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By T. McCallum, B. Wellbrook, T. Ratnaweera

"Pressure oxidation (POX) leaching of copper (Cu) concentrates continues to be explored as the next generation of leaching processes to sustain existing Cu Solvent Extraction/Electrowinning (SX/EW) operations as easily leachable ores become scarcer. The leach liquors produced, particularly from total pressure oxidation, contain elevated concentrations of Cu and acid, making solvent extraction processing more challenging. Addressing this challenge will require innovative processing techniques and continuous improvement to be successful in achieving satisfactory physical and metallurgical performance in the SX plant. The ability to efficiently process these feeds via SX plays an important role in the continued success of POX technology. Characteristics of a concentrate leach pregnant leach solution (PLS) are discussed, along with best practices that should be considered for processing by SX. Findings discussed in this paper will shed light on ways to reduce process risk and bring additional improvement to the industry with minimal change to the SX plant. INTRODUCTION Hydrometallurgical processing of copper concentrates continues to gain interest from the industry. Treatment by smelting and electro refining continues to dominate, accounting for ~80% of global copper production, but is faced with its own challenges. The case for increased hydrometallurgical processing has been discussed as high grade ore deposits are diminishing, capital costs for smelting are high, and the environmental aspects present challenges for sustainable practice. The hydromet copper industry is also turning a corner as easily leachable copper oxide deposits are depleting, and excess SX-EW capacity exists in certain regions. The transition to hydrometallurgical processing of copper concentrates will take a bit of effort as leaching of copper sulfides is difficult and byproduct credits must be considered. Various POX leaching processes have been studied and proposed to the industry as viable practices. Of the many processes, commercial use has been practiced with the Mount Gordon Copper Process, total and partial pressure oxidation by Freeport-McMoRan at their Bagdad and Morenci, Arizona complexes, the Sepon Copper Process in Laos, and the bioleach BIOCOP™ process in Chile. The experience related to the current paper centers around Cu concentrate leaching performed by Freeport McMoRan (known as CLP). The patented process was developed as an alternative to smelting and refining in 1998. The technology applies to both molybdenum and copper concentrates. Commercial CLP research and development began with Phelps Dodge in 1999 to 2001. The first commercial plant was commissioned in 2003 at the Bagdad operation. Initial operating conditions of the Bagdad CLP were under high temperature conditions before converting in 2005 to medium temperature conditions. In 2007-2009, the CLP technology was commissioned in Morenci, operating medium temperature and high temperature lite conditions until shutting down due to the economic downturn. The Morenci CLP restarted operation in April 2015 due to acid production benefits for the Morenci leach operations. Renewed solvent extraction test work initiated well before restart and has been an ongoing focus for further SX plant optimization."

Jan 1, 2018

By G. I. Voiloshnikov, V. E. Dementyev

Wide use of adsorption methods for metal recovery is one of the most important achievements of gold metallurgy of the last decades. Anion exchange resins or activated carbons may be used as adsorbents. This paper presents a brief overview of IRGIREDMET effotts on development, testing and implementation of techno­logical flowsheets using both adsorbent types and attempt to compare their technological properties. IRGIREDMET Institute was founded in 1871 as a laboratory for gold smelting and gold ore testing. In 1930 it obtained the status of the Research Institute. IRGIREDMET functioned as leading research center for gold mining industry in the former Soviet Union. At present it is the Open Joint Stock Company dealing with all s01t of research and design works for gold min­ing (ranging from geology to gold refinery). IRGIREDMET started development of ion exchange technol­ogy in 19641• The first stage of work (1964-1970) including development of principle flowsheet of RIP process was carried out jointly with the Moscow VNIIKHT Institute (All-Russian Scientific Research Institute of Chemical Technology)2• The flowsheet of RIP process is presented in Fig. I and includes the following basic operations: gold adsorption from pulp; washing of loaded resin; acid treatment; thiourea adsorp­tion; gold elution by acid thiourea solution; resin washing to remove thiourea; alkaline treatment of resin; resin washing and gold recovery from eluates by electrowinning. The technology developed and equipment used were tested for treatment of clayey ore of Kuranakh deposit at a pilot plant of the Lebedinsky gold complex ("Aldanzoloto" company, Yakutia, Russia). The pilot plant throughput was 200 t/day. At the same time IRGIREDMET conducted the tests on ion exchange technology for ore and concentration products of oper­ating gold plants and for ores of new deposits. Laboratory and pilot plant tests were done and developed initial data and process design criteria for designing of 15 plans of the former Soviet Union. In the course of this work a great number of newly synthe­sized anion exchangers including strong and weak base resins was studied, the peculiarities of anion exchange resins using two different raw material types ( ores and concentrates includ­ing clayey, carbonaceous, silver bearing, arsenic, antimony and base metals bearing products); some theoretical regularities of adsorption process were investigated; the technology of two stage adsorption of gold and silver from silver gold ore, improved flowsheet for gold elution and resin regeneration, design of adsorption equipment including pulsation columns, design of electrowinning cells were developed; conditioning technology for pulp with complex ion composition prior to gold and silver adsorption was developed, etc.3·8• IRGIREDMET specialists took part in commissioning of practically all the plants in the former Soviet Union using RIP and RIL process including Lebedinsky, Kuranakh, Sovetsky, Karamken, Matrosov's plant and Mnogovershinny plants. Due to this works RIP process became standard technology for Russia and the CIS.

