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By Manuel Viveros J.

This paper will deal with the type of rocks so called evaporites, which are sedimentary rocks produced by water evaporation from seas, lakes or marginal lagoons, in warm and arid climates. Salts derived from these deposits are precipitated according to their solubility; that is, the more soluble precipitates first, overlain by other sediments like silts, shales, limestones, sands, etc. The most common evaporites, according to their chemical composition, are : Chlorides Sulphates Carbonates Nitrates Borates Common salt, or halite, sulphates like anhydrite and gypsum, are the most important. Potassium chloride (silvite and carnalite) and potassium sulphate are of great commercial value.

Jan 1, 1974

By Paul E. Richardson, Edwin E. Maust

Cyclic voltammetry and surface potential (photovoltage) measurements have been carried out on galena electrodes in sodium tetraborate solutions with added HC1 and NaOH to adjust the pH over the range 2 to 13. The first technique shows that the surface species formed on moderate anodic polarization and reduced on subsequent cathodic polarization are the same over the entire pH range. At anodic potentials, a soluble metal species and excess sulfur are formed; at cathodic potentials, sulfur is reduced to a soluble species. More importantly, excess surface sulfur is formed spontaneously under zero current conditions in alkaline solutions. This has been shown to occur on both polished surfaces and on virgin surfaces produced by in situ cleavage under the electrolyte. The photovoltage gives some insight into the charge and potential distribution at the galena surface. This is found to depend on past electrochemical history and the n- or p-type semiconducting character of the electrode and is interpreted in terms of changes in the surface stoichiometry that occur during reduction or oxidation. The effect of surface stoichiometry on subsequent xanthate interactions is discussed.

Jan 1, 1976

By Craig E. Burson

This paper discusses the relationship between frother types and coal flotation as a function of particle size. It has been found that each frother has a unique size fraction that it will float effectively. This fact is very important when it comes to selecting a reagent scheme that will provide maximum recovery of both coarse and fine particles. Improvements in recovery can be attained when the chemical relationships between frother type and particle size floated are understood. Data from plant evaluations using commercial and developmental frothers are presented to verify the importance of frother types versus size fraction floated.

Jan 1, 1987

By W. M. Luff

The Brunswick No. 12 Deposit is a large polymetallic massive sulphide deposit, occurring in Ordovician age rocks of the Tetagouche Group. Silver is contained within the sulphide zones and economically it is the second most important commodity produced. Brunswick is one of the largest silver producers in Canada. The distribution of silver within the mine is presented, with examples from various levels. The concentration of silver can be shown to be related to both stratigraphy and structure. The mineralogy of silver in mill products is also presented.

Jan 1, 1986

By J. C. Norman

The boron review arrived too late to appear in the June issue. The United States was the world's second largest producer and the largest consumer of boron compounds during 1991. According to the US Bureau of Mines, boron mineral concentrate and chemical production in the US totaled about 1.1 Mt (1.2 million st), yielding about 608 kt (670,000 st) of BO, in 1991. Total estimated value was $440 million. That level of production was equal to 1990 revised production figures. Value was greater by $37 million, however, reflecting a strengthening of boron product prices. The US continued to supply essentially all its own boron while maintaining a strong position as a source to foreign markets of sodium borate products and boric acid. Domestic employment in the mining and beneficiation of boron products in 1991 remained at 1100 people, about the same level as in 1989. The Bureau of Mines estimated total world production of boron in 1991 - mineral concentrate and chemical - at about 2.9 Mt (3.2 million st). That corresponds to about 1.2 Mt (1.3 million st) of BO ,. World production in 1991 was about equal to revised 1990 levels. US production Mines and processing operations in southern California were the only domestic sources of boron mineral concentrates and chemicals in 1991. US producers, in order of quantity of production, were US Borax and Chemical Corp., North American Chemical Co., and American Borate Co.

Jan 1, 1992

By Michael Li, Kathryn Rogers, Arie Moerman, Mike Cooper

The Brunswick Mine, a Division of Noranda Inc., produces zinc, lead, copper, and bulk lead-zinc concentrates through underground mining of a large massive sulphide deposit. The mining method employed is longhole open stoping with delayed backfilling. In 1996 Brunswick began a review of its mining methods and backfilling operations. In 1997 the decision was made to convert the backfill system from cemented and uncemented rockfill to paste backfill prepared from mill tailings. This paper will describe the features of the backfill preparation and distribution systems, review the handling of technical issues, and discuss experiences since plant commissioning.

