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By P. V. Avotins, D. R. Nagaraj, S. S. Wang

Xanthates and dithiophosphates are the most commonly used collectors in the flotation of sulfide minerals. Other reagents such as thionocarbamates, mercaptobenzothiazoles (MBT), mercaptans and xanthogen formates occupy niche positions in industrial collector use. Over the last ten years there has been much activity by chemical companies to develop new collector compositions. The new collectors are aimed at meeting specific process needs such as recovering an increment of valuable metals, improved sulfide separations, increased flotation kinetics, and reducing reagents costs. A review of the patent literature shows that American Cyanamid (Cytec), Dow Chemical, Phillips Petroleum, Sentrachem Ltd., Henkel, Montan Chemicals and Elf Aquitaine, among others, have been active in sulfide collector research. Several companies have achieved considerable success in laboratory and plant tests of the new collectors; however, commercial acceptance for plant usage has been slow. Those most advanced have been plant tested extensively and some are in day-to-day use. The new collector types in this category are: Modified thionocarbamates, dithiophosphinates, organic sulfides, trithiocarbonates, monothiophosphates, and modified thioureas. Others such as substituted mercaptobenzothiazoles and monothiophosphinates have been tested in the laboratory. The chemistry of collectors developed in the last 10 years, their preparation, physical properties and their potential for commercial use are reviewed in this paper.

Jan 1, 1994

By K. S. E. Forssberg, K. Hanumantha Roa

Batch flotation tests are carried out with phosphatic material from LKAB, Sweden containing carbonatic and siliceous gangue while using sodium oleate as collector and sodium silicate as modifier. The pulp liquid is analysed for oleate, silicate, carbon dioxide, calcium, magnesium and phosphorous after each flotation test under different reagent conditions and flotation pH. Theoretical calculations of thermodynamic chemical equilibria in apatite-calcite-sodium oleate-sodium silicate system have been carried out with the help of SOLGASWATER computer program. During the calculations, the chemical variables are maintained similar to the operating chemical variables in flotation. A comparision between the experimental and theoretical chemical equilibria has been made and the flotation behaviour of apatite is discussed with reference to the theoretically calculated pulp model.

Jan 1, 1993

By D. K. Jorgensen

The Bullfrog and Montgomery-Shoshone deposits, near Beatty, NV, have a combined drill-indicated reserve of 15.8 Mt (17.4 million st) of ore. Average grade is 3.5 g/t (0.103 oz per st) gold and 8.2 g/t (0.24 oz per st) silver. The deposits occur in Miocene volcanic rocks that underwent large-scale movement within a detachment-faulted terrane. The principal host to gold mineralization is a strongly welded rhyolitic tuff that experienced brittle deformation during plate movement. Open space fractures and breccia were filled with quartz, calcite, and adularia accompanied by lesser pyrite, gold, and acanthite. Gold occurs as micrometer-sized particles within and adjacent to the low-angle fault and along associated listric-normal and tear faults. The Bullfrog and Montgomery-Shoshone are volcanic-hosted, detachment fault-related, epithermal quartz calcite stockwork gold deposits. Bullfrog's minable reserve is 13 Mt (14.3 million st) of ore grading 3.8 g/t (0.11 oz per st) of gold. At Montgomery-Shoshone, 2.7 Mt (3 million st) minable tons at 2.5 g/t (0.072 oz per st) are present. Preproduction stripping has begun at the Bullfrog ore body. A 7.7-kt/d (8500-stpd) carbon-in-pulp (CIP) mill is under construction. In 1990, Bond Gold expects to be producing about 6.2 t/a (200,000 oz per year) of gold.

Jan 1, 1990

By H. Zhu, A. G. Journel

Qualitative and interpretive information as obtained from geological and/or geophysical studies, in addition to precise measurement, is incorporated into the estimation process through an indicator variable. The indicator conditioned estimator is formulated as a cokriging, and its expression is data value dependent as opposed to that of the traditional kriging estimators. The solution of the dual cokriging system provides simultaneously an estimate of the unknown and an estimate of the conditional probability that the unknown belongs to a specific population or class. Being an unbiased and minimum-error-variance estimator by construction, the indicator conditioned estimator is better in the least square sense than the ordinary kriging estimator because it uses additional information carried by the indicator data. A case study using a large reference database is presented; the indicator conditioned estimates have a smaller conditional bias and a smaller error variance than the ordinary kriging estimates. The results also showed that the indicator conditioned estimator is more efficient for selection in mining.

