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By J N. Farrell

Metallurgists frequently use a small number of large samples to characterise expected mill performance, with the a priori assumption that these few samples are representative of the entire deposit. Geometallurgical sampling is becoming more prevalent as a way to use many smaller samples to indicate the expected recovery as part of the Mineral Resource or Ore Reserve estimation.Recent increases in prices for iron ore, together with the potential to produce high iron and low contaminant concentrates, have resulted in a renewed interest in recovering magnetite from banded iron formation and other deposits.Geometallurgical evaluation of magnetite involves approaches to sample preparation, sample analysis and resource estimation that are different from the methods commonly used for haematite iron ore. The magnetite sampling protocol is specific to each deposit, and is typically designed around a specific metallurgical flow sheet.The sampling protocol will typically include the use of Davis Tube analysis. The Davis Tube is a bench-scale test that is used for determining the mass magnetic recovery from a small amount of sample ground to a specific size. The magnetic concentrate may then be analysed and together with the mass magnetic recovery, may be used to simulate the expected mill recovery.During resource modelling, the mass magnetic recoveries and concentrate grades may be assigned to a block model using regressions with other chemical constituents, or may be estimated directly. For estimation of the concentrate grades, a weighting can be applied to account for the different mass magnetic recoveries from each sample and the impact of these differences on the concentrate estimates.This paper presents an overview of the use of metallurgical test data in resource evaluation for magnetite deposits.

Jul 11, 2011

By S DeKruijff

The Mount Isa Mines Copper Mine in Mount Isa started producing copper in 1966. The Copper Mine gradually increased production rates to nearly six million tonnes per year. Over the last three years the mine has been in a gradual ramp down due to the reduction of primary ore sources and head grade. The majority of ore sources are predominantly in pillar retreat sequences bounded by multiple fill masses. There also a substantial lower grade resource delineated to the south of the main orebody. These remaining ore sources present significant engineering challenges to obtain a safe and cost-effective extraction. Stope designs have become increasingly complex and require additional engineering and operations input and analysis. This paper describes the major planning and operational challenges and issues associated with the stope design and extraction of an orebody in the later stages of mine life.

Jan 1, 2000

By Holla L

There exist several legislative provisions in N.S.W. which work together to control surface subsidence due to extraction of coal by underground methods. The important ones are the Coal Mining Act, Coal Mines Regulation Act, Mine Subsidence Compensation Act and Dams Safety Act. In addition, there are guidelines laid down by the Chief Inspector of Coal Mines for mining under and in the vicinity of tidal waters and the ocean. There are also conditions of coal mining leases and conditions of approvals given to undertake various methods of mining which stipulate further controls. The legislative provisions and relative controls are designed to minimise surface damage, ensure safety , of major public utilities, control- surface land use and compensate damage caused by subsidence as a result of coal mining operations. They aim at balanced and responsible development of our valuable coal resources consistent with adequate safeguards to surface improvements and natural features. The paper discusses in detail these legislative provisions and the mechanics of their operation with a view to emphasising the fact that underground coal mining operations are undertaken responsibly and in a planned and rational manner for the overall benefit of the community. Further, the paper aims to demonstrate the need for legislative measures and conditioning of mining operations to keep abreast of developments in the knowledge and skills of mining and subsidence engineers and continuing improvements in mining technologies. Likewise there is a need on the part of engineers and those associated with introduction of new technologies to appreciate the requirements and existence of legislative and other measures having a direct or indirect association with surface subsidence as a result of coal mining operation.

