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By D. Harrington

TheRe has been, during the past year, a wealth of report data and discussion relating directly or indirectly to various phases of ventilation of metal mines, and many of the data are from foreign sources. The phase of the subject most generously accorded the attention of the technical press is that of cooling mine air, with much less attention to other fairly intimately associated features such as fan performance, friction factors, fires, mine gases, mine lighting, health of miners, and ventilation standards. Cooling Mine Air South Africa, with its very deep mining on the Rand and with fairly high working temperatures, 'contributes the most definite data on the subject of cooling mine air, and undoubtedly the most interesting issued are those from a paper by J. H. Dobson,' in which he gives a comprehensive review of the subject as gleaned largely by analyzing the data in three papers.2 Dr. Dobson's summation is decidedly interesting. In general it is recognized that the introducing into the mine and circulating to the working places of large volumes of pure air is the most effective method of giving deep, hot metal-mine workings reasonably efficient working conditions. A tabulation as to the cost of securing various amounts of cooling by circulating various volumes, from 230,000 to 760,000 cu. ft. per min., indicates that there are cost limits beyond which increase of quantity of air in circulation is impracticable, as the annual cost of circulating 230,000 cu. ft. of air per min. in a certain mine at a depth of

Jan 1, 1928

By B. P. Canning

In recent years much attention has been given to comminution theory and the design of crushing and grinding installations in large plants. The day of the small plant is not over, however, and we will attempt to analyze some cost aspects of conventional plant design, particular to their smallness. Small plants generally have the same design requirements as large plants, however, certain additional restraints are imposed which generally reduce efficiency and availability. The engineer must take particular note of these restraints in order to properly design crushing and grinding installations for these plants. Whatever equipment is selected for small plant crushing and grinding circuits, it is more costly on a per-ton capacity basis than for a large plant. Circuit Design Small crushing and grinding circuits of recent design usually are of one-line concept utilizing simplified flowsheets. This is the logical outcome of a cost evaluation excluding special considerations and is the basis of the circuit design discussion and cost evaluation which follows. Objections to the one-line concept have been voiced with arguments claiming little flexibility, low availability, higher disaster risk, etc., however, experience has proven these arguments not to be convincing. Equipment of sufficient capacity is available on the market for all normal applications up to the 4000 mtpd plant size here considered and the engineer has complete freedom of choice. Where separate treatment of ores is required, the single-line plant concept requires adequate ore storage be provided with facilities for clean-out between campaigns on one or the other ores. It is very difficult to justify parallel crushing and grinding sections for small plants as material handling is more difficult with small flows involved, and equipment costs become significantly higher. Cost Evaluation Criteria In order to evaluate the small plant comminution circuit on a cost-effectiveness basis, a test model is here established for a comparison basis. Although it is recognized that the parameters chosen will fit only certain metal mining applications, the cost trends should provide useful information for other applications. The test model used is a one-line comminution circuit which considers maximum space utilization in an all-enclosed plant. Plant feed is assumed to be 90 percent passing 12 in. with nominal maximum rock size