Jan 1, 1990

By D. C. Seidel, W. K. Tolley

Supercritical water alters the structure of common sulfide minerals by partially removing sulfur from the mineral structure. This discovery has been applied to the treatment of pyritic gold ores to improve precious metal recovery without generating or utilizing environmentally sensitive products such as S02, chlorine, or cyanide. Pretreating pyrite concentrates in supercritical water under mildly oxidizing conditions provided by certain metal oxides or oxygen improved gold leaching using thiourea. The pretreatment differs from chlorination or roast pretreatments in that elemental sulfur rather than sulfuric acid is the major product. A pyritic ore containing 58 g/mt Au was pretreated with oxygenated supercritical water at 24 MPa and 400°C, then leached with 20 g/L thiourea. With pretreatment, gold recovery was 90%; by contrast, gold recovery was below 10% without pretreatment.

Jan 1, 1990

By Arpad E. Torma

The introduction of biotechnological principles in hydrometallurgy has created new opportunities and challenges for the industry of mineral processing. During the 1950's and 608s, the mining wastes and unused complex mineral resources have been successfully treated in bacterial assisted heap and dump leaching processes, especially for the production of copper and uranium. The economic viability of bio- leaching technology lead to its world-wide acceptance by the mining industries. During the 1970's this technology grew into a more structured discipline which is called "biohydrometallurgy". Currently, bioleaching techniques are ready to be used, in addition to copper and uranium, for the extraction of cobalt, nickel, zinc, gold and silver from diverse mineral resources and for the desulfurization of certain coals. However, in a foreseeable future the biohydrometallurgical processes may be applied also for the treatment of high- grade ores and mineral concentrates using native and/or genetically engineered microorganisms.

Jan 1, 1989

By R. Frenette, A. W. Mo, H. A. Hamza

Fine particles present major technical and economic problems to those who deal with solid/liquid separation processes. In the coal industry the problem is compounded by the large amounts of produced fines such as those present in Western Canadian coals. Flocculants in the form of high molecular weight water soluble polymers are commonly considered an effective solution for the enhancement of the separation process. These reagents are relatively expensive especially when considering a low-price commodity such as coal. Optimization of the use of these reagents is therefore an operational necessity. Six polymers were evaluated as to their effectiveness in flocculating a fine coal tailing. Results were compared with those for a reference flocculant, in-use at that time in the washery. It was shown that, in general, flocculants significantly improve the solid/liquid separation process. The ranking of the flocculants as to their effectiveness in settling and filtration indicated that the best flocculants for settling were not necessarily the most effective for filtration. Flocculants that showed the best filtration improvement were generally cationic and those best for settling were anionic.

Jan 1, 1988

By Steven W. Hunt, J. Patrick Powers, Roger C. Ilsley

Artificial groundwater recharge has been used successfully to mitigate water level drawdown in upper alluvial deposits during construction of the Milwaukee deep rock tunnels. Recharge wells in rock as well as soil were used. The effort reduced settlements from consolidation of compressible estuarine deposits, and has minimized damage to existing structures. The paper describes the geology that presented the consolidation problem, and the hydrogeologic conditions that caused the drawdowns. Also presented are the details of recharge well design, construction, operation and performance in an urban environment. The project design calls for grouting and lining of the tunnels to control groundwater in the long term.

Jan 1, 1991

By R. E. Johnson, W. Kat, B. R. Palmer, van Sandwijk A., G. Van Weert, S. Honingh

In-plant recycling of dust from iron making BF's creates undesirable circulating loads of volatile trace elements such as zinc and lead. Disposal of such dusts creates environmental problems, hence a separate treatment is indicated. Since the bulk of the zinc and lead compounds occurs in the fine dust fraction; hydrocycloning the slurry from the BF gas cleaning operation results in upgrading the material for treatment. A process has been proposed, whereby the zinc and lead are solubilized from the fine fraction with spent hydrochloric acid from steel pickling. The stoichiometry of this autoclave oxidation process is adjusted to simultaneously precipitate, by oxyhydrolysis, most of the iron for recycling to the BF's. Lead and zinc are successively recovered from the filtrate as low chloride precipitates. This paper describes additional testwork, leading to the design of a pilot plant which was planned to begin operation in 1992.

