inherent advantage of the Turam configuration is that it provides more favourable dimensional relations. Thus, the primary field attenuates at a much lower rate than in moving-source configurations and, secondly, the method is size sensitive; i.e., conductor size affects the strength of the response, which is not the case with moving-source methods. These factors result in a considerably better potential depth penetration."

Jan 1, 1966

By N. Manopulo, J. Maier, L. Tong, C. Becker, P. Hora

The contribution presents a new finite element approach in which the common updated Lagrangian formulation is replaced by a spatial flow formulation applying a special arbitrary Lagrangian-Eulerian for-mulation (ALE). The description separates spatially the process in a die inside zone and in a profile zone. For the description of the inside zone, where the filling process occurs, a special Euler time independent mesh is applied. By this formulation the mesh has to be generated only once, which simplifies the generation of spatially optimized meshes. For mapping of the material flow during the filling process the method uses a flow surface traction method as applied in casting simulations. A further strength of the new method is the computational efficiency which allows the modelling of extrusion process with the highest complexity with a response time of 12 hours, which is important for the industrial optimization process.

Jan 1, 2015

By Garnet T. Page

"ABSTRACTThese societies •can help in such aspects of a vocation.al guidance program in secondary schools as: provide vocational and technical information, and assist with vocational exploration, such .as plant visits, films, etc. -as .an aid to the student in making a self-inventory. Evidence is increasing that employers' needs for engineers and scientists will not be adequately met in the future. Therefore, the E.I.C., C.I.M., .and C.I:C. recently revised and extended the activities of the Canadian Counselling Committee on Engineering and Science. This co-•operative .action is to be integrated with the educational system, nationally .and locally, and with provincial associations •of engineers and other groups interested in the provision of vocational information in engineering and science.DEFINITIONTHE scientific treatment of any subject requires consistent use of carefully defined terms. The National Vocational Guidance Association of the United States studied the problem of the definition of vocational guidance for .about 16 years, and in 1937 finally arrived at:""Vocational guidance is the pro-cess of assisting the individual to choose an occupation, prepare for it, enter upon and progress in it. It is concerned primarily with helping individuals make decisions and choices involved in planning a future and building a career -decisions and choices necessary in effecting satisfactory vocational adjustment.""RANGEAs a school enterprise, vocational guidance begins at that point in the individual's life when he finds it necessary to make choices that have a definite significance for his future vocation."

Jan 1, 1952

By A. Blackmore, D. Baker, L. Human

"Mechanical mixing equipment is common in a wide variety of mining, metals and process applications, such as hydrometallurgical reactors, solvent extraction, digestors, and tanks for storage of slurry or hydrocarbons. Computational Fluid Dynamics (CFD) has been applied successfully to single-phase mechanical mixing problems for several decades and is established as a reliable design tool. As computational power and CFD codes have improved over the years, there have been significant advances in modelling capabilities including improved models of turbulence, interaction of rotating and stationary components, multiphase flows, and modelling of free surface interfaces, for example. This paper will provide an overview of the application of CFD to mechanical mixing problems. First, it will review the traditional single phase Multiple Reference Frame (MRF) approach and introduce a range of advanced modelling techniques. Three examples of the application of CFD to industrial mixing problems will be given. It will be demonstrated that CFD is an effective tool for reducing technical risk in design, for identifying the root-cause of mixing problems, and testing modifications to existing operations."