Jan 1, 1982

By P. D. Southgate

VIBRATION, both ultrasonic and sonic, can affect the course of a variety of metallurgical processes. Reports of work on this subject have appeared at intervals over the last twenty years and a thorough review has been made by Hiedemann,' who gives a full list of references. It has been established that both refinement of structure and outgassing of the melt can be produced in most metals with sufficiently intense vibration. Many of the experiments in this field have been carried out using alloys of direct commercial interest in production- type casting equipment. Here a different approach is adopted, and simple binary alloys which exhibit different types of structure are used to facilitate examination of the effects produced under well-controlled conditions. Results from this kind of experiment should enable the basis of larger scale experiments with similar types of materials to be better substantiated. The alloys selected for this work are: 1) aluminum of 99.2 pct purity, the principal impurity being iron, near 0.4 pct; 2) A1-1.8 pct Fe, which is near eutectic composition; 3) A1-4 pct Fe—the second phase, of composition FeAl3, forms distinct acicular crystals; and 4) A1-12 pct Si—although this is of eutectic composition, the silicon normally appears in the form of large plates. Experimental Method There are three practicable methods by which acoustic vibration can be transferred to liquid metals: a) vibration of the whole of the container; b) electromagnetic induction; and c) insertion of a vibrating probe into the liquid. Method c is chosen here, and a frequency of 8 kc per sec is used. The end of the probe is electrically heated so that the metal near it will be the last to solidify. This ensures that vibration is transmitted directly to the liquid metal without passing through any solidifying and pasty intermediate region, which would attenuate acoustic waves severely. In addition, the heating prevents solid metal adhering to the probe, with consequent detuning. The transducer assembly is shown in Fig. 1. A stack of Permendur laminations 30 cm long acts as a half-wave vibrator and a winding along its length carries polarizing and energizing currents. It is joined by a half-wave coupling bar to a mild steel exponential horn, which tapers from 3.8 to 1.1 cm diam. A stainless steel stub 3 cm in length is welded on the free end. The assembly is supported by a plate located at the node of the coupling bar. Acoustic radiation losses are minimized by allowing the free end of the transducer to protrude above the surface of the cooling water. The exponential horn serves the function of matching the acoustic output impedance of the transducer to the radiation resistance of the probe into the melt. Electrical drive is provided by a 1 kw generator. Measurements of probe vibration amplitude during melt treatment are obtained from a gramophone pick-up with the needle attached to the wide end of the horn. This device is calibrated with a microscope before use. Liquid aluminum is very actively erosive and solution of materials with which the molten metal comes into contactcauses difficulties. Erosion of the probes in particular can be severe since it is greatly accelerated by the vibration. Tests of various acous-

Jan 1, 1958

By R. W. Young, Arthur F. Taggart

The tests herein described are part of an extended series of expel<ments, performed by the authors together with J. F. McClelland and L. W. Bahney, on the reclamation of metallics from foundry and manufacturing-plant scrap. The most obstinate problem encountered was the proper cleaning of the metal. Introduction In the manufacture of brass and brass products the weight of the finished product leaving the plant is much less than the total weight of. copper and zinc entering. A small part of this discrepancy is due to the unavoidable oxidation of the metals in melting, but by far the largest part of the loss is in the form of metallic particles of copper,. zinc, and brass. These losses occur principally at three points in the process: (a) in the casting-shop ashes; (b) in the slags from furnaces melting scrap brass; (c) in material spilled on the floor throughout the manufacturing process. The amount of these products in some plants is nearly 100 tons per 24 hours. Casting-shop ashes contain the metal spilled from the crucibles during melting and pouring, and the metal included in the slags formed in the melting process. The ashes also contain pieces of broken crucibles with adhering metal; 20 to 30 per cent. of unburned coal is also present. The metal in casting-shop ashes contains clean pieces of zinc or copper ingots weighing 1 to 2 lb., jagged pieces of metal of all shapes ranging in size from several inches down to the finest dust, and shot and botryoidal shapes ranging in size from 2 or 3 in. down to 0.01 mm. or less in diameter. Slags from furnaces melting scrap brass contain metal in the form of small shot. Floor sweepings occur in all shapes: spirals, thin shavings, pins and pin-like pieces, wire, rods, and buffing-wheel dust are the commonest.