Jan 1, 1993

By M. S. Janssen

The development of a design equation for, and the testing of, a constant- flow airlift pump IS described. The predictions of the new airlift model agree with the results of experiments carried out using riser diameters between 0.025 and 0.300 m, submergence depths between 5 and 10 m, suspension densities between 1000 and 1650 kg/m3, and a solids dg of 70 to 100µm. The predictions o the model also agree with data from the literature for submergence depths that reached 130 m. This airlift model was employed to simulate the pulp flow through a series of tanks, each of which was fitted with an airlift pump to transfer the suspension to the next tank. Particular attention was paid to the riser diameter, submergence of the airlift pump, and control of the air supply to the airlift pump during the simulated operation of a series of tanks. The results of the simulation highlight some design parameters that could affect the efficiency and operation of a plant that employs airlift pumps to transfer suspensions.

Jan 1, 1989

By Winfield G. Wright, Philip L. Verplanck, Douglas B. Yager, Dana J. Bove, M. Alisa Mast

The upper Animas River watershed is affected by metal-rich drainage from abandoned mines and by natural weathering of mineralized bedrock. To investigate the importance of natural metal sources, surface waters were sampled in a minimally mined but intensely altered area of the watershed. Water chemistry was strongly controlled by the degree of bedrock alteration. Propylitically altered rocks, which contain calcite, produced neutral waters with low metal concentrations, whereas quartz-sericite-pyrite alteration was characterized by acid-sulfate type waters with high metal concentrations. A mass-balance approach was used to estimate natural metal sources, which accounted for 56-905 of the dissolved metal load discharging from the study area

Jan 1, 2000

By Alden B. Carpenter

The Dead Sea is the only relatively large body of surface water having bromide concentrations comparable to those in the brines of the Smackover Formation in Arkansas. The Dead Sea, like the Smackover brines, contains a great deal of calcium and is very low in sulfate and iodide. The relationships between potassium, divalent cations, and chloride indicate that over 20 percent of the bromide in the Dead Sea is derived from some source other than by the evaporation of sea water. A similar type of study of the Smackover brines in Arkansas indicates that approximately 60 percent of the bromide has been derived from some source other than sea water. Both the Dead Sea and Smackover brines are very low in iodide suggesting that the excess bromide has not been derived from organic matter. The origin of the excess bromide is probably the same for both of these brines, but the source of this bromide remains unknown.

Jan 1, 1978

By G. A. Doyle

Until the suspension of conventional operations in 1996, the White Pine Mine was the second-largest active underground copper mine in the United States, underlying an area of approximately 30 km2 (13 sq. miles) in the Upper Peninsula of Michigan. The mine operator intends to initiate in-stope solution copper mining by circulating a solution (lixiviant) of mine water, sulfuric acid and ferric iron through rubblized ore. As planned, the solution would be retired in the mined-out stopes following completion of the solution-mining activities. Investigations into the fate of the retired solution indicated that the solution, through time, would change from an acidic, metal-rich solution to a near-neutral, reducing solution containing much lower concentrations of metals. Investigations included reaction-path modeling (EQ3/6) and laboratory and in-mine tests. The combination of neutralization and reduction will result in precipitation of most metals, primarily as metallic sulfates, chlorides and sulfides.

Jan 1, 1997

By David I. Dr. Hoyer

The Hicom mill is a conical mill in which a ball or autogenous load tumbles within a high-intensity acceleration field. An autogenous Hicom mill with a power density of about 1100 kw/m3 and a volume of just 4 litres reduced a 50 m quartzite feed to 90% passing 38 microns at a feed rate of 160kg/h (in closed circuit with a hydrocyclone). Batch tests have identified fracture, chipping and abrasion breakage mechanisms at pebble sizes of 5 to 50 mm. The special behaviour of the load in Hicom mills was exploited to develop a novel technique for estimating steady state autogenous load size distributions.

Jan 1, 1992

By Bernardo Portillo, Alejandro Perez, Daniel Norrgran, Joseph Wernham

High gradient permanent magnetic separators (termed "Ferrous Wheel") are described as used to recover the iron bearing minerals from mill tailings at the Grupo Acerero del Norte's Hercules iron mines in Coahuila, Mexico. The pilot scale test work as well as the "in-plant" test work provided the basis for a 385 MTPH plant expansion to be commissioned late in 1995. Approximately 6 million metric tons of flotation tailings averaging 50 percent iron, mostly as hematite, are contained in two separate ponds. The tailings are relatively fine at 93 percent -200 mesh and 72 percent -500 mesh. After testing various recovery methods, a high gradient permanent magnetic separator was selected to produce a preconcentrate prior to flotation. The separator uses a flux converging matrix to generate high gradient magnetic fields and capture the hematite. The advantage of the Ferrous Wheel high gradient permanent magnetic separator is the use of permanent magnets as opposed to electro-magnets. Further the vertical rotating ring is much more conducive to matrix cleaning as opposed to the conventional horizontal ring separators. This feature also allows the use of a wide range of matrix materials to achieve the optimum metallurgical response