Jan 1, 1986

By A Fareth

Constructed between 1885 and 1891, the New Croton Aqueduct (NCA) in New York State is a 50 km long (31 mi) brick-lined tunnel conveying water from the Croton watershed north of New York City to distribution systems in the Bronx and Manhattan. Except at two siphons, the aqueduct operates as an open channel conduit from the New Croton Reservoir downstream 39 km (25 mi) to the Jerome Park Reservoir in the Bronx. The remaining 11 km (6 mi) is operated as a pressurised conduit and includes a major siphon, of circular cross-section, under the Harlem River. The aqueduct has a flow capacity of approximately 1100 million litres of water per day (13 m3/s or 290 million gallons per day) and supplies on average ten per cent of New York CityÆs drinking water. The CityÆs water supply system is operated and maintained by the New York City Department of Environmental Protection (NYCDEP). This paper covers the work done during the three main stages of the program to rehabilitate the entire NCA: inspections, design and rehabilitation. It also includes some of the more interesting structural findings of the original construction as well as documents and drawings from the NYCDEP archives. The rehabilitation program has been underway in phases since 1993, with inspections scheduled to minimise outages, allowing this strategic aqueduct to remain in service during critical seasonal periods. The open channel flow section of the aqueduct in the north is horseshoe shaped, with inside dimensions of 4.1 m (13.6 ft) in width and 4 m (13.5 ft) in height. The pressurised section is 3.7 m (12.3 ft) in diameter, and includes a 90 m (330 ft) deep siphon under the Harlem River. A total of 163 million bricks were used in the construction, enough to build a 48 km (30 mi) wall around Manhattan Island, 3 m (10 ft) thick and 15 m (50 ft) high.Between 1993 and 1997 a series of in-tunnel investigations were performed in the open channel portion of the NCA, consisting of field inspection, non-destructive geophysical testing, and coring of the brick liner. Between November 2004 and September 2005, a major inspection program was conducted to assess the condition of the 11 km (6 mi) long pressurised section and all shafts, headhouses and blow-off structures along the entire 50 km (31 mi) alignment. Inspection methods included using an underwater remote operated vehicle (ROV) equipped with sonar and cameras to inspect the deep siphon, fibre optics examinations of probe holes drilled through and beyond the brick lining, and core holes and geophysical inspections to assess properties of the liner and behind-the-liner materials. A water pressure and test grouting program was conducted to assess methods and expected grout takes for the rehabilitation work in the pressurised sections. The rehabilitation program is anticipated to be completed in 2010.

Jan 1, 2008

By O S. Maluleke

In some deposits valuable heavy mineral quality is poor due to increased mineral surface coatings from higher slimes and more competent sand orebodies. Mineral surface coating can include silica or aluminium rich clay minerals and iron based minerals that render the final product quality off-specification, in this case specifically ilmenite and zircon. Conventional physical beneficiation processes such as magnetic separation, electrostatic separation and gravity separation are not able to remove these surface coatings. Surface dependent separation techniques such as electrostatic separators are affected by these coatings which hinders the rejection of non-valuable mineral from product. Attrition scrubbing is the most commonly used technique to reduce surface coatings, using mechanically induced particle to particle interaction, abrasion and shearing.In many cases it is a challenge to measure the surface removal efficiency of these scrubbing units. Elemental analysis techniques (ie X-ray flourescence) (XRF) in a multi mineral environment are unable to measure surface impurity reduction with enough precision. Mineralogical analysis (in this case Qemscan®) has constraints in terms of sample preparation with highly coated particles being plucked out during block polishing. This paper suggests a combination of laboratory separation techniques coupled with elemental analysis to evaluate the surface removal efficiency. Three different types of feed materials were used to analyse the efficiency of surface removal using production attritioner scrubbers. This approach relates the downstream beneficiation plant’s expected performance with that of the attrition scrubber’s scrubbing efficiency.

Oct 5, 2011

By C Ward, U Mueller

Compositional geostatistics is an approach developed to ensure that the constant sum constraint induced by geochemical iron ore analysis is respected in estimation and simulation. Jack-knifing and cross-validation were used within this framework to compare the results from ordinary cokriging of the additive log ratio (alr) variables with those from conventional ordinary cokriging. Two methods were used to back-transform the alr estimates: the crude additive generalised logistic back transformation and numerical integration via Gauss-Hermite quadrature. Previous work on a blasthole data set from a Yilgarn iron ore mine showed promising results, with the Gauss-Hermite quadrature method returning results comparable to ordinary cokriging from the point of view of bias, but superior in that the constant sum constraint imposed by geochemistry of the data was honoured. Other practitioners have noted that the linear interpolation of non-linear log ratio transformations will result in biased results, and that this bias can be masked in a (grade control) setting where the spatial density is high. To test this assertion, the methodology has been extended to successively lower spatial density data sets. The results and applicability to routine iron estimation are discussed.CITATION:Ward, C and Mueller, U, 2013. Compositions, log ratios and bias - from grade control to resource definition, in Proceedings Iron Ore 2013 , pp 313-320 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 12, 2013

