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By Robert A. MacGregor

"Following several months of test work, water leaching in mined-out areas at Stanrock commenced on a production basis in February, 1963. A combination of fast high-pres-sure washing and rewashing of stopes on a predetermined cycle, and the intermittent sprinkling of low-grade heaps, using both fresh water and recirculated acid water, has proved most successful. There was also a correlation of daily sampling data points to a relationship between the leach water grade and the grade of the material being washed, the leaching time and the location along the dip. An increasing tolerance for uranium by the acid-producing bacteria is also indicated. A steady production rate of 10,000 to 12,000 lbs. of u.08 per month is being maintained, with an over-all mine water grade of 0.25 lb. per ton and a pH of 2.3."

Jan 1, 1966

By B. Mishra, W. A. Averill

"The application of various hydrometallurgical, pyrometallurgical and electrochemical processes in the extraction, purification and production of radioactive metals as well as the use of various materials, ego metals and alloys, ceramics, polymers, etc. in the process, construction and handling equipment in the nuclear industry has generated a large stockpile of radioactively contaminated waste material and scrap metal which can not be directly discarded, recycled or considered for long-term storage due to its volume and potential hazards, without the separation of radionuclides. This paper reviews the emerging methods that have been investigated and suggested for dealing with some of these wastes and scrap material.The separation technologies studied for the recovery of radioactive components from the pyrometallurgical and electrochemical processing wastes have been discussed in details with results from some of the recent theoretical and physical modeling work as well as the data obtained from the actual waste treatment. Specific processes shall be described in terms of its advantages and limitations. These emerging separation technologies are being considered by the US Department of Energy as alternatives for dealing with the issues of environmental management [EM] and decontamination and decommissioning [D&D].IntroductionThe high temperature carbothermic or metallothermic smelting reduction methods for metal production are associated with the generation of significant quantity of waste as slags, flue dusts, sludges, residues, effluent salts etc. Certain hydrometallurgical processes also generate lots of aqueous waste due to the inherent nature of the technique. Also, the gas-based reduction processes are not applicable to many stable metal compounds, such as alumina, titania, beryllia, lanthanide and actinide oxides, etc. due to thermodynamic considerations. All these methods cause substantial environmental hazard. There is a need to develop alternative processes which have low waste or ideally a ""zero-waste"" generation.Pyrochemical processes using molten salts provide a unique opportunity for the extraction and refining of many reactive and valuable metals either directly from the beneficiated ore (aluminum, beryllium, neodymium, plutonium, uranium, etc.) or from other process effluent that contain reactive metal compounds. The processes reduce metal compounds electrolytically (A12O 3 and BeCI2) on a carbon anode or by calciothermic reduction (Po, Nd). The by-product, in the latter case, is a calcium oxide saturated halide salt. The waste-treatment to recycle the halide has to be done as a separate step or stored as a contaminated waste. A successful separation technology can provide a new insight to the waste minimization strategy for the nuclear industry."

Jan 1, 1996

By Fred N. Kissell, Andrew B. Cecala

In This Chapter [Where methane is emitted at longwall faces Where methane accumulates at longwall faces Using the modified shearer-clearer to eliminate ventilation eddy zones Using a walkway curtain to reduce methane buildup during the headgate cutout Control of frictional ignitions and The best location for the methane monitor] The methane released along a longwall face represents only 10%–20% of the total methane emitted from the entire longwall panel. Nevertheless, in very gassy coal seams, this methane released at the face can pose a problem because the shearer is a ready ignition source. Preventing methane ignitions at longwall faces requires four actions. The first is to provide better ventilation around the shearer to eliminate the ventilation eddy zones at the drums where methane builds up. These eddy zones are eliminated by mounting additional water sprays on the shearer to direct air into them. The second action to prevent methane ignitions is to install a water spray behind each cutter bit and regularly replace worn bits. Water sprays behind each cutter bit act to quench the hot metal streak that follows a worn bit when it strikes rock. The third is to ensure that no ventilation eddy zones are inadvertently created by poor placement of water sprays. The fourth is to ensure that the methane monitor on the shearer is in the best location to detect methane accumulations. ADDRESSING METHANE ACCUMULATIONS AT LONGWALL FACES3 Cecala et al. [1985a, 1989] and Denk and Wirth [1991] studied methane emission and ventilation patterns at longwall faces to find where methane accumulations are most likely. Although not always the case, the major source of methane at longwall faces is usually the breakage of coal by the shearer. Stress-related fracturing of the coal seam at the face, called bumps or bounces, can cause the release of additional gas (Figure 4–1).

