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By László Guczi1

Nanosize model gold particles with varying size were fabricated by deposition of a 10 nm thick gold film onto SiO2/Si(100) substrate by electron beam evaporation followed by modification using low energy Ar+ ion bombardment. The change in particle size were monitored by the Au 5d valence band states determined by ultraviolet photoelectron spectroscopy (UPS). The gold/iron oxide interface was studied by iron oxide deposition on gold. It was found that the energy profile of Au 5d valence band states are strongly redistributed with decreasing the gold particle size mostly affecting at the lowest and at the highest binding energies. The size effect in the UPS spectra can be interpreted by the energy redistribution rather, than by narrowing the 5d states. The iron oxide deposition increases the catalytic activity in CO oxidation whether it is on gold nanoparticles or on a continuous 80 nm thick gold film. The activity enhancement is significantly larger in case of gold nanoparticles. The interface interaction is operative in enlargement of the catalytic activity even if gold particles are not exposed to the surface, but they are located below the iron oxide layer.

Oct 1, 2003

By Ralph L. Rutherford

Introduction During the past twenty-five years we have seen considerable exploration for oil on the plains of southern and east-central Alberta. This exploration has to some extent gone on in cycles, with periodic starts, stops, and occasionally some reversals. Each major attempt is usually supplemented by the application of some new method of exploration and, following each period of exploration, drilling tests are made. Whereas oil-bearing horizons are the ultimate objective of these explorations, the preliminary investigation frequently aims at a discovery of structure based on the long accepted belief that accumulations of oil and gas are to a marked degree structurally controlled. At the inception of this general exploration for oil, it was natural that attention should be directed to areas where there was surface evidence of deformation of the underlying strata, but, as the programme progressed, it was found that these surface manifestations of structure were often deceptive when attempts were made to project them to depth, to involve the deeper strata. Drilling of test wells was the only satisfactory method of obtaining exact information.

Jan 1, 1946

By B. Dyck, C. Rodgers

ABSTRACT Cameco Corporation is revitalizing its Key Lake Operation uranium mill in northern Saskatchewan. The mill currently uses ammonia stripping in solvent extraction (SX) and ammonia yellowcake precipitation. As part of the revitalization, the company considered installing strong acid stripping in solvent extraction (used at its Rabbit Lake Operation), which would lead to using hydrogen peroxide for uranium precipitation. As part of the process evaluation, tests were carried out to study how the drying temperature in indirect fired dryers would affect the uranium peroxide yellowcake precipitate properties. This paper discusses the test work results, including the relationships between drying temperature and product reactivity with water, product colour, product grade, and energy input requirements.

Jan 1, 2012

By S. Gregory

Many gold treatment plants have sulphides and coarse particle gangue components that contain gold in their tailings (cyanide leach residues and flotation tailings). Coarse and very fine liberated gold may also be present in some tailings streams. Two issues usually govern the economics of recovering additional gold from gold occluded in sulphide and gangue particles. The liberation characteristics of the gold in the sulphide and coarse gangue (gold liberation versus grind size) is the first and most important of the two. If fine grinding can liberate a reasonable amount of the gold, then the next important issue is how effectively these two constituents can be concentrated. Flotation will achieve high sulphide recovery but is usually costly. Selectivity is also an issue because of entrainment. Continuous centrifugal gravity concentration offers a viable solution to the recovery of both sulphides and coarse gangue however selectivity is also likely to be a problem. The possibility of improving concentrate grade by using a Falcon B separator was investigated. This paper describes a program of test work carried out on a gold leach tailings using a laboratory Falcon '13' separator. The program involved three different bowl angles: 10, 12 and 14 degrees and two bowl speeds (giving 250 and 350G accelerations). A number of tests were also performed on samples that had free gold present to ascertain the size-by-size recovery of gold in these samples.

