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By A. V. Tarasov

There are still a number of copper smelters in the world using the roasting and smelting process flow diagram for treating sulphide raw materials. The technical, economic and environmental performance indicators of such operations are inferior to the respective indicators of advanced processes. First of all with respect to copper and sulphur recovery: 95% and 75% as compared with 98% and over 90%, respectively. Based on the studies of the single-stage smelting process to produce white metal and blister copper conducted during recent years an analysis of the feasibility of roastingsmelting technology improvement was carried out in the Gintsvetmet Institute to substantially increase the copper and sulphur recoveries. On the basis of this analysis, it was proposed to modernize the technology and equipment within the framework of the existing process flow-sheet. The proposed modernization implies an increase in the roasting temperature; higher desulphurization degree in the process of roasting; a number of modifications in the roaster design depending on the particular conditions of a given operation; addition of lime flux to the feed charge to roasting; and transition to combined calcium-silicate smelting slags. The metallurgical and energy computations made have indicated that the proposed modifications of the technology will improve the copper and sulphur recovery up to 98% and 90%, respectively. The required capital investments have been estimated using as an example a particular copper smelter, the payback period determined taking into consideration additional output, fuel saving and a reduction in fines for sulphur emissions. For comparison, the capital cost of a smelter modernization is given for change-over to basically new autogenous Ausmelt, Outokumpu and V anyukov smelting technologies.

Jan 1, 2007

By B. F. Giyani, D. Rahal

"Stirred media mills have proved to be more energy-efficient than the conventional ball milling for fine grinding applications. The mill performance is governed by a number of operating variables including mill stirrer speed, feed particle size, solids content and slurry rheology. A study was conducted to assess effects of mill speed, media size and density, and slurry density on the Stress Intensity (SI) in a VXPmill and thereby the relationship to mill performance. For the mill speeds tested, it was found that the optimum tip speed is 7 m/s. If the speed is too high (12 m/s) energy losses result due to mechanical friction losses and heat generation. If the speed is too low (3 m/s), the kinetic energy is not sufficient to promote breakage. The size reduction ratio increases with the increase in mill speed and the decrease in solids content especially in the coarse fraction particle sizes. The effect of slurry rheology on mill performance was shown by assessing the effects of increasing solids concentration and decreasing particle size. Rheological effects seemed to interact with mill speed such that the mill was less energy-efficient at higher solids content and at higher mill speeds particularly for grinding to fine particle sizes. There is an opti"

Jan 1, 2017

By K. Waters, A. Navarra, T. Grammatikopoulos

Strategic decisions to develop a mineral deposit are subject to geological uncertainty, due to the sparsity of drill core samples. The selection of metallurgical equipment is especially critical, since it restricts the processing options that are available to different ore blocks, even as the nature of the deposit is still highly uncertain. Current approaches for long-term mine planning are successful at addressing geological uncertainty, but do not adequately represent alternate modes of operation for the mineral processing plant, nor do they provide sufficient guidance for developing processing options. Nonetheless, recent developments in stochastic optimization and computer data structures have resulted in a framework that can integrate operational modes into strategic mine planning algorithms. A logical next step is to incorporate geometallurgical models that relate mineralogical features to plant performance, as described in this paper.

Jan 1, 2017

By Robert A. Creaser, David R. Lentz

Abstract - The Moss molybdenite deposit, which was mined during both world wars, is hosted in late Grenvillian granitic pegmatite dikes. These dikes are locally aplitic, and intrude the late tectonic Onslow syenite (probably correlative with the ~1090-1070 Ma Kensington suite), which is in turn intrusive into the 1170-1155 Ma Chevreuil intrusive suite of southwestern Quebec. A Re-Os model age of 1053 ± 4 Ma (8.3 ppm Re) was obtained for molybdenite from a pegmatitic veinlet within an aplitic phase of the dike. A much younger Re-Os date of 860.9 ± 9.2 Ma (6.9 ppm Re) obtained previously from a pyrrhotiteand pyrite-rich metasomatic vein might reflect Os diffusion during slow cooling of the Grenville province, because this age is consistent with K-Ar dates reported from the region. Alternatively, the similarity between these younger dates may be fortuitous, and may instead relate to sampling issues for molybdenite. The Mo-rich granitic dikes at the Moss deposit are similar to other Mo-rich A-type pegmatite-aplite granitic dike systems that formed immediately after the peak of the Ottawan orogeny (1070-1090 Ma), and possibly are more closely related to the Kensington suite than previously thought.