Jan 1, 1998

By W. C. Dailey

The National Steel Pellet Company is owned by National Steel Corporation, managed by the M. A. Hanna Company and located near the town of Keewatin in northern Minnesota. Annually, the concentrator processes 15.24-Mt (15.0 million It) crude taconite with eight 8.2-m diameter by 5.5-m long (27 ft x 18 ft) wet semi-autogenous (SAG) mills to produce 4.57-Mt (4.50 million It) of iron ore pellets. To improve operating costs and primary mill grinding circuit efficiencies, a task force on liners was formed with the operation, maintenance and engineering staff at N.S.P.C. along with the local supplier of mill liners. Results of the task force recommendations since 1980 along with improvements made in the primary circuit operations, are presented. Mill Liner Design and Metallurgy Changes The primary mill liner task force was formed in 1977. Its function was to improve the operating costs and milling efficiencies of the ten 8.2-m x 5.5-m (27 ft x 18 ft) wet SAG mills that were operating at the time. The SAG mills are driven by two 3500 HP motors drawing a total of 5450 kW at 76% of critical speed.

Jan 1, 1985

By Matthew Preedy, Anthony Pooley, Mike Wongkaew, Dirk Bakker, Raghu Bhargava

Sound Transit’s ST3 program will add 62 miles of light rail to the Puget Sound area, including connections to the neighborhoods of West Seattle currently anticipated by 2031 and Ballard by 2036. These connections include considerations for both elevated and tunnel alternatives, as well as a new downtown tunnel for which different configurations are being considered with potentially very different construction logistics and risk profiles. This paper describes the latest developments in the ongoing evaluation process that will inform the consideration of different tunnel and station construction methods, technical and operational challenges and contracting methodologies, including construction of deep stations in dense urban environments.

Jun 13, 2021

By K. F. Unrug

The research work reported in in this paper deals with the monitoring of roof behavior in a drift mine located in Eastern Kentucky operating in the Coalburg Seam. The thickness of the seam at the monitoring site ranges between 9 and 10 feet with the immediate roof changing from sandstone to shale then back to sandstone. Shale thickness varies between 0 and 2.5 feet. The characteristics of the immediate shaly roof were monitored with 38 dynamometers which were set up in three survey lines to cover the entire range of shale distribution. The dynamometers are capable of providing accurate load readings in the range of +/- 5 pounds. To closely observe the contribution of moisture toward roof deterioration the dynamometers were set up in intake and neutral airways. A television borescoping camera was used in conjunction with the dynamo- metric instrumentations at pre- determined observation holes to physically observe and record the separation process of the shale and sandstone stratum with respect to time. Monitoring took place between January 1985 through January 1986 in order to cover a full cycle of dry and wet mine conditions associated with the seasonal changes. Analysis of the data show a trend of roof deterioration induced by condensation and eventual penetration of moisture within the immediate roof bedding planes, leading to rapid disintegration of the mine roof.

