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By S. R. B. Cooke, J. Bruce Clemmer, Will H. Cognill, F. D. DeVaney

"INTRODUCTION The domestic production of potash has made rapid strides in the past 4 years. In 1929 the United States produced 109,820 tons of potash-bearing material, equivalent to 61,590 tons of pure potash (K20). In 1933 to this had increased to 331,110 tons, containing 143,378 tons of potash, due chiefly to the development of the potash deposits near Carlsbad, N. Mex. The potash ores of that district occur at a depth of about 1,000 feet and as mined consist of a mixture known as sylvinite containing about 40 parts of sylvite (KC1) and 60 parts of halite (NaCl). By careful mining the extraneous material does not amount to more than 2 or 3 per cent. Such ore was used in the experimental work here reported.The usual chemical method for the recovery of potash from sylvinite, while efficient in the production of pure potassium chloride, requires,expensive equipment and is costly to operate. It occurred to the Bureau of Mines that ore-dressing methods, which have been applied to other nonmetallic minerals, might be adapted for the production of a grade of potash suitable for the fertilizer industry. After preliminary study by the Bureau of Mines showed that ore-dressing treatment was possible the investigation was extended under a cooperative agreement between the U.S. Bureau of Mines, the Potash Company of America, and the Missouri School of Mines and Metallurgy, Rolla, Mo.ACKNOWLEDGMENTSAcknowledgment is here given for valuable assistance in the laboratory of R. G. O'Meara, assistant metallurgist. U.S. Bureau of Mines, Tuscaloosa, Ala. who was on detail at the Rolla station during the early work; by E. W. Gieseke and Albert Ollar, temporarily employed by the Potash Company of America; and to N. H. Lenz, an engineer temporarily assigned to the station."

Feb 1, 1935

By R. A. Keaens, L. C. IlsLey

For the purpose of this paper a junction box is defined as " a fused switch, inclosed in an explosion-proof compartment, provided with a ready means of connecting or disconnecting a trailing cable without exterior arcing." Junction boxes are intended for use 'at the end of trailing cables and are usually placed outby the last open break through in a coal mine. Where it is not safe to supply current through nips or a trolley, junction boxes suitably spaced along an entry permit tramming and movement of machines with safety, although not with any considerable speed. Junction boxes serve a threefold purpose: (1) They prevent dangerous arcing at the outby end of trailing cables; (2) they afford a safe, practical means of fusing or otherwise protecting the trailing cable; and (3) they provide an efficient means of transmitting power from the power circuit to the trailing cable. The first purpose is the most important from a safety standpoint. Dangerous arcing-that is, arcing capable of igniting gas-frequently takes place where trailing cab1c.s are attached to the power circuit. At either 250 or 500 volts only a very small arc is required to ignite mine gas. The usual method of connecting the trailing cable to the power circuit by cable nips or trolley taps does not make a good electrical connection; hence arcing may be expected at any time. Furthermore, junction boxes eliminate the personal hazard attendant upon the use of trolley taps by removing the possibility of accidental contact with trolley hooks or wire and the liability to injury due to manipulation of the device. In the general scheme of mine ventilation it is assumed that gas will not accumulate where junction boxes are placed, an assumption based on the normal operation of the ventilating system. In many

Jan 1, 1929

By R. V. Ramani, R. Stefanko, G. W. Luxbacher

Air Moving and Conditioning Association, Fan Application Manual Part 1, Fans and Systems, AMCA Publication 201, 1976a. Air Moving and Conditioning Association, Fan Application Manual Part 2, Troubleshooting, AMCA Publication 202, 1976b. Air Moving and Conditioning Association, Fan Application Manual Part 3, Field Performance Measurements, AMCA Publication 203, 1976c. Air Moving and Conditioning Association, Directory of Products Licensed to Bear the AMCA Certified Ratings Seal, Edition 27, August 1, 1975. Allan, A. L., Hollwey, J. R., and Maynes, J. H. B., Practical Field Surveying and Computations, American Elsevier Publishing Co., Inc., New York, 1968. American Society of Heating Refrigeration and Air Conditioning Engineers Std. 51-75, Air Moving and Conditioning Association Standard 210¬74, Laboratory Methods of Testing Fans for Rating. Anderson, T. C., and Nugent, J. W., "Mine Ventilation Pressure Differentials with a Programmable Hand Calculator," MESA Informational Report 1050, 1977. Atkinson, J. J., "On the Theory of the Ventilation of Mines," Trans. N. E. Inst., Vol. 3, 1854, pp. 118. Barnes, E. L. S., "Mine Ventilation Network Analysis," International Mine Ventilation Congress, Marshalltown, S. Africa, Sept., 1975. Boshkov, S, and Amontree, B., "How Operator Proximity Affects Anemometer Readings," Coal Age, Vol. 55, No. 5, 1950, pp. 85-56. Boshkov, S., and Wane, M. T., "Errors in Underground Air Measurements," Mining Engineering, Vol. 11, No. 7, November, 1955, pp. 1047-1053. Briggs, H., "The Underground Leakage of Air, Investigation of the Porosity Coefficient," Transaction of the Institution of Mining Engineers, Vol. 82, pp. 111-121. Brown, J. R., and Hinsley, F. B., "The Flow of Air in Bends and Straight Airways," Transaction of the Institution of Mining Engineers, Vol. 116, July, 1957, pp. 845-867. Burrows, J., "Measurement of Fan Pressures," Journal of the Mine Ventila¬tion Society of South Africa, Volume 27, No. 4, April 1974, pp. 57-63.