Jan 1, 1916

The North American Coal Corp. Increasing demand for coal, stimulated by the national energy shortage, and complicating and often conflicting, demands by government and ecology groups for better land reclamation methods continued to propel advances in surface mining technology during 1974. To meet current demands for coal (estimated at more than 700 million t for 1975 and 1.5 billion t in 19851, equipment manufacturers and coal operators concentrated on increasing the productivity of all surface mining equipment. The trend towards larger equipment, particularly in overburden removal, loading, and haulage machinery, prevailed during the year, notwithstanding the perennial debate over the economics and practicality of using large, inflexible equipment. Increasingly, the industry called on computers to monitor productivity and help design more efficient production systems

Jan 2, 1975

By R. P. Rothwell

Instruction by correspondence is certainly one of the most important and useful of modern educational methods. The paper on the " Scranton International Schools," by Prof. Stoek (Buffalo meeting, October, 1898),* gives an elaborate description of a single private enterprise in this direction, ignoring all others, and cannot be said to present a fair or impartial view of

Jan 1, 1900

By D. D. Pollock

Many constitution diagrams do not indicate the limits oJ solid solubility of the silver-rich solid solutions below 200°C. Thermoelectric measurements were employed to determine this limit in the nieighborhood of room temperature. The appearance of a second phase causes a discontinuity to occur in the tkevtrroelectric power as a function of cornposition at constant temperature and pressure. This discontinuity was employed to determine the limits of the silver-rich terzinal solid solutions of the Ag-A l, Ag-As, Ag- Bi, Ag--Ge, Ag-In, Ag-Pb, Ag-Sb, and Ag-Sn systenls at 30°C. CONSIDERABLE work has been done on the constitution of binary alloys of silver. The available data have been compiled by Hansen1 and Elliott.2 However, many of the binary diagrams do not show the limits of solid solubility of the silver-rich solutions below about 200° C. This work was undertaken in an attempt to extend these limits to the neighborhood of room temperature . PREPARATION OF ALLOYS All of the alloys were made with silver containing less than 0.014 pct (by weight) of impurities. The materials were weighed out into 225-g heats and melted in a high-frequency induction furnace. The indium, tin, and antimony alloys were melted in A1203 crucibles, under a boric anhydride cover, and were poured into split graphite finger molds. The aluminum, germanium, arsenic, lead, and bismuth alloys were melted in machined graphite crucibles; they were also covered with boric anhydride and poured into split graphite finger molds. The $-in.-diam ingots were heated to 750°C and were forged and hot-rolled down to 0.1 by 0.1 in. The wires were pickled in a 25 pct HNO3-75 pct H2O solution to remove any oxygen-rich surfaces. The wires were then annealed at 550°C for 2 hr in a dissociated ammonia atmosphere. They were then furnace-cooled for 20 hr to room temperature in this atmosphere. The wires were cold-drawn to 0.0808 in. diam. The finished wires were again annealed at 550°C in the same manner as in the first anneal. Thermoelectric Power. The thermoelectric power of a single specimen of each alloy was determined against pure silver which contained a maximum impurity content of 0.014 pct by weight. The wire specimens were straightened and then cleaned with ethyl alcohol. They were then reannealed in the same way as the finished wires to assure that any residual stress would be at a minimum level. Previous work has shown that the presence of small amounts of stress has the effect of decreasing the thermoelectric power. The alloy specimen was soldered to the pure silver wire to form the measuring junction. A standard set of copper leads was then soldered to the reference junctions of the thermocouple. These junctions were maintained in separate dewar flasks which contained finely shaved melting ice during the test. The thermal electromotive forces of the thermocouples were measured at four temperatures between 15° and 45°C. A known source of electromotive force was balanced against the output of the thermocouple until a null balance was reached. The data were then expressed in terms of the thermoelectric power at 30°C. The results were then converted to absolute thermoelectric power, s303.3 These data have an average error of less than ±0.2 pct. RESULTS AND DISCUSSION All of the experimental data are given in Table 11. Since the electromotive forces of the binary alloys of silver were determined against the pure silver from which they were made, the resultant thermoelectric powers are only a function of the intentionally added binary elements at the constant test temperatures. This provides a direct measure of the effects of the alloying elements. The absolute thermoelectric power of an alloy of silver is given4 by:

