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By A. G. Darnley

"The Geological Survey of Canada is devoting consider-able effort to finding ways to make airborne radiometric measurements both quantitative and reproducible. Equipment has been designed by Atomic Energy of Canada Ltd. to provide high count rates in order to minimize statistical uncertainty, this being essential to justify applying terrain clearance and Compton scattering corrections to the data. Correction factors have been determined experimentally and can be applied automatically. Considerable ground work has been undertaken in parallel with equip-ment development in order to determine field parameters.Two airborne gamma-ray spectrometers are described. One is based on three 5-by 5-inch Nal(Tl) detector crystals and is used in a helicopter; the other employs twelve 9-by 9-inch detectors and is used from a Skyvan aircraft. The former is being used to investigate the range of radiometric response from specific rock types, and for the correlation of ground and air measurements; the latter has completed initial trials and will be commencing experimental surveys during 1969.Results are given to show the comparative sensitivities of the various detector sizes, and operational requirements for a gamma-ray spectrometer survey are discussed briefly."

Jan 1, 1970

By V. T. Panayotov, M. I. Panayotova

Wastewater from mining and mineral processing activities is often polluted by anion forming metals, such as molybdenum and chromium. Low cost materials, including zeolites, are studied for removing heavy metals from wastewater. It is widely accepted that natural zeolites are not effective in removing metals in anionic form. The paper presents study on use of metal modified natural clinoptilolite to remove Mo (VI) and Cr (VI) ions from model soft wastewater. Modification with Pb, Fe(III), Zn and Ba increases clinoptilolite uptake capacity with respect to Mo(VI) at low pH values of the water subjected to treatment, the efficiency decreasing in the order Pb > Fe(III) > Zn > Ba. Only lead-modified clinoptilolite shows high uptake of Mo(VI) in acidic, neutral and slightly alkaline conditions. Modification with Pb, Ba and Fe(III) increases zeolite uptake capacity with respect to Cr(VI) from neutral water. The effectiveness of Ba-modified zeolite decreases in slightly acidic water. Over 90 % uptake of initially available Cr(VI) is achieved by lead-modified clinoptilolite both under neutral and slightly acidic conditions. Increasing the initial pollutant concentrations increases the removed amount both of Cr(VI) and Mo(VI) for Pb-modified clinoptilolite. The findings could be a basis for using the natural clinoptilolite to remove in consecutive steps: firstly Pb(II) and/or Fe(III) ions and then loaded zeolite to be used for Mo (VI) and/or Cr(VI) removal. The kinetics of Mo(VI) uptake by CL-Ba, CL-Fe(III), CL-Pb, and CL-Zn is best described by the pseudo-first order kinetic equation. The kinetics of Cr(VI) removal by CL-Ba, CL-Fe (II), CL-Fe (III) and CL-Zn is best described by the pseudo-first order kinetic equation. Kinetics of Cr(VI) removal by CL-Pb obeys the equation for the first order irreversible reactions. Finding way to remove anions-pollutants from the mineral processing wastewater will render this industry more environmentally friendly and socially acceptable.

Jan 1, 2016

By Erwin L. Zodrow

THE AUTHORS welcome this timely opportunity to comment o n a paper by MacLean and Merner (" Room-and- Pillar Mining at the Prince Mine of the Cape Breton Development Corporation " , ClM Bulletin , June 1978, pp. 59-62) concerning the rock falls and their relation to "a change in the strata". First, however, it is proper to express our gratitude to the Cape Breton Development Corporation, and in particular to A. R. MacLean, for making it possible for us at the College of Cape Breton to start two new collections. The first of these is a fossil plant reference collection from the Sydney Coalfield, Cape Breton (Upper Carboniferous period) , and the second is a documentation of the role o f pyrite in the formation of hydrated sulphates (samples from No. 26 Colliery, 1-B Mine, and the Prince Mine at Point Aconi). Conditions of sedimentation in the deltaic-type basin of the Upper Carboniferous time in the Point Aconi area were such that on the (coal) swamp, now represented by the Stubbart (or Hub) seam , (a) clays of varying thickness and extent were deposited , (b) biogenetic sulphur was introduced and (c) flora were buried. These are essentially the culprit s that make rock falls possible and at the same time predictable over large areas (in the present mine). The clays lithified to become shale, and biogenetic sulphur combined with iron to become pyrite (marcasite?), which exists as nodules and in fine-grained layers.

