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By R. W. Bartlett

High salinity geothermal brines typically contain up to several hundred parts per million of valuable heavy metals, and because of the large potential flow of geothermal brines from future power plants, metal production as a by-product could be significant A-planned 55-MW demonstration plant near Niland, California should generate enough spent brine to contain approximately $670,000 per year in gross metal values. Lawrence Livermore Laboratory estimates (1) a Salton Sea Geothermal potential of 1300 to 8700 MW, which would translate to possible yearly heavy metal values between $5,800,000 and .$l05,000,000. Since these estimates were made on a conservative basis, this geothermal reservoir is potentially a large ore deposit. The heavy metals in order of decreasing abundance in high salinity brines from the Salton Sea geothermal field are usually manganese, zinc, iron, lead, and silver. All but manganese and iron are valuable enough to be of commercial interest. Minor amounts of copper and arsenic are also present. Although heavy metal precipitates, particularly lead, have been found in scales within pipelines and obtained from steam flashing, most of the metals remain soluble during steam production; hence removal of the valuable metals from the spent brine before reinjection in ground reservoirs is indicated. Because the heavy metal concentrations are low, a very simple and inexpensive process is required. The heavy metal value in Niland brine is only ' about $1 per 1000 gallons; see Table 1. The brine composition shown in Table 1 was taken from one of the brine samples used in our study. Projected post-flash brine from a steam plant has somewhat higher Zn and Pb values, but the gross heavy metal value is still less than $2 per 1000 gallons.

Jan 1, 1980

By A. Pezzuto

"Pipes are used on mine sites in a variety of applications including transport of slurry, conveying clean and processing water, and in mine dewatering. Mine waters and slurries can cause pipe wear and failures via several mechanisms (or combinations thereof) such as abrasion, scaling, and corrosion. Polyethylene (PE) pipe materials have grown in popularity over the past several decades due to their chemical and mechanical properties (e.g., inertness, flexibility, relatively low density) and low cost. While PE is generally resistant to corrosion, it is subject to abrasion. To combat this, a novel, rubber-like liner is in development. In addition to comprehensive abrasion testing, however, the liner must be evaluated to see how it performs under other conditions. Here, a brief field study is described that tested PE pipes with the new liner against traditional PE pipes to specifically assess mineral scale buildup. The study was conducted in the Reiche Zeche study mine in Freiberg, Germany in six different locations with varying water qualities and flow conditions. INTRODUCTION Water and slurry conveyance are major operations on and around mine and mill sites, from mine dewatering, to tailings transport, to water treatment processes. Conveyance systems in such applications can include great lengths of pipe materials along with pumps and monitoring instruments, and thus represent significant capital investments. Due to the variability of the physical and chemical properties of water and slurries, pipe materials are subject to a wide range of conditions. These can cause pipe wear and eventually failure leading to serious economic, environmental and social, consequences. While pressure-induced pipe failures (e.g., ruptures or ""bursts”) can be immediate, most failure mechanisms involve gradual processes. Scaling and sedimentation can present major problems for pipe systems conveying highly mineralized waters. Sedimentation generally refers to the deposition of suspended solids, such as sand, clay, silt, or organic matter onto pipe surfaces. This phenomenon can occur due to a decrease in water velocity or particle collisions with the pipe wall. Scaling, on the other hand, commonly refers to the deposition of precipitated mineral salts (including oxides and hydroxides) onto pipe surfaces. Mine waters often have extremely high ion concentrations (i.e., high dissolved solids content) due to their interaction with enormous surface areas of minerals, which are exposed during mining and processing operations (Brown and Barley, 2002). As these waters are transported, slight changes in temperature, pressure or chemistry (e.g., pH or ORP) can cause instability with respect to ion solubility such that salt precipitation begins to occur. “Seed” crystals can rapidly grow and attach to pipes, either due to local surface phenomenon near the pipe wall (e.g., which can promote coagulation) or sedimentation of the precipitated solid. Whether due to suspended or precipitated solids, as the solids begin to stick to pipe walls, “aging” or hardening processes can commence; and the build-up of scale can become self-perpetuating as the scale itself provides an attractive “nucleus” for further attachment of particles or crystal growth (Muryanto et al., 2014). Over time, scale-buildup reduces the effective pipe diameter, which can ultimately result in decreased flow velocity, clogging and, in some instances, bursting (Dirany et al., 2016)."

