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By W. A. Rickelton, A. J. Robertson

The ability of triisobutylphosphine sulfides to selectively recover silver from acidic sulfate solutions containing zinc and copper is described. Selectivity is explained in terms of the concept of hard and son Lewis acids and bases. Silver is stripped from the solvent using a novel strip feed (thiosulfate salt), and the recovery of metallic silver from the strip liquor by electrolysis or cementation is suggested. The high selectivity of extraction for silver and the utility of the stripping reagent are demonstrated in continuous, countercurrent, mini-plant tests. Important reagent properties, such as hydrolytic stability and low aqueous solubility, are discussed.

Jan 1, 1988

By Shaoxian Song, Shouci Lu, Jingyon Gou, Pan Yiuwen

The calculated potential energies of interaction between hydrophobic particle of three minerals (rhodochrosite, quartz and talc) and air bubble show that the energy of hydrophobic interaction is the dominant factor for their attachment. An attachment rate equation, integrating particle -bubble collision and adhesion by introducing a "capture efficiency", has been put forward. It was found that the hydrophobic particle-bubble aggregates can not be disconnected in the bulk zone of flotation cell, whereas in the impeller zone the breakup may occur, particularly for the coarser particles captured by bubble. Finally, the flotation rate constant was estimated theoretically and verified by experiments.

Jan 1, 1995

By Jan K. Wolski

Detection of the air recirculation branches within a large ventilation network may be difficult, therefore a PC computer routine has been developed to perform this task in an efficient and reliable manner. This paper describes the method illustrated using a network with complex multi-recirculation circuits. The fact that only the air flow directions and not the flow rates are used in calculations is of some interest. The air recirculation during a real mine fire is demonstrated using the PCVENT program, whose version 4.0 includes current information about any recirculation branches during network calculations or during a fire simulation. This paper also discusses some transient problems related to air recirculation, and gives examples.

Jan 1, 1993

By L. D. Jayaweera, R. G. Robins

The pocessing of gold bearing sulphide minerals wr ich contain arsenopyrite and other complex arsenic sulphide minerals results in arsenic containing emissions and effluents which must be given careful consideration in relation to clean air and clean water standards. The sources of arsenic and the various process options for treating arsenical gold ores and concentrates are briefly reviewed. The problem relating to the removal of arsenic from gaseous emissions from roasting processes is considered. Residues from aqueous processing contain a variety of arsenical materials which have not been characterised, and the long-term stability of these is suspect. 'rhe use of lime to stabilise aqueous residues as either calcium arsenate or calcium arsenite has been shown to be inadequate for long term disposal since both compounds are converted into calcium carbonate due to the influence of carbon dioxide in the atmosphere. Ferric ion solutions have been used to precipitate ferric arsenate or to form ferric hydroxide which binds the arsenic for short term disposal, The long term stability of these ferric materials is poor, but could lead to the acceptance of a slow release option rather than complete containment of residues.

Jan 1, 1991

By D. Marinakis

Gas hydrates (GH) are crystalline compounds consisting of a water molecule lattice, in the cages of which suitably sized molecules, such as methane or other light hydrocarbons, are confined. Although this solid phase looks similar to common ice, it contains substantial amounts of natural gas. The necessary conditions for natural gas hydrate formation exist in some deep-sea marine environments and in permafrost regions. Despite the extensive research, which has been conducted in the fields of exploration and exploitation of natural gas hydrate deposits over the last decades, there is still great uncertainty over the estimated amount of hydrates that these reserves bear. The present work examines some key features of sediments which affect their capacity to host gas hydrates. The hydrate content of a natural hydrate formation is correlated qualitatively with factors such as temperature, effective porosity, mineralogical composition, bio-surfactants, pore pressure and compaction pressure.

Jan 1, 2006

By George D. Tikkanen

The world supply of zinc and lead is reviewed. The nature of zinc and lead deposits, production constraints, current production and reserves, new developments, possible future developments, and closures are considered. Lead sup- plies for the future are adequate. Zinc supplies are expected to tighten in the longer term due to growth in zinc consumption and orebody depletion.