Jan 1, 2001

By J. L. Yordan

An induction time apparatus has been constructed in the present work which has a sensitivity limit of 100-150 micro-seconds. The basic unit is similar to the one used by Eigeles and Volova (1960) and Trahar (1983), but it operates with a micro-computer and has a greater sensitivity. Using this apparatus, the flotation chemistry of the quartz-amine system has been studied. It has been found that at a given dodecylamminium hydrochloride concentration, the induction time is at a minimum at approximately pH 10.5. At this pH, the collector hydrolizes to form neutral amine and the flotation recovery reaches a maximumy,suggesting that iono-molecular species are the surface-active species responsible for flotation. This finding confirms the earlier conclusions obtained using the surface tension (Somasundaran, 1976; Finch and Smith, 1973) and contact angle (Smith, 1963) techniques. The induction time measurements have also been conducted as a function of particle size, collector concentration, indifferent electrolyte concentration and temperature. The results are compared with flotation data, and the activation energies for the bubble-particle adhesion have been calculated.

Jan 1, 1986

By Steve Rogers

Nautilus Minerals was listed on the Toronto Stock Exchange in May 2006. The company now has major mining companies Anglo America (5.7%), Teck Cominco (7.2%) and Epion Holdings (22.4%) as significant shareholders, and has raised approximately $US346 million dollars to develop the world's first deep-water mine. The company is currently targeting high-grade copper and gold in seafloor massive sulphide mineralization, located near plate boundaries in back-arch basins of the Western Pacific. The first mine scheduled to be developed by the company is located in 1,600 meters of water at Solwara 1, in the relatively quite waters of the Bismarck Sea approximately 50 km from the port of Rabaul, within the Territorial Waters of Papua New Guinea. During 2006 and 2007 the company completed detailed environmental and geological studies, culminating in a number of world firsts, including the world?s first NI 43-101 compliant resource statement and environmental impact study for a seafloor massive sulphide system. Permitting is well advanced for the project, with initial production scheduled for late 2010, subject to timely grant of the permits. Extensive government and stakeholder liaison and engagement has been undertaken throughout the projects life, and is a core feature of Nautilus' desire to "do it right" in all aspects of this new industry.

Jan 1, 2008

By Yoginder P. Chugh

Effects of moisture absorption on the behavior of the Dykersburg shale overlying Harrisburg coal seam in Southern Illinois are presented in this paper. Cylindrical samples of the shale 2.5 cm in diameter and 5.0 cm long were studied for weight gain and swelling strains at 90, 95, and 100 percent relative humidity and under immersed water conditions. After attaining equilibrium conditions, the samples were studied for changes in the strength and deformation behavior. The depth of moisture penetration was measured using the Vickers microhardness measurements. Using the basic mass transfer concepts, effective diffusion coefficients were computed for the shale.

Jan 1, 1980

By W. L. Fourney, D. C. Holloway, J. W. Dally

Introduction Improvements in the process of rock excavation by blasting involves better control of one or more phases of the fracture process immediately after detonating the ex- plosive charge. Total control of the process involves individual control of (1) The number of fracture planes. (2) The crack initiation sites. (3) The direction of crack propagation (usually radial). (4) The stress field driving the fracture front. Fracture plane control is usually accomplished today by using the smooth wall blasting method; however, investigations by the authors (1) indicate several areas where this method could be improved. These improvements include: a) generation of stress concentration factors at the location of the initiation sites; b) protection of the remaining region of the borehole wall to inhibit initiation of any cracks not associated with the fracture plane and fragmentation pattern; c) limit peak detonation pressures to avoid borehole crushing and maintain by stemming residual gas pressure in the bore- hole during the crack propagation period. This paper describes experiments con- ducted with a charge holding device fabricated from thin-wall steel tubing which was partially slit at fracture locations. The tube lined the bore-hole in laboratory tests to simulate smooth wall blasting. Results showed close control could be achieved relative to both the number and the location of the fracture initiation sites.

Jan 1, 1977

By Jon Y. Kaneshiro, Gregory E. Korbin, Stephen J. Navin, Larry J. Stout

Sewage presently being discharged into the Tijuana River Valley pollutes the valley as well as the beaches in the South Bay of San Diego, making the beaches unusable nearly year round. The SBTO will convey flows down a 8.5 m (28 ft.) by 58 m (190 ft.) deep drop shaft, through a 3.35 m (11 ft.) by 5.8 km (3.6 mile) long tunnel, and up a 46 m by 2.7 m (150 ft. by 9 ft.) riser shaft connecting to a 1.5 km (0.95 mile) of seafloor pipeline and 1.2 km (0.76 mile) of diffusers on the ocean floor. The drop shaft will be sunk through 38 m (125 ft.) of saturated sands and gravels and 20 m (65 ft.) into the dense fine sands of the San Diego Formation. The tunnel liner has been designed as a five piece, single pass, gasketed, bolted, reinforced concrete liner designed to withstand an external head of 76 m (250 ft.) of water and internal operating head of up to 27 m (89 ft.) and to accommodate movement at the numerous fault crossings. The tunnel is contemplated to be driven with a state-of-the-art Earth Pressure Balance Machine (EPBM) or slurry shield machine through a wide range of conditions from clay to gravel with boulders.

