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Etching solutions containing hexavalent chromium ions (e.g., chromic acid) are used in brass finishing, printed circuit board etching, preparation of plastic for plating, anodizing, and various other industrial surface treatment operations. As the solutions are used, hexavalent chromium ions are reduced to their trivalent state, contaminants accumulate in the solution, and the effective acid concentration is reduced. When the etching rate becomes unsatisfactory for the particular operation, the solutions are discarded. This is a problem because the discarded solutions are pollutants, and because replacing the etching solution is expensive. The Bureau of Mines has developed a process for regenerating these spent solutions and returning them to the surface treatment operation without interrupting the etching process. An electrolysis cell containing anode and cathode compartments that are separated by permeable membranes, is used for regenerating the spent solutions. The spent chromic acid solution is fed to the anode compartment and sui (uric acid is circulated in the cathode compartment. Application of a steady electrical potential of a few volts dc across the electrodes causes the copper ions and other contaminants in the spent solution to migrate through the membrane to the cathode compartment where copper is plated onto the cathode. Zinc and the other contaminants remain in the sulfuric acid. At the same time, the complex, trivalent chromium ions in the spent solution are attracted to the anode where they are oxidized to their original hexavalent state. The regenerated solution in the anode compartment is then recycled back to the plant?s etching operation for reuse.

Jan 1, 1980

By David S. Yang, Osamu Taki

The innovative Soil-Cement Mixing Wall Technique, developed independently in Japan, consists of mixing in-place soils with cement grout using multi-axis augers and mixing paddles to construct overlapping soil-cement columns. The applications of overlapped soil-cement columns include cutoff walls for groundwater control and structural diaphragm walls for excavation support. The special features of this technique include water tightness, versatile strength design, and efficient installation in subsurface materials varying from clayey soils to cobbles or soft rocks. Through the introduction of two recent subway projects in Japan, this paper presents the design parameters, construction procedure, quality control and performance of soil-cement wall for excavation support and groundwater control.

Jan 1, 1989

By L. Andrews

Nickel is recovered as a by-product of the platinum-producing process operated by Anglo Platinum. The metal is mined mainly as sulphide minerals contained in platinum ores. These pass through the concentrating, smelting and converting process route and nickel is finally recovered by electrowinning. Smelting of the concentrated ore in the electric furnace produces a melt with a high slag to matte ratio. The resulting furnace slag is granulated and later milled and floated to recover matte. A project was initiated to investigate the distribution of nickel in the slag in order to improve recovery. Slag samples were examined using a combination of chemical and mineralogical techniques. The granulated slag was found to consist mainly of a silicate glass phase, which reflects the composition of the molten slag in the furnace. Nickel occurs as free matte granules, as matte phases locked inside the glass, and in the glass phase itself. Whereas nickel in the matte is as sulphide, most of the nickel in the glass phase appears to be oxide- bound(i.e. in solid solution). Milled slag as flotation feed showed recovery-limiting features such as free matte with oxidized surfaces and unliberated matte inclusions in the slag. The biggest nickel losses, assuming no tapping problems, are in the glass phase solid solution. Only around 40% of nickel would be recovered from the slag, even under ideal conditions. Spoon and pot slag samples were also examined to see if casting and crushing would improve recovery. Although larger and therefore more easily recovered matte phases formed, nickel partitioned into crystalline silicate phases, limiting the maximum theoretical nickel recovery to 70%.

Jan 1, 2004

By A. J. Hendron, J. E. Monsees

INTRODUCTION This paper is the outgrowth of work done by the authors to prepare the seismic design criteria for underground structures on the Southern California Rapid Transit District (SCRTD) Metro Rail Project. It is a follow-on to a similar paper presented at the October, 1984, ASCE National Convention (17). For design, the earthquake-induced distortions recommended herein are to be added to the normal static loading conditions for the underground structure. This design approach has been used by 18 section designers on the SCRTD Project. Preliminary results from two- and three-dimensional finite element solutions have partially verified the approach. Areas where additional research is needed for special cases are identified. EFFECTS OF EARTHQUAKE The effects of earthquakes on underground structures may be broadly grouped into two general classes -shaking and faulting. In response to earthquake motion of bedrock (shaking) , the soil transmits energy by waves. Seismologists identify various types of earthquake waves, but underground engineers are generally interested in the effects of transverse shear waves which produce a displacement of the ground transverse to the axis of wave propagation. The orientation of propagation is generally random with respect to any specific structure. Waves