Jan 6, 2006

By Peter N. Holtham, Mary M. Ng

"Resistivity measurements of minerals in the laboratory are commonly made with a low DC voltage source. Common test voltages specified in the ASTM Standard D257 are 100, 250, 500, 1000, 2500, 5000, 10000 and 15000 V, however 100 and 500 V are the most frequently used. Resistivity results obtained in the laboratory have been used to infer the electrical behaviour of minerals undergoing electrostatic separation. However because the voltages employed in electrostatic separation in the plant are of the order of thousands of volts, typically greater than 15000 V, whether the laboratory results are applicable as a predictor of plant performance is a critical question. It is unclear whether resistivity values taken at a low voltage are characteristic of those seen in electrostatic separation, in which the minerals are exposed to a much higher voltage. No definitive answer could be found in the literature.In this work, the resistivities of zircon, rutile and ilmenite were measured in a corona field for the first time. The measurement principle was based on a technique developed to measure fly ash resistivity in electrostatic precipitators, however the test apparatus and findings are novel.Resistivities of rutile and zircon were found to be easy to measure. The values measured in a corona field were several orders of magnitude less than those obtained with a dc voltage of 100 V. Evidence of back corona was observed with zircon. When the voltage drop was greater than the sample layer could withstand a localised electrical stress developed, resulting in a voltage breakdown, at which point a sudden surge of corona current (back corona) was detected in the sample layer. Rutile, on the other hand, exposed to the same conditions as that of zircon (i.e. same temperature and applied voltage) did not exhibit any sign of back corona. Its resistivity across the range of test voltages (14 to 33 kV) remained fairly constant."

Jan 1, 2003

By Francisco Camus

El proceso de exploración en las campañas mineras es la primera fase del negocio y constituye una de los principales herramientas para su supervivencia, desarrollo y valorización de la industria. En este sentido, el presente texto señala la experiencia de Codelco en la exploración en Chile y su aplicación en Perú. Así, el conocimiento obtenido por Codelco realizado en el norte y centro de Chile, ha generado la formulación de modelos de exploración predictiva durantes los últimos diez años. Dichos modelos incorporaron el conocimiento logrado en el nivel de cada yacimiento individual, los entornos distritales y las franjas metalogénicas donde estos ocurren. En consecuencia, esta experiencia obtenida por Codelco y el reconocimiento de la continuidad en Chile, se extiende en el Perú y se presenta como una oportunidad de interés para el desarrollo de programas de exploración a futuro.

Sep 13, 2001

By Milson de Andrade Júnior

A Central Termoelétrica número 2 (CTE#2) possui três caldeiras de alta pressão que utilizam principalmente os combustíveis residuais dos processos siderúrgicos, com destaque para o gás de alto-forno (GAF), o qual está disponível em grande volume e com baixo custo. Como o GAF possui baixo valor calorífico, ele é enriquecido em duas misturadoras com gás de aciaria (GLD) e na ausência ou limitação deste, com gás natural (GN). A partir de 2014, devido a problemas com o gasômetro de GLD, passou-se a utilizar o GN com frequência para fazer o enriquecimento do GAF, o que gerava significativo impacto no custo do vapor devido o alto custo do GN. O sistema de injeção de GN nas misturadoras era controlado de forma manual e praticamente não acompanhava as variações no poder calorífico (PCI) do GAF. Percebeu-se que seria possível implementar um sistema de controle para as injeções que levasse em consideração o PCI do GAF, reduzindo o consumo de GN quando o PCI estivesse mais alto e aumentando o consumo quando o PCI estivesse mais baixo. Após a implementação deste sistema houve uma significativa redução no consumo médio de gás natural para enriquecimento do gás de alto-forno na CTE#2.