Jan 1, 1995

By Y. Topkaya, R. E. Johnson, D. Buttinelli, B. R. Palmer, A. Geveci, L. Stoppa, C. Lupi, F. Pochetti

Representative samples of a composite mixture of three typical Cu/Zn complex sulphide ores, namely Black-, Yellow- and Altered-ore, from the Cayeli deposit in Turkey, were used for leaching tests in 2.2 M FeCl3, or 1 M CuC12-2 M NaCl solution in the temperature range from 313 K to 363 K (40O to 90O C), with and without the presence of an organic solvent for elemental sulphur, such as CCl4. The leaching rates of copper and zinc were quite high, as expected, in FeCl3 solution and complete recovery of both metals was obtained at the highest temperature when the solvent was present. However in CuC1, solution, extraction yields of the order of 95% only for Cu and Zn were achieved and the positive effect of the solvent was not clearly shown. The kinetics curves of Cu leaching by FeCl3 indicated a model of reaction rate depending on the particle surface, as in a chemically controlled reaction, in tests with the presence of CCl4. Without the solvent, or in CuCl2 media, the model of the diffusion controlled reaction seemed to prevail. Values of apparent activation energy, in both of the leaching processes, were determined and compared with those reported in literature.

Jan 1, 1993

By Christian F. Baiz

A new agenda has risen. Born out of governments' policies and world economies, the years ahead will carry with them reduced growth. For inflation dependent and capital intensive industries, such as metals and mining, as well as most other natural resource industries, a period of long-term contraction in outmoded and costly capacity will evolve. This will be supplanted by new, lower cost capacity in some cases, but only if the total cost of production, including cash operating and debt service costs comes in at or below current market conditions. The industrial outlook can be characterized as bearish. As one major U.S. bank economist put it, mining companies planning their five-year forecast from 1984 out, should take the current market conditions and straight-line them to the end of the decade. With low growth and low inflation, the real price of metals will remain flat or slightly declining. As a result, capital funding will be problematic. The low cost producer, that is one with low cash costs and low principal and interest costs per unit of production, will succeed.

Jan 1, 1984

By James D. Bennett

Relationships among mine and injured miner characteristics and HSAC's degrees of injury are examined for 91,404 injuries in under- ground bituminous coal mines in the United States from 1975 through 1982. Injury severity varies by the mining system, geographical region, circumstances surrounding the injury, the injured miner's age, whether the miner was using powered equipment, the year which the injury occurred, and the location in the mine where the injury happened. Injury severity is not related to the injured miner's total mining experience, job experience, and experience in the mine in which the injury occurred.

Jan 1, 1984

By Robert M. Jimeson

The competitive market potential for solvent refined coal is estimated. Market advantages of solvent refined coal are enumerated. Markets are possible in combustion, railroad locomotion, and carbon electrodes. The combustion characteristics are consistent with expected air pollution restrictions on the emission of sulfur and particulate matter. A market potential of sufficient size exists to support the initiation of solvent refining in the United States. The market analysis should help fuel producers determine the advisability of their undertaking the solvent refining of coal.

Jan 1, 1969

By Fiona M. Doyle, Christopher R. Lubeck, Michael C. Chin

The fundamentals behind a novel approach for creating inorganic/polymer hybrids are described. The binding of +2 charged ions, specifically Cue-and Cat+, to ionic functional groups is explored through UV-Vis spectroscopy and zeta potential measurements. The novel approach uses an electric field to drive ions into a functionalized polymeric matrix, thereby inducing the precipitation of calcium phosphate species. Scanning electron microscopy images of the resulting composite illustrate the results of these precipitations with two distinct morphologies observed.

