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By John Ward Smith

The potential economic value of oil shale depends on the products from thermal degradation of the rock, because no other practical method for producing valuable material from oil shale has been found. Detailed study of thermal degradation behavior can aid in characterizing oil shales and their deposits and in evaluating oil-shale processing methods, Numerous publications describe various pyrolysis properties of oil shales (see surveys 3, 9, 11 and articles 1, 2, 4-8, 10, 12),4 but they do not describe a generally applicable analytical procedure for detailed evaluation of thermal degradation products. The analytical method presented here for such evaluations is designed to provide for: 1. Control of retorting conditions--temperature, heating, rate, reaction atmosphere--plus some control over retort pressure and carrier-gas flow, 2. Precise direct gravimetric measurement of the thermal degradation products--oil, water, gas, and spent charge (residue after thermal treatment of the charge). 3. Samples of all products. 4. Determination of the identities and amounts of gaseous compounds produced. 5. Elemental analysis and gross heating value of all products. 6. Determination of the distribution in the retorting products of the elements present in the original samples.

Jan 1, 1962

By Gale D. C, Giles D. E, James Parker A

A zinc-lead-iron sulphide concentrate from McArthur River can be leached at atmospheric pressure in aqueous solutions with HCI, FeCl3, CuCI2, HCl/02 HC1/02/ CuCI2, Cl2, and CI2/CuCI2 to extract >98 per cent zinc, >90 per cent silver, and <15 per cent iron in 1-7 h at 95°. Galena is more reactive than sphalerite and is converted to lead chloride. Except for leaching with HCI, elemental sulphur is the the main by-product of the leach with little or no sulphate ion detected. The rates and products of these reactions are compared. It is recommended that aqueous slurries of the concentrate (50 per cent w/v) are leached at atmospheric pressure with Cl2 in the presence of copper(II) chloride, which accelerates the extraction of zinc. Hydrochloric acid is a by-product which is consumed bYJeaction with fresh concentrate in air at 60°. Copper is subsequently stripped from the leach solution and recycled by reaction with fresh concentrate at 100°. The separation, recovery, and electrolysis of zinc and lead chloride is outlined since this process would produce Cl2 gas which can be recycled and used directly in the leaching stage.

Jan 1, 1976

By P. Fredriksson, S. Seetharaman

In the ladle refining process, the ?FeO?-content of the ladle slag is of great importance in the chemistry as well as the energetics of the process. An optimization of the process requires an accurate knowledge of the thermodynamic activities of ?FeO? in the ladle slags. Due to the discrepancies in the existing data, renewed attempts are being made at the Royal Institute of Technology to generate reliable data for binary, ternary and multi component slags containing ?FeO? at steelmaking temperatures. In order to measure the activities of ?FeO? in the slags, a gas equilibration technique was employed in the present work. The slags, kept in Pt-crucibles, were equilibrated with a CO-CO2-Ar gas mixture and quenched after equilibration. The chemical composition of the slag was analyszed. From a knowledge of the thermodynamics of Fe-Pt system, the ?FeO? activities in the slag could be evaluated. The results of the present studies, together with other literature values, were optimized in the slag software, THERMOSLAG® developed in the Royal Institute of Technology, Sweden. The results of the optimization are presented. Model calculations were performed with the KTH slag software, THERMOSLAG®, by using plant data from OVAKO Steel, Hofors, Sweden. It was found that oxygen estimations in the metal from the ?FeO? analyses of slags, obtained by conventional sampling and analysis methods, where less reliable. Estimation of the oxygen levels utilizing the sulphur partition between the slag and the metal were carried out using the THERMOSLAG® software. Reasonable estimations of the oxygen contents in the metal confirmed that this could be a very useful tool for the plant operator. Keywords: ladle, thermodynamics, slags, ?FeO?, experimentation, modelling, sulphur partition

Jan 1, 2004

By James C. Ray

DURING the summer of 1931, I spent four months in a study of the Willow Creek district, Alaska. This work was part of a general investigation of the territory contiguous to the route of the Government- owned Alaska Railroad. It was conducted by the U. S. Geological Survey to determine the real and potential merits of the mineral deposits, to stimulate development of them, and thus to increase the traffic on the Alaska Railroad.

