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By G. Sahasrabudh, G. DeIulii, K. P. Galvin

A novel agglomeration process has been developed, utilising a concentrated water in oil emulsion as a binder. The binder is typically 95 wt% water, the remainder being an organic phase containing kerosene and the emulsifier— sorbitan mono oleate (SMO) in equal mass portions. The binder can selectively agglomerate hydrophobic particles in less than 7 seconds. The agglomeration has proven to be highly effective in recovering any particle of virtually any size, provided the particle is hydrophobic. The approach has previously been applied to coal, magnetite and silica. In the paper, sodium isobutyl xanthate (SIBX) and its much longer chain version, potassium tetradecyl xanthate (C14X), were used separately as collectors to selectively agglomerate chalcopyrite from the ore. Xanthates attach to metal sulphides, thus hydrophobising sulphide mineral particles. Chalcopyrite is a sulphide mineral; however, it hydrolyses quickly in the presence of water. Ethylenediaminetetraacetic acid (EDTA) was used to remove the oxide layer formed at the surface of the mineral particles after wet grinding, leaving behind a freshly generated metal sulphide surface. After the EDTA treatment, the ore particles were quickly conditioned at an optimised pH as well as collector concentration and agglomerated. The agglomeration achieved a copper recovery of 75% within 7 seconds, consistent with the recovery achieved by flotation over much longer time scales. Keywords: Chalcopyrite, agglomeration, froth flotation, interfacial chemistry, X-ray fluorescence, selective hydrophobisation

Jan 1, 2020

By R. Mumbi, M. Peart, E. Arinaitwe, B. Mbao, J. Zulu

Since 1925, xanthates have been widely used in sulfide flotation due to their low cost, ease of manufacture, and ability to float most value species. However, the industry's increasing need for safer and more selective alternatives, driven by low head grades, poor-quality, difficult-to-process ore with complex mineralogy, and stricter environmental regulations, has led to the development of Solvay's AERO® XR series of collectors. These custom-formulated products are based on greener chemistries and offer metallurgical benefits that are similar to or better than those of xanthates, without the safety concerns. Developed through Solvay's Flotation Matrix (FM) 100 approach, the XR series collectors are suitable for a wide range of applications, including the processing of Cu, Zn, and Cu-Ni, as well as the flotation of precious metals. This paper will highlight the differences between xanthates and XR series collectors, and present case studies of their successful commercial application at various global operations.

Jan 1, 2023

By S. W. Robertson, M. T. Golela, S. Mxinwa

South Africa has one of the largest Cr-related industries in the world and generates large amounts of Cr-containing smelter dusts. It is normal practice to scrub Cr from the furnace off-gas in water, and to recover the Cr by adsorption, followed by recycling of the loaded adsorbent into the furnace. A study was conducted to find a low-cost adsorbent that is capable of removing sufficient Cr from the solutions generated by scrubbing. The test work focused on the evaluation of different clay minerals (attapulgite, bentonite, and kaolinite) as adsorbents for Cr. Cr(VI) could only be adsorbed after prereduction with e.g. ascorbic acid (ASA). An 80% removal of Cr(VI) could be achieved from a solution containing 20 mg/L Cr using bentonite clay after reduction with ASA. Attapulgite and kaolinite adsorbed less than 55% Cr after reduction with ASA. Both ASA and ferrous salts were found to be suitable reducing agents. The use of acid mine drainage (AMD) was also investigated as a low-cost alternative reducing agent, as AMD usually contains iron. The Cr(VI) reduction potential of the AMD was determined by redox titration against a solution containing 50 mg/L Cr(VI). Studies show that AMD can potentially be used as a reducing agent in a Cr removal process if it is available on site.

Feb 12, 2024

By B. Strohmeier

The role of large, ultra-high-powered arc furnaces in a fully integrated steelworks for the production of flat products is outlined, and an account is given of the technological improvements that have been implemented over the past few years to enable the arc furnace to remain competitive against the conventional route using blast furnaces and top-blown-oxygen steelmaking (LD). Modern secondary refining facilities have been installed, enabling the arc furnace to operate at high production rates in the manufacture of high-quality flat products.