Jan 1, 1968

By McDowell Graves, Joseph Jensen, W. D. Goold, M. L. Gwin

During the present year the Santa Fe Springs field has proved to be the most important oil field under development in the United States. Its production will exceed that of any other field. Without it, production within the United States would have been almost in even balance with consumption. The field has forced to the fore and compelled, more than any other single factor, serious consideration of the need of conserving the gas resources of the State of California. It has also contributed much to the development of new drilling equipment and important features in petroleum engineering, and has required the development of a new cement for use in deep wells because of high temperatures. It is the only oil field in the country where wells 8000 ft. deep have become so common that they are no longer given special attention. The field covers a little less than 1400 acres of land. In it 196 producing deep-zone wells have already been drilled since August, 1928, and 224 wells are still drilling. More wells may be drilled. This indicates that probably more than 450 wells will be drilled in the present campaign. In hardly a year&apos;s time it has caused the outlay of nearly $50,000,000 for drilling, and within the year 1929 it will have returned practically an equal amount of revenue. In contrast to conditions during 1923, when this field was once before an important and disturbing factor, the California oil industry has not been forced to refinance to meet the situation presented by such a large production of oil. There has been practically no unit selling and no stock selling, nor any unnecessary development far beyond the limits of the field. Production is now about 275,000 bbl. per day and gives every promisc of remaining at this figure or increasing to nearly 300,000 bbl. Six months from now the field should still be capable of producing more than 200,000 bbl. per day. Obviously, the need for conserving gas that would be blown to the air, incident to the production of so large a volume of oil, represents a problem in conservation deserving of the most serious attention of the oil industry and of the State of California.

Jan 1, 1930

Future of State and Federal Oil Regulation. BY NORTHCUTT ELY (Trans , vol 118 2400 words) The Interstate Oil Compact, ratified by six states and Congress in 1935, replaced the petroleum code, invalidated with other codes by the Schechter decision This compact endeavors, first, to conserve reservoir energy of oil pools through substantially uniform conservation measures by the states, second, it recognizes the state rather than the Federal Government as possessing the necessary police power for that purpose, third, it establishes an interstate advisory commission, so that orderly production in one state is not penalized by uncontrolled production in another, fourth, Federal interests are recognized in the control of hot oil, regulation of imports and fact-finding forecasts of supply and demand by the Bureau of Mmes It is not as complete an instrument as proposed by the Federal Oil Conservation Board in 1932, but is workable, and will be effective in proportion to the support given it by the industry Three results may follow First, now that fear of Federal control has subsided, the industry may lose interest in the compact and let it fall to pieces, second, if vigorously supported by the industry, the compact can accomplish most of the conservation objectives sought by the Federal control measures now believed unconstitutional, third, if the Compact fails, Federal regulation is almost certain to be revived, and can probably be sustained in connection with neutrality legislation, regulation of interstate pipe lines, and coordination of Federal and state gasoline taxes Nearly every step toward governmental regulation has originated within the industry state proration, the Federal petroleum code, Federal control of imports, Federal control of hot oil are examples The Compact shows a trend toward coordination between the powers of the industry, the state government, and the Federal Government If this arrangement fails through lack of interest by the oil industry, the next step is likely to be absorption by the Federal Government of the other two factors involved in the situation

Jan 1, 1937

By Kalanadh V. S. Sastry, D. W. Fuerstenau

A locked-cycle balling procedure has been designed to simulate continuous, closed- circuit balling drum operation in the laboratory. By this method, it is possible to simulate the surging in green-ball production rate and circulating load that is experienced in industrial balling circuits. Through an investigation of the effect of feed rate on the stability of the locked-cycle, balling process, it was found that higher feed rates lead to increasing instability in the process. An analysis of the experimental ,results is presented and the utility of the locked-cycle experimental technique for evaluating the stability of an industrial balling drum operation is discussed.