Jan 1, 1985

Following the Coalbrook Colliery disaster in 1960, Salamon and Munro (1967) established the well known empirical coal pillar strength formula in South Africa. This formula has prevented further violent multiple pillar failures. In 1996, a back analysis of the collapsed and uncollapsed cases in Australia led to the development of the Australian empirical coal pillar strength formulae. The original collapsed and uncollapsed coal pillar database of Salamon and Munro (1967) was updated in 2006. This study introduced various strength formulae for different coalfields and seams in South Africa through back analyses of collapsed and uncollapsed cases. Today, the resultant pillar strength formulae from these previous studies and the behaviour of coal pillars are mostly well understood and applied with confidence. However, it was assumed in the previous studies that the behaviour of pillars is not time dependent; therefore, the formulae established do not provide an associated time to failure of coal pillars. This paper attempts to evaluate the so called 'Geometrical Limits' concept to provide the Australian coal mining industry with a tool to assess the long-term behaviour of bord and pillar workings where the pillars are prone to failure due to spalling of ribs. In order to achieve this outcome, the principles of the safety factor concept and the probability of failure calculated using the coal pillar strength formulae have also been evaluated and practical design examples are presented in this paper.

Nov 25, 2010

By M. L. F. Paullo, S. Cristian Mejia, D. Roehl

"Rock fracture simulation most often presents non-linear behaviour due to loss of material integrity and strain concentration in the fracture zone. These strains generate local instabilities that propagate to the global system of equilibrium equations, generating convergence problems of the numerical solution. Often, in such cases, analyses in the post-critical regime are unfeasible. To overcome the numerical difficulties associated with problems of stiffness loss in the post-critical regime control methods, also called continuation methods, are employed. Among them are the arc-length method, the energy control method and the indirect displacement control method. These methods are employed in conjunction with a Newton- Raphson scheme for the solution of non-linear systems of equations. However, depending on the system instability, convergence in not guaranteed even with very small increments. In the present work these control techniques are investigated in combination with cohesive elements to simulate rock fracture. The constitutive model employed with the cohesive elements represents stiffness degradation through a damage law, which leads to serious convergence difficulties as reported in the literature. Here the continuation methods mentioned are applied to a Mode I rock fracture problem and to hydraulic fracture simulations. The effectiveness of the different continuation methods is compared.INTRODUCTIONThe process of rock fracture induced by the fluid pressure is called hydraulic fracturing. The propagation of a hydraulic fracture is a complex process, which is basically defined by the mechanical deformation of the rock, the fluid flow within the fracture and the fracture propagation itself (Mokryakov, 2011). In the works of Bendezu et al. (2013), Chen (2012) and Carrier et al. (2012), vertical hydraulic fracture propagation is modeled by cohesive elements with traction-separation law. The softening behavior of rock in post-critical regime is demonstrated by experimental testing and is characterized mainly by high strains and low stresses (Crowder and Bawden, 2004). This nonlinear behaviour can arise due to material nonlinearity, such as micro-cracking and damage, leading to softening behaviour (Chandrakant, S.D., 2012). The cohesive fracture model considers in its formulation the softening behaviour that most rocks present in post-critical regime with propagation criteria."

Jan 1, 2015

By Timothy L. Roberts

For many years practicing geotechnical and structural engineers in Texas and Louisiana were reluctant to include augered cast-in-place (ACIP) piles as a viable deep foundation alternate. Three primary concerns were the lack of a final driving resistance to confirm adequate capacity, the inability to inspect ACIP piles prior to installation, and the fact that pile integrity is highly dependent on the skill of the ACIP pile contractor's field personnel. The Deep Foundations Institute (DFI) Committee on Augered Cast-In-Place Piles has responded to these quality control concerns by establishing standards of practice for ACIP pile installation and ACIP pile inspection. Regional areas of the country have different subsurface soil and rock conditions and many times this will influence local installation and inspection requirements. The best way structural and geotechnical engineers can address quality control concerns is to be familiar with the DFI standards of practice, to know the special requirements for a particular project site, and to incorporate them into a well-written ACIP pile specification. The purposes of this paper are to: 1) review the main fundamentals of a successful quality control program, 2) describe how these fundamentals can be applied to the installation of ACIP piles, and 3) add personal experiences from ACIP pile projects in Texas and Louisiana. Nondestructive test methods are frequently used as a quality control tool to evaluate questionable piles. An additional brief discussion of two nondestructive test methods is presented to complete the paper.

