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By J. G. Paterson, J. A. Meech

Abstract-Activated carbon is a strong adsorbent for amyl xanthate, capable of removing from solution up to a quarter of its own weight in xanthate. In selective flotation systems where depression is unstable, separation efficiency increases with activated carbon additions. The improvements observed are brought about by two mechanisms. First, by removing stripped and residual collector ions from solution, competition between depressant and xanthate is reduced and depression is stabilized. In addition, the texture of the froth phase at high pine oil concentrations is modified by activated carbon such that better drainage between the air bubbles takes place, alleviating the mechanical entrapment of depressed mineral particles. In treating a bulk copper/lead concentrate produced from GECO ore, selectively between galena and chalcopyrite is increased when activated carbon is used. Although the rate of flotation of galena is marginally lowered by activated carbon, a small extension in the duration of flotation allows the lead recovery to increase by 19% at the same recovery of copper. An addition rate of 0.75 kg/ton (1.5 lb/st) of bulk concentrate is suggested as optimum from this testwork. However, the actual level wed in the mill is dependent upon the residual concentrations of collector and frother in the bulk concentrate Pulp.

Jan 11, 1978

By Ying-Chu Hoh, Renato G. Bautista

The chemically based models previously developed to describe and predict the distribution coefficients and separation factors for several different single and multicomponent metal extraction systems are presented in a more general form in this paper. The degree of formation of the aqueous phase inorganic metal complexes, the extraction mechanism of the complexes, and the equilibrium constant for the extraction reaction are used in the development of the models. The concept has been successfully applied to extraction systems where the organic solvent extracts an ionic species and where the organic solvent extracts only the neutral species. In addition, a model to describe a system where the organic solvent is extracting several extractable species has been derived on the same basis

Jan 1, 1981

Capital, as represented by mineral resources, is being exhausted rapidly without possibility of identical replacement. The public must be discouraged from thinking-why worry about the bank balance so long as there are plenty of blank checks? Instead of each man, woman, and child being owners of a mineral capital of $89,000 as former Secretary Ickes once stated, they are really the guardians of a mineral reserve which, when harvested, cannot be reproduced. The proper use of this material is the basis of modern civilization and military power. The best American institutions cannot be maintained or transmitted to our children unless this trust is guarded. It is unfortunate that more attention has not been focused on the fact that this country is headed for a have-not status in the family of great nations if some- thing is not done to preserve its mineral heritage. It is the privilege of the United States now to champion and implement democracy because it is industrialized and can get at its raw materials. A high price is being paid every day in mineral depletion for the privilege. No one can eat his cake and have it too. The United States still must face world-wide economic competition and, perhaps, World War III. In the final analysis all wealth comes from the ground, whether plant, animal, or mineral. Value is in-

Jan 1, 1950

By L. Graydon Carpenter, Donald E. Garrett

Probably the largest single tungsten deposit in the U. S. is one that has yet to produce any tungsten; it is not even listed in tables showing U. S. reserves. This deposit is at Searles Lake, Calif., where the brine contains about 70 ppm WO3. Small though the concentration is, the amount of brine in the lake is so great that it is estimated at 170 million lb of WO3 (8.5 million units), equaling the total of all other known reserves in the U. S. This dry lake is located in the basin formed by the Argus and Slate ranges in the northeastern corner of the Mojave Desert (Fig. 1). It consists of a massive salt body some 35 sq miles in extent, varying in thickness from 0 to 120 ft and containing more than 3 billion tons of salt. A central section of about L. G. CARPENTER and D. E. GARRETT are with the Research Dept., American Potash & Chemical Corp., Trona, Calif. TP 47881. Manuscript, Nov. 4, 1958. AlME Trans., Vol. 214, 1959. 8 sq miles is exposed salt; the remaining area is overlain by mud. Except for the exposed sodium chloride (10 to 15 ft thick) the body consists of a very complex and heterogenous mixture of soluble crystals, containing at least eight major phases. It is only about 53 pct solid, the voids being occupied by a dense brine which is the raw material for two chemical companies operating in the valley.