Aug 17, 2017

By Michael J. Castner

"INTRODUCTIONMultiple-seam mining is an ever growing concern for engineers and mine management in every portion of the mining industry and is especially true for coal mining operations. The goal of this report is to identify the location and severity of multiple-seam interactions, provide AMSS calculations performed on the worst of these locations, and follow up with a visual examination of the underground physical effects on the roof and ribs in the locations identified for analysis. Multiple-seam mining is increasingly being studied because:1. Multiple-seam mining can create a multitude of problems such as roof falls, pillar crushing, pillar failing, rib spalling, floor heave, and inundation of water, gas, or oxygen-deficient air that can disrupt mining operations and threaten the safety of the miners.2. Multiple-seam mining is becoming more prevalent due to the depletion of virgin coal reserves.Currently, coal mining in the United States has progressed to the point that a growing number of mining companies are operating in coal seams located above, below, and/or adjacent to previously mined out coal seams. As a result, the state and federal governments are enacting higher safety standards on mining operations. For example, in years past, pillars may have been properly designed to handle single seam interactions for a particular mine or mines; however, today, where mining is now being considered above or below a previously mined area, these loading conditions may not be adequate to handle the removal of additional seams above or below the previously mined reserve. Studies from 1981 estimated that two-thirds of the mineable coal reserves in the United States would be impacted by multiple-seam implications. Today, over three decades later, it is obvious that most of the remaining mineable coal reserve will be influenced by previously extracted seams. Thus, thefocus on multiple-seam mining interactions on current and future mining operations. In 2012, underground mining in the United States produced 342,287 thousand short tons of coal. Northern Appalachia accounted for over 30% (103,301 thousand short tons) of this total (U.S. Energy Information Administration, 2013). Rosebud Mining Company and Western Allegheny Energy (RMC and WAE) have a combined total of 23 actively producing underground mining operations and at least four new mines under or ready for development. All of these mines are located in coal seams (Upper and Lower Freeport; Upper, Middle, and Lower Kittanning) of northern Appalachia (Pennsylvania and Ohio). Currently, more than half of the RMC and WAE mines are dealing with multiple-seam interactions. Seven mines are undermining previously mined out coal seams, and five mines are overmining previously mined out coal seams. Also, between these companies, five mines have inner-seam sloping possibilities (2 completed, 3 planned), most of which will result in mining over or under previously mined areas."

Jan 1, 2015

By M. R. Geer

The cleaning of fine coal, particularly for metallurgical use, is receiving greater attention. An increase in the proportion of fine coal in the run-of-mine product has been created by changes in mining practice, and a concur-rent deterioration in the quality of the fines has occurred because of more widespread full-seam mining. These two factors, augmented by the depletion of premium beds of metallurgical coal in some areas and the resulting shift to "dirtier" beds, are providing the impetus for adoption of improved cleaning techniques. For example, froth flotation, which has been used for years in a few preparation plants, now is gaining more rapidly in acceptance. Similarly, the dense-medium cyclone, which is used widely in Europe for making difficult separations, recently has been introduced to the United States. Regardless of the cleaning process employed, the finer sizes of coal can be treated with maximum effectiveness only when they are removed from the run-of-mine product and treated separately. No present process can treat the full range of sizes together with complete effectiveness. Flotation is applicable only to the coal finer than a top size ranging between 14-and 48-mesh, and cyclones require removal of all material finer than 0.5 to 0.3 mm. from the feed. Thus, the trend toward more-effective cleaning of the fine coal imposes the attendant problem of fine screening. Whereas in the past there was little need to screen finer than about l/4-in., present developments indicate that fine screening will become increasingly prevalent.