Instantaneous outbursts of coal and gas have occurred in Australia in the Sydney Coal Basin since 1895 and in the Bowen Coal Basin since 1954. The largest has been about 500 tonnes of coal and so their magnitude and character have not approached those experienced in some other countries. The occurrence of CO2 with some Australian cases provides some similarity with the worst affected areas in France and Poland.The proneness of seams depends on coal rank and seam gas composition, among other factors. The proneness of places depends on depth, structure, intrusion, tectonism and other factors affecting the geometric, physical and chemical uniformity as well as details of mining. As a phenomenon due to gas and stress, prevention can be achieved by relief of high gas and/or stress condition. Alternatively, controls can be applied to render mining safe for personnel. Unfortunately day-to-day prediction is not widely and reliably achieved to allow selective use of prevention or control. The initial rate of desorption is the most promising day-to-day indicator.Various researches include gas conditions and parameters, stress and failure conditions and parameters, coal variables and geological variables in relation to prediction, prevention and control. Some assistance in research may derive from study of analogous phenomena of instantaneous outbursts of salt and other rocks and gas. It is concluded that in the Sydney and Bowen Basins, any coals with less than 30 per cent Volatile Matter (VM) ash free dry (afd) at depths over 200 m could be prone. Proneness increases with depth, with lower volatile content, with geological disturbance including faulting, intrusion and recent tectonics, with increased CO2 in seam gas, with narrow work and with other factors. Much more research is needed.Unfortunately outbursts are needed too, to provide the research with realistic data. With the problems of mechanism and prediction still being unsolved much research remains to be done. No present aspect of research is satisfactorily resolved.

Jan 1, 1983

Utah Development Company operates a mine at Blackwater with a present annual production of 4 000 000 tonnes of coking coal. Mineable seams outcropping on the company's lease are part of the Permian Mammoth Rangal Coal Measures. Current operations are based pre- dominantly on the Main Lower seam. Coal quality variations occur along the seam strike, in the direction of seam dip, within the seam plies and in isolated anomalous areas. Raw coal of non-specification quality is washed to reduce ash and sulphur and to improve the free swelling index. Raw coal meeting specification quality is sent directly to product, by-passing the washplant. Careful attention to mining, coal preparation and product blending is necessary to ensure that the combined product meets specifications.

Jan 1, 1974

The Bendigo Goldfield is AustraliaÆs second largest goldfield, having produced 22 million ounces of gold between 1851 and 1954. Development of the modern decline mine, initially for underground exploration and bulk sampling, commenced in 1998. The project is targeting new reefs below and along from historic workings beneath the city of Bendigo. The major technical challenge for the project is the inability to solely use drill core gold assays to estimate the grade of reefs, due to the coarsegrained nature of gold mineralisation, known as the nugget effect. In 2002, a program of bulk sampling commenced, resulting in the development of factors for converting drill hole grades to in situ reef grades. In mid 2006 commercial production commenced following the construction of a 600 000 t/yr processing plant adjacent to the Kangaroo Flat Mine portal, with plant feed being derived from four reefs in the Sheepshead and Deborah lines of reef. In early 2007 it became clear that the initial ore reserves had been overestimated, leading to an immediate change of strategy from production to exploration. A cash conservation program was also put in place. Exploration refocused onto the more historically productive Garden Gully and New Chum lines of reef, whilst a new grade estimation tool based primarily on the visual assessment of drill core was implemented. Immediate exploration success occurred with the discovery of four reefs in the Garden Gully line in early 2007. Successful step-out drilling during the year led to the decision to undertake trial mining in Gill reef. Trial production commenced in June 2008 and includes the processing of discrete ore blocks and the introduction of selective mining techniques. This paper examines the steps that have been taken to refocus exploration and to gain confidence in new exploration results, particularly through the visual grade estimation technique and assessment of trial mining Gill reef on the Garden Gully line. In addition, project factors relating to human skills, community relationships and financial management in a dynamic external environment are also addressed.

Jan 1, 2009

By Leach T

The Tolukuma Gold Deposit is hosted by metamorphic and volcanic rocks, and igneous intrusions. Dilatant structures for the main veining appear to be provided by post-metamorphic flexure/faulting; syn-mineralisation tectonics is recognised from the en-echelon patterns of much of the veining. A SSE trending structure containing high grade mineralisation has acted as a major dilational zone within or at the contacts of porphyry intrusions. An ESE trend has controlled numerous dilational structures splaying eastward from the SSE vein structure and containing medium grade mineralisation.Early hydrothermal activity (Stage I) is represented by unmineralised, pyrite-rich brecciation and fracturing. Associated chloritic veining is indicative of single phase neutral-chloride fluids upwelling in relatively low fracture controlled nenneahility