Jan 1, 1985

By F. Wang, P. Rosario, A. Vazirizadeh

Advances in data science, machine learning, and artificial intelligence are transforming mining and mineral processing, and making them more algorithm intensive. The paradigm is shifting from one of detection and control to one of prediction and optimisation. To build up reliable prediction and optimisation models these steps should be passed: collect, aggregate, cleanse, and process large amounts of complex, structured, and unstructured data as a first stage. Next, the right tools must be used to extract meaningful features from the operational data for the build-up of a prediction model. A grinding circuit is one of the challenging areas in terms of determining its overall efficiency and the prediction of product quality. In a processing plant, some of the KPIs are typically unmeasurable or infrequently measured for real-time application, e.g. ore grindability and grind size. However, these variables are required to calculate the grinding circuit efficiency and to model the operation performance. In this paper, advanced analytic tools have been used to extract one selected KPI (cyclone overall P80 or final grind size) and its relationship with measured variables for an industrial dataset. The results illustrate that the performance of the grinding circuit can be predicted for real-time monitoring by means of measured data. Keywords: Grinding circuit, data-driven, machine learning, process modelling, hybrid modelling

Jan 1, 2020

By M. Kumral, S. Li, M. Balci, Z. Shao

Main haulage roads play an important role in the performance of underground mines because of the cost of transportation of the extracted ore, equipment, and workers. During mine development, these roads are designed through manual tools or CAD-based software. However, the optimisation of these roads is still a complex problem due to some constraints such as minimum turning radius and maximum gradient. By utilising Dubins path theory, three elevation cases; namely low, medium and high are defined, considering gradient constraint as well as the minimum turning radius in a three-dimensional space. The shortest path between two points can then be found by the three-dimensional Dubins path algorithm with elevation constraint. As a further step, a three-dimensional Dubins path algorithm with elevation constraint for multiple points is also developed for multi-point cases. The effectiveness of these algorithms is tested through case studies in order to determine the optimal path between different points.

Sep 1, 2021

By A. Mainza, I. Govender, Elbasher M. E. Ahmed

A mechanistic description of axial segregation in rotating drum flows remains an open question. Consequently, optimal mixing of grinding balls and rocks for efficient breakage, maximum production of fines, and slurry transport is seldom achieved. Experimental and numerical studies of granular mixtures in rotating drums identify alternating axial bands that eventually coarsen in the long-term limit. Most models of axial segregation are limited to binary mixtures and cannot always predict the logarithmic coarsening effects observed experimentally. A key missing factor is a robust description of the axial free surface profile that is valid across a wide range of flow regimes. We present a practical model of the axial free surface profile by linking it to readily-derived geometric features of the cross-sectional S-shaped free surface profile. A parametric study shows good agreement with experimental measurements reported in the literature and heuristically valid trends.