Jan 1, 1986

By Peter J. Szabo

Many mining engineers tend to think of the economic analysis of mining ventures and projects on an f.o.b. mine basis. This is especially true of mines that are operated in an established domestic mining district. Here, transportation costs are many times smaller in comparison to overall delivered prices. One has only to consider the development economics of taconite mines in Minnesota with production destined for lower lake ports to see the truism of this statement. In the international arena, however, with consumers such as Japan and Europe located thousands of miles from source countries such as Brazil and Australia, the situation is different because mineral transportation is often a critical factor in determining project viability. This article is being presented to provide a basic understanding of the factors that govern ocean transportation of the three largest bulk mineral commodities shipped around the world: iron ore, coal, and phosphate. The major dry bulk commodity trades as a percentage of volume shipped are iron ore, 45%; grain, 25%; coal, 20%; phosphate rock, 5%; and bauxite and aluminum, 5%. Most of these commodities are carried by bulk carriers rather than tankers. These are vessels that have cargo, usually in solid form, loaded directly into the hold of a vessel by shore-side materials handling facilities or, in the case of a geared bulk carrier by the vessel's cranes and derricks. Gearless bulk carriers are used in most cases for iron ore and coal. Geared bulk vessels are mainly used for minor dry bulk trades such as ore concentrates (copper, lead, zinc, etc.), fertilizers (phosphate, potash, etc.), cement, petroleum, and coke. There has been, however, a trend toward using more self-unloading ships in both iron ore and coal ocean transport. And large vessels, such as the Universe Kure of Japan, have been designed with a cargo capability of 157 kt (155,000 dwt (deadweight tons)). Trade patterns of major bulk commodities are influenced by the Panama and Suez canals. Both of these canals have draft limitations that prohibit large, deep-draft, ocean-going vessels from using them for shorter trade routes used by Panamax and Suex vessels. The shipping industry has developed two widely used vessel classes; the Panamax and Suex vessels. The former is the maximum size vessel that can pass through the Panama Canal, usually 51-61 kt (50,000 - 60,000 dwt), depending on the season and draft of the vessel. The Panama Canal is usually 0.6-0.9 m (2-3 ft) deeper in the winter than in the summer. Thus, less cargo can be carried by the same size ship in the summer through the canal than in the winter. The Suex vessel is in the 71-81 kt (70,000-80,000 dwt) class. This larger vessel is able to transit the Suez since Egypt deepened the canal following the Seven Days War. Recently, the Suez Canal has been deepened to accommodate vessels with drafts as deep as 152 kt (150,000 dwt).

Jan 10, 1982

By John D. Kalasky

Ventilation is necessary in coal mines to supply fresh air to the working faces for the health, safety, and comfort of the miners, and for the circulation of air to the extent that it will dilute, carry off, and render harmless the noxious or dangerous gases generated. Adequate ventilation depends upon good face control, as well as upon a well designed and properly controlled overall ventilation system. Generally, this includes fans, airways, overcasts, air locks, regulators, checks, and canvas or plastic stoppings near the working places to prevent short circuiting of air, and effective bleeders to maintain a continuous flow away from the working places along the pillar lines at all times and to prevent diffusion of methane back to the pillar line in case of temporary interruptions in ventilation. In the development of a new mine, or the virgin area of an old mine, the main headings should properly be considered a construction project, designed with, only the number of permanently supported (roof) headings required to conduct the necessary air volume to and from the major panels in which mining is conducted by room and pillar or longwall methods. Although subject to hazards from methane quite frequently and requiring constant and careful attention at all times, development of headings has some built in safeguards which make it a less difficult problem in control of methane than exists in pillaring.