Jan 1, 2005

By J. Y. Kim, Kenneth Stowe, Stephen Chryssoulis

"A series of flotation tests was carried out on Brunswick Mining ore with various pH modifiers (soda ash, lime, KOH) and added ions (ferric, nitrate, sulphate) in the copper lead rougher circuit. The main objective was to identify downstream effects on sphalerite activation and subsequent zinc rougher flotation. Some significant differences in zinc flotation were obtained. Most notably, soda ash and nitrate ions had a positive impact and ferric ions a pronounced negative effect on selectivity.Selected products from the flotation tests were deslimed at 400 mesh, washed with methanol, air dried, placed in teflon vials purged with nitrogen and stored at -15 degrees C. Numerous liberated sphalerite and pyrite particles were selected under a stereoscope and placed in rows on indium foil. The surface compositions of the particles were analyzed with an innovative laser probe (LIMS). The very small analysis area of the LIMS enables the surfaces of individual grains to be characterized. In addition, the rapid analysis time allows a statistically significant number of grains to be analyzed quickly.Surface lead appears to play a major role in zinc activation/flotation. Possible mechanisms are proposed to explain the variations in metallurgical performance at the different test conditions.IntroductionAlthough the bulk composition of mineral grains is an important consideration for the mineral processor it is ultimately surface composition and topography (edges and dislocations preferred sites for reactions) that control reactivity in flotation and cyanidation (passivation, encapsulation and preg-robbing). Determination of the surface properties of particles from process streams poses a particular challenge for the surface chemist for a variety of reasons, including:"

Jan 1, 1994

By T. Scully

Since early days in coal mining, it has been known that some coals and the carbonaceous materials associated with them will heat and fire spontaneously. Many theories have been advanced to account for this phenomenon, but it is only within comparatively recent years that any scientific research has been carried out to determine the causes of this heating, the conditions which bring about its occurrence, and the reason why different coals heat with a varying degree of readiness. So far, this research has not cleared up these points entirely, but a great advance has been made in our knowledge of the matter. In general, any coal will fire spontaneously, although with a varying degree of readiness, provided conditions for its doing so are favourable enough. These conditions are that the coal must be in a fine state of division, that sufficient oxygen must be present for rapid oxidation, and that the air current passing must be so small that it is insufficient to carry off the heat produced by this oxidation. Many other minor factors, however, contribute to bring about spontaneous heating, either by producing initial heat themselves or by inducing the other major conditions.

Jan 1, 1931

By E. G. Baltuch

Natural Ventilation in mining and metallurgical processing applications is key to proper operation function. There are number of ventilator designs available to a project team or design engineers, the selection of which will affect both the type of building structure required, project costs and design performance which is difficult to rectify or re-engineer once implemented. Research and applied results, such as that performed by Air-Therm Inc., demonstrates that computational fluid dynamic simulation allows for 5 dimensional observation, analysis and optimization at significantly lowered cost than previously possible. These results have been fully implemented on a number of mining and metallurgical applications and the company continues to study, optimize and innovate as new tools become available to provide the best possible engineered solutions for particular applications.

Aug 1, 2013

By W. R. Bacon

"MAGNETITE HAS BEEN found in many .parts of the coastal area of British Columbia, but the more important deposits are on Vancouver Island and Texada Island. The locations of these deposits are shown on Figure 1.Interest in the magnetite deposits dates back to the 1870s, when land was acquired on the southwest coast of Texada Island by the Puget Sound Iron Company. This ground included the Prescott, Paxton, and Lake deposits. During the years 1885 to 1903, and 1908, 28,898 tons of magnetite ore was shipped to the company's blast-furnace plant at Irondale, Washington, U.S.A. This production was almost entirely from the Prescott open-pits.In the years following the Texada Island discoveries, other magnetite deposits were found in the coastal area, and various plans were proposed to utilize the local ores in the establishment of a steel industry in the Pacific Northwest. None was carried to fruition but, in 1951, open-pit mining was begun at Iron Hill, Vancouver Island, to furnish iron concentrates for steel mills in Japan. In 1952 mining of the Texada deposits was resumed to supply the same market. Production figures for these recent operations are as follows:"