Jan 1, 1960

By G. D. Markland

The Moose Mountain mine is located in a belt of Precambrian volcanic rocks situated 20 miles north of Sudbury, Ontario. It was the first iron mining operation in the Archean iron-formations of the Canadian Shield. The ore is believed to have been formed in an environment of active volcanism, being part of a pyroclastic and volcanic series where only the iron-formation and chert qualify as chemical sediments. The volcanic environment, subsequent regional tectonics and metamorphism produced orebodies which differ from the main sedimentary iron ranges of the world in such features as continuity, grade, structure and metallurgical characteristics. The orebodies occur as relatively small lenses which have been complexly folded, faulted and intruded by acidic and basic dykes.

Feb 1, 1966

By G. D. Markland

"The Moose Mountain mine is located in a belt of Precambrian volcanic rocks situated 20 miles north of Sudbury, Ontario. It was the first iron mining operation in the Archean iron-formations of the Canadian Shield.The ore is believed to have been formed in an environment of active volcanism, being part of a pyroclastic and volcanic series where only the iron-formation and chert qualify as chemical sediments. The volcanic environment, subsequent regional tectonics and metamorphism produced orebodies which differ from the main sedimentary iron ranges of the world in such features as continuity, grade, structure and metallurgical characteristics. The orebodies occur as relatively small lenses which have been complexly folded, faulted and intruded by acidic and basic dykesAlthough the basic mining and beneficiation methods are simple, detailed geological control in exploration, planning and operation has been necessary to apply detailed selective techniques to the large-scale open-pit methods necessary in profitable iron mining.The milling and pelletizing processes are sensitive to minor variations in ore grade, grain size, fabric and mineralogy. Although detailed correlations of geological information and mill performance are still not entirely satisfactory, general working relationships have been determined with simple testing procedures. These are of in-creasing use in forecasting production and in ore-blending processes.The application of geology to mining and milling operations at Moose Mountain represents a departure from general practice in iron ore operations."

Jan 1, 1966

By Ashraf M. Eid

Most research dealing with the problem of laterally loaded piles has been the response of individual piles subjected to lateral loads and/or bending moments. However, piles are seldom used individually but are normally constructed in clusters or groups. Little information is available of the effect of pile-soil-pile interaction (PSPI) on the performance of the group. This may be attributed to the difficulty of carrying out full-scale tests. Such tests are prohibitively expensive and require special installations to provide the required large lateral loads. The problem of laterally loaded single piles or pile groups involves the complexity of extending the theoretical solutions to the limits where the actual soil behaves nonlinearly. As the load increases, the elastic soil behavior cannot be adopted for design. Nonlinear soil behavior or the elasto-plastic behavior is evident. This research consists of experimental and theoretical models. The experimental work was conducted on models of free head pile groups in different configurations. The piles were in a sand formation and compared to the behavior of a single pile. The possible factors that influence the group behavior could be visualized. The experimental data was also compared to the widely used theoretical approaches to determine their adequacy. The analytical model makes use of the finite difference approach to calculate the soil non-linearity. A new approach equates the measured ground deflection and maximum bending moments of each row at every load level with the analytical model of single pile. This is the Deflection-Moment Fitting (DMF). The most suitable non-linear soil modulus modes and row contributions could thus be determined. Design of pile groups can be based on data pertaining to soil characteristics of the single pile. Results of the analysis were consistent with other approaches and proved to be adequate for design.