Jan 1, 2017

By Robert L. Akright

The Sumich (Victorine) gold mine is located in the Toiyabe Mountain Range on the east side of Victorine Canyon, a north-trending branch off Kingston Canyon in the northwest quarter of Section 27 and southwest quarter of Section 22, T16N, R43E, in the southern end of Lander County, Nevada (Fig. 1). HISTORY Discovered in 1862, the Victorine reached a peak of development between 1872 and 1887. The "Victorine" and "Morning Star" lode mining claims, located on the outcrop of a prominent auriferous quartz vein, were patented in 1869 and 1891, respectively. 1, respectively. Gold ore was mined underground in adits driven, on the level, directly into the side of the mountain. Ore brought to the surface was trammed about 457 m (1500 ft) south on a track constructed along the contour to ore bins. From this transfer point, the ore was moved by aerial tram to the bottom of the canyon then hauled by horse-drawn wagon to the mill located about 3.2 km (2 miles) east down Kingston Canyon. Exact details of the milling process used on the Victorine are lacking, but old reports mention water-driven stamp mills, amalgamation, chlorination, and cyanidation. Gold and silver mill products are reported to have been sent to England for final refining. High-grade gold values of 103 g/t (3 oz per ton) remaining in mine walls and on outcrops, attest to the lack of success in treating the Victorine ore in the early mills. The Victorine mine may have been worked sporadically after 1887 with little success. In 1934, control of the property was acquired by William P. Moloney, an attorney from Marion, OH, who also control- 1 led an interest in the successful Goldacres mine in Lander County, NV. This property was studied, sampled, and metallurgical tests were done in 1934, but no development resulted from this work.

Jan 1, 1990

By Harold L. Lovell

Problems associated with fines (minus 6 mm, 1/4-inch) production, preparation, and utilization have long plagued the coal industry and are now more acute than ever. Continuous deep mining systems create more fines which have moisture; content greater than natural levels from dust control spraying and often add substantial levels of mineral matter due to mining selectivity constraints. Frequently, during preparation, more -fines are developed to achieve improved component liberation. Coal consumers often specify small sizes whether for carbonization, combustion, or conversion. Wet beneficiation systems process fines by several' types of unit operations, but usually must also incorporate costly and complex dewatering systems to reduce the moisture content of the products. Existing pneumatic preparation systems are constrained between product equality and yield by the sharpness of separation. These limitations become more severe with decreasing particle size and increasing feed moisture content. Control of particulate emissions, both process and fugitive, during pneumatic preparation, can be forbidding. A pneumatic preparation-process which would overcome these constraints, could be most enticing. The DryFlo system is being evaluated to quantify performance characteristics as regards these constraints.

Jan 1, 1976

By K. P. Chong

Fracture toughness of oil shale is an essential property in fragmentation to optimize particle sizes and permeability distributions in in-situ processes. Fracture mechanics of oil shale has been based on conventional fracture mechanics using notched samples and assuming the material to be isotropic and elastic. Oil shale is a layered material more accurately characterized as transversely isotropic. The senior author proposes to use a semi- circular core specimen with a center crack subjected to three point bending. Singular crack tip elements with isoparametric elements are used. The precracked semi-circular disk is modeled under displacement loading. The effect of crack length on the non-dimensionalized stress intensity factor is investigated by strain energy method, ellipse method, and stress method. Very close agreements are found. The fracture toughness is obtained by compressing the specimen in to failure. Parameters such as oil yield are investigated.

Jan 1, 1984

By J. R. J. Edwards

Jaspilite, a mineral consisting of silica and iron oxide in varying proportions, is one of the host rocks of the high grade ore deposits situated in the Middleback Range of South Australia. As a result of laboratory investigations, a flowsheet was postulated for the beneficiation of jaspilite to produce an acceptable grade product for feeding to blast furnaces, The flowsheet involved the reduction of the hematite in the haspilite to magnetite, the grinding of the reduced product to 95 pct minus 325 mesh Tyler followed by wet magnetic separation, hydroseparation and filtration to yield a magnetite concentrate. Agglomeration of the fine concentrate would then be necessary to meet the physical requirements of blast furnace feed. To prove the postulated flowsheet, to obtain a more accurate estimate of costs and to obtain design data for a commercial installation, a pilot plant was constructed at Whyalla, South Australia.