Jan 3, 1959

By John Philip Zannaras

John Philip Zannaras (Registered Professional Engineer, Congress, Ariz.)- The authors show in their [Fig. 4] the cumulative results of grinding with two sizes of bails, one 30 mm and the other 20 mm. The Gaudin-Meloy probability for breakage for a single fall used by the authors in their paper is given by their [Eq. 6]. Another form of [Eq. 6] is given by Gaudin-Meloy in their paper as follows: [ ] From the definition of A given by Gaudin-Meloy it is obvious that A30 is greater than A., it therefore follows from the foregoing equation that according to the Gaudin-Meloy formula the probability of breakage for a single fall of all the balls in the 20-mm experiment was more than 2.25 times the probability of breakage in a single fall of all the 30-mm balls which is contradicted by the authors' experimental evidence in [Fig. 4] in which is shown that much more grinding took place with the 30-mm balls. In fact the authors present convincing evidence that the Gaudin-Meloy work is erroneous because their work is based only on a geometric configuration and on ambiguous and uncertain definition of A and disregards the fact that the distribution of fracture depends on other important and indispensable factors including the intensity of stress caused on the feed grain by the balls. That there is an immense and chaotic variation of stresses caused on the feed grains by the balls is shown by a formula, derived by this writer and published in 1955. The derivation of this formula is given in the Appendix of this discussion; it contains the variables in the operation of ball mills and is based on the science of mechanics-not on probabilities. [ ] where T is the unit stress in pounds per square inch produced by the moving load, h is the height in feet through which P has fallen, E is the modulus of elasticity of the rock, P is weight of one ball, and L is the size of the grain (assumed to be a cube of side L). It will be shown by this writer's formula that when a 30-mm ball strikes any size of feed grain it will cause 1.837 times higher stress than the 20-mm ball when striking the same size grain. It will be shown that when the 30-mm ball or the 20-mm ball strikes a feed grain of 0.1 mm it will cause 90 times more stress on the grain than when it strikes a 2-mm grain.

Jan 1, 1974

By AIME

AS the Petroleum Division rounds off the first quarter century since its evolution from technical committee status, there steps to the long line of notable men who have presided over its activities a young man, currently of Tulsa, one Herbert F. Beardmore by name. For one year, as Chairman for 1946, the Division will be his oyster. hi; baby, his responsibility. "Herb" Beardmore was born at Columbus, Ohio, Feb. 6, 1904, and lived there until he was thirteen. Then his family moved to Oklahoma City, and later sent him to the University of Oklahoma, where he graduated in 1925 with a B.S. in engineering geology. His final year in college was the first year in which a petroleum engineering course was taught at the school. Since his course of study so closely paralleled that of a petroleum engineer, he has frequently been spoken of as the first petroleum engineering graduate from the University of Oklahoma. Out of college he went to work as an oil-field roustabout in the Ranger, Texas, field for Jake L. Hamon. This work consisted of all manual labor phases of cable-tool operation and beam-pumping of oil wells. He moved in 1926 to Bartlesville, to become a gas engineer for the Indian Territory Illuminating Oil Co., where he was employed in gas-well drilling, gas production, and transportation, mostly in Osage County, Oklahoma.