Jan 1, 2005

By Karl Gugel, Dante Garcia, Peter Czel, Eduardo Nunez, Joshua Morales, Boris Sullcahuaman

Real-time operational excellence is achieved through the seamless integration of various components. Key aspects include precise instrumentation, real-time data collection, data analytics, and an efficient optimization platform. Additionally, to ensure success, the real-time optimization platform must be incorporated into the site’s internal process control system (Nunez, 2022). This paper provides an overview of practical lessons and best practices for autogenous (AG), semi-autogenous (SAG), and ball mill (BM) grinding. It highlights the implementation of advanced instrumentation, specifically vibration sensors on the rotating mill shell. The paper also delves into the application of advanced analytics necessary for generating new measurements that accurately represent real-time grinding activity in the mill. These Advanced Analytics Measurements (AAM) are compared with well-known grinding curves to determine the optimal grinding point. The discussion focuses on key industry opportunities using real-time mill shell vibration results to derive new correlations and optimize the grinding process.

Feb 1, 2025

By H. R. Babitzke

The purpose of this investigation was to develop an alloy of columbium for use at high temperatures and for nuclear applications. The properties of possible alloys were determined, and the more promising ones were selected for further improvement. Criteria for selection were machinability, hardness, workability, tensile strength, and oxidation resistance. Thirteen 100-gram ingots, ranging from 100 percent columbium to 100 percent vanadium, were prepared and subjected to various tests. Also included for comparison were zirconium and the zirconium alloy, zircaloy-2. Test results showed that a columbium alloy, containing 10 atomic percent vanadium merits further development. Besides being workable at room temperature, the columbium-10 atomic percent vanadium alloy has oxidation resistance superior to the other alloys of the series and is also superior to zirconium or zircaloy-2. The latter two materials have comparable neutron-absorption cross sections. The strength and hardness values of the alloys tested were found to increase with increasing vanadium content, reaching a maximum at 50 atomic percent vanadium and decreasing with further increase in vanadium. This behavior is typical of binary alloys wherein each element will retain any proportion of the other in solid solution. INTRODUCTION There is an increasing need for alloys for service at high temperatures. Since current world reserves of columbium metal approximate 1,500,000 tons (1),4 this metal is now readily available. Columbium can ties; be considered a practical base material for high-temperature alloys required in nuclear reactors and in aircraft and space vehicles. General requirements chosen are: (1) Workability, (2) satisfactory mechanical properties at temperatures approaching 1,000° C., and (3) resistance to oxidation at such temperatures.

Jan 1, 1962

By S. Banisi, H. R. Iran-Manesh, M. R. Shayestefar, H. Shekarchyan

"Flotation circuit of the Sarcheshmeh copper mine processes 41,000 t/d of ore at 0.9% Cu. Chalcopyrite and chalcocite are the main copper bearing minerals which are concentrated in three stages of roughing, cleaning and recleaning. Due to major changes in the reagent addition regime, make-up balls combination, and throughput to the primary mills an increase of 2.6% (from 87.2% to 89.8%) in the sulfide copper recovery was obtained during a period of six years. In order to investigate a rather large variation of monthly recovery (i.e., from 89.0 to 91.2%) of the plant after implementation of the changes, a study was undertaken to trace mineralogically possible causes of such a behavior. During a five-month period, monthly composite samples of feed and tailings of the flotation circuit were taken. At the first stage, the polished sample preparation method and the mineral counting procedure were optimized through a detailed study. Liberation degrees and types of locking of valuable minerals in both streams were determined in three size intervals of +75, +38 and –38 microns. It was found that for both recovery levels (i.e., 89% and 91.2%), there was no significant difference in the liberation degrees of valuable minerals in the flotation feed; the average liberation degree was 57.1% with a standard deviation of 3.1%. On the other hand, in the case of high recovery level (i.e., 91.2%) there was a reduction of 15% in the amount of free valuable minerals in the tailings stream. The highest reduction was found for the -38 micron size range in particular for chalcocite. It was concluded that compared to the grinding circuit the change in the flotation circuit had the significant effect on the plant recovery increase.INTRODUCTIONThe Sarcheshmeh copper ore body contains 1 billion tonnes averaging 0.90 % copper and 0.03 % molybdenum. It is located southeast of Iran and currently processes 41,000 t/d of ore. The concentrator has been in operation since 1982. Last year, the concentrator produced 130,000 tonnes of copper and 4,000 tonnes of molybednite concentrate. An expansion to the plant which will increase the throughput by 50% is under construction and will be effective in 2003.After three stages of crushing, the ore with a F80 of 12.7 mm is fed to 8 parallel ball mills in closed circuit with cyclones to produce a product 70% finer than 75 microns. The concentrate of the first stage of flotation is reground and the tailings constitute the main component of the plant final tailings. A concentrate with an average grade of 30.5% Cu is obtained after cleaning and re-cleaning stages. At the present time, the average sulfide copper recovery of the plant is 89.8% which varies depending on the operating conditions and ore type."