Jan 1, 2005

By E. Dernedde

Cell rooms of aluminium smelters have large openings in the sidewalls and in the roof. These openings provide a high ventilation rate, which removes heat and contaminants emitted by the reduction cells and thereby ensures acceptable working conditions inside the cell room. However the large openings make the airflows through the smelter building sensitive to the wind. In this study equations for the airflow through the openings of a smelter building exposed to crosswinds were developed and verified against plant measurements. The equations were then used to estimate the airflows through a two-storeyed smelter building containing VS Soderberg cells. Wind protection by wind-covers over the sidewall openings and by upwind buildings made the airflows through the building less sensitive to the wind. Physical and mathematical modelling showed that working conditions inside the wind-protected cell room would be acceptable for crosswinds at speeds up to 16 km/h. These predictions were confirmed by measurements taken in a VS Soderberg smelter.

Jan 1, 2007

We describe a new method of characterising the effect of dissolved materials on the rate of coalescence of bubbles in aqueous media. Single bubbles were allowed to rise to meet the surface of an aqueous solution, and the time of persistence between arrival and bursting of bubble was measured as a function of solute concentration. A laser beam was placed just above the surface of the liquid, with a detector in the light path, so that any disturbance at the surface could be seen as a break in the beam. The arrival of a bubble at the surface could be detected from the behaviour of the trace on an oscilloscope, and when the bubble broke, another significant change in the signal could easily be seen. The time between disruptions was reported as the persistence time. The effect of a homologous series of n-alcohols (C1 to C8) on the persistence time was measured, in aqueous solution. It was found that with increasing concentration of a particular solute, the persistence time increased up to a point, and then declined. However the magnitude of the persistence time was found to increase with increasing numbers of carbon atoms in the molecule. Bubbles of 1, 2 and 3 mm diameter were used. Persistence time increased with increasing bubble diameter, the maximum values observed being of order 100 secs. For a given solute, the persistence (drainage) time increased with increasing bubble diameter. The concentration Cmax at which the maximum persistence time was observed, was found to be independent of the bubble size. It decreased uniformly as the carbon number increased, and was well correlated by the function y1/2 (dy /dc) -2 I dc)-2 . There was no apparent correlation with the surface excess at maximum persistence time.

Jan 1, 2006

By C. Feng, D. W. M. Arrigan

Arsenic is often associated with gold mining operations and poses a significant health and environmental hazard. While a number of technologies are available for removing arsenic, none of them is effective under all conditions. Although adsorption is a promising approach, most methods focus on the purification of water under neutral or acidic conditions and tend to be less effective in gold mining process waters, operating under alkaline conditions. In this study, the removal of As (III) and As (V) from both arsenic-only solutions and simulated process waters using composite magnetic nanoparticles was investigated. The nanoparticles consisted of magnetite (Fe3O4) or maghemite (?-Fe2O3) cores covered by various metal oxides with Langmuir adsorption capacities of As (III) and As (V) ranging from 31.4 to 79.1 mg/g and 10.2 to 25.5 mg/g, respectively, in arsenic-only solutions at pH 9. Their adsorption capacities were further recognised by the adsorption tests conducted in simulated process waters. The ability to remove As (III) is of particular importance as it is harder to remove it from alkaline solutions. The magnetic cores allow simple and efficient magnetic recovery of the As-loaded nanoparticles.