Jan 1, 1998

By Adrian Brown

Pilot Hole ?X? was drilled to test the formations through which the ventilation shaft for the proposed U.S.B.M. demonstration oil shale mine will be drilled. Five permeability tests were performed at various stratigraphic levels within this hole. The test method used was that of pumping fluids out of the hole for three hours, using the air lift method, followed by a three-hour period where the recharge was observed. Transmissivity and permeability results were determined from these test data. The test procedure used is described and supporting data for the hydrologic tests are provided.

Jan 1, 1977

By G. E. McElroy, D. Harrington

In connection with the cooperative metal-mine dust and ventilation investigations of the U. S. Bureau of Mines and the U. S. Public Health Service , some underground data have been obtained with intent to ascertain the adaptability of the katathermometer for determining the comfort of working places in mines . This preliminary study indicates that the instrument will probably be useful for making routine determinations of comfort conditions in our mines , and that it may also prove an important accessory for investigative work on problems in ventilation and kindred subjects ; in both coal and metal mines , although the instrument should probably be altered somewhat for maximum utility under the varied conditions in the mines of the United States . The katathermometer is an instrument contrived by Dr. Leonard Hill , an eminent English physiologist , and its various features have been fully described by him in his book entitled " The Science of Ventilation and Open Air Treatment . " He made exhaustive experiments and concluded that the rate of cooling of the human body was the controlling factor in determining comfort or discomfort , and then set out to make an instrument that would measure this rate of cooling . The resulting instrument the katathermometer measures its own rate of cooling when its temperature approximates that of the human body and thus serves as an index of the rate of cooling of the body itself . - The instrument consists of an alcohol thermometer having a cylindrical bulb 1 inches long and 3/4 inches in diameter, and a stem about 8 inches long graduated from 95 to 100° F. This temperature range gives a mean temperature of 97.5° F. ( 36.5° C. ) , which is approximately that of the clothed body surface . The stem terminates in a small reservoir which serves the double purpose of acting as a safety overflow in case of overheating the bulb , and of insuring a regular rate of cooling by the time the meniscus has fallen to the 1000 point .

May 1, 1922

By Mike Lewis

"Descending several stories down a metal staircase into a shaft spanning a quarter city block -- soon to become Roosevelt Light Rail Station in Seattle, WA -- visitors are greeted with four perfectly round, precast concrete-lined horizontal holes leading deep into the earth. The sound of water trickling out from a small drainage trough can be heard over the faint echoes of construction within. Upon entering, the light is dim, but the air is clear with barely a dust particle flowing through the sunbeams. This type of air quality is only accomplished with diligent controls, and JCM Northlink, the company in charge of building the Northgate Link Extension Project, is taking those measures seriously.Commissioned by Sound Transit, JCM is a joint venture of three companies: Jay Dee Contractors, Frank Coluccio Construction Co. and Michels Corp. The tunnels JCM constructed are intended to provide fast, reliable underground rail service, as well as relieve one of the region’s most congested traffic areas. The $440 million project will connect the Northgate, Roosevelt and University District neighborhoods north of Seattle to the downtown corridor and SeaTac airport further south.The scope of this project includes excavation for two light rail stations, boring of two parallel 5 km- (3.3-mile) long light rail tunnels in six runs and the construction of 23 cross passages. Begun in 2014, Sound Transit estimates that crews excavated more than 382,000 m3 (500,000 cu yds) of soil and installed 7,352 precast concrete tunnel liner rings during the shaft construction and boring phase. Now that tunnel boring is complete, JCM is in the process of constructing the cross passages, which act as maintenance areas and escape routes for passengers. Throughout the entire process, the company has utilized atomized mist to control particle emissions.“Our dust control needs change at every phase of the project and don’t go away until the project is fully complete,” said a JCM safety representative. “We found that different dust suppression technologies were needed at different intervals, but atomized mist seemed to fulfill our needs at every step.”"