Jan 1, 2003

By Lyden, Joseph P.

THE Picher Mining Field, fig. 1, which lies between Baxter Springs, Kansas, and Commerce, Okla., is the most intensely mineralized and the largest zinc-lead ore producing area in the Tri-State District of Missouri, Kansas, and Oklahoma. It has a vast lateral extent of underground workings that is unequaled for the observation of the geology of zinc-lead ore bodies in sedimentary horizons; and thousands of churn drill holes in the unmined areas supplement the underground observations with useful data for the interpretation of the geology. This paper is confined to the ore deposits of the Picher mining field. The reader is referred to the bibliography for the general geology of the Tri-State district which has been ably covered by many geologists. The writer was co-author of several publications on the Tri-State district.- This paper is necessarily a repetition of parts of those publications but contains a few changes and additions on the deposition of the minerals. The parts of this paper concerning mineralization maps and pipe slump-structures are not covered in the above publications.

Jan 1, 1950

By J Loeb, J Dampney, P Cameron

Optimisation of Blast Design and Execution must be done right the first time. It is too late after the ore is broken. Consequences of poor design and execution negatively affect productivity from load and haul through the primary crusher to processing and hence reduce mine site profits. Harnessing and utilising ‘big data’ from geology, geometallurgy, drill hole location, powder loading, blast timing, blast movement and fragmentation to close the loop in blast design and optimise the blast increases productivity across the entire value chain from Mine to Mill. As the internet of things and artificial intelligence increases the quantity of data available, being able to capture and utilise this data to advantage is a challenge. Recent advances in software and hardware together with the increased power of cloud computing allows engineers to close the blasting loop to increase mine site productivity. Numerous case studies over the years detail significant gains from implementing the innovative technologies available to Mine to Mill projects. The opportunity is available for all members of the multi-discipline teams at each mine site to actively ensure productivity improvements are realised and maintained not only in their area, or silo of responsibility but across the entire mine site. This paper refers to recent case studies which outline how significant improvements in productivity are available to all mining operations to increase mine site profitability and dividends to shareholders.

Jun 22, 2022

By Terry J. Close

In 1986 and 1987, at the request of the U.S. Bureau of Land Management, U.S. Bureau of Mines personnel studied 7,040 acres of the 7,240-acre Sheep Mountain Wilderness Study Area (OR-006-003) in order to evaluate its identified mineral resources. The area studied is along the divide between the Snake River and Pine Creek about 1.5 mi south of the village of Oxbow in Baker County, OR. No mineral resources or mineral-related activities were identified in the Sheep Mountain study area. The basalt covering most of the study area has no known mineralized sites. However, it contains common agate and opal that is of limited interest to mineral collectors. This basalt (stone) could be used locally as construction material (crushed stone or fill); however, suitable material is wide spread in the region and more accessible to possible markets.