Jan 1, 2017

By Neville Jordison

Indirect, gravity flow, heat exchangers have become a well established technology in mineral and metallurgical process plants. The technology is a conventional heat exchanger using high efficiency plates, with a free flowing bulk solid on one side of the exchanger and a fluid on the other side. This simple concept leads to many opportunities for achieving greater energy efficiencies in process plants. Indirect heat exchange is much more efficient than direct heat exchange using air such as in a fluid bed or rotary device. When air is used directly, large fans are required, it may also be necessary to chill the air, both high consumers of energy. By contrast, using water as the cooling medium requires only low horsepower pumps, typically only 10% of fan HP. Furthermore there are no stack emissions with the requirement for removal of dust or emissions. Indirect heat exchange also creates the opportunity to recover energy. This can work in two ways: energy can be recovered from a hot bulk solid, to heat pressurized hot water for steam generation or preheat air. Alternatively recovered energy from elsewhere in the plant in the form of hot water, steam, air or thermal oil can be used to preheat a bulk solid.

Jan 1, 2011

By H. M. Woodrooffe

IT IS WELL KNOWN that chrysotile asbestos from various occurrences exhibits varied physical properties and certain differences in chemical corn position, both of which conditions may have an important bearing on the industrial utilization of the fibre. The usefulness of a harsh fibre in the manufacture of asbestos cement products and of low-iron fibre for certain electrical uses are examples. It is also .possible to obtain a fibre with a texture too harsh and brittle to be of economic value. Much research into the structure of the mineral and to a lesser degree observations relating the water of combination to certain physical properties have ?been reported. This paper is an attempt to show that the pyrolysis of ?chrysotile takes place in three stages and that the conditions of pyrolysis are peculiar to the fibre and may afford some clue to the variations in physical properties of asbestos fibres which affect their utilization.

Jan 1, 1956

By A. Mitura

The paper presents the initial investigation of possible energetic applications of chosen wastes from groups: 06, 03, 05 and 01, including coal slimes being secondary product of hard coal processing. These categories of wastes are catalogued according to the polish law, where 06 ? wastes from production, preparation, purchasing and application of products of non-organic chemistry; 03 ? wastes from wood processing and from plates and furniture, celluloid mass, paper and card board production; 13 ? oil wastes and wastes from liquid fuels; 01 ? wastes produced by searching, extracting, physical and chemical processing of ores and other mineral raw materials. The change of combustion heat value was evaluated in produced energetic mixtures containing these types of wastes together with the change of their individual components. All combinations of ingredients were taken into consideration giving 256 various mixtures, from which 36 were selected to investigation. This allowed the performance of statistical factor analysis. For such prepared materials the application of regressive method was proposed in purpose of calculating combustion heat value and then the comparison of empirically determined and theoretically calculated heat values was performed. The change of regressive coefficients can be determined by the nature of Hess law (eq. 1) what was investigated and the attempt of its explication and validation was done.

Aug 1, 2013

By William Petruk, Donald Leroux, Michael Cooper

"Brunswick's primary flotation circuit (CuPb) produces a low grade concentrate containing considerable amounts of undesirable sphalerite and pyrite. To determine the cause of the poor selectivity, a series of Quantitative Mineralogical Analyses (QMA) were performed on several CuPb circuit streams. It was observed that significant fractions of sphalerite and pyrite reporting to the concentrate was liberated, meaning that their depression was not complete. The study highlighted the need for some R&D efforts to be spent in sulphide flotation fundamentals.IntroductionThe viability of many mining projects strongly depends on the performance of their concentrators. More than ever, competitive grade concentrate and high metal recoveries are criteria of paramount economic importance. The selectivity of solid/solid separation processes used in concentrators must be maintained at high levels or continuously improved.Flotation is the solid/solid separation process used by most base metal producers. In spite of its low operating cost, flotation remains a very complex process. To make it selective, precise reagent dosages and electrochemical conditions must be maintained. The difficulty in controlling flotation lies in the numerous heterogeneous reactions that can take place between the different solid, liquid and gaseous phases involved. This complex chemistry makes flotation selectivity difficult to understand and, therefore, to improve from a theoretical point of view.Brunswick Mining and Smelting, near Bathurst N.B., operates a 10500 tpd concentrator which produces four concentrates through five stages of sequential flotation (Figure I). Various reagents are added at key process stages while the ore undergoes different electrochemical conditions. Although the selectivity is important at all stages, the performance of the very first separation, the CuPb circuit, is the most critical. It is here where mineral misplacement to the wrong stream has the greatest economic consequences."