Jan 1, 2015

By A-A. Bogno, M. Rappaz, J. Valloton, H. Henein

"Rapid solidification of Al-Cu droplets of eutectic composition was carried out using Impulse Atomization in an argon atmosphere, to study the microstructures forming at different cooling rates and undercoolings. Two distinct morphologies were observed within the investigated Al-33wt%Cu droplets microstructures: (i) A regular lamellar morphology and (ii) an undulated morphology. The volume fraction of each type of morphology was measured as a function of the droplet size and the nucleation undercooling was deduced using the hypercooling limit equation. The scale of the microstructures was determined through measurements of inter-lamellar spacing across and along the growth direction. Growth velocity and undercooling were deduced using Jackson and Hunt (1966) eutectic growth theory. Finally, mechanical properties were estimated through micro-hardness analysis using a Vickers hardness tester, revealing exceptional properties for an aluminum-copper alloy. Indeed, the hardness values, increasing with growth rate and undercooling, were 3 times higher than the values obtained in hypo-eutectic Al-Cu alloys.INTRODUCTION Eutectic alloys are very attractive due to their good fluidity allowing ready shaping of parts in casting processes as well as in thermal spray deposition. In addition, they yield microstructures with high mechanical properties, by the virtue of their scale/size which is defined by the solidification parameters and the thermodynamic and thermophysical properties of the given alloy. Therefore, it is important to understand the relationship between the microstructures and the solidification parameters of eutectic alloys in order to control their solidification path and mechanical properties. The latter could be improved by either adding an appropriate strengthening component to a base eutectic material (Böyük, MaraslI, Kaya, ÇadIrlI, & Keslioglu, 2009) or by refining the microstructures for more effective dislocation pinning (Campbell & Campbell, 2003). Tailoring the microstructure can also be beneficial to chemical (Freitas, Osório, Spinelli, & Garcia, 2014; Osório, Freire, Caram, & Garcia, 2012) or electrical (Kaya, 2012) properties of the material. Eutectic-type microstructures, usually formed from liquid (eutectic transformation) or solid (eutectoid transformation), are made up of two or more different phases, generally of lamellar or fibrous (rod like) morphologies (Kurz & Fisher, 1998). In general, a binary eutectic structure can be regular (when both phases are non-faceted) or irregular (one of the two phases is faceted), the two solid phases having roughly the composition of the liquid from which they are formed."

Jan 1, 2017

By Bryan Tisch

Goal of GMGE ??To advance mine reclamation through the beneficial use of organic residuals for the sustainable establishment of bioenergy crops and other productive land uses Objectives ??To advance the current ?standard? of mine reclamation by demonstrating that mining lands can safely become agriculturally ?productive? through the use of organic residuals. ??To generate and compile sound scientific data that can be utilized by stakeholders to better assess the environmental impacts of utilizing these materials. ??To complete a manual of best practices regarding the utilization of organic residuals on mine lands. *Considerable effort to be placed on operations/implementation side of utilizing residuals ?rather than just pure research

May 1, 2011

By H. A. Kee

In the mining industry, as in other business, one of the more satisfactory results of sincere but cheerful effort lies in the proper completion of undertakings and problems, which, to be successful, must continually hold the interest of all concerned in the work. In most undertakings, genuine interest and satisfaction is largely dependent on the proper appraisal of opportunities presented, and the opportunity to associate ourselves with sinking operations at McIntyre central shaft, from the surface to a depth of 4,133 feet, was genuinely appreciated. This opportunity was made possible by the previous persistent and successful leadership of Mr. J. P. Bickell, President, with the assistance of his associates, and of the general manager, Mr. R.J. Ennis, in the development of the McIntyre Porcupine mine, and I beg to state that any success in this sinking operation was very largely due to the congenial co-operation and splendid workmanship of Captain Martin C. Horne, his shift bosses, leaders, and all those who worked with us . Our slogan throughout was " Safety First for Pleasant and Efficient Workmanship," and this general policy made it possible to sink and timber 2.,123 feet during the first year without a serious accident.