Jan 1, 1993

By A Kindred

The Bogong Hydropower Development is a 140 MW high head power project currently under construction in Northern Victoria. The project is the final link in the Kiewa hydroelectricity scheme, which was originally constructed in the 1950s. Due to its location in the Alpine National Park, the waterway for the Bogong project must be located entirely underground. A series of shafts and tunnels is being constructed to transfer the water from the headworks at McKay Creek to the new power station located on the shores of Lake Guy in Bogong village. The difference in elevation between the headworks and the power station is greater than 420 m, which poses particular issues for the design and construction of the waterway. The purpose of this paper is to describe the design and construction planning aspects of the tunnelling and shaft excavation and lining works for the waterway. The tunnelling works includes 5.7 km of hard rock tunnel boring machine (TBM) driven tunnel, 1.1 km of drill and blast tunnel and two deep shafts. The tunnels and shafts are lined with a mixture of permanent rock bolts and shotcrete, concrete lining and steel lining. The viability of the Bogong Hydropower Development relies heavily on the ability of the TBM to excavate at high speed through the East Kiewa Grandiorites. Particular attention was given during the construction planning stage to understanding the excavation characteristics of this material, and designing a suitable hard rock TBM that would be capable of meeting the program requirements of the project.

Jan 1, 2008

The mostly submerged New Zealand sub-continent has a complex geological history and an active oceanographic regime that provides opportunities and challenges for offshore mineral exploration. Known deposits include polymetallic Fe-Mn nodules and crusts, polymetallic massive sulfides, phosphatic nodules, titanomagnetitie ironsands and placer gold deposits. Currently exploration interest is high with some 3.5 per cent of the EEZ under prospecting permit or application.   Article 76 of the UNCLOS convention allows coastal states to have sovereign rights over areas of the seafloor that are natural prolongations of the landmass that constitute submerged parts of the continental margin as extended continental shelf. New Zealand has substantial areas of elevated ridges and plateaux beyond the 200 M EEZ that form extended continental shelf. New Zealand has nearly completed a ten year, $44.4 M programme to define its outer extended continental shelf. New Zealand will lodge its outer limits of the extended continental shelf with the UN-appointed Commission on the Limits of the Continental Shelf in 2006, which if accepted, will enclose ~1.8 million km2 beyond the existing EEZ. Ocean Survey 20/20 is a follow-on marine mapping programme to underpin resource exploration and environmental management of the EEZ and extended continental shelf.

Jan 1, 2005

By D Clarke, R Simpson

The Main lode in the Anwia Gold deposit is difficult to interpret due partly to the fact that three separate grid and drill hole orientations exist over the area and partly due to a lack of understanding of the controls on the high-grade mineralisation. Scattered high gold grades and multiple veining orientations add to the confusion. Sectional interpretations of the lode are often misleading due to the multiple orientations of drilling. Initial attempts to define a high-grade constrained geological model were not successful due to the inability to establish any geological continuity that would hold together in three dimensions. As a consequence the initial geostatistical domaining for the Main lode at Anwia comprised a simple broad mineralised envelope split by the weathering profiles. Subsequently an analysis correlating subjective qualitative logging information with grade plus utilisation of LeapfrogTM software, together with extensive geological re-interpretation resulted in the definition of a coherent high-grade shoot within the Main lode. The resource was re-estimated including this new domain as a high-grade hard boundary. Estimations on both models were carried out using uniform conditioning, which is a recoverable resource estimation methodology that estimates tonnages and metal above a series of cut-offs for SMU (selective mining unit) sized blocks. This paper compares the tonnages and metal contents that are calculated from the two estimation runs, both at a zero cut-off and a series of higher cut-offs. The results confirm that the estimation methodology has been implemented correctly as the tonnage and metal content at zero cut-off is the same for both models. The resource tabulations and grade tonnage curves predicted by the two models highlight the differences that can occur at higher cut-offs when realistic high-grade domaining is implemented. The results also reinforce the point that recoverable resource models are intended to address selectivity issues and are not substitutes for good geological modelling. Recoverable resource techniques, such as uniform conditioning, will not correctly estimate high-grade zones that have not been explicitly modelled.