Jan 1, 1946

By A. A. Burr, D. Caplan

IN carrying out experiments in metal-gas systems, it is often difficult to estimate how long a reaction period must be allowed for equilibration. This is especially true in systems for which the diffusion coefficient is not known. In an investigation of the Cr-O system, the necessary information was obtained in the way described subsequently. Two pieces of chromium sheet of different thicknesses were packed in mixed powders of chromium and Cr2O3 and sealed into an evacuated metal capsule by welding. Austenitic stainless steel proved suitable as a capsule material up to 1350°C and molybdenum at higher temperatures. The capsule then was heated at a specific temperature for a time sufficient to saturate with oxygen the thinner but not the thicker specimen. The time is readily estimated from a preliminary experiment if a sufficient thickness differential is chosen. Under these experimental conditions, the metal sheet is exposed to a partial pressure of oxygen equal to that of the dissociation pressure of the oxide and hence can become saturated with oxygen without developing any second phase. After cooling, both samples were analyzed for oxygen by the vacuum fusion technique. Assuming that the surface of the specimens is kept saturated with oxygen throughout the experiment, the diffusivity can be calculated by application of the appropriate solution to Fick's second law. This is most conveniently accomplished by use of a plot of mean fractional saturation (Cm-Co) / (Cs-Co) vs (Dt) ½/L as given by Darken,' where t is time, L the half-thickness of the sheet, and D the diffusion coefficient. Cm, the mean concentration at time t, is given by the oxygen percentage in the thicker specimen; Cs, the constant surface concentration, is the oxygen percentage in the thinner specimen; Co is the oxygen content of the original chromium sheet. (Cm-Co) / (Cs-Co) is calculated and the corresponding (Dt) ½/L is read from the graph and D thereby calculated. By performing the experiment at two temperatures and plotting log D vs 1/T, the D for any temperature is established. (The activation energy for diffusion may be obtained from the slope of the line.) Once D is known as a function of temperature, it is a simple matter to estimate the correct reaction time for experiments with single specimens at other temperatures by equating (Dt) ½/L to its value for effective saturation. Darken' points out that this is approximately unity. The solubility of oxygen in chromium, as determined from the thin samples at each temperature, proved to be approximately 0.03 pct at 1350°C and less at lower temperatures. Due to low solubility and to the known difficulties of the vacuum fusion method in this low range, the values obtained for D (5x10-0 sq cm per sec at 1350°C) are estimated to be correct only within an order of magnitude. Nevertheless, the method has proved useful in estimating reaction times. Its usefulness will be greater in metal-gas systems where the solubility is appreciable. A second function of the method is to permit the determination of diffusion coefficients in systems for which the conventional techniques are experimentally difficult or impossible.

Jan 1, 1956

By William P. Blake

The frequent association of apatite in layers in the midst of magnetic iron-ore is highly significant of a stratified and organic origin of both minerals. Usually the phosphate of lirne is more abundant

Jan 1, 1893

By W. F. James, Richard Murphy, S. N. Kesten, A. H. Lang

The paper is a summary of information on Canadian deposits of uranium and thorium up to the end of 1948, prepared by geologists of Eldorado Mining and Refining Ltd. and by the specialist on uranium deposits for the Geological Survey of Canada. The paper contains a history of Canadian uranium and thorium discoveries, a working classification of the deposits, fairly detailed descriptions of the Eldorado mine and of properties in northern Saskatchewan, and shorter accounts of several other discoveries.

Jan 2, 1950

The technique of hard facing can be a quick and economical means of prolonging wear-life of many metals, but maintenance personnel must first select the proper alloy from the hundred that are available. Even then, roper selection is effective only when it is properly applied by the welder. To complete the successful weld, several hints are offered:

Jan 4, 1978

By H. W. Turner

In addition to the deposits mentioned by Mr. Lindgren? the following may be noted: 1. In the " Dardanelles quadrangle," of the map of the U. S. Geological Survey, 3 miles NW. of Tower Peak, there is a considerable mass of quartzite, marble, and dark, fine-grained. gneiss. At the edge of the coarsely crystalline white marble, having a width of about 400 ft., is a white schistose rock, which,

Jan 1, 1904

By Andrew S. M’Creath

THE treatment which a steel receives, and the uses to which it may be applied, are frequently determined by the percentage of carbon which it contains; and especially is this the case in the different steel works in this country. The part which this element plays in the composition of steel is such an important one that a process for its accurate determination becomes an absolute necessity.

Jan 1, 1877

Because common salt, sodium chloride, is necessary to all animal and much plant life, it is probably the most widely used of all mineral commodities, except for water. Nevertheless, of the total salt consumed, only 7% is used for food, including animal food. Two-thirds of the total is used as chemical raw material, principally for making such basic chemicals as chlorine, caustic soda, and soda ash. Other uses are for road thawing (16%) and water softening. Some 162.5 million tons of salt were used, worldwide, in 1972 (Table 15.4F.1). Production is from bedded salt deposits, salt domes, and evaporation of brines, including solar evaporation of seawater. Production is worldwide from at least 20 countries, of which the United States, China, USSR, the United Kingdom, and West Germany are the leaders. Consumption increases about 7 % annually. Reserves are plentiful: Other important sodium salts are soda ash (sodium carbonate) and salt cake (sodium sulfate). Soda ash comes mainly from the Solvay process (70% ) , which uses salt, limestone, and ammonia as raw materials. A large and growing portion of United States production is from mining large bedded deposits of trona, a natural hydrated sodium carbonate and bicarbonate found in Wyoming, and from brine evaporation in California. Soda ash is used for glassmaking, phenol, soap, detergents, and bleaches. Half of the United States salt cake used is a byproduct from rayon manufacturing. The other half comes from brines and playa lakes in California, Texas, and Wyoming. Salt cake is used mainly for papermaking. ACKNOWLEDGMENT Appreciation is expressed to William B. Dickson, president, Salt Institute. [ ]