Jan 1, 1977

By J. D. Davis

Coke Since the beginning of manufacturing of metallurgical coke in the United States, which dates from about 1859, Pennsylvania has main tamed supremacy in coke production Available statistics for the year 1880 show an output of 3,338,300 short tons, which was neatly trebled by the end of the succeeding 10 years. From this time on the increase was steady, though not rapid, and in 1922 the total production was 13,991,892 tons, which is approximately 37 per cent of the total coke production of the United States. The main reason for the rapid development of the coke industry in Pennsylvania lies in the abundance of coals particularly adapted to beehive coking, for which purpose the Pittsburgh bed in the Connellsville district has long been looked upon as standard At first practically all metallurgical coke was made in beehive ovens, the only exception being the short lived and wasteful method of coking in piles, byproduct owns did not make then appearance until after 1893 The suitability of a beehive coking coal cannot be accurately predicted from its chemical analysis, but it can be said, perhaps, that the volatile matter should be about 32 per cent, and that the oxygen content should not be mole than 10 pet cent or less than 4 per cent The sulphur and phosphorus content should be small-not over 1 25 per cent sulphur and under 0 02 pen cent phosphorus-and the ash content should not be over 7 per cent The Pittsburgh bed at Connellsvnlle fills these requirements well, as may be seen from the following representative analysis. Analysts of coal from Pittsburgh bed Moisture 1 70 Volatile matter 31 10 Fixed carbon 59 80 Ash 7 40 Sulphur 0 85 B t u 13,990

Jan 1, 1928

By Lloyd A. Morley, Robert Stefanko

1. Anonymous (Berggewerkshaftliche Versuchsstrecke), "75 Jahre Berggewerkshaftliche Versuchsstrecke, 1894-1969," 1969. 2. Anonymous, British Symposium on Flameproofing and Intrinsic Safety, IEEE Conf. Report Series No. 3, 1962. 3. Anonymous (Ministry of Fuel and Power), "A Review of Electrical Research and Testing with Regard to Flame-Proof Enclosure and Intrinsic Safety of Electrical Apparatus and Circuits," 1943. 4. Australian Standard Specification, ASC-98, "Electrical Equipment for Explosive Atmospheres," 1970. 5. Belgium Standard Specification, Norme NBM 286, "concernant la protection par enveloppe antideflagrante," 1965. 6. Bossert, J.A., "Approval for Electrical Equipment for Hazard Locations," paper PCI 66-33, IEEE 16th Annual Petrol. and Chem. Ind. Conf., L. A., California, Sept. 15-17, 1969. 7. Bossert, J.A., "Intrinsic Safety in Canada," Electrical Safety Practices, ISA Monogram, vn. 112, 1969. ,8. British Standards, BS229, "Flameproof Enclosure of Electrical Apparatus," 1957. 9. British Standards, BS4683 Part 1, "Classification of Maximum Surface Temperatures," 1971. 10. British Standards, BS4683 Part 2, "The Construction and Testing of Flameproof Enclosures of Electrical Apparatus," 1971. 11. Brown, G.R., and Silver, S., "An Explosion Hazard Due to Inflam¬mation of Aluminum Particles in Flat Flanges of Flameproof Enclosures," CEAL No. 197, Canadian Explosive Atmospheres Labor¬atory, 1969. 12. Campbell, J.D., and Chudleigh, J.P., "Problems Encountered in Designing Electrical Systems for Hazardous Areas," paper PCI-69¬31, IEEE 16th Annual Petrol. and Chem. Ind. Conf., L. A., California, Sept. 15-17, 1969. 13. Canadian Standards Association, C22.2 No. 30, "Explosion-Proof Enclosures for Use in Class I Hazardous Locations." 14. Dainty, E.D., and Brown, G.R., "Explosion Gas Temperatures at the Entrance to Flanges of Enclosures Containing 8.5% Methane-Air Mixtures," CEAL No. 196, 1969.

