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By Ito H, Noguchi F, Ueda Y

DTA curves of synthesis lead sulfide and commercial. lead concentrates during oxidation were measured to clarify the mechanism of ox- idation of lead sulfide. The oxidation reac tions could be divided to elementary reactions with production of basic lead sulfates such as 2PbO PbSO4. An existance of iron sulfide played an important role of the oxidation of lead concentrates. The oxidation rates of lead sulfide were measured in the wide range of oxygen potenti- als using IR type SO2 gas-meter. The oxidation rates under low Po 2 which corresponds to the direct oxidation smelting were much lower than those obtained under high Pot. The combustion temperatures of lead sulfide were also measured by hot thermocouple method. Those values were extremly low compar- ing the oxidation temperatures obtained by DTA.

Jan 1, 1987

By S Hapugoda, Y Tang, L Lu

The steel industry is one of the global leading CO2 emitters, accounting for approximately 7 per cent of global anthropogenic CO2 emissions. In 2022, the world produced 1878.5 Mt of crude steel. About 70.8 per cent of the world’s crude steel was produced by integrated steel mills through the blast furnace and basic oxygen furnace (BF-BOF) process, while the remainder was produced largely by mini mills using electrical arc furnaces (EAF). Compared with gas-based DRI and scrap-based EAF processes, the direct CO2 emissions from the BF-BOF process and the coal based DRI and EAF process are significantly more, as both the processes rely heavily on fossil fuels, such as coke and pulverised coal, to provide energy and reduce iron oxides. Hydrogen is very reactive and reduces iron oxides to metallic iron without generating CO2. Therefore, substitution of hydrogen for fossil fuels in these processes presents a good opportunity to significantly decarbonise the steel industry. This paper will first discuss the thermodynamic and kinetic characteristics of hydrogen and carbothermic reductions of iron oxides and then examine the behaviours of different ore types present in Australia iron ores during hydrogen reduction.

Sep 18, 2023

By Bourne R. W, Smith T

This paper presents initial findings of a project examining novel processes for the treatment of refractory sulphidic gold concentrates. Non-oxidative roasting of such concentrates for 12 hours at 750¦C resulted in the finely disseminated gold agglomerating to form discrete grains. The pyrite and arsenopyrite decomposed to form pyrrhotite, whilst the labile sulphur and arsenic driven off was collected on a condenser as a mixture of elemental sulphur, metallic arsenic and various arseneous sulphide compounds. As a result, the cyanide solubility of the gold contained in sulphidic refractory gold concentrate from the Emperor mine in Fiji improved from 54.5 per cent to 98.4 per cent; from the Fimiston mine in WA (65.2 per cent to 96.6 per cent), from the Windarra mine in WA (69.6 per cent to 91.3 per cent), from the Harbor Lights mine in WA (20.4 per cent to 60.7 per cent), and from the Wiluna mine in WA (12.6 per cent to 28.0 per cent). The non-oxidative roasting conditions have not been optimised for each of these minerals. Subjecting the non-oxidatively roasted minerals to mild oxidative acidic iron sulphate pressure leaching (with typical temperature of 100¦C and typical oxygen overpressure of 500 kPa) to remove iron and so further liberate finely disseminated gold, resulted in the cyanide solubility of the gold exceeding 96 per cent for each of these five concentrate types (including those from Harbor Lights and Wiluna). Thiourea leaching of the sulphur-rich residues under acidic conditions resulted in remarkably high gold extractions being achieved. These novel processing options need to be optimised, and their economic viability established.

Jan 1, 1991

By Casale G

This paper discusses a long range mine plan development at the Santa Fe Pacific Gold Twin Creeks Mine based on the reserves of Mega pit. The key constraints of the schedule development included two types of mill ore targets (sulphide and oxide mill ore), consideration of blending of six chemical constituents (sulphide sulphur, carbonate, organic carbon, the ratio of iron/[arsenic, antimony]), and mining of acid generating and acid neutralizing waste at pre-defined proportions. Solution approaches, selected results, and project experiences are discussed.