Jan 1, 1949

By W. Lodge, G. Rasmussen

"The carbon-in-pulp (CIP) process has been the dominant gold recovery technology since the 1980s. During all this time carbon measurement, and control of the carbon transfer pumps has been largely manual in nature. Such manual operation inevitably limits process efficiency, potentially resulting in higher gold solution losses, and higher cost of circuit operation. Based on the authors’ experience, average plant solution loss is in the range of 0.02-0.03 ppm Au, as opposed to the general industry target of 0.01 ppm Au or less. Gekko Systems, in conjunction with Curtin University’s Gold Technology Group, has developed a carbon concentration meter, the ‘Carbon Scout’ meter. The meter automatically measures carbon concentration in all tanks, providing more frequent and more precise data. Combined with SIMCIL, a CIP circuit process model which is used to determine the optimum set points for the circuit, the meter should ensure lower gold solution losses, and more efficient operation of the carbon circuit. This paper will review they critical factors for good carbon management, the development of the meter and results from the first plant installation. Additional benefits of the Carbon Scout, including improved health and safety and the opportunity to measure other key variables in the leach/adsorption circuit from one central location will also be described.INTRODUCTION The carbon-in-pulp (CIP) process was first introduced to the gold industry in the early 1950s at the Carlton Mill in the USA (Fast, 1988), with the modern version of CIP becoming fully developed with large scale installations in South Africa in the late 1970s (Laxen, 1982). CIP quickly became the technology of choice for new operations, and for the retrofitting or upgrading of existing operations. In the 1980s the carbon-in-leach (CIL) circuit configuration became the process design of choice due mainly to its lower capital costs. With 40 years of operational experience, CIP/CIL for gold recovery is now mature a technology, whose operations and limitations are well understood. To extract further efficiencies from such technologies, by improving recoveries and/or reducing operating costs, is challenging and may require new approaches to circuit management. Gekko Systems, in association with the Gold Technology Group at Curtin University, has developed the Carbon Scout, an automated carbon measurement device. This device replaces manual measurement of carbon concentration in carbon adsorption tanks, providing more frequent and more accurate data for control of the CIP process. Data from the Carbon Scout can be used to automatically control the carbon forwarding pumps."

Jan 1, 2018

By L. Mercier, R. Narendrula, F. Desmarais, L. Amaratunga, A. Aledresse

Thiosulfate is recognized as a promising alternative lixiviant to cyanide for the extraction of gold from ore bodies. Gold thiosulfate ([Au(S2O3)2]2), however, is not well-adsorbed by activated charcoal, making industrial scale use of thiosulfate for gold leaching impractical at present. Because of their high specific surface areas (500-1000 m2g-1) and uniform open-framework nanoporosity (pore channel diameters in the range 3-10 nm), functionalized mesoporous silicas are widely recognized as highly effective materials for the selective, rapid and high capacity uptake of mercury, gold and platinum group ions. In the present work, the efficient and rapid adsorption of gold thiosulfate by thiol-functionalized mesoporous silica (hereafter designated MP-HMS) is demonstrated, whereby the thiol groups in the materials bind with the gold complexes by ligand displacement. The adsorbed gold could be leached out using cyanide, regenerating the adsorbent for further uptake cycles. Functionalized mesoporous silica is thus a promising candidate for the preconcentration of gold from thiosulfate leachate solutions.