Jan 1, 1973

By D. Christofferson

As an alternative power source to eliminate trailing cables, ESD Corporation is installing a flywheel system on a shuttle car. Flywheel power is extracted by a high-speed generator, developed by Lear Siegler Corp,, and the system -- including vacuum and lubrication and cooling auxiliaries -- is supplied by the aerospace group, Rocketdyne Division of Rockwell International. The flywheel system is being developed under a three-year contract with the Department of Energy. It is a follow-up contract to a previous DOE-contracted study by General Electric Co. in which it was shown that a flywheel can be a feasible power source for a shuttle car from technical, economic, and safety standpoints. This paper addresses the status of the program, design decisions established, and plans for laboratory test procedures and underground demonstration. The flywheel-powered shuttle car is a conventional 6-ton capacity shuttle car equipped with a 7-rotor flywheel energy storage package. The energy package is the sole source of power for the shuttle car through a complete mission duty cycle (MDC) of tramming to the miner, receiving a load of coal, and returning to the secondary haulage system. Energy stored in the system exceeds MDC requirements and waiting times to provide an ample margin of reserve energy. The energy storage system is recharged by spinning the rotors back up to maximum speed each time the shuttle car comes back to the secondary haulage system. The electrical charge motor is connected to a power source to recharge the system while the load of coal is being discharged.

Jan 1, 1982

By Thomas L. Kesler

Lithium raw materials usable with present technology consist of pegmatite ore and surficial evaporite brine. Those advantageously located now supply world markets. Materials of similar grades and magnitude, but less favorably located, will come into production as present sources are depleted and markets expand. Some of these potential supplies have been explored, and are reserves in the sense of known availability and quality. Reserves herein are of two classes, those proved by close drilling and assaying, and those of only probable status because their scale and grade are unsystematically indicated. Possible resources include similar materials whose bulk can only be inferred on indirect evidence. All figures apply to total materials in the ground. No allowance is made for losses in mining, evaporation, beneficiation, or chemical processing.

Jan 1, 1977

By B. K. McMahon

Block caving is an efficient mass-production method for the underground mining of large orebodies. However, the block-caving method requires a substantial investment in developmental works, based on the assumption that the rock will cave. Efficient block caving is prevented if the rock forms stable arches or breaks into fragments that are too large to pass easily through the finger raises. Under these conditions, the cost of the additional labor, drilling, and blasting required to assist caving may be sufficient to make marginal orebodies uneconomic or alternative mining methods more attractive. Reliable methods for the prediction of the block-caving behavior of an orebody are clearly needed at the initial planning stage. These methods should be capable of considering both geological and engineering aspects of a block cave, as experience has shown that the manner in which a block cave is initiated and developed may be almost as important as the geological conditions such as the nature of the rock material, degree of alteration, characteristics of the joints and faults, etc. The initial state of stress in the rock mass should also be considered.

Jan 1, 1969

By R. B. Lawrie

Diesel powered underground mining equipment is presently the most productive, safest and efficient equipment used in underground mining operations. The widespread application of this equipment to underground mining is restricted, however, largely because of the difficulty of controlling the diesel engine exhaust emissions. This paper briefly examines control devices currently available for underground application, and also discusses the theory and mechanics of controlling diesel missions with particulate traps and filters.

Jan 1, 1985

By F. Qiming

By means of flotation experiments, potential-pH diagram, electrochemical testing and X -ray photoelectronic spectrum (XPS), the main factors (the thermodynamics and the property of surface products) influencing the separation of sulfide minerals (such as galena and chalcopyrite) in the collectorless flotation are studied. The actual conditions (Eh, pH) of separation are not conformable to the results of thermodynamic calculation. The kinetic behavior of oxidation of sulfide minerals and the property of oxidation products are the decisive factors of the separation of sulfide minerals in the collectorless notation.

Jan 1, 1992

By S. W. Thomas

One of the most difficult tasks associated with placer mining is the sampling of the deposit. More placer projects have failed due to inaccurate assessment of the reserves than to any other reason. Within the realm of placers, those containing valuable minerals with a high unit value .are more difficult to sample than those with larger bulk, lower unit value minerals. Some items to consider when sampling a placer deposit are as follows: A) A relatively large size sample is needed for accurate valuation of the ground being tested. Placers are composed of many sizes of gravel which makes a representative sample difficult to obtain. B) When sampling placers for high unit value minerals such as gold, any error in mineral content of the sample will be magnified in the calculation of reserves.