Jan 1, 1995

By J. E. Hoffman, Corby G. Anderson, T. J. Keefe, O&apos, Suzzann M. Nordwick

Antimony removal has become necessary as it is commonly found in precious metal refractory ore bodies. The Sunshine Mine in Kellogg, Idaho has recovered metallic electrowon antimony from its argentiferous tetrahedrite (Cu2S'Sb2S3) deposits for over fifty years. Recently, Sunshine conducted an intense research effort to improve and modernize its antimony facility. This paper presents information which was learned about the antimony electrowinning processes and the development of a single¬-electrolyte antimony electrowinning technology. The relevant effects of process variables were investigated. The research results and the relevant chemistries involved in metallic antimony electrowinning will be discussed.

Jan 1, 1993

By K. M. Stone, N. J. G. Masson, A. C. Woollett

The Jabali zinc deposit in Yemen contains at least 9.4 Mt (10.4 million st) of ore at a grade of 10.7% zinc, 2.2% lead and 77 g/t (2.2 opst) silver. The zinc occurs as smithsonite with minor hydrozincite. The Jabali ore does not produce a zinc concentrate of sufficient grade to be acceptable to a conventional zinc smelter, and it has been necessary to formulate a less-conventional development plan. This involves the construction of a mine and concentrator at Jabali and a metal production facility using a new flowsheet designed specifically for the treatment of oxide material at Yanbu, Saudi Arabia. To give the facility the necessary economies of scale, the Jabali concentrate will be supplemented by feed from other deposits, this may be either oxide or sulfide material. The paper outlines the geology and proposed mining and treatment operations at Jabali, presents the flowsheet for Yanbu and estimates preliminary costs for both operations.

Jan 1, 2003

By James J. Guesk, Robert W. Reisinger, Timothy C. Richmond

A high-altitude (2,900 m [9,500 ft]) historic underground copper mine in Wyoming is discharging copper-laden water with a neutral pH into an otherwise pristine creek. The Wyoming Abandoned Mine Land program is reclaiming the site under a CERCLA deferral agreement. The clean-up goal is to reduce copper in the mine discharge so that the creek can eventually support a trout fishery. A pilot-scale passive treatment test utilizing sulfate-reducing bacteria has been conducted at the site beginning in summer 1997. Test results show significant reduction in copper concentrations in near-freezing mine water at flow rates ranging to 19 liters per minute (5 gpm)

Jan 1, 2000

By Edward Donovan, Bryan Knott, R. E. Melley, O&apos

South Bulga Colliery, located near Singleton in the Hunter Valley region of Australia, began longwall production in late 1994. The mining conditions there are conducive to high productivity with good roof conditions and a shallow seam with production areas located close to the portal. When the longwall was commissioned, the low capacity and availability of the conveyor system greatly curtailed the mine's productivity. A number of changes were made to the conveyor system culminating in a drive change out to improve the system. Using South Bulga as a case study, this paper aims to demonstrate the absolute necessity of a reliable, high performance conveyor system for the viability of a mine, and some of the factors that are needed to ensure a conveyor system performs as intended. These factors include a thorough understanding of the individual components and how they influence and interact with each other; a system design that is tolerant of variations in component performance and the necessity of robust and reliable communications and PLC programming.

Jan 1, 1996

By Michel Dagbert

The determination of the precision of reserve estimates (tonnage, grade, quantity of metal) for an entire deposit or a large block in a deposit has received some attention in the early developments of geostatistics. A general formula to derive the estimation variance of any linear combination of a large number of sample values can be found in any geostatistical textbook like David (1977) or Journel and Huijbregts (1978). A particular case of this general formula is of course the kriging of the entire deposit. However, besides the technical difficulty of dealing with many samples the application of this formula necessitates the knowledge of the covariance between any two samples in the deposit. This is quite unrealistic in the usual case of limited stationarity where the assumption of a covariance or a variogram just function of the distance vector between two samples is only valid for samples within the same area of restricted size.

Jan 1, 1982