Jan 1, 2011

By Z. Zhao, B. Li

"Fractures are the key channels for fluid flow and mass transport in fractured rocks of low/negligible matrix permeability. In single rock fractures, surface roughness causes fluid flow in tortuous paths, and reduces the overall fracture conductance. A number of empirical models have been proposed to relate the reduced hydraulic aperture to the mechanical aperture due to surface roughness, which were revisited and compared. Using two of those relationships between hydraulic apertures and mechanical apertures, we studied the influences of local surface roughness of fractures on fluid flow and solute transport processes at the macroscopic scales of fracture networks. The results show that fracture roughness can affect the flow rates and residence time to varying extent, mainly depending on the empirical models between hydraulic apertures and mechanical apertures. However, fracture roughness has negligible influences on the general patterns of fluid flow (channeling) and solute migration (e.g., travel paths and shape of breakthrough curves). This is because the connectivity of a fracture network is mainly determined by other geometrical parameters (fracture positions, orientations, and lengths), rather than roughness or apertures. INTRODUCTIONIn fractured crystalline rocks of low or negligible matrix permeability, fluid flow and contaminant migration mainly occur within the connected fractures. An understanding of fluid flow and contaminant migration in fractured rocks is a crucial issue in many deep underground projects, e.g. underground repositories for radioactive waste, CO2 sequestration, enhanced geothermal systems, oil and gas production, etc. Rock fractures are typically rough-walled, and surface roughness appears to have first order control on the mechanical and hydraulic behavior of single rock fractures (Boutt et al., 2006).It is well known that the mechanical aperture of a rock fracture is usually larger than its hydraulic aperture, due to fracture surface roughness (Tsang and Witherspoon, 1983). However, for naturally fractured rocks including numerous discontinuities, the effects of this reduced hydraulic aperture in local fractures on macroscopic fluid flow and solute transport in complex fracture systems still remain unclear. Many previous studies assumed identical hydraulic and mechanical apertures in discrete fracture network models for simplicity (Min et al., 2004; Zhao et al., 2011). Therefore, the main objective of this study is to evaluate the influences of local surface roughness of fractures on fluid flow and solute transport processes at the macroscopic scales of fracture networks, by employing the empirical models that relate the hydraulic aperture to the mechanical aperture."

Jan 1, 2015

By A. S. H. Kabir

Due to the high specific strength and excellent corrosion resistance, Ti-6A1-4V has been widely applied in aerospace industries. In this study, the welding performance of 3.2-mm and 5.1-mm thick Ti¬6A1-4V sheets was studied using a 4 kW continuous wave Nd: YAG laser. It is found that the use of filler wire, matching the parent metal composition, can bridge the joint gap and produce full penetrated welds up to a width of 0.6 mm without cracking. The laser welds were characterized in terms of the bead geometry, defects, microstructures, and hardness. With increasing joint gap, the percent porosity area increased, reaching just over 1% of the fusion zone area at a gap width of 0.6 mm for the 3.2 mm and 5.1 mm thick sheets. The maximum underfill depth in the Ti-6A1-4V laser welds was about 5% or 7% of the sheet thickness for the 3.2-mm and 5.2-mm thick materials, respectively, meeting the AWS D17-1 specification. The microindentation hardness was maximum in the fusion zone and sharply decreased through the heat affected zone until reaching the base metal value.

Jan 1, 2011

By Jae-Chun Lee, Sadia Ilyas

We investigate the technical feasibility of bioleaching of metals from low grade sulphidic ore. Experiments were conducted with an adapted consortium of Sulfobacillus thermosulfidooxidans and Thermoplasm acidophilum in batch bioreactors (1.5 L), small columns (10 kg ore load, 8 % S0 sludge) and large columns (80 kg ore load, 12 % S0 sludge). Approximately 83 % Ni, 85 % Cu, 55 % Fe and 81 % Zn was leached out in batch mode while 93 % Ni, 89 % Zn, 81 % Cu and 65 % Fe was leached out in column reactors. Bioleaching potential improved by acid pre-leaching, adaptation of microbial consortium and periodic bleeding of effluents.

Jan 1, 2014

By G. D. Ruttan

"LYNN LAKE, in northern Manitoba, has become Canada's second nickel-producing area. The discovery by Sherritt Gordon Mines of nickel ore in an entirely new district was the result of systematic prospecting of a belt of volcanics and sediments situated 100 to 150 miles north of the Company's former copper-zinc mine at Sherridon, Manitoba.Prospecting in this area was begun in 1937 and continued each year until 1941, when Austin McVeigh, a company prospector, found a patch of sulphides on a gabbro outcrop near a small lake named Lynn Lake. Samples from this sulphide indicated nickel and copper in significant amount. In 1943, magnetometer work disclosed a number of weak anomalies in low ground near the discovery. In 1945, staking was followed by geophysical surveys and diamond drilling, which continued through 1947. During this period the A, B, E, EL, and Corebodies were located and partly outlined. The discovery of the high-grade ""EL"" orebody in January 1947 was the turning point in the estabishment of the mine. Subsequent development, including additional exploration on surface and under-ground, evolution of a new metallurgical process, financing, erection of a mining and milling plant, hydro-electric power development, building of a rail line from Sherridon (by Canadian National Railways) and a refinery at Fort Saskatchewan, Alberta, culminated in August 1954, when the first shipment of nickel left the refinery. This paper, presented at the 1955 Annual General Meeting of the C.l.M. in Toronto, was one of a symposium covering the whole operation."