Jan 1, 1976

By James P. Munroe

Appalling as has been the loss of life in the last 51 months, there is one slight compensation: no longer will there be in the world a cripple, in the old meaning of the term. Men handicapped by wounds or disease, there will be, unfortunately, and in numbers beyond what the world has known since the wars of Napoleon; but neither they nor the industries from which they were called off to war will be "crippled" in the sense in which both would have been had mankind not learned the lesson of conservation and come to understand that the most important field for such conservation is not in the forests and the mines but among men and women. From the beginning of the Great War, France, Great Britain, Belgium and most of the other Allies have studied the problem of restoring the soldiers and sailors injured through war to physical and economic efficiency; and from their experiences, especially from that of Canada, the United States has learned much. Consequently, our task of preparing for the return of our disabled men has been easier and, in some ways, more comprehensive than theirs. Complex as are the details of the machinery which the United States has set in motion to take care of the men injured by wounds or disease, the plan itself is simple. Taught by European experience, the Surgeon-General of the Army and the Bureau of Medicine and Surgery of the Navy have provided, on both sides of the Atlantic, every known surgical and medical facility for restoring the injured or diseased man to a physical condition as nearly normal as possible. While in the hospital in Prance or England, on the transport coming to America, and in the hospital here, the disabled man is incited in every way to believe in his future efficieney, to want to be a normal worker, to desire to retake his place in that society of workers from which he went, temporarily, to do the greater work of preserving civilization. Furthermore, since purposeful occupation is now regarded as an essential form of treatment with most men in the hospital, especially in the convalescing stage, many of these men will have been actually started on the road to earning before they are discharged from the army surgeon&apos;s care.

Jan 1, 1919

By E. K. Soper

It has been observed that where veins or other types of orebodies are intersected by cross faults, the continuation of the ore deposit below the fault is often of lower grade than that portion above the dislocation.&apos; In some mines, the reverse of these conditions has been noted, and the richest ore is found to occur in that portion of the vein beneath the fault intersection. Such instances seem to be less frequent than those where the richest ore is above the offset. The important and widespread influence of fault and vein intersections upon the localization of ore shoots is well known,2 but the factors that govern the position of the ore shoot relative to the fault intersection seem to be less clearly understood. The richest ore may be above or below the fault, or it may occur at the point of intersection, or there may be no change. Recent observations made by the writer in mines in Idaho and Montana suggested a possible explanation for the changes in the richness of ore below certain types of fault intersections. These observations have been supplemented by a study of the literature containing detailed descriptions of ore deposits at a large number of mines in North America. The results of these studies are presented herewith in the hope that they may lead to further discussion of this important phase of ore deposition. Relative Age oF Faults Faults which intersect veins and other ore deposits may be either pre-mineral or post-mineral in age—that is, they may be older or younger than the deposits which they intersect. Many veins are formed along

Jan 1, 1918

By D. M. Bondurant

AT the present time, the coal industry is greatly interested in any method or machine that will cut the cost of producing a ton of coal, while at the same time producing a product of quality and grade suitable to the customer. Comparatively new and, as yet, little known, auger mining is proving a profitable method of coal recovery. It may be used for the production of low-cost, high-quality coal with equal success from both the hard-to-mine seams, those with banded impurities and bad roof conditions, and the more easily mined seams as classified according to conventional mining methods. A number of units are now in operation and production information is available that should be of particular interest to coal operators and of general interest to anyone associated with the coal-mining industry. Auger mining refers to coal extraction with large size augers capable of drilling to great depths and having a high capacity. Consideration of the equipment and methods used in drilling an ordinary shot-hole will give a picture of auger mining on a smaller scale. At present, auger mining is used largely for recovery of coal from the highwall after strip mining becomes uneconomical because of the type and the thickness of the overburden which must be moved. Coal augers have many of the advantages of present continuous mining machines, along with many more. The four distinct operations of conventional mining-—cutting, drilling, shooting, and loading— are eliminated and replaced by the combined operation of boring and conveying of the coal. The coal recovery auger is an adaptation of the horizontal rock drill used for drilling shot-holes to shatter and loosen overburden in strip mining operations. During the war the Becker County Sand and Gravel Co. of Summersville, W. Va., experimented with drilling coal with 6 and 9-in. rock augers. The results led to the successive development of the 20, 24, 30 and the 36-in. machines, the latter having appeared in the coal fields within the past six months. Because of the great success of the smaller size