Jan 1, 1978

By Tsuyoshi Adachi

Photovoltaic (PV) system is especially taken notice as one of important renewable energy resources, because PV has potential to provide a certain amount of energy supply as well as without greenhouse gases emission. Considering recent rapid increasing demand for PV system, more expansion of PV system is expected in the future. However, some precious metals and minor metals such as silver, indium and others are used as component materials of solar cell in PV system. Even if energy supply would become renewable, strict limitation of these metals still remain because amount of natural resources and recycling of metals has restrictions intrinsically. The aim of this study is to reveal the possibility of materials supply restrictions for Photovoltaic system quantitatively and to propose several measurements to assess supply risks for materials. Especially, silver supply potential which is used as wire line in PV system as well as PV demand forecast to estimate material use in the future are focused on. We divide underlying supply risk into 5 measurements and analyze them by time series, i.e. price volatility, resource potential, recycling ratio, production type and supply concentration are investigated. Comparing these factors of silver with other metals, the potential of silver supply for PV is presented. In addition to it, we propose another method to quantify country risk applied an insurance pricing model in finance pricing theory and combine it with the supply concentration measurement. As a result, supply risk of silver will increase gradually in the near future because of its resource constraints and supply-demand balances although silver market is sufficiency competitive one. From the country risk analysis, Peru is not only a significant supply country but also has the highest country risk. Some higher risk countries will increase the level of supply risk even if the concentration ratio of supply indicates moderate level.

Aug 1, 2013

By J. H. Nantel

Indications are that underground mining is gaining favour with large and small mining companies due to environmental and sustainability concerns. Dramatic changes to mine fill technologies will be needed in order to keep pace with these emerging trends. The industry will be compelled to gravitate toward zero discharge mining operations. Innovative handling of mine tailings will become a focal point in this effort. The challenges are to use a greater portion of the residues and to manufacture a fill with better properties. This is a tall order that can only be addressed through a systematic research and implementation process involving mining companies, universities, research organizations, manufacturers and governments. The mining industry has to be at the forefront of this technology push in mine fills for the future mines. It will also be called upon to lead the way in other research areas. The industry will have to partner with other technology providers: universities, government laboratories and consultants.

May 1, 2007

By J. E. Ryan

General Description Due to the extreme cold weather experienced in Flin Flon during the winter months, thought and precaution were necessary in the design of the plant buildings. The machine shop, carpenter shop, drill shop, and coal plant buildings are similar in the building materials used in their construction. They are sided with two-inch shiplap, insulated with celotex and asbestos paper, and covered with corrugated iron on all side-walls. Roofing consists of 2 by 4 lumber on edge, laminated, and further covered by celotex and three-ply roofing. These buildings are heated by means of unit heaters. The heaters are primarily steam-heated radiators, through which the air of the buildings is circulated by electrically-driven fans. Our machine shop is located to the east of, but central to, the main operating buildings of the mine and plant, and is so connected by a net work of tracks as to be able to serve all portions of the entire plant conveniently. The building is divided into two bays, the main bay 53 ft. by 340 ft., and the east bay 24 ft. by 340 ft. The shop office and drafting room, a two-story annex 24 ft. by 30 ft., is located on the west side of the shop. The arrangement within the shop is such as to house conveniently the several departments, namely, heavy machine tool section, repair floor section, boiler shop heavy tool and floor section, blacksmith heavy tool and forge section, tool room, electric welding rooms, stock room, tin and copper shop, and electrical parts and armature winding and repair shop (see Figure 1). All the heavy tools, the repair floor section, and railway tracks are so located in the large open bay as to be fully serviced by an electrically operated 15-ton bridge crane, with a span of 50 feet and a travel the full length of the shop. A standard-gauge railway track, branched off the main line, penetrates the full depth of the building. This track lies along the extreme east side of the main bay, allowing easy entrance and movement of rolling stock and heavy machinery, loaded on standard flat-cars, to the repair floors in the main bay. Eight jib cranes, affixed to building columns, further facilitate the heavy repair work throughout the various shop divisions. Our light and heavy machine tools are standard equipment, not unlike tools used in mine, mill, and railway shops.