Jan 1, 1960

By G. X. Wang

The nonliving dried water hyacinth (E. crassipes (Mart.) Solms) roots were investigated for biosorption of cadmium and lead and other heavy metal ions in aqueous solutions. Dried water hyacinth roots, when suspended in solution, strongly and rapidly sorb several different metal ions. Factors such as reaction time, pH, initial concentration of metal ions, presence of other metal ions and biomass concentration were investigated. Metal ions, including Cd2+ and Pb2+, were bound to the root in a very pH-dependent manner, with the binding increasing after about pH 3. High levels of removal were obtained. The adsorption was shown to follow the generalized Langmuir adsorption equation. The relative affinity of the roots for lead is greater than for cadmium. The maximum sorptions of the roots were about 33 and 86 mg/g for cadmium and lead, respectively. Only 15-20 minutes were required for the process of uptake onto the biomass to occur. The batch sorption kinetics of the uptake of cadmium and lead can be described by an apparent first-order reversible reaction model. The roots could be regenerated after the metal ions were stripped. A solution of CaCl2 in acidic medium appeared to be the best eluant for desorbing the sequestered Cd and Pb completely at pH 3. The kinetics of the metal stripping process was quite rapid. Successful desorption of Cd and Pb from the biomass by acidic CaCl2 solutions revealed that the metal uptake phenomenon is reversible, implying physical sorption of Cd and Pb.

Jan 1, 1997

By M. Soderstrom

In a solvent extraction (SX) plant, stage efficiency calculations are used to determine mixer efficiency. With modern extractants and mixing equipment, it is generally taken for granted that stage efficiencies will be above 95%, but this is not always the case. Dependant on mixer/solution conditions, stage efficiencies can occasionally be low, therefore leading to higher reagent usage. Proper methods to identify when stage efficiency performance is below expectations, and ways to identify if it is an equipment or chemical issue are valuable tools for a plant metallurgist. With these tools and skills an on-site metallurgist can more quickly return their SX plant to proper operation. This paper will discuss methods for analyzing stage efficiency, evaluating factors that may affect stage efficiency, and evaluating the impact of stage efficiency on the overall operation.

Jan 1, 2010

By John B. Goddard

Crystallization of ammonium paratungstate (APT) is frequently the last effective purification step in producing high-purity tungsten. However, crystallizer mother liquors are often several times higher in tungsten than predicted by the solubility of APT. The formation of heteropoly anions, particularly those containing phosphorus and silicon, is largely responsible. Solubility of tungsten in APT mother liquor can be linearly correlated with the concentration of these and other impurities. The problem can be overcome by direct treatment of the crystallizer feed solution with alum. By appropriate treatment, the aluminum hydroxide flocculates and is easily filtered, resulting in a purified low-aluminum crystallizer feed from which high APT yields can be attained.

Jan 1, 1984

By S. Chander

A series of nonionic and anionic surfactants were tested to enhance the flotation response of a low rank coal. An ethoxylated octyl phenol and several polypropylene polyethylene block copolymers were tested as nonionic surfactants. The anionic surfactant was a dioctyl sulfosuccinate. All the surfactants employed improved the yield significantly but the influence on grade was complex. Separate studies were conducted to determine the emulsification behavior of the surfactants. For the nonionic water soluble reagents tested, a correlation between emulsifying power of the surfactant and flotation was observed. An increase in the number of droplets produced in surfactant containing systems was considered to be the main reason for increase in the yield. Since it increased the number of collisions between dodecane droplets and coal particles. When a surfactant was introduced into the flotation pulp prior to addition of dodecane, it decreased the benefits of the surfactant significantly. The decrease was attributed to an increase in the wettability of coal and a decrease in the surfactant available for emulsification. When a suitable surfactant was added as a solution dissolved in the oily collector, a considerable increase in yield was observed.

Jan 1, 1993

By T. M. Gurr

In response to concerns voiced by local, state, and federal agencies and various environmental groups, the Central Florida Phosphate Industry and various governmental agencies have been investigating methods to accelerate the consolidation of waste clays generated during phosphate washing and beneficiation processes. The objectives of research efforts have been to reduce the storage volumes required for clay waste, accelerate reclamation and to return the land to approximate pre-mining topography. Government and industry research to accelerate waste clay consolidation has evolved two general methods: gravity thickening and chemical flocculation. Gardinier, Inc. one of the phosphate mining companies, evaluated the use of synthetic (polyacrylamide) flocculants as an alternate waste clay thickening method in response to mining conditions encountered at their Fort Meade Mine and the proposed North Hardee County extension of the Fort Meade mine (Figure 1). After considerable research and evaluation, the Alsthom-Atlantic Clariflux Super-flocculation method was chosen by Gardinier, Inc. as a method to seriously consider for use at their Fort Meade mine.