Jan 1, 1986

By Jack G. Pippenger

The Coteau Properties Co.'s Freedom Mine is a surface lignite mine that uses large draglines, trucks and shovels, tractor-scrapers and bulldozers to uncover a single coal seam. In 1989, a work order system was instituted to record data by equipment type, cost, productivity and distance. The system was also used to provide historical information to plan the most efficient and economic use of each equipment type in the mining operation. The Coteau Properties Co. is a wholly owned subsidiary of The North American Coal Corp. The company was formed in 1972 to supply lignite from its Beulah-Hazen coal reserve to a coal gasification project and an electrical generating facility located near Beulah, ND. The reserve consists of a single coal seam between 3 and 7 m (10 to 23 ft) thick. The overburden above the coal is predominately glacial tills and clays and ranges from 6 m (20 ft) to more than 60 m (200 ft) thick.

Jan 1, 1994

By W. W. Roepke, B. D. Hanson

A major problem facing the coal mining industry today is the need to meet more stringent dust standards due to quartz. When secondary suppress ion is not adequate, the time-consuming and costly cut-and-try method of modifying the mining machine is used in the hope that it will reduce dust generation. The Coal Cutting Technology Group, at the Bureau of Mines' Twin Cities Research Center, has developed an inter-active computer program for drum- type cutting systems to help identify, in advance, modifications that offer the best potential for reducing dust. The program, Relative Dustiness Indicator (REDI), evaluates machine dimensions, seam characteristics, and operator-controllable variables for dust generaton, energy, forces, and product ion.

Jan 1, 1986

By J. Yordan, J. Zinterer

Effective removal of ink particles by froth flotation is of up-most importance in paper recycling. In this study, the potential use of talc particles as carriers of difficult-to-float fine ink particles is investigated. In order to accomplish ink particles removal, the interactions between talc and oily- ink particles in aqueous solutions containing flotation chemicals was studied by zeta potential distribution measurements and with the impinging jet apparatus. The chemical conditions under which talc-ink adhesion occurs are identified and reported.

Jan 1, 2003

By S. Formby, J. Avraamides

Transportation of sodium cyanide from factory to minesite often attracts adverse comment from both the community and government agencies. In Western Australia the transportation of 30% w/w aqueous sodium cyanide solution raised fears in the community concerning the safety of such material in the event of spillage. The Chemistry Centre of Western Australia initiated a study of the effects of such a spill, to determine appropriate short and long term response strategies. Factors which were considered included the rate of hydrogen cyanide gas release under various climatic and soil conditions and the effect of alternative treatments in reducing such emissions. The data collected have been used to plan emergency response procedures.

Jan 1, 1989

By Bruce A. McKinstry

For many major mining projects the time frame from initial planning to production can be measured in terms of decades. Hecla's Silver Shaft project, which is scheduled to go into production by the end of this year and includes a complete surface facility, shaft with an ultimate depth of 2,348 meters (7,700 feet), complete ore pass and loading pocket system, and 610 meters (2,000 feet) of development drifting and stope preparation, was initially concieved in the Fall of 1979. This duration of a mere four years from conceptual engineering to production is a testimonial to what can be accomplished when a progressive mining company and an innovative contractor work together as a team rather than developing into two warring camps as often happens.

Jan 1, 1983

By Robert D. Gibson, E. Donald McKay, Paul B. DuMontelle

Subsidence of the land surface in some parts of Illinois is caused by underground coal mining. The U.S. Bureau of Mines is backfilling abandoned mines at selected sites in southwestern Illinois in an attempt to support failing mine openings. The Illinois State Geological Survey assists the Bureau by developing geologic and engineering information. As part of this investigation, television probes of fifteen injection borings in Belleville augmented conventional methods of study. The television probes of uncased sections of borings revealed several phenomena. Water erosion caused shale beds to slough, which partially filled some borings. Fractures caused by subsidence were identified, and excellent views of underground mine workings provided documentation of the mining method. The condition of mine timber was evaluated. Pack walls supported some openings. Both floor heave and roof fall were observed to be causes of failure in the mines.

Jan 1, 1982

By Michael D. Zuber

This paper discusses the use of a coalbed methane simulator that has been modified to account for the removal of grid blocks as a function of time to estimate gas emission and production for a variety of mine-associated problems. The specialized features of the simulator are presented. Example applications illustrate the models' use in estimating methane emission rates during mine roadway development, and estimation of longwall panel degasification by horizontal boreholes.