Jan 1, 1935

By L. K. Smith, C. R. May, K. R. Schrag, H. Buchwald

"New contracts for 65 million long tons of coking coal valued at over $900 million, over the next 15 years, herald the rebirth of Alberta's coal industry. The industry is optimistic that export orders may reach 20 million tons per annum by the mid-1970's. Coal will be extracted from underground and surface mines and it is expected that the total labour force will double from the present 1,200 men within the next two years. Ali the health hazards associated with coal mining are likely to be encountered and it will be incombent on the Provincial Department of Health to specify the standards which relate to health and environment where no such standards have previously existed. This paper examines some of the problems which are being encountered in setting up an environmental health program and reviews the practicability of environmental monitoring methods, with special reference to respirable dust."

Jan 1, 1969

By J. S. Fox

Major-element data for unaltered, unmineralized felsic host rocks from a number of stratigraphically simple, massive volcanogenic Zn-Cu(-Pb) sulphide deposits of low metamorphic grade have been compiled. The petrochemical affinities of these host rocks have been determined (by standard means and by discriminant analysis) and compared. This comparison indicates that volcanogenic deposits in felsic terrains are not restricted to the classical calc-alkaline rock association as previously thought, but can actually be hosted by rocks showing a range of iron content. There is a positive correlation between differentiation trend and are tenor. Zn-Cu ores usually have iron-rich felsic hosts (most Canadian Shield deposits); Pb-Zn -Cu ores have iron-poor felsic hosts (Japanese, Iberian and Tasmanian deposits). This parallels the antipathetic relationship between iron content and background lead levels evident in young, unmineralized, island arcs as well as in many older belts. Correlations between differentiation trend on one hand and massive ore mineralogy and the relative proportions of various rock type (including rhyolite, quartz-porphyry and coarse pyroclastic rocks) on the other are also evident. It is concluded that the recognition of a calc-alkaline differentiation trend cannot be used as a prospecting guide, as has previously been proposed. However, in view of the above correlations, the recognition of a given trend may aid in the formulation of an effective exploration philosophy.

Jan 1, 1979

By H. Sahay

"DISCLAIMER NOTICEThe views and conclusions contained in this presentation are those of the author and should not be interpreted as necessarily representing the official policies or recommendations of the Department of Mines and Energy, Government of Newfoundland and Labrador. ABSTRACTThis paper describes the main testing procedures that should be carried out to evaluate the capacity and capability of the service brakes on the large-size diesel-electric trucks now in common use at open-pit mining operations. Brake testing programs in general are described, and then consideration is given to different techniques of service brake testing, brake performance evaluation, braking energy and typical performance characteristics.IntroductionThe first diesel-electric truck with a capacity of about 85 tons was introduced in 1963 by Unit Rig and Equipment Company of Tulsa in cooperation with General Electric Company, who successfully developed and supplied the most important component- motorized wheels. Since then, its popularity and numbers have continued to grow, and now more than 3700 such units are in operation in mines around the world. In Canada alone, their number is more than 700, including about 150 in the Province of Newfoundland and Labrador. Similarly, their size has also grown from that initial capacity of 85 tons to 350 tons.Although the introduction of the electric trucks proved to be invariably economical, their indiscriminate use was not without severe consequences. Many runaways and even fatalities occurred when the dynamic retarder failed while the truck was travelling loaded down severe grades. The service brakes in such cases proved incapable of stopping runaway trucks, mainly due to their limited capability and the fading caused by excessive heat produced during the act of braking itself. This eventually led the various governments, the open-pit operators and the manufacturers to seriously question the braking capability as well as function of both service brakes and dynamic retarders. Extensive testing"

Jan 1, 1980

By Habib Zughbi, Paul Zulli

"A key step towards sustainability in iron and steelmaking is to optimise the use of raw materials and energy consumption, and consequently minimise CO2 emissions. Models based on a Process Integration (PI) approach play a key role in evaluating various scenarios and the impact of introducing changes in raw materials and operational conditions on the overall energy consumption and CO2 emissions. BlueScope uses a PI based comprehensive model for its Port Kembla Steelworks (PKSW), called the Integrated Steelworks Energy and Emissions Model (ISEEM). ISEEM is tightly coupled to the configuration of PKSW. It is based on mass and energy balances as well as thermodynamic relationships. ISEEM is a steady-state model and is used to predict overall and detailed unit-by-unit energy consumptions and CO2 emissions. It is also used for plant-based scenario modelling. This paper investigates the impact of major changes to PKSW configuration, including the shutting down of a blast furnace and cokemaking battery, on the energy consumption and CO2 emissions of the plant. It discusses some of the issues involved in updating the model and some identified opportunities."