Jan 9, 2017

By C. Vipulanandan

With the aging infrastructure, there is a need to maintain and extend the service life of steel structures in general and steel piles in particular. Steel piles support not only vertical loads but also dynamic horizontal loads in onshore and offshore applications. In order to select the appropriate methods to repair corroded steel piles used in onshore and offshore application, corrosion mechanisms were investigated with the rate of corrosion in various environments. The corrosion rate of steel in soil, water and soil-water interface varied from 2 to 500 µm/year. Based on literature review and analyses, the repair methods can be broadly characterized as protective coating, electro-chemical methods, wrapping and encasement and partial replacement of steel. Also, methods to evaluate the repair materials and the repair configuration have been documented.

By Fennell B

A process for the recovery of cobalt from a speiss produced at Sulphide Corporation is presented. The speiss is leached in oxygenated sulphuric acid to dissolve the metallic iron at a pH of around 4. The resultant iron (11) is subsequently oxidized in the leaching vessel and precipitates as goethite. Acid is regenerated in the precipitation allowing dissolution of further speiss. Subsequent to the conversion of most of the iron in the speiss to goethite, conditions become sufficiently oxidizing to dissolve cobalt. Cobalt is not co-precipitated under the leaching conditions, yielding a pregnant solution containing the cobalt and some iron (11). The principal advantage of such a process is the significantly lower acid consumption over that obtained by complete dissolution followed by selective precipitation. An impure product of cobalt hydroxide can be obtained from the pregnant solution by neutralization.

Jan 1, 1983

By K. Hanson

When done properly, benchmarking is an extremely effective tool for assessing ones performance, finding areas for improvement, and identifying strengths. However, when done improperly it can be an exercise in futility and result in incorrect observations and conclusions. A primary pitfall of benchmarking is collecting too much unreliable information. Surprisingly, the evolution of data storage and the ease of data collection are not helping with better data collection. Instead, it is just allowing one to collect more information, while at the same time inundating one with too much data. Additionally, the process of data collection can be tedious and is often times delegated to the least experienced individual resulting in unreliable and incorrect data collection and entry. Another primary pitfall of benchmarking is metrics that are cost based or poorly designed. Cost based metrics typically involve comparing unit mining costs ($/tonne). Between mines, unit mining costs are not very well correlated and have become further complicated by significant regional cost variations and mining inflation in the last years. Likewise, poorly designed metrics lead to poor benchmarking results. Examples of poorly defined metrics include: metrics that rely on information that is difficult to collect, metrics that are poorly defined, metrics which are too site focused, and metrics that measure low consequence practices.

Jan 1, 2011

By Robert W. Geehan

"INTRODUCTION A preliminary examination of the Argentena mine was made in 'January 1945 by an engineer of the Bureau, who recommended investigation by diamond drilling. The Bureau conducted a core-drilling project at the mine from April 30 to August 4, 1946. Claims investigated are in sec. 33, T. 24 S., R. 58 E., Mount Diablo base and meridian, in southern Clark County, Nev., about 2.2 miles west of Goodsprings.The Argentena mine has been an intermittent producer of zinc-lead-silver ore since 1926. During the war years, ore was shipped to the Government stock pile at Jean, Nev., and to the International Smelting F. Refining Co.'s smelter at Salt Lake City, Utah. The mine has been shut down at intervals because of lack of a market for mixed oxidized zinc-lead ore.The 12 holes drilled by the Bureau totaled 1902 feet. The program was designed to test for faulted portions of the ore bodies know in the mine and to test favorable areas for similar ore bodies. As a result of this program, one faulted segment of the ore body was found, and it was established that no one was present in a second fault block. Similar blocks remain unexplored in the vicinity of the mine. Two holes drilled in favorable areas several hundred feet from the mine failed to discover new ore bodies."