Jan 1, 1932

By F. J. Perzak

The Bureau of Mines conducted a flammability study of plastic ventilation ducts. Six rigid 16-in-diam fiberglass-reinforced plastic ducts from five manufacturers were examined using laboratory-scale, large-scale, and full-scale fire tests. The laboratory-scale tests included the American Society for Testing and Materials E162 radiant panel test, the E2863 oxygen index test, and the standardized small-scale flammability test (S3FT) developed by the Mine Safety and Health Administration (MSHA), U.S. Department of Labor, and replicated by the Bureau of Mines. Ten-foot lengths of the same ducts were also subjected to a large-scale vertical fire test, and 20-to 30-ft lengths were tested in a full-scale in-mine fire test at the Bureau's Lake Lynn Laboratory mine. The data from the laboratory-scale radiant panel test and oxygen index test indicated that the ducts were fire-resistant, However, five of the six ducts failed the S3FT and vertical fire tests, and four of the ducts failed the full-scale in-mine tests with flame propagation rates that ranged from 3 to 10 ft/min. The results indicate the need for improved fire-resistant plastic ducts. The good agreement between the S3FT re-sults and the vertical and full-scale tests show that the S3FT provides a good indication of the flammability of fiberglass-reinforced plastic ducting under realistic fire conditions.

Jan 1, 1987

By F. V. Antonio, R. S. Pizarro

Masbate Gold Mines, dormant since WWI I, are now back in operation. The ore treatment plant incorporates carbon-in-pulp processing, utilized because of the ready availability of coconut shell charcoal in the Philippines and the high clay content of the ore. A detailed description of the plant, including the surprisingly fast and efficient alcohol stripping facility is presented. Operating data for the plant is provided together with an interesting performance evaluation of mechanical versus air- lift agitated leach tanks.

Jan 1, 1981

By R. G. Henley

Mount Isa copper concentrate was combusted in a laminar-flow furnace. The conditions simulated those likely to be encountered in flames in flash smelters of the Outokumpu (air as oxidant) and INCO (oxygen as oxidant) types. The range of conditions studied was as follows: T 400-1400°C, 02 0-100%, SO2 0-95% for residence times up to 0.23 s. The distribution of sulfur, arsenic and lead between the particles and the gas phase was studied. Combustion was very rapid provided the concentrate was adequately dispersed, i.e., no agglomerates. The importance of the latter is discussed. It was possible to oxidize 80% of the sulfur present in the con¬centrate after only 0.1 s reaction time at 1000°C in an atmosphere contain¬ing 8.5% 02 and 12.5% SO2. Best volatilizations (90% of the As, 52% of the Pb) were obtained under localized conditions attained in an air-type flame. Average volatilizations were: air-type flame, As 50%, Pb 32%; oxygen-type flame, As 40%, Pb 30%. The substitution of oxygen for air reduced the arsenic volatilization. The products of combustion were mainly cuprospinel and cuprite; small inclusions of elemental copper were found in some of the particles. At high temperatures, there was a loss of copper due to vaporization of CU( g) CuO kg) (g)

Jan 1, 1983

By T. F. Bamber

The South Nottinghamshire Area has not been greatly troubled by spontaneous combustion until the last few years, during which the Blackshale Seam has been developed and exploited. The problem was first encountered at a colliery which was heavily preoccupied with a major reconstruction scheme, and with the sudden appearance of a completely new hazard both men and management had to adapt themselves very quickly to meet the situation. The paper contributed to the Symposium by the South Nottinghamshire Area illustrates the problems by reference to actual incidents, and shows how the lessons learned from them have been applied to the shaping of future policy on the avoidance and treatment of spontaneous combustion.