Jan 1, 1995

By Worotnicki G, Tillmann V. H

Past experience with fully bonded cable dowels placed as a means of reinforcement in highly stressed crop pillars at the New Broken Hill Consolidated Limited (NBHC) mine indicated such support was not fully effective. Typically overbreak of the crown occurred leaving long lengths of cables hanging from the back stripped of grout and rock with the potential load carrying capacity of the cables not having been fully utilised. This mode of behaviour had been observed in the cable dowelled crowns of three longhole open stopes (EROS) mined to the No. 12 level at NBHC. A system of support with improved mechanism of load transfer from rock to cable and capable of full utilisation of cable strength was proposed for the crown pillars of future Stopes.

Jan 1, 1983

The operators of the iron ore railroads in the Pilbara faced problems of excessive wear between rail and wheels as the tonnage hauled increased in the early 1970's. Joint research projects were begun between Hamersley Iron, Mt Newman Mining and the BHP Melbourne Research Laboratories to study these problems and recommend solutions. The particular problems of wheel rail interaction were solved by asymmetrical profile grinding of the rail and modifications to the machining of the wheels. Rail materials were improved through increasing yield strengths by alloying and by heat treatment. Wheel materials were improved by alloying. The economic benefits of these improvements have been demonstrated by much reduced re-rail requirements and other reduced maintenance costs.

Jan 1, 1986

Traditional techniques for extracting pillars in thick underground coal seams in India are reviewed. Problems encountered are principally control of roof strata and low recovery. Recently developed mechanized methods and projected newer techniques are discussed.

Jan 1, 1986

By Buizen M

An investigation into the mechanics of sub-surface deformation caused by caving of the extracted area behind retreating longwall faces has been completed by the Subsidence Engineering Section of the New South Wales (NSW) Department of Minerals and Energy. Changes in strata bulk permeability were also measured by standard packer tests undertaken before and after mining. The strata movement was measured by a multi-wire borehole instrumentation system consisting of mechanical anchors installed at different horizons in a borehole extending from the surface to the coal seam. The mechanical anchors were collected to suspended weights on the surface by stainless steel multi-strand wires. The movement of these weights was monitored as the longwall face approached and retreated past the borehole. The anchors did not move significantly until the face went past the borehole. For subcritical extraction geometry with the extraction width to mining depth ratio of 124, the caving zone extended to roughly 9 times the extracted seam thickness above the seam roof. Tensile strains within the overburden tended to be much more closely related to stratigraphy than to the proximity to the extracted seam roof. Larger tensile strains were associated with layers of sandstone, siltstone and conglomerate, whereas layers of mudstones, claystones and coal underwent much smaller strains indicating subsidence in blocks. A beller correlation was observed between pre-mining Rock Quality Designation and permeability than between rock type and permeability. This correlation was less evident in the post-mining core logs. There was an overall increase in bulk permeability after mining.

Jan 1, 1990

By Gunther L. M, Rich N

Remapping of the Burdekin Basin has resulted in the subdivision of the three formations (megafacies) previously recognised in the Late Devonian Dotswood Group. Nine dominantly volcaniclastic facies are now identified within the three megafacies, representing coastal plain, floodplain lake, alluvial plain, ephemeral lake and alluvial fan depositional environments. The Dotswood Group was deposited during a major regressive phase that began at the end of the Givetian, continued throughout the Frasnian and ended in the early Famennian.The proposed depositional model completes a southeasterly progradation of coastal plain facies over shoreline and nearshore marine facies established in the underlying Fanning River Group. Uplift and associated acid-intermediate volcanism to the south of the Burdekin Basin, resulted in the deposition of a volcanogenic alluvial fan facies locally preserved along the southwestern margin of the basin. Tuffs and ?ignimbrite were deposited in widespread floodplain lakes which lay behind the coastal plain. An alluvial plain traversed by southward flowing rivers, formed the northern margin of the basin.