Jan 1, 1997

By D. W. Boening

Xanthate salts have demonstrated effectiveness as a flotation reagent in the recovery of heavy metals from mining wastewater. However, due to their strong ionic potentials, they are generally toxic to aquatic life. Under ambient environmental conditions, the half¬life of a xanthate is approximately four days. As a soluble salt, xanthates will complex with the metallic ions contained in water and fish. Some researchers have proposed that this complexing may extend the halflife, as well as optimizing the transfer of a given metal from solution across the gill surface. Leakage of xanthate treated wastewater into the surrounding surface waters is the most common route of exposure for aquatic plants, invertebrates and fish. Because this is an emerging mineral-recovery technology, more information is needed regarding xanthate toxicity and environmental fate before environmental impacts can be assessed with any degree of certainty.

Jan 1, 1999

By Alain A. Sonntag

This paper presents the most recent developments in KREBS technology directed towards treating higher throughputs, increasing efficiencies and providing further improvement in SX technology with a new concept: the submerged launder. Industrial plants built in the last past few years and using these improvements are described.

Jan 1, 1989

By R. Lai

This paper describes the application of a cyclonic flotation column (CFC) for coal cleaning. A CFC makes use of centrifugal force to create a density gradient in a column to augment the froth flotation process. In a CFC, a series of angular helical inserts is attached to the wall of a conventional column, and coal slurry is mixed with a series of impellers attached to a central shaft. The hydrophobic froth concentrates near the center shaft and moves upward, while the relatively heavy hydrophilic particles concentrate near the wall and are guided downward by the helical inserts. The results of pyritic sulfur removal from an Upper Freeport coal during CFC flotation are discussed.

Jan 1, 2003

By L. Alan Weakly

Coal mines and power plants utilize different methods to control dust for the safety of their workers and to protect their installations. The methods that they use are limited by the Environmental Protection Agency or the states in which they operate. Now there is a new technology for controlling dust at conveyor transfers! The Passive Enclosure Dust Control System utilizes several proven technologies to mitigate fugitive dust. This new system has been proven to be four times more effective than standard enclosures utilizing bag house collection and is considerably less expensive to install and operate.

Jan 1, 2000

By James P. Rider, Robert P. Vinson, Fred N. Kissell, Jon C. Volkwein, Gregory J. Chekan, Jay F. Colinet

The Thermo-MIE personal DataRAM dust monitor (pDR) is a light-scattering instrument approved for use in gassy underground mines by the U.S. Mine Safety and Health Administration (MSHA). However, the use of lightscattering monitors has been inhibited by concerns about inaccurate readings resulting from changes in dust size distribution and composition, as well as concerns about the impact of moisture in the mine air. Because of this concern, the National Institute for Occupational Safety and Health (NIOSH) has evaluated the pDR using available data from laboratory tests and mine surveys. The data show that accuracy can vary widely from test to test and mine to mine. In most cases, the results can be improved by using a companion gravimetric measurement to adjust the pDR data.

Jan 1, 2005

By Douglas J. Pendrell, Marvin D. Simmons, E. Raymond Boc

The U. S. Army Corps of Engineers is in the early stages of design for an estimated 14 m (46 ft) diameter tunnel in northeast New Jersey. This tunnel will carry flood waters from the upper end of the Pompton River in Wayne County, to an outlet in Newark Bay, a distance of 33 km (20.5 miles). The tunnel will be constructed by a tunnel boring machine (TBM), the size of which is unprecedented at the present time. The alignment is through Triassic and Jurassic sandstones, siltstones, and shales that include three beds of basalt that range in thickness from 76 to 310 m (250 to 1020 ft).

Jan 1, 1991

By J. R. Sturgul

A dynamic input-output model for a coal power enterprise that now includes four underground coal mines, three coal washing plants, a power plant and a railway transportation system was developed. The model is applied to analyze investment alternatives for long-term development, including the expansion of existing mines, the opening of new mines, the construction of new coal washing and power plants and the upgrading of the railway system. As a result, the optimal investment strategy with capital schedules and projected sector outputs is obtained. Also, the importance of the new power plant to the strategic development of the company is demonstrated. It is concluded that, without applying a dynamic input-output model, it would be much more difficult or impossible to conduct such a systematic and compete analysis.

Jan 1, 1999