Jan 1, 1976

By G. L. Gates

The comments by George L. Gates are appropriate to the characteristics that we sought to feature in our study and they are appreciated by the authors. In our laboratory deposition tests the smoothness of the surface seemed to be more important than the type of surface. However, we also noted that even where very smooth glass, plastic or polished metal coupons were used, scale deposition still occurred though the rate varied. Much more information is needed, however, and new work to solve the mineral scale deposition problem by mechanical and chemical means is expected to continue.

By R. W. Smith

An amine used as a collector in a commercial flotation process is usually a rather impure substance. The differences in ionization constants and solubilities of various amines undoubtedly affect their collecting power or strength. This investigation explores some of the differences among several amines of similar (although not precisely the same) chain lengths. An attempt is made to relate the differences to both observed contact angle and Hallimond tube flotation behavior in quartz systems.

Jan 1, 1974

By D. B. Reger

DAVID B. REGER.-T Want to 'add that since this paper was prepared a well is now being; drilled it the location recommended do the last page. It was not, however, done at my instance; it was done at the instance of Dr. White, the State- Geologist of West Virginia, who has been trying for several years to induce the large oil and gas companies to make a test of some of these, deep sands in West Virginia and a well is now just being started in Wood County, right at this immediate

Jan 4, 1917

By R. A. Foos

During the radium boom in the early part of the twentieth century, the basic chemistry of uranium was fairly well defined. Uranium production has progressed from the status of a radium by-product to a very important industry. With the ever increasing need for more efficient and cheaper methods of processing uranium ores, new techniques are being developed. Since uranium and vanadium often occur together in nature, the latter element will also be considered. As production rates, costs, and certain aspects of uranium chemistry are still classified by the Atomic Energy Commission, these will not be discussed. Domestic uranium deposits, in general, are composed of the minerals carnotite, which contains hexavalent uranium, and to a lesser extent, pitchblende and uraninite, which contain tetravalent uranium. Carnotite also usually contains vanadium. The uranium and vanadium contents of these ores vary considerably. The ores currently processed on the Colorado Plateau assay from 0.2 to 0.4 pct U and from trace amounts to 5.0 pct V. On the other hand, the phosphate rock deposits of the southeastern U. S., from which uranium is also recovered, contain only about 0.01 to 0.02 pct; processing of the

Sep 1, 1956

Although the meeting of the Institute in St. Louis Will not occur until September, 1917, the committee in charge is already making attractive plans, and we append hereto a tentative skeleton program which will give some notion of the opportunities that will be offered: St. Louis is situated in the midst of. a district which contains not only a great many interesting examples of mining, but also all types of industrial manufacture of interest to members of the Institute, and it affords abundant opportunities to visit and see these plants. Further announcement will be made from time to time as the committee's plans take more permanent shape. .

Jan 2, 1917

By Hemendra N. Kalia

A method is proposed for the preliminary design of coal mine openings and pillars using existing design formulas. The suggested method incorporates geophysical and core logging techniques, as well as the structural properties of the rock. Some of the existing design equations have been simplified and are included. It is anticipated that the additional cost of rock mechanics tests and logging work will be more than offset by the increased coal recovery that does not jeopardize the safety of miners,

Jan 1, 1977

By William Loblowitz

A simplified system of flotation testing has been developed recently at the Bureau of Mineral Research of Rutgers University. The technique involves the known principle of skin flotation and can be used with minute quantities of sample and reagents in a beaker. A vessel containing the conditioned sample with added water and flotation reagents is held inclined and rotated slowly. Water-repellent particles come in contact with air and float on the surface of the liquid, while wettable particles are submerged. The float is poured off and filtered whereas the nonfloat remains in the beaker. The filtrate may be returned to repeat the process.

Jan 6, 1951