Jan 1, 1990

Mineral resource estimation is commonly based on the accumulation of a series of local estimates. At times, the distribution of these grade estimates is not appropriate to the grade distribution of the data on which the estimates are based. Mineral resource grade estimation has an increased potential of being in error as the grade variability increases. As the mineral commodity value increases, greater grade variability within the mineral resource is tolerated. This paper directs its attention to mineral properties where the data average grade is 20 per cent or more than the data median grade at a specific cut-off grade. A mineral resource estimate is enhanced if it is supported by graphs which demonstrate that the sample data have been separated into appropriate geological domains. Each geological domain has a unique grade distribution signature, which can be graphically demonstrated simply and objectively. This signature will usually be evident well before the Indicated mineral resource estimates are available. The paper looks at the use of the log probability and MedAve plots to assess how effective domaining has been. It further outlines how the MedAve plot can be used to assess the integrity of the mineral resource grade estimate within a geological domain with the data on which it is based. The paper suggests that the overall grade of a mineral resource at any cut-off grade will be closer to the data median grade rather than the data average grade. Tips are provided to ensure that the odds reflected in the data grade distribution are not ignored and hence the risk that the project is affected by unrealistic estimates of the overall mineral resource grade is reduced.

Jan 1, 2003

A metallurgical balance drawn around a mineral processing plant or smelter must involve all process streams crossing the plant boundary. Modern sampling theory, as formulated by Gy, and sound statistical method can be used to determine the uncertainties in the observed assays for the set of balance analytes and in the mass flow rates of the process streams for the balance period. These uncertainties can then be used together with the material balance equations to arrive at adjusted component mass flows that satisfy the material balances exactly. To determine whether or not the data is consistent with the level of uncertainty in the data and with the material balance equations, a goodness of fit test is applied. This goodness of fit criterion is the principal tool to quantify the quality of the material balances. The mathematical structure of the statistical material balance problem poses a number of challenges. For example, while the variances of the adjusted component mass flows do not vanish, the variances of the sums of the adjusted component mass flows about each balance node do vanish, simply because the balancing computation demands that the balances close exactly. Even though it can be shown that the variances of the adjusted component mass flows are always lower than the estimates for the corresponding unadjusted component flows, it is still not possible to construct a confidence interval on the component mass flow into (and out of) a balance node using the adjusted component flows. On the face of it, such a confidence interval is exactly what is most desired from the balance calculations. The problem arises because the balance problem is a data adjustment rather than a parameter estimation problem. It is possible, however, to calculate the recovery of a component to a product stream and determine a confidence interval for the recovery value. It is also possible to calculate an uncertainty in the mass flow of any balance species in any process stream, before and after balancing.

Jan 1, 2005

The subject of octanes and knock in petrol engines is of general interest, not only to the engineers and chemists in the petroleum and automotive industries, but also to the motorist who wishes to see some light through the haze of propaganda regarding "super" petrols. A mixture of petrol vapour and air will explode when a spark is passed through it if it contains more than one and a half per cent. or less than six per cent. of petrol vapour by volume. In a petrol engine the mixture has to be within the explosive range before it will operate. When the spark is passed it 'ignites the petrol vapour-air mixture which burns with rapid but finite progress of the flame front 'through the unburnt gases in much the same manner that a charge of dynamite is consumed. The turbulence of the gases in the cylinder under normal operating conditions more than doubles the velocity of the flame front and enables the combustion to be completed by the end of the working (expansion) stroke:KNOCKIf the cylinder head 'is poorly designed or is covered with a deposit of carbon, it is possible for "hot spots" to develop, and these can ignite the mixture before the spark is passed. This pre-ignition gives rise to an engine knock but is accompanied by a dull thud rather than the ringing knock associated with the true "knocking" found in a petrol engine and attributed to the detonation of the mixture. Until a few years ago it was thought that this detonation was due to a shock wave produced by the rapid combustion of the mixture, and sufficiently intense to cause ignition of...