Jul 1, 1947

By R. Brown, A. J. S. Spearing, M. Treinen, M. Theisinger

The mining and use of coal creates a significant amount of waste material that needs to be safely disposed of. It is likely that in the medium term, the Environmental Protection Agency (EPA) in the U.S. will categorize all such products as a new category – special waste. This would make the materials subject to many of the requirements for handling toxic waste, which will complicate the disposal of such products and significantly increase the disposal costs. Underground disposal would, therefore, seem to be the obvious solution, especially if the placed material can have low or no permeability, so that water table pollution does not present a serious long-term issue after placement. Significant additional advantages could be derived from this backfilling, including the reduction or elimination of surface subsidence, increased extraction, reduced surface waste disposal footprint and the elimination of explosion-proof seals in worked out areas. The research using a specific coal waste product as a typical example proved that the method of placing the backfill at a high density with low permeability is technically viable, but it must be made more cost effective and the other potential benefits quantified and costed in order to present a true comparison.

Jan 1, 2010

By M. G. Zabetakis, T. D. Moore

The use of a partially slotted 6.5-inch-inside-diameter vertical pipe to remove methane from a longwall gob area at a depth of 2,260 feet in the Pocahontas No. 3 coalbed ms investigated. The value of gas removed by such a pipe under free-flow conditions was found to equal the cost of the installation in this case. Approximately 25 percent of the available methane passed through the pipe without the use of an exhauster; an additional 10 percent was removed when an exhauster was employed. The diversion of methane through a vertical slotted pipe to the surface permitted the use of increased mining rates and decreased the ventilation air requirements.

Jan 1, 1972

By CH. Liu, H. X. Jiang, X. Xiao

"A study has been conducted to characterize the fatigue life in 7050-T7451 thick plate by the comparison between an experimental alloy and commercial alloy. The fracture origins were specified and their sizes were measured by scanning electron microscope (SEM). Additionally, the size, number density and spatial distribution of porosity in the experimental material and commercial material were characterized and compared, using X-ray Computed Tomography(XCT). The results showed that microporosity was the predominant site for crack nucleation and subsequent failure of the experimental alloy. However, as for the commercial alloy, fatigue cracks were found to originate from constituent particles. The presence of microporosity in 7050-T7451 thick plate reduced fatigue life of an order of magnitude or more compared to the commercial alloy. The relationships between size of origin and fatigue life were proposed. It was showed that the fatigue endurance was reduced when the size of porosity increased.INTRODUCTION 7xxx series aluminum alloys, due to their combination of high strength, high resistance to stress corrosion cracking, and good fracture toughness, are widely used in structural engineering applications where high-strength and low-density characteristics are fundamental design requirements (Williams& Starke, 2003). Every designer is striving to find an optimal combination of properties including strength, corrosion resistance and fatigue resistance (Wanget al., 2016). Based on the design principles of aircraft, a higher fatigue resistance of aluminum alloys are required. Thus, many investigations have been carried out on the microstructures and its effect on fatigue properties of the 7xxx series aluminum alloy (Robson, 2004; Schubbe, 2009).Microporosity, which is a common defect in casting materials, can lead to a significant deterioration of mechanical performance and fatigue resistance, especially in the high alloyed 7xxx aluminum alloys. The actual valid loading area decreases due to microporosity, which results in detrimental effect on the mechanical properties. Many experimental studies have been conducted in this research field. Mayer et al.(2003) investigated the fatigue properties of magnesium alloys produced by high-pressure die-casting. The results show that porosity in magnesium alloys greater than0.18mm diameter may be considered as the most important material defect for high cycle fatigue and fully reversed loading conditions. Nadot et al.(2004) found that the near surface defects are much more dangerous than the internal defects. Wang et al.(2001a) used the Weibull statistics method to analysis the influence of the microporosity, oxides and particles on the A356-T6 alloy fatigue life. The results show that, the porosity is more detrimental to fatigue life than oxide films and particles. With regard to fatigue resistance, although the deleterious effect of microporosity has been generally acknowledged, a quantitative understanding between casting microporosity and fatigue life in 7050-T7451 plate is not well established."