Jan 1, 1974

Develop a safe, efficient filter for removing diesel particulate matter (soot) from the exhaust of underground mining machines equipped with water scrubbers. Approach The Bureau of Mines and the Donaldson Company, Inc., jointly developed a low-cost, disposable, pleated-media filter (PMF) system. The system is intended for use on Part 36 permissible equipment or other machines equipped with water scrubbers. The PMF is installed downstream of the water scrubber to take advantage of the cool exhaust produced by the water bath. This demonstration system was tested on three Jeffrey 4114 Ramcars and a Wagner LST-5 scoop at Utah Fuel Company's Skyline mine near Scofield, Utah. Figure 1 illustrates a clean filter element being inserted into the canister on the Ramcar. How It Works The PMF system consists of a water trap, an optional over-pressure relief valve, filter canister, and PMF Under normal operations exhaust from a vehicle equipped with a water scrubber is heavily laden with water, especially on immediate startup of the engine. The water trap is designed to remove most of the water droplets from the exhaust before they enter the PMF, thus improving PMF performance. The over-pressure valve is designed to limit the exhaust backpressure by venting off some exhaust gas before the: filter. It is attached to the water trap upstream of the PMF. Figure 2 illustrates and shows a break out sectional view of the location of the PMF on the Ramcar.

Jan 1, 1991

Only limited work has been reported in the literature about the use of latex in soil. Unisol 91 2,3 (a 9:l oil-latex emulsion made b International Synthetic Rubber Company) and Phil1ips Petroset4 geotechnic emulsions are surface soil stabilizers which penetrate a maximum of two inches, but do not reduce permeability. Diamond Alkali 5 found that styrene-butadiene rubber latex as a one percent latex-soil mixture reduced permeability to 0.7 from 21 feet per year under a head of twenty feet of brine. We have found no literature reference for use of latex as sealant at depth in the soil, although asphalt has been applied at depth using civil engineering methods6,7. Most of the materials investigated as soil sealants in the present work were latexes, although some studies were also conducted with a variety of inorganic and organic chemicals. Of the latexes tested, most were rubber but a few were plastic, e.g. polyvinyl chloride. Sealants examined in this investigation are listed individually in Table I with supplier, code number, and other pertinent information. The materials consisted of the following general classes with additional details as indicated: 1.Anionic latexes: a. styrene-butadiene copolymers and terpolymers (SBR) b. butadiene-acrylonitrile copolymer (Paracrils®) c. polyvinyl chloride homopolymers and copolymers (WC) d. ethylene-propylene terpolymer e. vinyl acetate homopolymers and copolymers (VA) f. acrylics (acrylate copolymers) g. 2-chlorobutadiene homopolymer (chloroprene) (prepared specially as cationic material coagulated by soil). 2. Water Soluble polymers: a. polyvinyl ether b. methylcellulose c. polyethyleneimines d. polyacrylic acid homopolymer e. copolymers and terpolymers with acrylic acid types (water soluble as sodium or ammonium salts) f. alginates g. monomers (for polymerization in soil, e.g. acrylamide)