May 23, 1905

By Scott D. Thomson

The client for this project specializes in the use of state-of-the-art technology to fabricate and assemble composites and metal-bonded structures for commercial and military aircraft programs. One of the key components for this operation at the client's plant is a highly precise computer-numerical-controlled router known as the Shoda Machine. This machine tool was installed at the plant in July 1998 for the manufacture and inspection of aircraft parts, and it is extremely sensitive to deflections. To monitor the occurrence of deflections, an internal laser system continuously checks the machine calibration. Deflections in excess of 5/1000-inch in the foundation on which the machine rests require costly periodic re-leveling and recalibration of this tool. Therefore, a significant problem arose when measured deflections during machine operation were as large as 20/1000-inch. In addition, the foundation was cracked in at least three places as a result of elastic foundation movement caused by dynamic loading as well as shrinkage and loss of base support. Deciding on a remediation procedure to alleviate or eliminate these problems involved the following important considerations: (1) achieving the client's need for reducing deflections to less than 5/1000-inch, (2) minimizing the repair cost as much as possible, and (3) reducing the time required for implementation of the foundation remediation solution. After evaluating the advantages and disadvantages of several alternatives, jet grouting was selected as the most suitable solution. The jet grouting program provided columnar elements of soilcrete to remediate the Shoda Machine foundation.

Jan 1, 2003

By Christopher Mark

The Analysis of Retreat Mining Pillar Stability (ARMPS) program has been used to evaluate room and pillar retreat mining layouts since it was first released in the mid 1990s. After the Crandall Canyon mine disaster focused attention on the importance of pillar design, ARMPS became an essential component in most Roof Control Plans developed by mine operators. In 2010, NIOSH released ARMPS version 6, which features a ?pressure arch? loading model for deep cover room and pillar mining. NIOSH has also provided general guidance for using ARMPS, including design criteria based on statistical analyses of an extensive case history data base. Many real-world retreat mining scenarios entail mining configurations that ARMPS does not directly address. Some of these situations that the MSHA Roof Control Division (RCD) has encountered in the course of its reviews of more than 100 ?complex and non-typical? plans are ? Unmined pillars are left at the mouth of a retreat panel that function as a ?composite barrier pillar? ? The floor is extracted on retreat, increasing the mining height ? More than one row of bleeder pillars is left in an adjacent, previously mined panel ? A retreat panel is located above or below a gob area in a previously mined seam ? Bleeder pillars are partially extracted on retreat RCD has developed solutions that allow these situations to be fitted into the ARMPS framework, and these are presented in this paper. Also discussed are some of the rules of thumb that have been developed for various input parameters, such as the treatment of inseam rock and slab cuts into solid coal.

Jan 1, 2011

By Ernie Doell, Trung Nguyen

"In early 1995 Cluff Mining commissioned a newly constructed high density tailings thickener at its Cluff Lake uranium mill. The 85 ft diameter high density thickener is one of the first of its kind in North America, and incorporates the novel paste technology in its design to produce densified (in the range of 60 -65% solids) mill tailings suitable for stable deposition in the tailings management area. This paper discusses the impetus behind the installation of such an unconventional thickener, and the many trying experiences in making it operational.IntroductionCluff Mining, a wholly owned subsidiary of Cogema Resources Inc., is the operator of a uranium mine and mill complex at Cluff Lake which is located in northern Saskatchewan. Since 1980, the company has developed and mined out several different ore bodies within the Cluff Lake region for the production of uranium concentrates, commonly known as yellow cake. Based on the known ore reserves, the Cluff Lake operations are projected to last till the early 2000's.Tailings from the Cluff Lake mill have been discharged to a tailings management area consisting of a tailings pond and two facilities for primary and secondary treatment systems. The tailings pond has an impervious bentonite lined dam, and it is divided into a solids and a liquids holding areas. Until the beginning of 1995, the mill tailings were discharged in two separate lines to the solids pond; one line carried the slurry residue of 45-50% solids (w/w) from the CCD circuit, and the other discharged raffinate tails containing less than 1 % (w/w) gypsum precipitate. Supernatant in the solids pond is treated in the primary treatment system prior to discharging to the liquids pond. Figure 1 shows the site plan of Cluff Lake tailings management area.It has been estimated that by the end of 1995 the solids pond would be filled to about 60% of its design capacity, and probably would be full before the year 2000. Therefore, Cluff Mining had to consider a more efficient tailings disposal method that could extend the service life of the existing Cluff Lake tailings management area. A high density tailings thickener was believed to be the most practical and economical system for tailings disposal at Cluff Lake mine."