Jan 1, 1986

By A. H. Kaksonen

Numerous reactor designs for biological sulfate reduction have been reported. Fluidized-bed bioreactors (FBR) can efficiently retain biomass and allow high mass transfer and reaction rates. This work reviews the development of various sulfate-reducing FBR processes for treating acidic metal- and sulfate-containing waters and recovering metals from bioleaching liquors. The FBR process performance was evaluated with continuous flow experiments under various operational conditions: fluidization rates, influent pH values, metal, sulfate and salt concentrations, hydraulic retention times, electron and carbon sources, and temperatures. Substrate utilization and sulfide inhibition kinetics were determined with batch FBR-kinetic experiments. An artificial neural network (ANN) model was used to predict the performance of the FBR. Sulfate-reducing bacteria (SRB) were characterized in FBRs with molecular and culture-based approaches with the aim to gain a better understating of the bioprocesses. Based on the studies, FBRs are well suited for the combined removal of metals, acidity and sulfate from water.

Jan 1, 2010

By John E. Good

A new coal boom is under way in western Canada. As recently as the mid-1960's, the coal industry in western Canada was considered stagnant and, by some people, dying. But Japan's growing need for coking coal, which became more pronounced in 1966, sparked great interest in western Canadian reserves.' As a result of a rapidly expanding export market and growth in domestic demand, Canadian coal production spurted to 16.6 million tons in 1970. Production in 1965 was 11.5 million tons. Today, about 60 percent of Canada's output comes from western Canada, but by 1975, 87 percent (23.1 million tons) is expected to come from this area, and 96 percent (68.3 million tons) by 1990. Opening, developing and operating new coal mines to meet the needs of a rapidly expanding market for western Canadian metallurgical coals pose some unique and difficult problems. Covering nearly every aspect of opening properties in remote areas, the problems are met in exploration, transportation, construction, mine operations, coal preparation, manpower and ecology. Paul Weir Company has been involved as coal consultants on various projects in western Canada for some years. In presenting this paper, we make no attempt to present an in-depth or detailed analysis of any one specific situation. Each has, or would have, its own peculiarities or characteristics, both physical and economic. Instead, the objective is to provide for those not intimately

Jan 1, 1972

By Peter Bush

The deposition of metastable carbonate minerals in ar. aid, sheltered, coastal environment, leads to the formation of a flat, coastel, sabkha plain. The ground waters of the sabkha plain are modified by evaporation, precipitation of salts and reaction between ions in solution and the host carbonates. The resulting brine is similar to those found in fluid inclusions associated with Mississippi Valley type deposits. The aragonite and high magnesium calcite found in the sediments can concentrate lead and zinc from sea water. On diagenesis the lead and zinc are released into the sabkha brines.

Jan 1, 1979

By R. Gradnik

The continuous need for infrastructure expansion forces the mining industry to develop underground structures into more sensitive and violent environments. When underground excavation enters into deep and high stress rock conditions, geotechnical designers find themselves faced with the difficult task of selecting a rock support system that will meet today's stringent requirements. Whatever support system is chosen, it is mandatory that potential rock movement be controlled. All this has intensified the development of safety systems and new, unique solutions which can enable construction companies to go both, further and deeper, without reducing the level of safety. To address these needs, Atlas Copco developed the Roofex® bolt, specifically designed to withstand large static and dynamic deformations under prespecified load conditions. The Roofex Rock Bolt acts as stiff support up to a designable load level before the sliding effect of the mechanical frictional system is triggered and allows highly controlled rock mass movement without loosing the support function.

Jan 1, 2011

By S. K. Kawatra, H. J. Haselhuhn

"Thickening is used during two primary mineral processing operations: water removal and desliming. During water removal, the pulp density is increased through the injection of flocculants. These flocs settle and create a dense pulp while clarified water is removed through the overflow. During desliming, fine particles are removed through the overflow. Desliming can also be used as a mineral separation process known as selective flocculation-dispersion, where valuable minerals are flocculated and gangue minerals remain dispersed and exit through the overflow.There are many ways to analyze thickener performance on a laboratory scale, but these analyses often do not correlate well with full-scale performance. Some pilot-scale systems have been designed using a semicontinuous approach, but the amount of material required to perform their tests can make semicontinuous pilot thickeners impractical for most applications. This paper focuses on the design and optimization of a continuous pilot-scale deslime thickener that requires minimal material to operate. The design, optimization strategy, and an example study of reagent selection are demonstrated. IntroductionMany laboratory methods have been employed to size and optimize thickener performance. The most common of these include the Coe and Clevenger method and methods derived from the Kynch theory of sedimentation. The Coe and Clevenger method was developed in 1916 and was proven for slurries that do not require flocculation to settle. This method proposed that the settling rate of the pulp is only a function of the solids concentration. It is executed by creating slurries of several different concentrations of solids and performing bench-scale settling tests in graduated cylinders. For each concentration, a thickener unit area can be determined using the following equation (Coe and Clevenger, 1916; Laros, Slottee and Baczek, 2002):"