Jan 1, 1996

By H. J. McQueen

Before 1950, hot working was simply deforming above the recrystallization point and gave a soft product compared to cold working. From 1960 onwards, improved testing in compression and torsion (stress, strain rate, temperature, quenching) provided valid specimens for microstructural analysis by polarized optical and transmission electron microscopy (TEM). Indeed, TEM was essential to uncovering the hot working mechanisms because it could distinguish between cold and hot substructures (dynamic recovery) in either initial or new grains (dynamic recrystallization). Over the years, teams at Concordia, McGill and UBC obtained NSERC support for students and equipment. CANMET built up a hot forming group having capabilities from high-rate cam-plastometer compression to rolling of experimental alloy billets; this was combined with latest metallographic instruments for fundamental research. Al alloys of every class (2000, 3000, 5000, 7000, 8000) were studied to understand the effects of solutes, precipitates, dispersoids and composites. The complex flow patterns in extrusion were clarified and modeled by finite element methods. Physical simulations of rolling schedules (up to 20 passes and reductions of 98%) by torsion provided evidence of microstructure development during both the passes and the softening intervals, thus clarifying development of texture in different alloys. The results frequently appeared in proceedings of Light Metals symposia and Canadian Metallurgical Quarterly

Jan 1, 2011

By M. Jarvis, D. B. Dreisinger, T. Hitchins

Mineral carbonation (MC) has been extensively researched all over the world since it was found as a natural exothermic process to permanently and safely sequester CO2. In order to accelerate the natural process, various methods for carbonation of Mg-/Ca-silicate minerals and other industrial wastes have been studied. It has been found that the MC efficiency will increase with an increase of CO2 pressure, retention time, temperature, mass ratio of Mg or Ca to Si in minerals, specific surface area, and the slurry concentration in a specific range, and with the introduction of an effective catalysts, for example, 1M NaCl and 0.64M NaHCO3 or carbonic anhydrase. However, there still is not a successful industrial application because of high economic cost and slow reaction rate. It is not economic to exploit Mg- and Ca-silicate minerals deposits or tailings to sequester CO2 by MC, due to the cost of grinding and heat pre-treatment and in some cases the whole sequestration process may result in more CO2 emissions than the amount of CO2 sequestered, due to the requirements of energy inputs. The process however, may be profitable as a whole (with carbon credits). It is suggested to combine MC with recovery of valuable metals from ore deposits in order to reduce the cost for MC by cost sharing for mineral recovery.

Jan 1, 2017

By L. Voisin, E. Díaz, V. Montenegro, W. Kracht

Grinding media is of great concern in the mining industry mainly because its consumption represents an important part of the costs during mineral processing and consequently, of the total mining business OPEX. In addition, grinding media consumption impacts directly on flotation performance through negative contamination by corrosion, affecting the pulp chemical potential, complicating the understanding and control of the process, as galvanic interactions between mineral species also occur. In addition, during the process there is also a physical consumption of the grinding media through erosion and impact. In both cases, mineralogy has an important role because pulp abrasion power, chemical reactivity, rheology, hardness and other variables depend on the minerals contained in the pulp and their interactions. In the present study, a geometallurgical and phenomenological model, which describes the grinding media consumption and its relationship with mineral hardness expressed by Bond Work Index, was obtained based on advanced mineral characterization techniques such as Hylogger3TM, X-ray diffraction, X-ray fluorescence and experimental grinding tests using a laboratory mill applied on Chilean copper pulps. The results obtained show that pH has an important effect on grinding media consumption, because corrosion varies with hydrogen ions availability. Also, mineral hardness depends on mineralogical composition, but textural analysis must be performed to have a better description of this property. Finally, minerals present in a sample define the grinding media consumption mechanism, because a sample with harder minerals and a greater value of Bond Work index is capable of protecting grinding media from impact wear, while a sample with lower hardness but with a big sulfide minerals content would be more aggressive with grinding media because corrosion is more important in this case. The geometallurgical model obtained is capable to relate the grinding time, mineral hardness, content of sulfide minerals and grinding pH to estimate the grinding media consumption.