May 1, 2021

By T. Z. Sehume, J. R. Bunt, J. C. van Dyk, C. A. Strydom

"SynopsisCo-pyrolysis of four biomass samples (hardwood chip, softwood chip, pinewood chip, and sugarcane bagasse) with an inertinite-rich medium rank C South African coal was investigated. Proximate and ultimate analyses of the chars prepared using a heating rate of 10°C/min up to 1100°C in a nitrogen atmosphere were used to compare the properties of the biomass and the coal chars. Similar gross calorific values (28.5–29.1 MJ/kg) for the woody biomass-coal blended chars were observed, which were slightly higher than that of the coal char sample (26.5 MJ/kg). CO2 surface areas of the chars of the woody biomass samples (328.1–329.4 m2/g) and of the blends (238.5–271.5 m2/g) were higher than that of the coal char sample (94.2 m2/g). Thermogravimetric (TG), differential thermal analyses (DTG), and calculated weighted averaged TG curves indicated that the influence of the biomass on the pyrolysis rate of the coal is small and vice versa. The CO2-producing reactions of the coal were slightly enhanced during co-pyrolysis.IntroductionCoal utilization has led to rising concerns about adverse impacts on the environment (global warming) caused by toxic gases (H2S, SOx, NOx, and CO2) and remaining waste. Biomass is considered to be CO2-neutral with regard to the greenhouse gas balance, and is regarded as a renewable source that assists in reducing CO2 emissions when compared with coal (McGowan, 1991; McKendry, 2002). Biomass currently makes up approximately 14% of the world’s energy sources (McGowan, 1991; McKendry, 2002). Coal combustion and gasification are prominent processes in South Africa (in producing synthesis gas and energy) due to the abundance of coal in the country. Some of South Africa’s coal resources are, however, high in ash content and also are inertinite-rich, which renders them more difficult to use industrially than vitrinite-rich low-ash coal (Jeffrey, 2005; Strydom et al., 2011). There is a need to investigate the properties and behaviour of the inertinite-rich high-ash South African coals and especially their interaction with local biomass sources. The gasification process occurs through various stages, of which pyrolysis of the char residue forms an integral part (Bunt and Waanders, 2009). Currently, particular interest is shown in the co-utilization of coal and biomass to produce synthesis gas via the gasification process (Usón et al., 2010; McGowan, 1991; McKendry, 2002). Investigating the co-pyrolysis of the South African coal and local biomass material is thus the first step in evaluating the use of local biomass sources for co-gasification purposes."

Jan 1, 2015

By J. E. Xu, J. Y. Zhang, M. Q. Sheng, K. Wan

"SynopsisThe densities of selected CaO-Al2O3-MgO slag systems were measured at 1823K by the Archimedean method. Thirteen different slag compositions were chosen based on different levels of the MgO content and the mass ratio of CaO/Al2O3. The results indicated that the density of the slag decreases with increasing MgO content (from 0–3.78 mass%), but increases with further increases in MgO content up to 11.33 mass%. At a fixed MgO content of 5.5%, the trend of density change with CaO/Al2O3 in the slag is similar to that for changes in MgO content. On the basis of the regular solution approximation rules of excess molar quantities, an attempt was made to estimate the molar volume of the slags investigated. The application of the molar volume model confirmed that the present expanded approximation rules are applicable to predict the molar volumes of the melts discussed.IntroductionDensity is one of the most important fundamental properties of slags, which influences metallurgicaly phenomena in many ways. Density is sensitive to the nature of the chemical bonds and the species in the melt, and is of great importance not only for theoretical research on the structural properties of molten slags, but also for industrial applications. Density is also required to estimate other key properties used to assess the behaviour of high-temperature molten oxides, e.g. viscosity, surface tension, and thermal conductivity.Liquid calcium aluminate slags that contain magnesia are the basis of most ladle slags for secondary refining processes. The CaO-Al2O3 binary phase diagram (Hallstedt , 1990) shows the eutectic composition (50 wt% CaO and wt% Al2O3) has the lowest melting temperature. The main emphasis of this study is on the 12CaO·7Al2O3 refining slag with MgO additions. The CaO-Al2O3-MgO ternary system is of considerable importance in industrial metallurgical processes, and is fundamental to the understanding of metallurgical slags, ceramic materials, and geological phenomena."

Jan 1, 2015

By B. S. Xakalashe, M. I. Khama, Q. G. Reynolds

The carbonaceous reduction of manganese ore is an energy-intensive process that releases large amounts of pollutant gases. In an attempt to circumvent the greenhouse gas emissions, this research investigates hydrogen as an alternative reductant. The reduction of manganese ore with hydrogen results in the structural changes in the intermediate products, which might limit the diffusion of the reactant gases through the pores. Computational fluid dynamics (CFD) models capture the structural changes and predict the rate controlling mechanism and this is key in designing the prereduction reactors. The current work uses CFD models to predict the degree of reduction in a shaft furnace under hydrogen reducing conditions. Manganese ore is described as a collection of scalar and tensor fields such as thermal conductivity of the porous medium, density, and viscous resistance. The results indicate that advection contributes significantly towards the overall transport of hydrogen to the reaction sites. Porosity of the final product was found to be higher than porosity of the raw material.