Jan 1, 1996

By D. Harrington

The occurrence of dust in mines has always been a source of trouble, but for any years, and virtually up to the beginning of the present century, relatively little of a definite nature was known as to the numerous ill effects of dust in mining operations. Even today, with the west amount of time given and attention paid (for at least 40 years in various, countries) to research and observation en dust in mining, and in spite of the experience with it, much information remains to be obtained, before definite, well-authenticated statements can be made as to numerous features connected with the occurrence of dust in Dines an of its effect upon the health and safety of the worker. One statement that can be made with relatively good assurance of being uncontradicted in that dust is a real menace to the well-being of mine workers, and this includes both health and safety. In addition, dust in and around mines and mining plants is one cause of large financial losses to mine owners and operators. FORMATION OF DUST IN COAL MINES IN THE UNITED STATES One definition of mining is "the processes by which useful materials are obtained from the earth's crust; " since virtually all of the useful materials of or in the earth's crust either are solids or must be reached by penetrating through solids, the materials that are moved in mining must necessarily be broken or disrupted, so that almost every phase of the work of loosening the material and transporting it is likely to produce dust.

Jan 1, 1939

By Maurice A. Ponti

The D.C. Water and Sewer Authority is implementing the Anacostia River Projects component of its Long-Term CSO Control Plan, including 21 kilometers of 3.7- to 7-meter-diameter CSO near-surface diversion storage/conveyance structures and flood relief, pressurized-face, soft ground tunnels at a maximum depth of 65 meters. This paper describes a project-specific soil grouping system that is primarily based on soil characteristics for tunneling derived from tests including Atterberg limits, grain size, swelling, mineralogy, triaxial, pressure meter, and consolidation, which differentiates the project from past area tunnel projects using descriptive systems based primarily on area geology.

By Bauer, Steve, Colin Goodwin, Gerald, Randy Dempsey, Courtland

"The City of Ottawa’s Combined Sewage Storage Tunnel consists of two interconnected tunnels totaling 6.2 km with a diameter of 3m including access shafts and hydraulic structures which connect to the City’s most critical sewers. This tunnel will be built 15m to 30m below ground in the downtown core adjacent to, and crossing below, the Light Rail Tunnel, which introduces additional considerations in terms of sequencing and risk mitigation. The City embarked on a unique Procurement Process to address the risks involved with a large tunnel project and those associated with tunneling below downtown, underneath and adjacent to UNESCO World Heritage Sites, and connecting to live critical sewers. This paper describes the unique procurement approach employed and the contractual risk mitigation measures developed to provide the best value while minimizing risk. Specific features include Market Sounding, using a Fairness Commissioner, Contractor Prequalification and Risk Mitigation Measures in the Tender documents. INTRODUCTION This paper describes how the City of Ottawa (the City) and the project design team developed a strategic Procurement Process and Tender that incorporated industry best practices for technical and contractual risk management for the Combined Sewage Storage Tunnel (CSST) project. The process was unique in that, while it employed a systematic review of project risks, it also solicited input from industry, stakeholders and provincial and federal partners to develop the request for Tender for this traditional design-bid-build project. Key drivers for this approach were initiated from the City’s concerns for cost control, cost certainty and overall project risk mitigation. To address these concerns, the City implemented the risk review and mitigation process right from the project design team selection. It was critical that the project design team embraced this risk management philosophy and carried it through each phase of the project. This paper serves as an excellent resource for municipalities or other owners embarking on a similar tunnel project, on how to properly apply industry best practices and the benefits of using them."