Jan 1, 1951

A method for determining the relative degree of oxidation of concentrate samples was established, and various surface-active materials and protective systems were examined as oxidation inhibitors. Sodium oleate was-the most effective of the materials tested, and a plant trial

Jan 1, 1963

By Roberts T. J, Thomson I. A

Mill scale, which contains a high proportion of magnetite and wustite, was added to the feed to the Whyalla grate kiln pellet plant during the production of acid pellets for domestic consumption. Its addition resulted in increased production -rates together with reduced consumptions of bentonite, fireclay and fuel. Mill scale was particularly beneficial when treating feed containing difficult to process, earthy, high ignition loss iron ores. Test work in the laboratory and subsequent plant experience showed that the magnetite and wustite oxidised in the drying and preheat sections of the travelling grate. The additional heat reduced gas flows through the grate kiln system, aided the drying of green balls containing earthy ores and increased the preheat strength of the balls. These advantages were offset to some extent by higher power consumptions to grind the harder mill scale and process difficulties caused by the contamination of mill scale with oil and coke.

Jan 1, 1974

Roadheader tunnelling machines have been used in Australia by both mining companies and contractors involved in the mining and con- struction industries since the early 1970's. They have both advantages and limitations, and this paper discusses machine excavation from the point of view of a contractor who has both reaped the benefits and suffered the conse- quences of using roadheaders. The paper also includes brief descriptions of three projects tackled by roadheader, all the projects being Declines.

Jan 1, 1987

The thick coal seams of the South Maitland field are the only ones in New South Wales which have been worked extensively to heights beyond 3.8 m (nominal "thin" seam height). Under shallow cover only minor difficulties were experienced in developing first workings but later the widespread occurrence of incidents of spontaneous combustion and the growth of "creeps" extending over large areas gave the field its own peculiar problems. As the mines have driven under deeper cover extreme difficulties in forming development roadways have been experi- enced. Various methods have been adopted in an attempt to overcome the problems of the field.

Jan 1, 1976

The paper outlines the development and objectives of the slim core (50 mm dia.) testing procedures employed at the Company's Central Research Laboratories with particular reference to washability studies required for coalfield evaluation. It shows that when the routine test procedures, that have been developed for cores recovered form the Sydney Coal Basin, were applied to Bowen Basin Coals some of the washing data obtained appeared to be suspect. Though yield indications appeared to be of the right order, product ash, required separating gravity and percentage of near gravity material were found to be at variance with bulk washability data. The results of a correlation study made on an underground seam from the Bowen Basin comparing slim core, hulk sample, and pilot plant washing data are given. The results of a series of studies including washability studies made on slim cores, strip samples, large diameter cores and bulk samples, pilot washing trials and computer simulations of washery circuits treating Lilyvale seam coal from the Bowen Basin are shown.

Jan 1, 1977

By Smitham J. B

A selection of Australian washed coal samples was examined to determine the effect of sample hydrophobicity (rank) and particle size on froth stability in the flotation process. The results indicate distinct rank-based variations in froth volume and stability for flotation tests conducted without the use of collector, over a series of particle size distributions.High-rank coals showed a greater tendency to generate stable, high-volume froths than coals of lower rank. Implications for circuit design and operation are outlined.

Jan 1, 1988

By Swanson AR, Nicol SK

A study has been made into the influence of feed size distribution on the flotation response of coal. The results show that a full description of the flotation response of a coal must not only consider the inherent floatability of the coal, but also, the size distribution of the feed to flotation. The performances of a number of flotation circuits were compared using a coal which was "poorly floating" because of its size distribution. Split feed flotation, two stage reagent addition, and reflotation of classified tailings all gave better yields than that obtained by conventional single stage flotation. The optimum flotation circuit for the washing of the coal in question, was reflotation of classified tailings.

Jan 1, 1978

By Molloy GR, Eaton RA

The crusher development programme for 7ft Super Extra Heavy Duty (SXHD) Symons cone crushers commenced in 1984. The main objective of the programme was to run the crushers at maxi- mum power for the full life of the liners. This would give a finer product sizing enabling grinding and flotation plant throughput to be maximised. The study was conducted along two basic lines of attack, the first main- taining an effective profile through the life of the liners, the second improv- ing the properties of the liners. It has been found that crusher liner life can be extended and crushing efficiency improved by modification of liner composition and profile.

Jan 1, 1988