Jan 1, 1952

By O. Hall, V. P. Row

Diamond drilling has become a very important factor in mining. It is the most satisfactory method of obtaining proof of the existence of an orebody and of determining the character and extent of the body in measures where a core can be made. Large investments are based on the information obtained. The method of development, the mine and reduction plants, and subsidiary essentials established are often without other information. The Mond Nickel Co. has drilled about 50,000 ft. (15,240 m.) per yr. for sevéral years and has given considerable study to the question of improving the methods and of overcoming the limitations of this means of securing information. One of the main limitations of the diamond drill has been its inability to drill a straight hole. To depths of 1000 ft. (304 m.) the deflection is often not large but all holes tend to curve and take somewhat erratic courses. A hole running at a small angle to a fissure plane tends to run along the fissure. If the hole is at a large angle, the tendency is to penetrate the fissure plane at right angles. The face of the bit having one side in solid formation beyond the fissure, the other in the selvage of the fissure, tends to turn, the rods curving to the extent of their clearance in the hole. Usually rock measures have somewhat regular fissuring or strata and holes take somewhat similar courses, usually at right angles to the fissuring or strata. Excessive pressure or short or worn core barrels increase curvature. Slow speeds, correct feeds, sharp bits, and core barrels the full size of the bit, tend to decrease curvature but do not prevent it Curvature once started increases rapidly. The disappointments from crooked holes have been numerous. Discoveries have later been found to be on the properties of others. One Canadian company had a hole, supposedly discovering ore 300 ft. (91 m.) from old workings, unexpectedly turn in 8 ft. (2.4 m.) of wooden core from a timber in the old workings. In many cases the information secured by a curved hole is satisfactory, if it can be accurately surveyed. The inclination of the hole at any point

Jan 1, 1920

Jan 9, 1950

By J. Mazia, H. Rosenthal

An investigation has been made of residual stress in the head and body of caliber 0.30 cartridge cases. The head was divided into four ring-lie sections which were cut off by a jeweler&apos;s saw. Spring-out was measured after a radial cut had relieved the circumferential bending moment. The residual stress corresponding to the observed spring-out was calculated by formulas in which the computed stress was a function of wall thickness. All rings sprang open, indicating compressive stress on the inner wall and tensile stress on the outer wall. The production stress-relief anneal of 475 F. for 45 min. reduced the stress to almost half. The priming and crimping operation, however, again raised the stress, especially in the flange section. The dect of stress-relief heat treatments on residual stresses in the body of caliber 0.30 cartridge cases was investigated by the split-ring method. Although this method did not reveal any large stresses in the body, the neck before mouth anneal was found to contain a computed stress of 30,000 psi. at the surface. This value was reduced to 15,000 psi. in 120, 30, and 15 min. at 400, 475, and 500 F., respectively.