Jan 1, 2015

By Z. G. Tao, Y. Y. Peng, W. L. Gong, M. C. He

"This paper presents an overview of the major landslide hazards in open pit mines in China, the currently used landslide control and monitoring techniques, and development of a new slope control technique incorporating the reinforcement, sliding force monitoring, remote sensing and forecasting in one system in order to constrain the displacement of the sliding blocks in the landslide to minimized the influenced area and provide precise warnings timely for the imminent landslides. For implementation of the new technique, a novel rock cable with large deformation and high resistance (also known as HE cable) was developed, which can elongate as long as 2m. At the same time, the necessary and sufficient condition for initiating a landslide and energy balance equations are formulated. Based on the proposed mathematical models and Beidou satellite system, the software and data transmission hardware for remote sensing and forecasting were developed the new landslide control technique has been applied successfully in 245 landslide sites in 12 provinces across China. In this article, two practical application cases in the open pit mines are reported.INTRODUCTIONChina is one of the countries in the world with the most widely distributed landslides and suffering the heaviest damage. According to the incomplete statistics, landslide hazards have caused death of hundreds of people and direct economic losses of several hundred million RMB each year. The landslide hazards have a great impact on the life and property safety of the people, safety of the infrastructure, as well as the social stability. Thus development of new techniques for forecasting and prediction of the landslides is imperative and of great importance. In general, the forecasting and prediction of the landslides consists of three major aspects, i.e. sliding time forecasting, landslide activity intensity forecasting and landslide hazard degree forecasting. Since a considerable part of the landslide-suspected area are adjacent to the residential areas or important infrastructures, development of the advanced landslide control and monitoring techniques to cope with the sliding time forecasting problem is more important.Over the past one hundred years, the most widely used slope monitoring techniques are based on displacement monitoring (Xu, et al. 2007; Toshitaka, 1998). In the early days owing to the limitation of the technology and equipment, the ground surface displacement and underground water level change were inspected mainly by man power for inferring the possibility of a landslide. In recent several decades, more and more ground surface displacement monitoring devices were brought to the market, such as the automatic total station, theodolite, digital level, borehole inclinometer and GPS based instruments, etc. Based on these modern techniques, some advanced instruments have been developed and applied to the landslide monitoring, for example, the “landslides early warning monitoring system” (Leonardo, et al. 2002), the “In-SAR” technique (Reevea, et al. 2000), the GPS and satellite geodetic survey based technique (Reevea, et al. 2000), and real-time telemetry technology (Xu, et al. 2007). These monitoring approaches have made significant contributions to the landslide disaster monitoring and forecasting. The major limitations for the ground surface displacement monitoring techniques are lie in the inconsistence between the displacement in ground surface and that in the sliding surface for the sliding mass, resulting in low degree of forecasting accuracy."