Jan 1, 2017

By T. J. Lutz, S. Gallagher, J. R. Srednicki, J. J. Sammarco

The Illuminating Engineering Society of North America reports that an underground mine is the most difficult environment to illuminate (Rea, 2000). Researchers at the U.S. National Institute for Occupational Safety and Health (NIOSH) Office of Mine Safety and Health Research (OMSHR) are conducting ongoing studies designed to explore different lighting technologies for improving mine safety. Underground miners use different visual cues to escape from a smoke-filled environment. Primary and secondary escapeways are marked with reflective ceiling tags of various colors. Miners also look for mine rail tracks. The main objective of this paper is to compare different lighting types and ceiling tag colors to differentiate what works best in a smoke-filled environment. Various cap lamps (LED and incandescent) and lasers (red, blue, green) were compared to see which options resulted in the longest detection distances for red, green and blue reflective markers and a section of mine rail track. All targets advanced toward the human subject inside of a smoke-filled room to simulate the subject walking in a mine environment. Detection distances were recorded and analyzed to find the best cap lamp, laser color and target color in a smoke environment. Results show that cap lamp, laser color and target color do make a difference in detection distances and are perceived differently based on subject age. Cap lamps were superior to lasers in all circumstances of ceiling tag detection, with the exception of the green laser. The incandescent cap lamp worked best in the simulated smoke compared to the LED cap lamps. The green laser was the best color for detecting the tags and track compared to the red and blue lasers. The green tags were the easiest color to detect on the ceiling. On average, the track was easier for the subjects to detect than the ceiling tags.

Jan 1, 2013

By F. Dehghani, M. Kebe, H. Askari-Sabzkoohi, T. Ghosh

The depletion of bauxite reserves around the world has necessitated the search for viable alternative sources of aluminum. The major non-bauxite source of aluminum is alunite [KAl3 (SO4)2(OH)6]. Lixiviation is the common industrial process to recover aluminum from alunite. Due to the presence of quartz (40%) as the main gangue mineral, this process causes the formation of Sodium aluminosilicate and Potassium aluminosilicate complexes that leads to loss of alunite, and chemical reagents. Thus, pre-concentration of alunite is required to remove the gangue minerals. Because of the low degrees of freedom (DOF) of alunite, froth flotation, as a preconcentration method, is a viable alternative to increase selectivity in downstream processes. In this work, the possibility of Alunite preconcentration with micro flotation and mechanical flotation cells was studied. The influence of type and dosage of collector, pH, solid percent, particles sizes were considered on the flotation. Flotation tests were designed based on Taguchi method, followed by performing based on surface charge differential between alunite and quartz on direct and revers flotation. In the reverse flotation, Ca+ 2 and Ba+ 2 were used to activate the quartz surface. Under optimum conditions of reverse flotation, alunite grade and recovery were 40% and 62.1% respectively. In the direct flotation, the surface of alunite was activated by F- . The grade and recovery were 50 and 89%, respectively.

Mar 2, 2022

By Y. C. Guan

The leaching kinetics of chalcopyrite in ammonium iodide solutions with iodine has been studied using rotating disc. The variables studied J include the concentrations of lixiviants, rotation speed, pH of the solution, reaction temperature, and reaction product layer. The leaching rate was found to be independent with the disc rotating speed. The apparent activation energy was measured to be about 50 kJ/mole from 15°C to 35°C, and 30.3 kJ/mole from 35°C to 60°C. Experimental findings were described by a kinetic model, and the overall rate was found to be: (formula)

Jan 1, 1997

By A. Gungor

Thermal treatment can significantly improve industrial comminution operations by reducing energy requirements and increasing mineral liberation. The assistance of thermal pretreatment prior to grinding by microwave heating is scrutinized in this study. For this purpose three copper ore samples with different chemical composition were used. To see the effect of microwave heating on ore; work index, breakage rate and breakage distribution functions of original and heat treated samples were examined. The results obtained in this study did not show significant improvement in the grindability characteristics of the studied ores with microwave heat treatment. The inadequate amount of microwave transparent matrix was the main reason for the absence of cracks and micro-fractures in the microwave heated copper samples.

Jan 1, 1999