Jan 1, 2003

By M. Christou

The LIFE-Environment Demonstration Project ?Treating Waste for Restoring Land Sustainability?(www.bangor.ac.uk/ies/TWIRLS/TWIRLS_home.htm), a project initiated by the University of Wales, Bangor, UK in which NAGREF is a partner, aims to demonstrate the effective use of industrial and municipal wastes for the remediation of post-industrial and degraded sites in urban and rural sites. Within the framework of this project, a schist quarry, which is located in a mountainous area near Athens and which has been exploited in the past for cement production, was chosen for bioremediation experiments in collaboration with the quarry owners, TITAN Cement Co. Three different areas within the quarry were selected representing 3 different topographies. These were a compacted, flat area with seasonal water logging (untreated control), a gently sloping, land formed area; and artificially created mounds of overburden rock material formed on the flat area. Compost produced from mixing municipal waste, green waste and digested sewage sludge at the recycling plant of the Association of Communities and Municipalities in the Attica Region (ACMAR), near Athens was used for nutrient amendment. Six replicates of three treatments were applied with varying compost application rates in order to examine the effect of the addition of organic matter in the establishment of suitable vegetation on the infertile schist material. Pine trees (Pinus halepensis Mill.), 4 per replicate, were pocket planted in a volume of 3 liters of schist or schist-compost mixture (1:2 and 2:1). Tree height, main stem diameter and branching were measured following planting and these measurements will be repeated annually to test hypotheses that compaction and water logging reduce Pine establishment by natural regeneration and that nutrient addition improves establishment of pine on schist waste. The availability of nutrients and variation in other soil physico-chemical parameters will also be studied in each treatment and related to plant growth. As a demonstration project, open days are planned on the site for the public and official bodies involved in municipal waste handling and other relevant areas. The aim of these will be to illustrate the effective re-use of waste for the sustainable restoration of post-industrial and degraded land.

Jan 1, 2006

By Steven Tubbs

Steven Tubbs From mine to farm is a long journey for Florida's phosphate, but it is an important one to the American farmer who uses phosphate fertilizers to replenish the soil and produce the crops which eventually wind up on the American dinner table. In this phosphate-food connection, transportation plays a vital life-giving role, a role that is unique because of the large quantities of phosphate produced and the mineral's location in relation to its markets. Florida Leads World Florida is the world's largest phosphate producer, supplying 80% of the nation's and a third of the world's annual total. About 95% of Florida's phosphate goes into agricultural chemicals, with 90% going into fertilizers. Phosphate production is primarily concentrated in west central Florida, with the exception of mining and processing in north Florida by Occidental Chemical Co. The phosphate rock is beneficiated at the mine sites and then is transported out of Florida in a raw state, or to one of the industry's 18 chemical complexes where it is processed further. In 1981, Florida produced more than 42 Mt (46 million st) of phosphate rock-a 1% decrease from 1980. The industry also produced more than 12 Mt (13 million st) of phosphate chemical products in 1981 and transported them to both domestic and foreign customers. This year, the state's phosphate production and shipments are substantially lower than recent annual levels because of a depressed worldwide phosphate market. With production down slightly in 1981, shipments declined and company inventories increased dramatically. Phosphate-related shipments through the port of Tampa alone fell 20%. As a result, in 1982, phosphate operations cut production to reduce inventories. According to the Fertilizer Institute, during the fiscal year ending June 30, 1982, phosphate rock production fell 18%; phosphate rock shipments, 28%; finished fertilizer production, 30%; finished fertilizer shipments, 25%; and phosphate rock exports declined by 20%. Despite depressed conditions, Florida phosphate production and shipments are expected to increase in the near future with more rock being processed into fertilizer products. Phosphate is one of Florida's major industries. The US Bureau of Mines estimates it contributed $3 billion to the state's economy in 1981 and an additional $1.4 billion to the US economy. In addition, phosphate exports contributed to

Jan 10, 1982

By Robert A. Pimentel

Dust is still a major problem in increasing production from longwall faces. Over the last decade, significant improvements have been made in the development of techniques for reducing dust exposure on conventional and continuous sections. But virtually no improvements have been made in dust control on longwall sections. It is true, that there are many more continuous mining sections than longwall sections in the United States and that the number of workers overexposed on continuous miner sections is much larger than the number on longwall sections. However, the problem on continuous miner sections appears much easier to solve and, in fact, we believe that the techniques are available to get virtually all continuous miner sections in compliance. The problems on longwall sections are much more elusive. Also, the number of longwall sections in the United States is expected to increase during the 1980's. Thus, dust control on longwall sections remains a formidable and important problem. Companies operating longwall sections with a dust problem are faced with the tasks of having to quantify the various dust sources, of selecting proper techniques to reduce the problem, of implementing the techniques and of evaluating their effectiveness.

Jan 1, 1983

By Atmesh K. Sinha

The market for thermal coal has recently been growing rapidly and it is projected to continue to do so in the foreseeable future. Both the national and international markets often demand high Btu low sulfur thermal coal in order to minimize the cost of utilization and meet the environmental restrictions. High quality thermal coal can be prepared to compete in the utility market by desulfurizing the high Btu midwestern coal and blending it with low sulfur western coal which is usually low in Btu content. The methods that can be used for optimizing the coal preparation plant operating parameters for physically desulfurizing coal is presented.

Jan 1, 1984