Jan 1, 1945

By M. S. King

In the design of foundations for large structures and of safe mine openings in rock, the results of laboratory and small-scale in-situ tests are often used to predict the behavior of the material as a whole. For reasons of simplicity in these analyses, the rock is usually treated as an ideally elastic, isotropic material. It has been observed, however, that most rocks are neither isotropic nor ideally elastic. This observation is particularly true for rocks subjected to low confining pressures. It is therefore necessary to investigate further the effects of anisotropy and nonlinearity on the mechanical behavior of rocks. When small differences in stress and strain only are involved, the rock may be treated as an elastic material. The elastic constants for such a material subjected to a particular confining pressure can be calculated from the classical theory of elasticity for different degrees of anisotropy. There are two experimental methods by which this can be done: first, from measurements of static stress-strain relationships; second, from elastic wave velocities measured in the rock. The former yields the static elastic constants, and the latter, the dynamic constants. The static constants will be equal in magnitude to the corresponding dynamic constants only if the rock is ideally elastic. Walsh and Brace1 have reviewed theoretical studies of the elasticity of rock considered as a material containing pores and cracks. They re- ported that the presence of sharp, narrow cavities at low confining pressures strongly influences the mechanical properties of a rock. A considerable reduction in magnitude of elastic moduli is associated with the presence of inhomogeneities such as cracks or joints. The elastic properties appear to approach those of the uncracked material in magnitude as the cavities are closed by higher pressures. Walsh and Brace

Jan 1, 1970

By Alexander B. Morris

In a recent paper on the intermittent injection of gas in gas-lift operations as opposed to continuous injection, Morgan Walker presented a comparative table showing the effect on oil and gas production from the same wells under the two methods of operation.&apos; This table carried a column showing the formational gas-oil ratios under each method, computed by deducting the volume of input gas from the volume of trap gas. During the entire spring and summer of 1928, the present writer had been engaged on some extensive test car tests of rich gas in Glenpool, seeking, primarily, for an explanation of the apparent loss of gasoline during the summer season between the field meters and the plant master meter. Tests at several of the field meters where the richest gas was obtained regularly failed to check with other tests on the same gas made farther along the line, and the difference was not made up by the quantity of drip gasoline collected between the points. In the course of these tests, the final outcome of which is immaterial to the present purpose, an attempt was made to construct a curve representing the relationship between gasoline content of the gas in gallons per thousand cubic feet and the shrinkage in the volume of gas treated as a result of removing the condensible fractions. Such a curve was made, expressed in units of gallons per thousand cubic feet on the abcissa and the ratio vapor volume to liquid volume on the ordinate. This curve is a rectangular hyperbola and shows that 3 gal. of gasoline taken from 1000 cu. ft. of raw gas as a vapor occupied much less space, per gallon, than did 1 gal. of gasoline taken from 1000 cu. ft. of another sample of gas. This is, in general, corroborated by converting to the same units the residue settlement curves prepared by the Tidal Oil Co. and by the Natural Gasoline Manufacturers Assn., though the three curves, when plotted together, occupy entirely different positions on the paper, as shown in Fig. 1. The bearing of all this on Mr. Walker&apos;s discussion of gas-lift is this: if the formational gas is to be computed by deducting the input gas from the trap gas, some correction must be made for the vapor volume