Jan 1, 2016

Recovery of Rhenium from Mineral Raw Materials of Kazakhstan

Sep 13, 2010

By Yoshinori Iwasaki, Shosei Serata, Yutaka Mochida

A new comprehensive insitu instrumentation technique named this RCC Method has been developed for rapid assessment and improvement of the structural stability of underground openings. When applied to tunnel construction, the degree of present and prospective safety of underground openings can be determined in quantitative terms within 10 to 20 minutes of microcreep observation. When applied to mining, roofs and floors can be stabilized by controlling the stress conditions. This stress control method has eliminated the need for intensive roof bolting and extensive floor renewal in all cases where it was applied. Use of this technique is illustrated by field examples from the Seikan Undersea Tunnel of Japan and deep potash mining in Canada. NEW INSTRUMENTATION TECHNIQUE: THE RCC METHOD Failure problems in underground excavation usually arise in weak non-elastic grounds where conventional rock mechanics theories of elasticity are not only useless but also misleading. Presently, discontinuity planes in the ground are being considered a factor in assessing these failure problems, and while this development is interesting academically, it is not of much use in actual excavation work, where it is nearly impossible to identify and quantize all existing planes of discontinuity. Even if such an extraordinary task could be accomplished at an underground excavation site, effective use of the data would be difficult and impractical for rapid excavation work, with the possible exception of rare cases of ideally elastic ground.

Jan 1, 1976

By P. Favreau

"This paper describes the progress accomplished at the Noranda Technology Centre in the field of three-dimensional computer-aided underground blast design. Traditional methods of laying out underground blasts are reviewed, and the new computer-aided approach is described. Time savings achieved through the use of BLASTCAD can be advantageously used to better engineer blasts, using models and blast vibration analysis. Future work involving the attachment of blast models directly to the system is also addressed.IntroductionThe Noranda Technology Centre's (NTC) Environment and Mining Laboratory, in cooperation with the mining operations of the Noranda Group, is committed to the development and implementation of new technologies in the field of mineral extraction . Within the frame of its research program, the Blasting Technology Program is developing computer "" tools"" designed to assist the blasting engineer or technician. These computer "" tools"" are regrouped under a global software system called BLASTCAD.The BLASTCAD project started in 1990 at NTC. At that time computer programs designed to calculate and model various blasting parameters had been accumulated. These programs cam e from different sources and were mutually incompatible. Furthermore, they were developed as research programs with tittle effort spent on user interface. These programs are very useful, but are highly specialized, need large input files and can be quite tedious to use as ""standalone"" packages .Therefore, the situation being faced was one where all these programs were available at the Noranda Technology Centre, but not a t the operations. The two following options were then considered: 1. continue to run all the models and programs at the Noranda Technology Centre, and present results through reports to the mines, or2. regroup all the different programs under a single one that would make them share the same data base and be transported to the user. This second option is the one that was adopted; the result is BLASTCAD."

Jan 1, 1993

By A. L. Engel

In recent investigations of chloride Volatilization of gold at the Reno Station, it was found that the addition of small amounts of copper and NaCl to the charge brought about improved volatilization of the gold. The investigations described in this report were concerned with the recovery, in an aqueous medium, of fumes from chloride volatilization of gold. It was attempted to discover a suitable aqueous medium that would permit absorption, solution, or precipitation of all the volatilized gold immediately upon contact with the medium. A simple laboratory apparatus was employed to produce fumes by volatilization. To this furnace was attached an absorption train consisting of a series of chambers containing the aqueous medium, through which the fumes were drawn by suction. A satisfactory synthetic ore that contained metallic, gold in a quartz-matrix was made and utilized, enough. gold being present in a' small amount of material to permit an accurate, metallurgical balance of the volatized values' to be obtained in all the experiments.

Jan 1, 1949

By Gandhi

Piled raft foundation under uniformly distributed vertical loads has been analyzed using Finite Element Method. The soil is considered to be linear elastic, isotropic, homogeneous. The raft,pile and the soil have been idealized with eight noded brick elements. Parametric study have been carried out varying pile length, soil modulus, raft thickness, and pile spacing. Design charts have been produced to achieve 50% load sharing between pile and raft for optimum design. Data available in literature is compared with the design chart results and found satisfactory.

Jan 1, 1996

Incorrect sampling and measurement operations and misunderstanding the components of variability can cause huge economic losses to the mining industry. The main objective of this paper is to illustrate by means of four historical facts how Codelco has been evolving in those issues since the late 1980s. The El Abra bias, the awareness of the different kind of sampling errors and the role of Francis Pitard, the awareness of weighting errors, and the understanding of the components of nature and process variability are described. It has been a slow but a consistent process. Much progress has been achieved but still there are many opportunities for improvement to transit from the tonnage culture to the productivity culture.

Jan 1, 2008