Jan 1, 1987

By T Tan, C P. Holmes, C E. Hartford

Transportation of iron ore from the mine to the plant is critical to business success. Ore from the mine may have to be transported across states, countries and even continents to get to the processing plant or export facilities, and ultimately to the client. Numerous transportation steps may result in potential logistical difficulties. Companies are continually seeking ways to increase production rates, decrease delivery times and reduce operating costs. Transportation cost is a major component of the total cost of mining iron ore and therefore requires effective use of transport systems.Bottlenecks in iron ore transport systems, due to material handling issues, can result in loss in profit in the order of millions of dollars per hour. Bottlenecks can be seen anywhere in the transport system where the desired flow rate cannot be achieved. These bottlenecks occur for various reasons such as increasing throughput in a transport system originally designed for a lower throughput resulting in plugged transfer chutes, changing material characteristics (eg finer material, increased moisture content), changing to a new type of material or blend that again alters handleability, or changes in operational philosophy due to equipment availability or process utilisation.Stockpiles may have limited live capacity such that an adequate amount of ore may not be readily reclaimed when required (eg to fill a complete train’s railcars). In bins and hoppers, material may discharge through a central flow channel resulting in the formation of a stable rathole, which can then collapse causing material to flood the downstream system and cause significant downtime for clean-up (eg railcars beneath train load outs). In transfer chutes, bottlenecks can be caused by pluggages or downtime required for the change-out of liners due to excessive wear. In ship loading, long settling or de-aeration time, or material exceeding its transportable moisture limit (TML) may result in further bottlenecks. These bottlenecks all have associated costs because of the need to address their causes and because of the lost opportunities for throughput.This paper will discuss how bulk material technology and proper understanding of material flow characteristics can be applied to mitigate bottlenecks. It will discuss how to predict potential bottleneck locations through a scientific method of analysis and evaluation to determine if an increase in throughput of an existing transport system is possible, as well as whether or not a new material will flow reliably through an existing system.CITATION:Hartford, C E, Holmes, C P and Tan, T, 2015. De-bottlenecking iron ore transportation from mine to plant, in Proceedings Iron Ore 2015, pp 393–398 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By Euler De Souza

Backfilling in Canadian mines has been practised for close to 100 years and evidence anticipates the application of mine fill technology at an increasing rate during the foreseeable future. The evolution of backfill technology is closely related to the advancement of modern mining methods and the development of new backfill technology continues to evolve. The authors, after conducting extensive surveys of backfill practices in underground mines across Canada, have concluded that, because backfill operations employ large quantities of cement and experience large costs associated both with backfilling practice and cement use, opportunities exist for reducing backfill energy costs and enhancing the application of alternative cementing agents in backfill. Consequently, the authors have developed an alternate, equally effective and lower cost binder agent replacement for cement, and incorporated waste glass into the development of a lower cost backfill (glassfill). This paper presents the results of two design stages associated with the development of glassfill: strength development and flow performance. The advancement of this technology has reached a stage that should promote industrial implementation within the Canadian mining industry. A number of Canadian mining operations exhibit potential for plant optimization through possible binder source replacement, and might thus realize associated reductions in backfill and energy costs.

Apr 1, 2005

By J. A. Venter, M. K. G. Vermaak

There are practical indications that flotation recovery of palladium bismuth tellurides is poor. This work tested whether this can be caused by a lack of interaction of the collector with the telluride. Impedance measurements, voltammetry and Raman spectroscopy were performed to determine the interaction of dithiocarbonate collectors (KEX) with Pd-Bi-Te. Impedance measurements showed lower capacitance values in solutions containing KEX indicating the formation of a continuous surface layer. Anodic and cathodic polarization diagrams show the mixed potential tobe higher than the reversible potential of the xanthate-dixanthogen equilibrium reaction; hence the formation of dixanthogen on the surface is possible. Electrochemically controlled in situ Raman spectroscopy did indicate the presence of bulk diethyl dixanthogen on the surface. Raman spectroscopy has confirmed the co-presence of xanthate with dixanthogen, indicating that xanthate retains its molecular integrity when it adsorbs on the surface of the Pd-Bi-Te. As a result, the mineral surface is expected to be hydrophobic and a lack of collector interaction with the mineral is not the reason for low PGM recoveries experienced. Keywords: Raman spectroscopy; Pd-Bi-Te; ethyl xanthate; platinum flotation; Great Dyke; Pd-bearing bismutho-tellurides and moncheite.

Jan 1, 2004