Jan 1, 1930

By M. B. Bever, A. B. Michael

The solidification of aluminum-rich aluminum-copper alloys was investigated for different solidification rates. The measured amounts of nonequilibrium eutectic were compared with the amounts calculated on the assumption of no diffusion in the solid. The morphology of the eutectic was studied and dendritic spacings were measured. Compositions of the cored primary solid solutions were determined by quantitative autoradiography after activation of the solute copper by neutron irradiation. CONSIDERABLE progress has been made in recent years toward an understanding of the solidification of metals. This is especially true for the factors involved in nucleation, the controlled growth of metal crystals from melts, and various aspects of the freezing of ingots and castings. Many features of the solidification process, however, are not understood adequately and much further work is required. In the research reported here the solidification of a series of aluminum-rich aluminum-copper alloys was investigated. Different degrees of deviation from the idealized case of equilibrium solidification were attained by varying the rate of solidification. Thermal analysis and microscopic examination were supplemented by lineal analysis and autoradiography. The latter required the use of radioactive tracers and was adapted to the quantitative determination on a microscale of concentrations of copper dissolved in aluminum. The tracers were produced in situ by activating the copper with neutrons. These techniques permitted a correlated interpretation of the temperature-time history, the amounts of nonequilibrium eutectic and the general morphology of the alloys, and yielded quantitative data on microsegregation. Nonequilibrium Solidification In the general case of the solidification of a solid solution in accordance with the phase diagram, the composition of the coexisting liquid and solid must change continuously. This change requires diffusion, which at best remains incomplete in the solid during solidification. The resulting inhomogeneity of the solid solution crystals is well-known as coring, dendritic segregation, or microsegregation. The generally accepted analysis of coring assumes that, 1—no diffusion occurs in the solid, 2—diffusion is complete in the liquid, and 3—the composition of the solid formed on cooling through any infinitesimal temperature interval is given by the solidus of the phase diagram. On this basis, In this equation m designates mass, x designates the concentration of solute and the subscripts L and S refer to the liquid and solid phases, respectively; the subscript o indicates the initial state, in which the liquid is identical with the entire system. Eq. 1 or its equivalent has been derived repeatedly&apos;-7 and an analogous equation, known as Rayleigh&apos;s equation, has been used for distillation. The assumptions on which Eq. 1 is based do not include an infinitely fast cooling rate as sometimes stated. In fact, Olsen and Hultgren %ave shown by experiment that very high solidification rates suppress coring, presumably by preventing diffusion in the liquid and by the effect undercooling has on the composition of the nucleus. Coring thus occurs at rates of cooling which are too fast for a close approach to equilibrium in the solid and too slow to suppress diffusion in the liquid and to cause marked undercooling. If the liquidus and solidus approximate straight lines, Eq. 1 simplifies to The fraction of liquid present at any temperature during nonequilibrium solidification can be calculated from Eqs. 1 or 2. By the lever relation it is

Jan 1, 1955

By John R. Spencer

A capillary tube variable volume cell is described, which has operated satisfactorily over a range of 100°F and 3,500 psi to 550°F and 1,500 psi. The cell contents are entirely visible over the length of the capillary with the exception of a space at the top amounting to three per cent of the total volume. Observations on the critical behavior of simple systems have been greatly facilitated by the apparatus, it being possible to establish the critical conditions for a particular mixture in the course of a day&apos;s run. INTRODUCTION Many types of apparatus have been designed for obtaining data on the phase relationships of hydrocarbon systems. Such apparatus can in general be subdivided into two classifications; (l), indirect measurement of phase volume, and (2), direct visual observation of phase volume, each of which has outstanding advantages and disadvantages. Indirect measurement of phase volume requires the use of rather elaborate apparatus including internal probes in which are located the device for determining the locus of the interface between phases. Such equipment is by its very nature costly, and is complex from the standpoint of operating technique. Probing techniques can be used, however, over wide ranges of temperature and pressure with a high degree of reproducibility. Apparatus for visual observation of phase behavior obviously has the advantage of enabling the experimenter to see exactly what takes place, but because the material to be tested is contained in a cell constructed of both metal and glass, is limited severely as to the temperature range of operation. Furthermore. the maximum pressure usually is limited by the choice of material used for sealing the glass to the metal, and by the strength of the glass itself. In the interest of increased efficiency of observation, as much of the cell as possible should be visible to the eye. Glass capillary tubes have been used successfully but have always given difficulty at the metal-to-glass seal. An apparatus has been devised to overcome the problems of sealing and resistance to temperature effects that have heretofore been the limiting factor with glass apparatus in the observation of phase volumes at elevated temperature and pressure. APPARATUS The objective which dictated the general arrangement of the apparatus (Figs. 1 and 2) was simplicity of operation. The air bath, A, was constructed of an iron framework to which was attached approximately one inch of glass wool bats which were covered on the outside with "Masonite." A roughly octagonal center piece was installed to provide forced circulation of the air by the fan, B, past the heaters, D, cell, F, and thermoregulator, C, respectively. The entire top of the box is removable to facilitate charging of the cell and to permit easy maintenance. Two windows are provided before and behind the cell to allow the operator to observe the contents against the background fluorescent light, E. The heaters,

Jan 1, 1951