Jan 1, 2017

By L. P. Chrismas

"IN 1975, Nova Scotia produced 1.8 million tons of coal with a FOB mine value of $47.6 million. Of this total, about 30 per cent or 600,000 tons was coking coal and the remainder was steam and industrial-grade coal. The Nova Scotia Power Corporation consumed 630,000 tons in three generating stations and 570,000 tons were sold to Sydney Steel for making coke for its steel operations. Exports, principally to Great Britain, comprised 370,000 tons in 1975 in addition to the 300,- 000 tons shipped to other provinces for use by cement and pulp and paper companies. In 1975, just over 100,000 tons of coking coal were imported into the province from Alberta. Before 1975, low-volatile coking coal was traditionally obtained from the United States. In 1975, production came from seven individual mines and one project involving reclamation from mine dumps in Pictou County. Of the seven producers, four are owned by the Cape Breton Development Corporation, a federal Crown corporation; the remaining three are small independent mines, but, even though small, they are sizeable contributors to the economies of their local areas. After 101 years of continuous operation, Devco's Princess mine was closed in 1975. The Nova Scotia coal industry, in terms of value, accounted for about half of total mineral production in 1975. The industry provides jobs for 3,000 men and women. It is also significant that in 1975 Nova Scotia produced about 6.5 per cent of Canada's total coal production of 28.3 million tons. Detailed statistics on Nova Scotia's coal industry appear in the Appendix."

Jan 1, 1976

By M. Abdollahi, M. R. Khalesi, Y. Kianinia, A. Khodadadi Darban

High cyanide consumption during the processing of gold ores with high sulphide minerals can make the typical cyanidation uneconomic. Also cyanide is a toxic material and environmental concerns of cyanide compounds are serious. Optimization of cyanide consumption requires a methodology to estimate the amount of exposed cyanicides, the kinetic of their dissolution and estimation of formation of cyanide complexes which consume the free cyanide. In this paper, a methodology to estimate cyanide consumption by modeling the minerals and gold leaching kinetic based on a liberation model and speciation of all possible cyanide related species in the solution is presented. The results showed that this methodology could successfully estimate the cyanide consumption based on mineralogical data with very lower number of parameters compared to empirical models present in the literature, while it offers the prediction of formation of all cyanide complexes which could be used for optimization purposes.

Jan 1, 2017

By P. Rosario

"Current industry practice for HPGR assessment and sizing relies on conducting a series of tests using pilot-scale machines with roll diameters of 700 mm to 1000 mm. Substantial amounts of sample are required for such pilot test programs, typically 1 to 10 tonnes of the sample is needed depending on the level of study and complexity of the resource. Collection of large quantities of representative samples during the early stage development is challenging and expensive, thus significantly hinders the HPGR technology from being incorporated into early-stage designs. A robust and reliable laboratory test is therefore needed to allow a fair consideration of HPGR for early stage projects. With support from the Canadian Mineral Industry Research Organization (CAMIRO), the NBK Institute of Mining Engineering at the University of British Columbia (UBC) developed a suite of Piston Press bench-scale tests that correlated to pilot and full scale HPGR operating information (Davaanyam, 2015; Davaanyam et al, 2015; McClintock, 2018). The Piston Press Tests (PPTs) are capable of assessing the HPGR technology at the scoping, pre-economic analysis (PEA), and pre-feasibility (PFS) stages of project development. This paper will briefly describe the theory on which the PPTs are based, and then presents a case study conducted for a copper deposit to show how the PPTs are being used for scoping and pre-feasibility level studies. Specifically, the PPTs are being used to provide information for preliminary sizing and selection of an HPGR and to assess the effect of ore variability on HPGR performance. The results are also applied to developing HPGR circuit designs and can be incorporated in simulation so that optimum design parameters can be selected.INTRODUCTION It is widely accepted that high pressure grinding rolls (HPGRs) offer a viable energy-efficient solution for the modern comminution flowsheet design. Table 1 summarizes selected examples of HPGR applications in the hard rock mining industry. The main benefits of HPGRs are energy savings which leads to lower operating costs, and its stable operating characteristics that can better cope with variations in ore hardness when compared to the conventional SAG mill-based comminution circuits."