Mar 4, 2025

By J. Sjöberg, T. Savilahti, S. B. Umar

"Sublevel caving in Malmberget mine results in mining-induced surface deformation. One of the currently mined orebodies is the Printzsköld orebody. As mining deepens there is need to assess the behaviour of the cave formed in the subsurface above this orebody. Numerical analysis was used to assess the effects of extraction to deeper levels and perform strength parametric studies. Stress redistribution was studied, and the results showed high stress buildups in the hangingwall and the crown pillar. Two failure mechanisms have been identified – shear and tensile. Reducing cohesion by 50% increased the area of the yielded zone by more than 100% in the hangingwall.IntroductionThe Malmberget mine is owned and operated by the Luossavaara-Kiirunavaara AB (LKAB) mining company. Iron ore is extracted by large-scale sublevel caving. The mine comprises a total of 20 orebodies, about 10 of which are in production today (Figure 1). The mine is located in the municipality of Gallivare, about 100 km north of the Arctic Circle (Figure 2).Successful sublevel caving requires progressive caving of the orebody after initial blasting. This results in caving of the hangingwall, sometimes all the way to surface, resulting in surface deformation. As mining progresses to deeper levels a larger area is affected by deformation. Over the years, extraction from the Malmberget orebodies has led to deformation of the ground surface, affecting residential areas and existing infrastructure.Forecasting the caving process is not straightforward as it can be rapid or slow, depending on the rock mass conditions, stress conditions, the failure mechanisms at work, etc. Moreover, several of the orebodies in Malmberget are non-daylighting, which makes reliable caving analysis even more difficult, primarily since there is less available experience from such cases. The present study was designed to improve the understanding of the caving and deformation mechanisms at Malmberget, and in particularly for the Printzskold orebody"

Jan 1, 2017

By E. J. Y., G. J. McLachlan, E. Amini, Koha

Inferring individual component flotation rates from recovery-time data of ore complexes is important in optimising and designing minerals processing plants. However, existing two-component first-order flotation models are computationally intensive to solve using conventional non-linear least squares regression. In this paper, a Convolutional Neural Network (CNN) is used to approximate the inverse function which predicts the two-component first-order model parameters using recovery-time data. This paper compares the accuracy and computation speed of the proposed CNN against traditional non-linear least squares regression on 1 million generated data based on a known two-component firstorder kinetic model. It is shown that using a CNN is possible to approximate the inverse function for the non-invertible two-component model with recovery-time as an input matrix for convolution operations. The CNN method is 450 times faster to compute than the Trust-Region (TR) non-linear least squares regression algorithm. However, the CNN model is less accurate compared to the TR algorithm overall. Keywords: Flotation kinetics, convolutional neural network, inverse problem, modelling and simulations

Jan 1, 2020

By E. J. Boome, A. C. Schmidt

Pert, and how Pert techniques can be used in modern mine management By E. J. Boome, A. C. Schmidt C.A. (S.A.) This paper covers the stages of planning required to be performed and the implementation of the plan from grass roots to the partial completion of the sinking of a mine shaft system. The various steps involved in the planning are also examined in some detail. The experience gained in this project and the conclusions reached convince the authors that Pert Planning is a valuable aid to top management.