Jan 1, 2015

By William W. Shilts

"In carrying out a geotechnical survey of a proposed gas pipeline route from the Arctic Islands south to Longlac, Ontario, the Polar Gas Consortium contracted the drilling of several hundred 2- to 2D-m-deep boreholes in drift and bedrock. Samples from these holes were made available to the Geological Survey of Canada, where they were subjected to stratigraphic and trace-element geochemical analyses. The geochemical characteristics of the clay and sand-sized heavy mineral fractions of till samples from these boreholes have been summarized in a series of geochemical profiles.From the proposed pipeline terminus at Longlac northward to the vicinity of God's River in Manitoba, tills contain significant amounts of Paleozoic carbonate rocks and Proterozoic sedimentary rocks derived from the Hudson Bay basin and lowlands. Within this section, two sites were enriched in base metals, indicating the possibility of local mineralization of possible economic interest.From God's River northward to Seal River, Manitoba, no evidence of local mineralization was noted. The heavy mineral fractions of the tills are universally enriched in Mn-rich siderite thought to originate on or in the Paleozoic section of the Hudson Bay lowlands.From Seal River northward to Thelon River, near Baker Lake, tills contain only components originating west of the Hudson Bay sedimentary basin. Near the Keewatin-Manitoba border, all till is enriched in uranium, which probably originates in the ""young"" porphyritic granites underlying much of the region, and produces a distinctive airborne radiometric anomaly.At the Thelon River, multiple till sections are variously enriched in Cr, Ni, U, Cu and Mo in the vicinity of a distinctive aeromagnetic anomaly.From Thelon River northward, several coincident zones of chromium and uranium enrichment are found where the line of boreholes crosses east-west-striking belts of volcanic, ultramafic and sedimentary rocks of the Prince Albert Group.The results of this study indicate that till tends to have characteristic element associations or concentrations over each of several broad regions along the pipeline route. These are related both to large-scale bedrock associations and to largescale effects of glacial dispersal. In addition, the samples, collected more or less at random with respect to local bedrock geology, have intersected several small-scale geochemical anomalies that appear to be related to zones of mineralization of possible economic interest."

Jan 1, 1980

By Alan Bateman

Introduction A few years ago the name Katanga recalled, to those interested in copper, a far-off country in central Africa where deposits of huge size were beginning to pour a stream of copper into the world's markets. But no one heard of the adjacent part of northern Rhodesia as a potential copper region. It was then a bush-covered wilderness, with a few lonely, widely-spaced villages, and here and there a copper prospect that created but little outside attention. There was also one struggling mine whose development created pessimism. The low-grade carbonate outcrops of Rhodesia did not compare favourably with the rich carbonate ores of Katanga. And, since Katanga was mining only oxidized ores, it was then thought that this adjacent region likewise would contain only oxidized ores. The one mine that had been started, Bwana M'Kubwa, was working on low-grade carbonate ore at a loss. The outlook was not promising. But, a little over three years ago, the aspect changed. The vision of one far-sighted engineer embraced the possibility that here copper sulphides might underlie those low-grade carbonate croppings. His courageous associates furnished the capital; drilling commenced, and the great Roan Antelope mine rapidly emerged. In quick succession, the N'Kana, Mufulira, N'Changa, N'Changa Extension, and Chambishi mines were heard from. Prospecting and development are now proceeding apace, towns are being hewn out of the virgin bush, plants are being reared, and ramifying branch railways are being pushed out from the single line of steel that now connects Rhodesia with the coasts to the south. A great new copper-mining centre is in the making, about which the world will hear much in the future. As with most new mining camps, rumors abound regarding its ore possibilities; some are correct, some are erroneous, and reliable information unfortunately is all too scanty.

Jan 1, 1930

By T. G. Joseph, M. J. Bolster

ABSTRACT This paper explores passive seismic measurement as an alternative, nonintrusive approach to conducting annual brake testing on surface mine sites. Dictated by the test site location, this evaluation adhered to the brake testing procedure as per British Columbia occupational health and safety regulations. Results showed excellent correlation to those reported via conventional practice: Comparing stopping distance, time, and velocity for the proposed instantaneous passive seismic versus conventional approaches, less than a 0.5% variance was evident. A viable alternative, the passive seismic approach, allowed an entire fleet of trucks to be sequentially evaluated for annual brake testing without disrupting operations by installing mechanical testing equipment.

Jan 1, 2012

By J. F. Wright

INTRODUCTION Eighteen years ago about half a dozen experienced prospectors moved from northern Ontario to northwest Manitoba to prospect 'greenstone' areas shown on geological maps of .parts of northern Manitoba prepared by J. B. Tyrrell, D. B. Dowling, and Wm. Mclnnes. Gold-bearing quartz was soon discovered by these men in this new field, and in succeeding years many more prospectors entered the district. A number of the pioneers are still prospecting, and since 1913 mineral deposits have been discovered each year in widely separated areas of the large district extending 150 miles eastward from the 102nd meridian and 60 miles north of latitude 54°30'. The majority of the discoveries, however, have been made near Schist, Elbow, Wekusko, and Kississing lakes. One hundred or more mineral occurrences of some merit are known, the main types being sulphide replacement bodies containing nickel-copper or copper-zinc and gold-bearing quartz veins. Some underground exploration or diamond drilling has been completed on 25 or more of the prospects. Up to the present, three ore-bodies, namely, Flin Flon, Sherritt-Gordon, and Mandy, have been proved. Of these, Flin Flon, the largest, is estimated to contain from 16,000,000 o 19,000,000 tons of copper-zinc ore carrying some gold, silver, and lead. Next in importance in regard to tonnage is Sherritt-Gordon, with a calculated reserve of nearly 5,250,000 tons of copper-zinc ore carrying less than $1.00 combined gold and silver.