Jan 1, 2006

By B Zhao

Gas and coal dust, as potential harmful elements (PHEs) produced during mining, are considered two serious threats to the safe mining and the health of miners because of its explosive and pathogenic properties. To solve this problem, compound reagents enhanced water spraying technology was used to control the gas and coal dust in excavation working face in this study, and spray testing platform and wind tunnel were used to investigated the suppression effect for gas and coal dust. In addition, sink test, and agglomeration experiments were also used to analyse its suppression mechanism. Testing results show that the dust reduction efficiencies of compound reagents enhanced water spraying technology for four different particle sizes were 80 per cent, 91.43 per cent, 94.74 per cent and 94.46 per cent, and improved by 14 per cent, 10.86 per cent, 8.42 per cent and 4.25 per cent compared to water spraying. Moreover, the gas suppression efficiency also can be increased more than 20 per cent. Sink test, and agglomeration experiments results show that compound reagent improves the spreading efficiency of the liquid on the surface of the coal by changing its wettability, and this process can not only slow down the desorption rate of gas by forming a water-sealing effect in the coal surface indicated, but also promote the agglomeration of fine-grained coal dust.

Oct 12, 2022

By P Stoker

The need for quality assurance and quality control (QA/QC) in the sampling and assaying of minerals is fundamental to the reliability and confidence of a mineral resource estimate, reserve estimate and possibly profitability of a mine. In spite of this, QA/QC practices in the mining industry are commonly applied poorly, or misunderstood. As New Leaders, we should aim to correct the poor practices and become fully informed on appropriate procedures. This paper uses worked examples that show the usefulness and importance of best practice QA/QC procedures. Fundamentals of reviewing the performance of the laboratory by examining the results of client inserted standard reference material (standards), blank material and duplicate samples are discussed. To do this, three examples from Australian data sets have been used. For each example, simple and efficient plotting techniques are suggested with subsequent evaluations of each plot. The first case study compares the results of internal standards from a laboratory with blind standards (where the expected value is unknown to the laboratory) submitted by the client. It was demonstrated over time that the laboratory was unintentionally analysing the internal standards in a different manner to the remainder of the sample batch. In this example, not understanding the cause of a high negative laboratory bias could have led to poor understanding of the depositÆs grade and in the extreme a proposed mining operation may have reached operational stage with a subeconomic grade. The second case study discusses the quality of blank material submitted by a mining operation to monitor cross-contamination within the laboratory. The blank material contained background levels of the element under investigation. This created uncertainty in the assay results, which could have led to the need for additional assays and drilling programs. Finally, the third case study demonstrates the use of the relative paired differences (RPD) technique to cross-validate the results from duplicates and repeat analyses from two laboratories. The three examples given show either laboratory or operational error. If left undetected, each example could have had serious implications for the mineral resource estimate and ultimately, the mining operation. These examples are not isolated occurrences; poor QA/QC practices are an industry wide problem exacerbated by rapid staff turnover and increased contractor positions on-site. New Leaders must be equipped with a thorough grounding in QA/QC best practices to improve its application and confidence in the results of sample analysis.

Jan 1, 2009

The south-east Missouri cobalt-copper-lead-zinc district is the worldÆs largest lead producer and a significant producer of by-product zinc, copper, cobalt, silver and cadmium. Current production in the district comes from six or seven mines in the Viburnum Trend. Most ores in the Viburnum Trend are characterised by a small number of minerals with simple compositions. Portions of some orebodies contain ores that exhibit greater variations in mineralogy, and these include shale-hosted lead- copper ores, bornite ores and nickel-arsenic sulfide ores. Ore textures include both replacement and open space filling textures, and the paragenetic sequence for the ores is characterised by repetitive periods of deposition of all of the ore and gangue minerals. Ore microscopy is an effective tool for not only the identification of the minerals and textures shown by the ores, but also to determine the mineralogy and textures responsible for beneficiation problems. An interesting variety of sedimentary and structural ore controls have determined the locations of individual orebodies in the district. Based upon the positions of orebodies with respect to Precambrian ridges and knobs, together with areal patterns of mineral/metal zoning, it is interpreted that the ore fluids came from diverse directions to form the deposits in the district. It is concluded that the Old Lead Belt subdistrict was mineralised by fluids that flowed from the north-east and north-west, the Fredericktown area by fluids from the north-east, the Indian Creek subdistrict by fluids from the north-west and the Viburnum Trend by fluids from the north-west and west.