By K. Muchima, C. Siame, L. Little, B. Kaputula, Q. Mclennan

"The variability of copper mineralization at Kansanshi mine significantly affects the efficiencies of the processes used to recover copper. Quantifying this variability is therefore essential for monitoring and optimizing the performance of the concentrator, which comprises three different flotation circuits (sulphide, mixed, and oxide) and an atmospheric leach circuit. Onsite automated scanning electron microscopy with energy-dispersive X-ray spectrometry (Auto-SEM-EDS) is used to analyse routine weekly composite samples for each circuit, providing detailed analyses of bulk mineralogy, copper deportment to different minerals, mineral liberation, and associations. Weekly mineralogical trends are used to assess changes in process performance, and characterization of the copper losses has inspired a number of projects to target the specific particle types responsible for the main losses. In this paper we describe the relationship between mineralogy and plant performance at Kansanshi, and discus IntroductionKansanshi is a copper and gold mine located in the Northwestern Province of Zambia, with an annual production in the region of 250 000 t of copper and 160 000 ounces of gold. Ore mined from the epigenetic vein-hosted deposit is classified into three ore types based on the extent of oxidation and supergene enrichment. Sulphide, oxide, and mixed ore are fed to separate mineral processing circuits tailored for recovery of the dominant copper minerals in each. After comminution to a target grind size of 80% passing 150 µm, each ore type is subjected to flotation to recover the copper sulphide minerals (chalcopyrite, bornite, chalcocite, covellite). The oxide float tails and a large proportion of the mixed float tails are then treated by atmospheric leaching to extract copper from the remaining copper-hosting minerals, which include cuprite, malachite, chrysocolla, and delafossite. Some native copper is recovered by flotation and some of it is recovered by leaching. A small portion of the combined concentrate from all circuits is subjected to high-pressure leaching and the rest is sent to the smelter. Sulphuric acid produced during smelting is used for the atmospheric leach."

Nov 1, 2018

By J. O. Jensen

A method is described for the determination of cyanide in gold slurries, based on amperometry. The measured current is proportional to the concentration of cyanide, and is not effected by pH or by the concentration of oxygen in solution. It is also unaffected by other ions that may be present in gold-leaching solutions, including sulphide, thiocyanate, and thiosulphate. The current depends on the temperature, and an activation energy of 17,9 kJ/mol was determined Since the current is controlled by the mass transfer of cyanide to the anode, it depends on the conditions of agitation. In tests on an operational gold plant, slurry was pumped directly from the top of the leaching tank, through the measuring cell and back into the tank. The results indicate that the instrument is a promising alternative to the instruments currently available. The readings from the instrument remained in calibration for at least two days, showing that the instrument would need to be re-calibrated by the operating staff at regular periods.

Jan 1, 1994

By S. O. Bada

Coal is a complex mixture of organic and mineral constituents and is the most abundant resource of fossil energy in the world. In recent years, significant research into dry coal beneficiation has gained much attention, primarily due to the need to improve grades and reduce the environmental contaminants in coal without the use of water, and to achieve this in as cost-effective manner as possible, relative to wet beneficiation processes. This paper seeks to review the application of various electrostatic separators with their process principles, to draw comparisons between different dry beneficiation techniques with specific emphasis on the tribo-electrostatic separation method, and finally to report the results of tribo electrostatic separation conducted on various South African coals. Previous research conducted on Indian, European and American coals has indicated that this technique is likely to lead to significant economic benefit through the reduction of ash content, NOx and more specifically Sox by separating out the liberated Fe-S-bearing minerals prior to utilization. The removal of the latter suite of minerals is also likely to significantly reduce or eliminate the emissions of associated trace elements, including mercury and arsenic. The research results reported in this paper indicate that the rotary tribo-electrostatic process has the potential for significant upgrading of high ash pulverized South African coal. The impact of various operational parameters was investigated and key factors established for the optimum recovery of low ash and low sulphur fine coal.

Jan 1, 2010

By J. P. Gouvea

Back-analysis of two mining-induced tremors in 2011 was used to determine a modelling criterion for the entire Klerksdorp Goldfield (i.e., Vaal Reefs region). At that time, most mining operations in the region were owned by AngloGold Ashanti (AGA) and shared many geotechnical similarities. By 2018 AGA had sold off all its Klerksdorp operations to different mining companies, which continued applying the 2011 modelling criterion. As mining activities became more remote, scattered, and isolated, the extraction of isolated blocks of ground and remnants became increasingly necessary. However, the inherited criterion allowed only minimal or no mining activities at these areas. Keeping in mind that safety is the overriding consideration, an innovative numerical modelling approach, which includes the application of peak particle velocity designs, was developed to provide practitioners in the Klerksdorp Goldfield with a suitable criterion to justifiably and safely mine isolated blocks of ground and remnants. This would not always be possible if a conformist approach was used.