Jan 1, 2018

By L Dixon, J Carter, K Auyong

Fourier transform infrared (FTIR) spectroscopy and other near infrared (NIR) tools have been used in the bauxite industry for many years. Infrared spectroscopy exploits the differences in chemical composition and lattice structure to produce a characteristic response. Spectral devices, such as those from ASD Inc and the HyLoggerTM, provide qualitative mineralogical data targeted towards hydrated minerals detected in the near and short wave infrared region. The FTIR spectrum extends into the mid and thermal infrared range and can therefore respond to the presence of silicates and oxides, in addition to hydrates and carbonates.The key to successful utilisation of infrared spectra, however, is the interpretation methodology. In this study, FTIR spectra were calibrated against quantitative X-ray diffraction data for the determination of the mineralogy of iron ore. A full pattern profiling machine learning technique was utilised for the calibration, and the assessment of the regressions determined from an independent validation set. The abundance of key minerals – hematite, goethite, kaolinite and quartz – were determined and the results correlated against X-ray fluorescence assays and loss on ignition data. The results of the study indicate that spectral techniques using a full-pattern profiling machine learning approach and artificial neural networks can be used successfully to obtain objective and quantitative mineralogical data to support field observations and analytical results for iron ore resource modelling. A comparison of this technique to the cost, quality and timeliness of other quantitative mineralogy tools is also made.CITATION:Carter, J, Auyong, K and Dixon, L, 2017. Determination of iron ore mineralogy using Fourier transform infrared spectroscopy and machine learning, in Proceedings Iron Ore 2017, pp 519–528 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

By Stephen M. Smading

Unique onsite assembly of a 12.43 m Main Beam TBM and back-up system was completed on September 18, 2008 in the remote mountains of the Sichuan province of China. The equipment was assembled onsite, without previously having been assembled and tested in a factory, utilizing a method called Onsite First Time Assembly (OFTA). The Jinping-II hydroelectric project features four parallel headrace tunnels approximately 18 km long, two of which will be excavated by TBMs and two by drill and blast. A nearby fifth tunnel is being excavated by a 7.2 m TBM to draw down ground water in advance of excavating the headrace tunnels. This paper addresses the following topics: ¦Project description including geology and terrain; ¦The decision process leading to onsite first time assembly, the assembly process and logistics, and lessons learned; ¦Design features of the TBM and back-up system; and ¦Operational history from startup to the writing of the paper.

By Chris Bennett, Drupad Desai, Kirit Mevawala

INTRODUCTION The design/build (D/B) philosophy of contract delivery is neither new nor unusual when it comes to at-grade, elevated or high-rise structures. But when it comes to constructing underground facilities, there were no examples to be followed in early 90sin the continental United States or its territories. When DMJM+HARRIS was selected as general architectural and engineering consultant for the Tren Urbano (TU) project in Puerto Rico, one of the requirements of the Federal Transit Administration (FTA) for funding commitment was to use TU as a demonstration project utilizing design/build contract delivery method. Now fifteen years later, New York City Transit (NYCT) has instituted a similar requirement for their first Tunnel Boring Machine (TBM) contract for the Second Avenue Subway. As with most construction mega-projects, lots of things have happened and there were several lessons learned from the TU experience that are now being applied to Second Avenue. Both of these projects require building tunnels and underground transit facilities in heavily traveled corridors of an urban city, in the vicinity of active business and commercial enterprises. To enhance the challenge, there are noise and vibration sensitive and historic urban receptors either over or along both the transit corridors. Column free Tren Urbano station caverns over18 m (60 ft.) wide were built in soft ground conditions within 3.6 m (12 ft.) of the surface under an aging heavy utility corridor, while NYCT tunnels with station structures stretching the limits of rock caverns to 34.8 m (100 ft.), were planned in rocky geology with the presence of shear and fault zones and some mixed face conditions. BACKGROUND During the early period of design/build experimentation, the speed with which the contract procurement packages could be put together enabled the owners to take advantage of the major efforts underway to rebuild the infrastructure that was suffering from post-World War II neglect. Use of design/build for new starts was unheard of and most of the projects were smaller in nature in order to allow the methodology to be tested. Development of functional design packages with the understanding that the D/B

Jan 1, 2005