Jan 1, 2008

By D Thornton

Geologists use large data sets and spend many hours and much computing time modelling the distribution of minerals throughout a rock mass. Significant investments in drilling, assaying and quality assurance and quality control (QA/QC) are made before sophisticated geostatistical techniques are applied to the collected data. A large amount of research has been done in this field such that the ore control model is a reasonably accurate reflection of the mineral that is actually in the ground. However, after all this effort, the mining engineers then work just as diligently to blast the in situ rock mass to a particle size that can be efficiently handled and further reduced by downstream comminution processes. In open cut mines, this invariably requires large amounts of explosive energy that displaces the ore boundaries from where the geologists originally defined them. Failure to accurately account for blast movement will result in misclassification, whether that is ore to waste; low grade to high grade; sulfide to oxide; or other contaminates û collectively referred to as ore loss and dilution. The financial consequence of getting this wrong is substantial and not well quantified. This diminishes all of the good geological QA/QC done in defining the ore. This paper discusses various technologies used to physically measure blast-induced orebody movement and the difficulties in modelling this with a purely theoretical approach. Rock mass structure, blast energy, design and timing contours all have significant and interrelated effects on blast movement vectors. Measured blast movement has a large variance due to the uncertainly of many of the controlling parameters û arguably dominated by the heterogeneous nature of the rock mass. Although there have been significant advances in blast movement modelling capability in recent years, this unpredictable blast movement limits their use in the context of production ore control. Certainly, without physical field measurements, accurate predictions of movement are near impossible.Limitations of traditional surface markers in determining three-dimensional (3D) blast movement within the orebody are also reviewed, and advancements in accurately measuring these vectors within blasted ore discussed

Sep 26, 2011

By AUIMM AUIMM

Continuous Improvement The Council of the AusIMM should expedite the introduction of a continuous professional education policy along the lines of that to be proposed to you by David Pollard today. The Education and Accreditation Committee must continually review the training needs of the next generations of mining industry professionals. It should continue to demand and encourage the creation of the schools for the training of such people. The AusIMM could even put greater onus upon university researchers to accredit university post graduate degrees.

Jan 1, 1994

By B Cronin, M Gao, M F. Young

Fine grinding technology has become extremely important for Mount Isa Mines Limited in the last decade for flowsheet development for the McArthur River deposit and in rejuvenating the Lead-Zinc Concentrator at Mount Isa. Regrinding products with 80 per cent passing seven microns and 12 microns were required, respectively, for the McArthur River ore and the Lead-Zinc Concentrator at Mount Isa. Development of the ISAMILL, a horizontal stirred mill with a gross mill volume of 4000 litres (a net volume of 3000 litres), has been successful in delivering the required grinding product sizes with an energy consumption acceptable to a mining operation. The ISAMILL performance for processing both lead and zinc streams at Mount Isa is discussed in this paper, including the milling energy efficiency, the media wear and the size-by-size recovery data for one flotation process following the fine regrinding stage. The potential use of the ISAMILL technology at various phases of the mining cycle is also discussed.

Jan 1, 1998

By Y L. Ma, M Chen, W Bruckard

With the extensive exploitation and gradual depletion of high-grade copper reserves, the mining industry is paying more and more attention to the hydrometallurgical extraction of copper from lowgrade and arsenic bearing copper ores. Hydrometallurgical processing, such as heap leaching, column leaching and bioleaching, provide a viable alternative to the traditional pyrometallurgy due to its harmony with the environment, moderate capital investment, and low operating costs. However, the slow leaching kinetics of enargite (Cu3AsS4) and chalcopyrite (CuFeS2) remain problematic for commercial leaching practice. The formation mechanism and the nature of the passivating layers during leaching is still a matter of debate in hydrometallurgical research. In this study, the dissolution mechanism of enargite and chalcopyrite in sulfuric acid solution was investigated using a range of electrochemical and spectroscopic analysis methods. Electrochemical oxidation of enargite demonstrated an obvious passivation region from 500 to 750 mV (Ag/AgCl). The formed passivation film was found a n-type semiconductor behaviour, which is different from the original enargite with a p-type behaviour. The results of X-ray photoelectron spectroscopy (XPS) suggested that a nonstoichiometric film Cu(3−x)As(1−y)S4 (x>>y) accumulated on the electrode surface, which accounted for the obvious decrease in current density in the passive potential region. For chalcopyrite, three important potentials of 550, 680 and 730 mV which are related to the formation and dissolution of passivation film were observed based on the cyclic voltammetry (CV) and potentiodynamic polarisation. Raman and X-ray absorption near edge structure (XANES) spectra studies of the chalcopyrite electrodes after being treated under these three potentials indicated a metal-deficient sulfide of Cu1−xFe1−yS2 (y>>x) might be responsible for the passivation phenomenon. Hence, it is concluded that the passivation of enargite and chalcopyrite are similar which are caused by metaldeficient sulfide surfaces although the compositions of the metal-deficient sulfide are different.

Aug 24, 2022