Jan 1, 1972

By Thomas V. Falkie, R. Venkataramani

Anderson, L. B., 1963, "Multiple Regression Techniques Correlate Experimental Data," Chemical Engineering, V. 70, N. 12, pp. 223-228. Aubert, E. J., Lund, I. A., and Thomasell, A. J., 1959, "Some Objective Six-Hour Predictions Prepared by Statistical Methods," Journal of Meteorology, V. 16, pp. 436-46. Barrett, A. L., 1958, "Alternating Current in Continuous Mining," Mechanization, V. 22, N. 9, pp. 83-86. Bower, A. B., Jr., 1970, "Bit Design: Key to Coal Cutting," Coal Age, V. 75, N. 7, pp. 70-72. Bower, A. B., Jr., 1971, Personal Communication dated April 29, 1971; General Electric Company, Mining and Metallurgical Products Department, Detroit, Michigan. Burt, C., 1950, "Group Factor Analysis", British Journal of Statistical Psychology, V. 3, pp. 40-75. Cady, L., Gertler, M., Gottsch, L., and Woodbury, M., 1961, "The Factor Structure of Variables Concerned with Coronary Artery Disease", Behavioral Science, V. 6, pp. 37-41. Cattell, R. B., 1965, "Factor Analysis: An Introduction to Essentials I. The Purpose and Underlying Models," Biometrics, V. 21, N. 1, pp. 190-215. Christensen, R. W., Heins, R. W., Babcock, W., and Tonn, R., 1971, "The Effect of Material Properties on Materials Handling Processes," Six Month Technical Report, (August 1971) to Advanced Research Projects Agency, U. S. Department of Defense; The University of Wisconsin. Collins, G., 1961, "Factor Analysis," Journal of Advertising Research, V. 1, N. 5, pp. 28-37. Cooley, W. W., and Lohnes, P. R., 1962, Multivariate Procedures for the Behavioral Sciences, New York: John Wiley and Sons, Inc. Cree, J. 0., 1956, "Power for Continuous Mining," Mining Congress Journal, V. 42, N. 10, pp. 49-52. Draper, N. R., and Smith, H., 1966, Applied Regression Analysis, New York, John Wiley & Sons, Inc. Griffiths, J. C., 1966, "A Genetic Model for the Interpretive Petrology of Detrital Sediments," The Journal of Geology, V. 74, N. 5, pp. 655-672.

Jan 1, 1972

By Robert L. Chufo

The U.S. Department of Energy Pittsburgh Research Center,1 has developed and field tested a spatial, spectral sensor for measuring the thickness of mineral deposits. Knowledge of the dielectric constant of the material is not necessary because the electrical properties of the media are determined automatically along with the thickness or distance measurement. The technology was developed to measure the thickness of coal remaining in the roof and floor of a mine or the thickness of a coal pillar remaining between two mining entries for the purpose of guiding a mining machine. However, field tests have shown the new technique is equally valuable for measuring the thickness of each layer in a multilayer manmade structure such as highway paving or building foundations and the thickness of geological deposits other than coal, such as, salt, granite and sandstone. The noncontacting electromagnetic technique uses spatial modulation created by moving a simple dipole sensor antenna in a direction along each axes to be measured while the complex reflection coefficient is measured at multiple frequencies over a two-to-one bandwidth. The antenna motion imparts spatial modulation to the data and enables frequency domain signal processing to solve the problem of media, target and antenna dispersion. The technique overcomes the problem of multipath reflections from nearby metal structures and avoids the use of radio frequency absorbing material. In its present form the system measures material thickness of zero to over 3 m to within ±2.5 cm accuracy. The system parameters are variable to suit the application but for most applications default values of 40 cm antenna motion with measurements made at 401 frequencies from 0.6 to 1.4 GHz at each of 32 antenna positions with a power level of 0 dBm or less are more than adequate to provide a satisfactory signal-to noise ratio. In the range of 0 to 10 m the system operates in the continuous wave mode and by simply turning off the transmitter for ranges beyond 10 m the problems of time domain processing are entirely avoided. The technique can be implemented with a vector network analyzer, a servo controlled L-band antenna positioner, an IEEE488 bus controller and a process computer. An electronics package designed and constructed to operate in the harsh mining environment and providing 1, 2 or 3 dimensional image presentation is being evaluated as a replacement for the network analyzer. Key words: Ground penetration radar, Spatial, Spectral

By J. C. Franklin

An experiment was conducted by the U.S. Bureau of Mines and the Canada Centre for Mineral and Energy Technology (CANMET) to measure the emanation rate of radon from cemented unclassified mill tailings in two dewatered stopes of a uranium mine at Elliot Lake, Ontario, Canada. The radon was monitored upstream and downstream and in both stopes to determine the concentration in the stopes and the amount exhausted from both stopes. The emanation rate was determined to be 0.55 pCi/cm2 sec-1 from the mill tailings, which is approximately 1,000 times higher than the average flux in the mine before backfilling.

Jan 1, 1982

By Franklin D. Cooper

This chapter includes tables for 1979 that were not available in time for publication in the 1978-79 Minerals Yearbook, but it does not include corresponding tables for 1980. The value of raw nonfuel mineral output in 1980 was estimated at $24.8 billion, 8.5% above the 1979 value. Of the 21 metal commodities produced, quantitative output increased for 11 and decreased for 10. The values for 10 metals were up, 10 were down, and 1 was unchanged. Among the 47 non-metallic commodities produced, 14 showed quantitative increases, 32 declined, and 1 was unchanged. In terms of value, 32 nonmetallics increased, and 15 declined.