Mar 14, 2024

By P. J. Petit

"The complex planning required to achieve any planned production yields multiple and dissociated responses over the life of project (LOP). The customary decision-making process negates the possibilities of developing optimized and integral solutions from operating levels up to business and strategic levels. This results in an inefficient project or overall underperformance of the operation.In the project setting, disconnected trade-offs and improved performance studies become inadequate, because they are site-specific and use only a few comparative parameters. They are often based on a small data-set.Decisions taken to achieve overall objectives require the correct determination and dissemination of key performance indicators (KPIs). The KPIs indicate efficiency in operation, whereby the marginal rate of technical substitution corresponds to the rate of production. It is the necessary condition for optimization. Performance realization for sustainability follows optimization modelling, the latter often being presented with financial results such as business net present value (NPV). It considers techno-financial constraints and provides a strategic and aligned outlook of KPI decisions for an enhanced and integrated outcome.This paper explains a mining case study that is rendered efficient, and through business optimization (BO) short-term and sustainable targets are reached. Business optimization increases the NPV by 14.7%. This is achieved by challenging conventional decision-making associated with maximizing business value by including environmental externalities within the LOP."

Jan 1, 2016

By X. Zhang, Z. T. Yuan, C. Zhang, H. M. Zheng, X. M. Wang, L. X. Li, N. Li

In metal mines, comminution is commonly used to liberate minerals for subsequent mineral concentration processes, such as flotation, magnetic separation and gravity separation. However, ores are aggregates of valuable minerals and their disseminated gangue minerals, and these minerals exhibit diverse comminution behaviours. In carbonate-bearing iron ores, hematite, siderite, and quartz are the predominant minerals, of which hematite is the objective recoverable mineral. In this regard, the present study aimed to identify the imperfections in siderite minerals by X-ray computed tomography (XCT), and thus quantitatively characterise their size and shape in terms of Feret diameter and aspect ratio, as well as other parameters. XCT images indicated the protogenetic ubiquity of pores <5 μm in diameter and cracks of 7-8 μm inside siderite particles. In the ground product of artificially mixed siderite and hematite, siderite particles were smaller than hematite particles. Siderite particles had a larger surface area and greater surface roughness than hematite particles of the same volume, which was attributable to the intrinsic holes and cracks in siderite particles. This study provides an insight into the relationship between the inherent imperfections of minerals and their comminution properties. Keywords: Siderite; X-ray computed tomography; particle imperfections; grinding behaviour; sliming

Jan 1, 2020

By S. Blancher, A. Perroton, H Smith, T. Nzima, T. Wallmach, V. Dieudonné

Chromite beneficiation is generally performed by crushing and density separation using spirals. At the Dwarsrivier Chrome mine spiral efficiencies seam to vary, the reason for which is not evident. This sometimes results in the production of low-grade products, which are sold at relatively low prices. This paper represents a Qemscan® study that investigated mineralogical reasons for these variations. Variations in liberation of chromite particles as well as variations in chromite compositions were investigated. The results showed that the so-called low grade chromite product can be improved to become a high grade chromite product by means of a refinement in mineral processing. A detailed Qemscan® database (SIP file) was developed to account for variations in chromite chemistries. It can be shown that chemical variations with respect to Cr, Al, Mg and Fe in chromite particles reporting to the scavenger tails are larger than in the high grade product. A combination of these chemical variations together with a decrease in liberation of chromite particles in the scavenger tails can potentially help to recover more chromite particles from this specific process stream.

Sep 1, 2021