Jan 1, 1949

By J. E. Armstrong

"Pinchi Lake and Bralorne Takla mercury mines; Canada's only producing mercury mines during the past war (1939-1945); occur within the Pinchi Lake mercury belt. This belt is in central British Columbia; and is approximately 150 miles long extending from southeast of Fort St. James northwest to the headwaters of Omineca river.During the field season of 1937 cinnabar was discovered by J. G. Gray of the Geological Survey in Permian limestone on the north shore of Pinchi lake, where the main showings of the Pinchi Lake mercury mine were later developed. Following the publication of Gray's report claims were staked in the spring of 1938, and later that year were optioned to the Consolidated Mining and Smelting Company, and in June 1940 a reduction plant with a rated capacity of SO tons a day was brought into operation. In 1943 the plant had a capacity of more than 1,000 tons a day. The grade of ore treated was reported to average S to 10 pounds of mercury a ton, and production during the years 1940 to 1944 exceeded 4,000,000 pounds. The Bralorne Takla mercury mine, which is 90 miles northwest of the Pinchi Lake mercury mine, was brought into production in November 1943 with completion of a 50-ton mill. During the next 10 months more than 100,000 pounds of mercury were recovered, and the grade of the ore was reported to average 15 to 20 pounds of mercury a ton. During the war, production from these two properties was far in excess of Canadian requirements, and Canada was able to supply the United Kingdom and United States with part of their need.s. Both properties ceased operations during 1944, and, due to an excessive supply of mercury, have not yet reopened. The Pinchi Lake mercury belt lies along a northwest-trending major fault zone called the Pinchi fault zone (Fig. 1). This zone is approximately 150 miles long and varies in width from 200 to 1,000 feet . It forms the northeastern edge of a northwest trending fault belt up to 10 miles or more wide in places. In general the northeastern margin of the Pinchi fault zone represents the contact between closely folded, stratified Permian rock:s on the southwest and Mesozoic formations and Omineca intrusions on the northeast. It seems probable that the fault zone marks the site of major thrust faulting from the southwest and that the Permian rocks moved up with respect to the Mesozoic formations. Intense faulting occurs in the Permian rocks within the fault zone. There the more important faults trend north and northwest, dip steeply west and southwest, and may join a major low-angle thrust fault at depth."

Jan 1, 1954

By R. J. Smyth

A Steel Compression Reinforcement Repair Technique (PetroSleevel) system has been developed that has the ability to repair pipeline defects such as stress corrosion cracking (SCC) without requiring welding to the operating pipeline. The Technology has been used to repair active cracking in ERW seam and cracking in the pipe body. All repairs were performed while the pipeline was in operation. This paper will discuss the engineering theory, testing performed to verify the engineering theory, and examples of actual sleeve installations.

Jan 1, 2005

By M. Turek

Cost management in the conditions of increasing competition and unforeseen market turbulence constitutes one of the key areas of the enterprise?s activity. In the last two years the demand for hard coal on the domestic and global market of non-renewable resources has increased significantly. Polish hard coal mining industry, as an industry in the stage of decline, received a chance for rejuvenation. However, one of the most significant conditions of seizing this opportunity is the rationalization of mining costs and improvement of production effectiveness. Due to the significance of this issue, the main objective of the paper is to identify the possibilities of improving the production effectiveness in the hard coal mining industry. In order to meet such an objective, in the first part of the paper we measured effectiveness in the Polish hard coal mines in years 2006- 2011. The research encompassed three out of five mining enterprises operating in the country. Then based on the received results, guidelines concerning the improvement of effectiveness of production were created, taking into consideration infrastructural, technical, economic and organizational determinants. Furthermore, opportunities and threats for improving the production effectiveness, stemming from the external conditions have also been indicated.