Jan 1, 1931

By George S. Rice

Foreword Explosion hazards differ widely in the mines of different fields or coal basins. They also differ as between different mines in the same basin or fold, because of variations in gas entering the mines, and because dust conditions and explosion hazards are affected by the mining methods employed and the organization of the work. It is unquestionably true, however, that there are greater differences in explosion hazards in mines of different coal fields or basins than between different mines of the same field or basin. In these respects, the coal fields and individual mines in Alberta are not exceptional. The same conditions obtain in various countries where coal is mined, and are found in single States, as for example in Colorado, where coals are mined ranging in character from sub-bituminous to anthracite, and in attitude from flat horizontal to steeply pitching beds. The U.S. Bureau of Mines, at its experimental mine near Pittsburgh, Pa., has made large-scale tests of the relative explosibility of dusts of coals, ranging in rank from Wyoming sub-bituminous coal containing 19 per cent moisture, to anthracite from Pennsylvania, and including samples from a mine in the Crowsnest Pass district, B.C., and from a Vancouver Island mine. The Bureau has also made similar tests of the dust of coal from a Yorkshire mine which the British Safety-in-Mines Research Board uses as standard.

Jan 1, 1927

By K. Baris

Methane (CH4) present in coal seams, generally known as Coalbed Methane (CBM), Coal Mine Methane (CMM) or Coal Seam Gas (CSG), is a major energy source, as it is the primary constituent of natural gas. At the same time, released methane is a potent greenhouse gas (GHG) and a major safety hazard in underground mining operations. Therefore, a considerable effort has been undertaken to develop coal bed methane extraction and utilization technologies that can achieve both environmental and safety benefits. Countries with significant coal reserves and gassy seams, i.e., USA, Australia, Canada, China, India, Poland and Germany have developed mature methodologies and practices to extract, before and during mining, and utilize significant amounts of methane from coal seams. Nevertheless, on a global scale, methane recovery remains untested and many technical and economic challenges require urgent attention. The research presented in this paper, sponsored by the United States Environmental Protection Agency (EPA), is focused on the Zonguldak Basin, the only hard coal region in Turkey. The basin is known to contain very gassy coal seams and consists of three major regions: Armutcuk, Zonguldak and Amasra. Among the three, the Amasra coalfield is considered as the most favorable for CBM recovery, as it comprises of deeper coal seams and where a private company, Hema Enerji A.S. (Hema) is already developing coalbed methane production facilities. This study aims at developing a reservoir model to predict the potential CBM recovery from the CBM-2 well, the only producing CBM well drilled by HEMA Enerji A.S in the Amasra coalfield. History matching was utilized to model the 15-day production data and uncertainty analysis was performed to estimate the optimum values for the reservoir parameters. The produced model yielded an average production rate of 143 m3/day for 10 years. The total amount of CH4 to be produced during this period was 0.53 million m3. Furthermore, the total amount of GHG to be avoided was estimated at 6585 tCO2e.

Aug 1, 2013

By S. K. Kawatra, S. J. Ripke, T. C. Eisele

It was determined by the authors that the water that remains in the filter cake after filtration in iron ore concentrators can contain several hundred times greater concentrations of calcium ions and other cations, due to surface chemical effects carrying the ions along with the water. Filter cake from two plants was analyzed. The water retained in samples of magnetite concentrate filter cake in Plant 1 contained 5088 ppm calcium and 5995 ppm magnesium, while the Plant 2 filter cake contained 231 ppm calcium and 119 ppm magnesium. These levels were dramatically elevated compared to the water that was removed from the concentrate by filtration for recycle to the plants (9 ppm calcium/15 ppm magnesium for Plant 1, and 11.9 ppm calcium/9.3 ppm magnesium in Plant 2). In addition to possible effects on agglomeration performance, the presence of these cations also affected the efficiency of filtration. In order to reduce the effects of these cations on filtration in Plant 2, carbon dioxide was injected into the slurry before it entered the filter press. This was found to increase filtration rates by up to 23.7%. Comparison of the results from the two plants shows that the concentrations of cations present in the filter cake will vary greatly from plant to plant, with correspondingly large variations in their effects on plant operations.