Jan 1, 1928

By A. Navarra, C. Arrancibia, R. Yañez, C. Acuña, F. Valenzuela

"Discrete event simulation (DES) is a suitable framework to evaluate and optimize the dynamics of sulphide smelters. In particular, iron-nickel-copper-cobalt sulphides undergo continual oxidation within a roasting or smelting operation, followed by batch oxidation within the converting operation, thus producing iron-free Bessemer matte (or blister copper, in the case of copper smelters); this semi-finished product undergoes further processing to produce nickel, copper and cobalt products, and to recover precious metals. The juncture between continuous smelting and batch converting is often an appropriate focus for the earliest phases of DES development, since it is typically a major bottleneck within nickel and copper smelters; later phases may include increasing levels of detail for auxiliary unit operations, as well as plant logistics. Moreover, DES can support matte-slag chemistry, including Gibbs free energy balances to determine the iron speciation within the slag. DES is therefore capable of linking the fundamentals of oxidation reactions to the intricacies of plant dynamics.INTRODUCTION Discrete event simulation (DES) is gaining acceptance within the extractive metallurgy community, as a technique that quantifies the system-wide performance of metallurgical plants under conditions of uncertainty (Wheeler & McGinty, 2015). In particular, over 90% of smelters that process nickel-copper-cobalt sulphides and copper sulphides exhibit similar semi-continuous dynamics (Crundwell et al., 2011b; Schlesinger et al., 2011b), in which the converting aisle produces batches of material that are sent for further processing (Figure 1). Thus the tools and practices that are developed for a specific sulphide smelter are often relevant to numerous other smelters.The juncture between continuous smelting and batch converting has long been a focus for discrete event simulation (Welgama et al., 1996). Nonetheless, the broad acceptance of DES in nonferrous smelters has been hindered by interdisciplinary barriers that divide industrial and metallurgical engineers (Navarra et al., 2016; Noorossana et al., 2012); this divide has been less severe in steel plants (Hollocks, 2006). In recent years, DES has been used in copper smelters to analyze crane-and-ladle motions (Coursol et al., 2009a), reverts production and consumption (Noorossana et al., 2012), and innovative control systems (Herrera et al., 2016); additionally, DES models have accounted for shutdowns and random breakdowns to provide realistic assessments of copper smelter capacities, thus guiding equipment upgrades (Campbell et al., 2013; Coursol et al., 2009a). All of these studies feature a Peirce-Smith converting aisle similar to Figure 1 that, under normal operations, constrain the smelter throughput, and are thus a bottleneck (Campbell et al., 2013; Navarra et al., 2016)."

Jan 1, 2017

By George Carico

Research and related demonstration projects are being conducted in West Virginia on both existing and former coal surface mine lands to determine potential post-mine land re-use options that offer the greatest likelihood of future benefit and success. Examples of projects include renewable energy considerations that incorporate solar, wind, and/or biomass options, and contain components designed to educate business, government entities and the local community on renewable energy options and potential opportunities Multiple property re-use options are being researched and evaluated, based on site-specific conditions and characteristics, including infrastructure, local community needs and regional economic conditions. Re-use options being explored include innovative uses and needs, such as specialty housing, unique business and industrial needs, and an extensive variety of recreational and small business opportunities that best fit the specific needs of the local community and regional economic structure.

Aug 1, 2013

By Zhong Zhang, Xijia Wu, Prakash C. Patnaik

"The integrated vehicle health management (IVHM) aims to provide life cycle management decisions for military platforms and their propulsion systems with reduced life cycle cost and increased operational readiness and safety. Among all the issues of IVHM, understanding the physics of failure and predicting lifetimes of the critical components are at the core: the decision makers have to know when and how components may fail in order to plan ahead. The difficulties to tackle failure problems lie in determining the material response to cyclic and dwell loading in a hot and/or corrosive environment, which all combined to induce multiple deformation and damage mechanisms, resulting in mix-mode failures. Decisions on component replacement (material substitution) and mission planning must be based on quantitative knowledge of the failure physics to mitigating the risk. This paper addresses the critical failure issues including creep, low cycle fatigue (LCF), thermomechanical fatigue (TMF); and presents a mechanism-based approach to life prediction. The mechanism-based approach, by its physics, is widely applicable over the entire operational spectrum of both structures and engines, and therefore is suitable for IVHM purposes."

Jan 1, 2015

By Zhou Yanwen, Fudong Wang, Shing Liu

Mixed CrB2 and MoS2 powder (Cr:Mo=1:1 atomic %), without any further process, were used as the targets to be sputtered and deposited onto stainless steel and silicon substrates by pulsed DC power supply. The structures and properties of the CrBMoS films were then analyzed by using SEM, XRD, micro-hardness tester. The SEM morphology of the films showed dense, defect free structure, and the preferred orientations of the films were CrB2 (111) and MoS2 (200) according to XRD spectra. The thicknesses of the films were measured and the relationship between the deposition rates and pulsed factors was determined. The films, with the micro-hardness as high as 19GPa and friction coefficient as low as 0.02, could be considered to be the hard solid lubricant films.