Jan 1, 2019

By Baseer Abdul, Edouard Asselin

Hydrometallurgical leaching of sulfide concentrates of copper and nickel at medium temperature (150°C) produces residues that contain sulfur and iron bearing minerals and phases. During leaching, and depending on various process parameters, iron may be precipitated as hematite, goethite, jarosite or other oxyhydroxides, which may be more or less crystalline. Hematite is the favored precipitate because it is the most environmentally stable and does not ad/absorb as much copper, nickel or other solution constituents during precipitation. However, the low solubility of iron during the medium temperature processing of sulfide ores can favour the formation of poorly crystalline, nano-scale iron oxide/oxyhydroxide phases. In some cases these phases have been positively identified as the metastable ferrihydrite, which transforms into iron oxides such as goethite, hematite and magnetite over time. A better understanding of what may help drive this transformation during leaching would ultimately result in lower valuable metal losses and more stable leach residues. Higher acid concentrations result in increased copper extractions and favor the formation of hematite during concentrate leaching, rather than other metastable phases. Furthermore, commercially available water displacement formula “WD40®” and other novel reagent(s) affect Fe precipitation and sulfur chemistry, leading to very different process outcomes such as improved extractions and larger, more easily separated, sulfur particles.

Jan 1, 2017

By S. Kashani-Nejad

The formation of oxides during the dehydration of MgC12,6H20, Bischofite, was studied by heating the bischofite over a range of time and temperatures in ambient atmosphere. Using a methanol-leaching technique developed by authors, the oxides that formed were isolated, identified and assayed. Three distinct regions of oxide stability were identified. The oxide produced at dehydration temperatures less than 300 °C was Mg2(OH)3C1,2H2O; at 300 °C, mixtures of MgOHC1 and Mg2(OH)3C1.2H2O were formed and at 400 °C, MgOHC1 was the only oxide produced. The presence of MgO observed in the products of the dehydration of bischofite at temperatures above 400 °C was due to the thermal decomposition of the MgOHC1 that was formed while the sample was heating to over 400 °C.

Jan 1, 2006

By M. Maccagni, J. Nielsen

"The recovery of lead from battery paste has been investigated for a long time and with the use of many different electrolytes. A number of processes have been presented, but none of them reached even the demonstration step. Engitec has developed a new concept for the battery paste electrowinning using a chloride electrolyte fed through a very innovative flow cell. The process has passed the lab and the demo scale and it is ready to be introduced on the market. In this paper, a description of the process will be provided.INTRODUCTIONThe need for improved energy storage systems as well as the introduction of commercially viable electric vehicles is providing a strong compulsion toward the research of new batteries. The lead battery is playing an important role because it is inexpensive, reliable and it is the most recycled material. This last aspect marks the lead acid battery as quite peculiar making it both the primary lead based product and the main raw material for lead production.In the last years the legislative pressure has become very strong and has forced the lead production to react through the introduction of important process innovations and market changes. The dispersive products, such as additives for paints and for fuel as well as bullets, have been practically banned all over the world while the battery market continues to grow. The lead acid battery remains the cheapest and most integrated energy storage system available and is improving to meet the new technical challenges. This is testified by the news coming from the development of new and more efficient lead acid batteries which are confirming their leading position.Unfortunately, the image of lead is very negative in the public opinion and some important actions are required to try changing this sentiment. Among them, better information to the market and users and the introduction of new and cleaner technologies in the production of lead can help."

Jan 1, 2016