Jan 1, 1985

By Shawn Boltz, Erik Westman, Derrick Chambers, Xingdong Zhaoa, Qiankun Zhua

Microseismic passive velocity tomography is becoming an effective technology for large-scale mining-induced stress monitoring in underground mines, especially in the field of early warning of mining-induced hazards. Aiming at the problems of missing low-magnitude events in traditional microseismic monitoring, as well as the potential to increase the resolution of the tomograms in both time and space, a microseismic passive velocity tomography analysis method based on the template matching method was proposed. First, the template matching method was used to pick microseismic events. Then, the probabilistic, non-linear, global-search earthquake location method was used to locate the events and calculate travel time and travel distance. Finally, the fast-marching method was used to carry out passive velocity tomography analysis to image the movement of the abutment stress associated with the longwall. The results show that the selected templates can identify more microseismic events than the traditional microseismic analysis, and the variation trend of events in each day is consistent with the data from the traditional analysis. Using microseismic event locations, travel times and travel distance can effectively complete microseismic passive velocity tomography analysis in each day during the study period and can effectively identify the forward and side abutment stress zones of that longwall panel. This study provides a reference for the identification of mine-induced high stress zones, which has implications for hazard identification and mitigation, with increased resolution of the tomograms in time and space.

Jun 25, 2024

By M. J. Zdunczyk

Located approximately 50 miles northeast of Knoxville, Tennessee, Short Mountain Silica mines the Clinch Formation, an orthoquarzite, for silica sand. In 1980, a Knoxville resident and area contractor visualized mining Short Mountain for silica sand. Because APG Industries, the main market for the glass sand product, was only 48 kilometers from the site, many silica sand companies became interested in the property. In 1986, J.D. Nicewonder began to develop the site, and in May of 1988, APG Industries received the first sand shipment.

Jan 1, 1992

By L. M. English

In the past 30 years, the research arena has changed significantly in all fields, mining included. The relative representation of the topics of research, how the research is performed, and who has performed the research have all changed significantly over these decades. Although there are a lot of subjective ideas concerning these changes, and there is a fair amount of anecdotal "analysis," there has been no actual study of these trends to verify the facts. The period studied is divided into six five-year periods for the purposes of comparison. Some of the trends analyzed are as follows: ? Co-authorship ? Research areas ? Research sponsors ? Cooperative efforts

Jan 1, 1995

By S. Chander

The mechanism of oxidation of sulfur in pyrite is a function of the rate and driving force for oxidation. New evidence is presented in this article to show that at moderate potentials, a sulfur-rich hydrophobic layer is formed. Under ordinary conditions, the sulfur layer is covered with a layer of iron oxides, hydroxides, sulfate or oxy-sulfide ions. Under these conditions, pyrite is hydrophilic. In the presence of iron-chelating agents or iron sequestering ions, iron layer might not form. Under these conditions, sulfur-layer is exposed and pyritic might become hydrophobic. Stronger oxidizing conditions decompose the sulfur-layer, thereby making the surface hydrophilic.

Jan 1, 1992

By Tsutomu Yanagase

Non-ferrous smelting industry in Japan often had the severe problems about the over production of sulfuric acid. There has been such a closed relation between amount of sulfuric acid from non-ferrous smelting industry and the products of copper, zinc and lead metals that the production of one ton of copper accompanies three tons of H2S04. When the proper balance exists in both markets this situation certainly brings bigger profits. In Xining and Metallurgical Institute of Japan the research commitee concerned with the fixation process of sulfur in non-ferrous smelting industry was established in 1977 and continued the activity for four years untill 1981. This paper will introduce some of the activities involved in the report published by the committee.

Jan 1, 1982

By James J. Scott

Shale formations are the Nemesis of the Mining Engineer. Shales react to changes in environment in the most unusual and unpredictable manner. Increase in temperature may cause spalling, increase moisture and compression induced fractures may occur, and if a full face is exposed it may deteriorate due to atmospheric exposure. Combine only small amounts of shale in layered fashion with hard brittle competent rock and the whole structure may be fractured and fail due to stresses generated in and around the shale. In this paper the author will discuss failure mechanisms encountered under various field conditions and remedial action which may be employed by the engineer.

Jan 1, 1969

By C. K. Blankenship

The competitive forces now driving the electric utility industry and the constraints of regulation at all levels are changing the way we will all do business now and into the next century. Utilities are using every technological tool at their disposal to find optimum solutions to challenges in every aspect of operations. In fuel planning and procurement, these tools include models that predict which dispatch line-up will comply with environmental regulations at minimum cost. This paper presents how those tools are being used for Duquesne Light Company.

Jan 1, 1995