Aug 1, 2013

By K. Mayhew, K. Murray

The CESL Copper Process was developed as a hydrometallurgical alternative to smelting and refining for copper sulphide concentrates. As the majority of such concentrates contain appreciable gold and silver values, effective recovery of these metals is essential to the economics of this technology. Unfortunately, conventional cyanide processing cannot be used on the residue from the copper process, clue to its unusual characteristics when compared with naturally occurring gold and silver ores. An abundance of elemental sulphur, as well as the presence of cyanide soluble copper, leads to the formation of both thiocyanate and copper cyanide which is detrimental to process economics clue to excessive cyanide consumption. This, however, can be reduced to acceptable levels by process innovations such as pressure cyanidation and cyanide recovery. This paper outlines the successful application of the CESL Gold Process to various gold-bearing copper concentrates from bench to demonstration scale.

Jan 1, 2011

By P. Mageau-Béland, È. -M. Proulx, M. -C. Patoine

Over the past six decades, Hatch has helped several industrial processing facilities in debottlenecking their operations, allowing them to produce more with the same equipment, to reduce and even eliminate expenditure investments, or to increase the return value of their expansion projects. These successes result from the application of a proven analysis approach that can be applied to any industrial facility. A five-stage methodology is discussed and demonstrated with a specific example of a nickel concentrator optimization study. The first stage is an observation stage which allows to meet key actors at the plant, develop mutual understanding of problems, understand operating philosophy, and efficiently collect large amounts of operating and maintenance data. Following is a data compilation stage during which data is analyzed over a representative time period to identify parameters that significantly affect the production, to evaluate data reliability and to define the focus of the upcoming analysis. Quantitative metrics are defined using statistical tools such as pivot tables, histograms, percentiles and MDR (Maximum demonstrated production rate during 3 to 7 consecutive days). Then, the production bottlenecks are identified by a thorough analysis of the facility’s control philosophy, process throughput, equipment capacity, availability, downtime causes, and interaction between components of each circuit. Understanding the maintenance practices and frequency of planned shutdown is also critical to this analysis. Opportunities for improvement are identified in collaboration with the operation, maintenance and engineering teams, ranked as a function of their impact on the bottlenecks and prioritized. The final and most critical stage involves engagement with the plant stakeholders, namely the operators and the maintenance staff members, to present the results of the analysis and obtain their participation in the implementation of the solutions. The benefits of the case study translated into: 10% production capacity gain, improved maintenance planning and avoidance of several million dollars of investment.

Jan 1, 2016

By Georges Houlachi, Akram Alfantazi, Maysam Mohammadi

Manganese ions in zinc electrowinning electrolytes form a protective MnO2 layer that ultimately decreases Pb contamination in the zinc product. In this study, the effect of dissolved Mn2+ on the electrochemical performance of Pb, Pb-Ca and composite Pb-MnO2 anodes was investigated. The properties of the MnO2 layer formed on these anodes were studied and compared. Potentiodynamic polarization and cyclic voltammetry experiments were performed in 180 g L-1 sulphuric acid to study the electrochemical reactions occurring on the anodes. The anodes were subjected to galvanostatic polarization at 50 mA cm-2. The morphology and uniformity of the MnO2 layer on the anodes were examined using scanning electron microscopy (SEM). Experimental results revealed that the MnO2 layer formed on the composite anode was more compact and uniform compared to that formed on the Pb and Pb-Ca anode. It was also observed that the cell mud formation rate, and consequently manganese ions consumption, depended on the anode type. Although initial formation of the MnO2 layer decreased the oxygen evolution overpotential, its growth might negatively affect electrocatalytic activity of the anodes.

Jan 1, 2014