Jan 1, 2004

By Laura Prati

Gold-on-carbon catalysts resulted very active and selective in liquid phase oxidation [1, 2, 3] and during past studies we established that activity is ruled by two factors: particle dimension and gold exposure on the carbon surface [4]. These two parameters are also connected to the nature of activated carbon where the chemical nature of the surface oxygenated groups probably plays an important role [5]. Our studies, focused on the design of an active gold-on-carbon catalyst for liquid phase application, were aimed, operating a fine tuning of all the parameters involved in determining activity, to optimize gold-on-carbon preparation, keeping in mind that gold particle activity increases with decreasing particle size and increasing gold exposure. Gold sol immobilisation represents a versatile methodology in preparing gold catalysts [6]: throughout this work we used as sol stabilizing agent, the N-dodecil-N,N-dimethyl-3-amino-1-propan sulphonate (SB), that provides both sterical and electrostatic stabilisation, a condition we already demonstrated necessary to preserve particle dimension when carbon is used as the support [6]. We generated different gold sols by varying the relative amount of reagents (HAuCl4, SB, NaBH4), the type of alkali and the temperature of the gold precursor reduction. Moreover, as we had recently evidenced that there is also a carbon effect [5], we employed only one active carbon to immobilize the sols.

Oct 1, 2003

By J. D. Clucas, D. B. Dreisinger

"The Starved Acid Leach Technology (SALT) has been developed by Search Minerals to extract nickel and cobalt VALUES (from nickel laterite ores (saprolites) and Caron plant residues. The technology consists of sulfuric acid atmospheric leaching of the ores or residues followed by neutralization and recovery of nickel and cobalt. The acid addition is carefully controlled to maximize nickel and cobalt extraction while minimizing overall consumption of acid by various gangue reactions. The final recovery processes can be tailored for maximum economic benefit. The use of resin-in-pulp processing is advocated as the most cost effective method for initial recovery of nickel and cobalt from lower grade materials. INTRODUCTIONCommercial processes for laterite ore treatment vary according to laterite type and local conditions. The two general categories of laterite ore are saprolites and limonites.Saprolites are generally treated by pyrometallurgical processes for reduction of nickel to matte or ferro nickel alloys. The high cost of drying, chemical reduction and electric furnace smelting requires that the saprolite grade for economic processing is of the order of 1.8% nickel or higher. There are of course large amounts of saprolite that fall below this “cut-off” grade that are not currently economic.Limonites can be treated by the Caron Process which involves drying of the ore, a reduction roast of the whole ore to reduce nickel and cobalt (and some iron) to the metallic state followed by ammonium – ammonium carbonate solution to leach nickel and cobalt. Nickel and cobalt recovery are low (70-85% for Ni and 20-50% for Co). The Caron plant tailings therefore contain high levels of unrecovered nickel and cobalt. Relatively few plants have used the Caron Process and new installations are not anticipated due to the high energy cost of drying and reduction roasting. Nevertheless, plants in Brazil (Niquelandia), Australia (Yabulu) and Cuba continue to operate.The high pressure acid leach (HPAL) process was pioneered at Moa Bay in Cuba in the 1960’s in the treatment of limonites. In the 1990’s the HPAL process was touted to revolutionize the nickel industry with low capital and operating costs for new installations. Murrin Murrin, Cawse and Bulong in Australia were started and in each case the technical difficulties of operating at extreme temperature and pressure conditions and the challenges in “ramping up” a complex hydrometallurgical facility conspired to cause these plants to fail economically. At present, Cawse and Bulong are closed and Murrin Murrin continues to operate after undergoing a financial restructuring."

Jan 1, 2012