Jan 1, 2015

By S. McPherson, M. Chalkley, R. Ellenwood, W. Nicot

"The Moa JV was formed in December 1994 as a 50/50 joint venture between Sherritt Inc. and General Nickel Company S.A. of Cuba. The joint venture consists of the mine and Pedro Sotto Alba processing plant in Moa, Cuba and the Corefco refinery in Fort Saskatchewan, Alberta, Canada. Throughout its now nearly 23-year history, the Moa Joint Venture has faced a number of global, operational and process challenges. Global challenges have included high input costs such as for fuel oil and sulphur, as well as low nickel prices. Operational and process challenges have included increasing ore haulage distances, decreasing ore Ni + Co grades, and increasing ore impurity contents. For example, increases in impurities such as Mg and SiO2 in the ore result in increasing acid demand in leaching and decreasing solids content of preheated leach feed slurry, respectively. In spite of these challenges, the mixed sulphide production capacity from the Moa Joint Venture has increased from 12,500 to 37,000 t/y Ni + Co since 1994 by judiciously targeting expansion projects and by continuously performing process and operational improvements.INTRODUCTION The Pedro Sotto Alba high pressure acid leach (HPAL) plant at Moa Bay, Cuba has a long history (Maslenitzkiy, 1969; Chalkley, 1996; Carlson, 1960; Roy, 1961; Carlson 1961). The plant was constructed by Moa Bay Mining Company and started up in late 1959 after several years of process development by Freeport Nickel Company, including operation of a 10 t/d plant in Hoskins Mound, Texas and a 50 t/d plant in Port Nickel, Louisiana (Southwick, 2004), as well as development work by Chemical Construction Company (Chemico) to precipitate metal sulphides (Roy, 1955a; Roy, 1955b). The Moa plant had an original reserve of 50,000,000 t of ore, graded at 1.35 wt% Ni, 0.146 wt% Co, 3.70 wt% Si, 1.00 wt% Mg and 4.5 wt% Al. At original design rates of 2,000 kt/y of ore, the design capacity of the plant was around 25,000 t/y Ni + Co as a mixed sulphide product, which would be shipped to the Port Nickel Refinery in Louisiana for processing. In 1960, the plant changed ownership and was restarted in 1961 under Cuban management. Between 1961 and 1989, the plant was also supported by involvement from the former USSR, supplying spare parts and consumables. In 1994, Sherritt Inc. partnered with the General Nickel Co. S.A. of Cuba and formed the Moa Joint Venture. This joint venture includes the mine and Pedro Sotto Alba HPAL processing plant in Cuba and the Corefco refinery in Fort Saskatchewan, Alberta, Canada. Under this partnership, ore is processed in Cuba to produce a nominally 55 wt% Ni and 5 wt% Co mixed sulphide product that is shipped to Canada and processed by Corefco to produce class 1 nickel, high grade cobalt and byproduct ammonium sulphate fertilizer."

Jan 1, 2017

By Marlin E. Sandlin

NORTH-CENTRAL United States is now, and will continue to be, a natural market for Canadian crude oil. This area is a natural market for many basic reasons. There are no physical barriers along the border of our countries. This market is in dose proximity to Canadian production. This market is already joined by crude oil pipe-1,ines to numerous producing areas of Canada. The tariff barriers are reasonable. We are not handicapped by mandatory quota restrictions. There are many of us who desire lo sell Canadian crude oil in this market. Further, and what is really important, there are many of us who desire to buy Canadian crude oil for this market. It is fundamental that for crude oil to be sold in the world market, it must ?be sold at competitive prices. At the same time, it is important that such competitive price must result in a fair price for the crude oil at the we1lhead. The factors of nearness to market, cheap pipe line transportation, and reasonable United States tariffs, all tend to make ?possible a competitive market and a fair wellhead price.

Jan 1, 1958

By R. A. Mantz, V. N. Balbyshev, A. N. Khramov, N. N. Voevodin

Corrosion protection properties of the hybrid organo-silicate coatings on aluminum substrate can be significantly improved by means of encapsulation of organic corrosion inhibitors within the coating material. In order to achieve sustained release of corrosion inhibitor and long-term corrosion protection, a secondary chemical equilibrium of either ion-exchange interaction with the coating matrix or cyclodextrin-assisted molecular encapsulation of the inhibitor has been employed. Several organic corrosion inhibitors, such as mercaptobenzothiazole, mercaptobenzimidazole, mercaptobenzimi¬dazolesulfonate, and thiosalicylic acid have been examined by a group of electrochemical methods including potentiodynamic scan, electrochemical impedance spectroscopy, and scanning vibrating electrode technique. It has been found that the formulations that contain ß-cyclodextrin demonstrate superior corrosion protection capabilities as the complexation equilibrium results in a continuing delivery of inhibitor to corrosion sites. The approach is considered a promising way for active corrosion protection of high-strength aluminum alloys when integrity of barrier coating is compromised.

Jan 1, 2004