Jan 1, 1981

By T. A. Kubala

Electric discharge ignition has been reinvestigated in a modified Hartmann apparatus for lycopodium powder with air. Minimum stored energy to ignite air dispersions of lycopodium was 25 to 30 mj; ignition occurred with 1 gram of lycopodium dispersed into the 2.7-liter vessel. Ignition energy was measured as a function of the weight of powder used, although some reservations are expressed concerning the uniformity of the lycopodium-air mixtures. In particular, wall layers of lycopodium, remaining after dispersal of 1 gram of lycopodium, were as easily ignitable as the most easily ignited air dispersion. Thus, an unanswered question has arisen concerning the role of surface coatings in the flammability of all marginally ignitable mixtures.

Jan 1, 1981

By C. M. Frost

Crude shale oil produced during in situ retorting by the Bureau of Mines at Rock Springs, Wyo., was refined by three schemes. In the first, the crude oil was fractionated to raw naphtha and 400° F+ residuum. The residuum was hydrogenated over cobalt molybdate catalyst at 815° F and 1,100 psig. The blended raw and 160°-400° F hydrogenated naphthas were hydrodenitrified and then catalytically reformed. The 400° F+ hydrogenated oil was catalytically cracked. In the second scheme, the crude was hydrogenated over nickel-tungsten catalyst at 800° F and 1,500 psig. The hydrogenated fractions were processed by methods used in the first scheme. The third scheme resembled the second but, prior to hydrogenation, the crude was "hydrostabilized" over cobalt molybdate at 500° F and 500 psig. Yields of reformate and cat-cracked gasoline as volume-percents of the crude, and research-method octane numbers (with 3 ml TEL) for the three methods were as follows: First method, 32 pet reformate, 90 octane; 19.5 pct cracked gasoline, 99.2 octane. Second method, 29 pet reformate, 81.1 octane; 21.3 pct cracked gasoline, 99.6 octane. Third method, 28.2 pet reformate, 86 octane; 28.7 pct cracked gasoline, 95.9 octane.

Jan 1, 1974

By Jon K. Ahlness

The Bureau of Mines, in cooperation with the Institute of Mineral Research of Michigan Technological University, and the Upper Great Lakes Regional Commission, conducted an investigation of electronic sorting of native copper ore from Upper Michigan. This report is based on research by the Institute of Mineral Research under contract to the Bureau. The test program evaluated the use of belt and rotary sorters on various size and grade fractions of ore. Both plant-scale sorting and lab sorting tests were run. The plant sorting objectives were to determine the sortability of different ores and the efficiency of the electronic ore sorters. High-and low-grade ores from both conglomerate and amygdaloid types were separated into four size fractions. The two larger sizes were sorted on belt sorters and the two smaller ones on rotary sorters. Copper recoveries ranged from 20.0 pct from a feed grade of 0.40 pct to 80.3 pct from a feed grade of 1.08 pct. Lab sorting tests of conglomerate ore were run to determine the efficiency of a belt sorter equipped with a second sensing coil located above the belt and to determine the sorting characteristics of larger ore size fractions than those used in the plant sorting. Copper recoveries from the combined feed sizes ranged from 47.0 pct from a feed grade of 0.13 pct to 96.8 pct from a feed grade of 4.87 pct. For all the ore types except one, it was found that the copper recovery increased with the feed size.

Jan 1, 1980

By Charles W. Huggins

The Bureau of Mines investigated palygorskite, a natural asbestiform material, to accumulate knowledge that might serve as a foundation for future synthesis of a similar material. Unit cell, chemical analysis, DTA, TGA, optical constants, and electron microscopy data were obtained. Selected palygorskite samples of bettor than 97-percent purity were used to obtain this information. Chemical analysis revealed the following formula: (OH2)4 (OH)2 Ca0.01Fe0.02K0 .c3Mg2.10A12.00Si7.93020.3.91 H2O. The optical constants for sodium light are a = 1.522; S = 1.530; ?=1.533; biaxially (-). The following orthorhomibic unit cell constants were determined: ao = 12.690 A, Z = 2, bo = 17.857 A, Dx = 2.327. co = 5.207 A, Identical diffraction patterns resulted from the three palygorskite samples that were studied. X-ray, chemical, DTA, TGA, and optical data were compared with literature values for similar fibrous materials. X-ray diffraction lines were indexed. Several electron micrographs were made to compare the structures of palygorskite and attapulgite with that of chrysotile. The micrographs revealed extremely short laths for attapulgite, very long flexible laths for palygorskite, and tubular structure for chrysotile.

Jan 1, 1962

By J. H. Perry, D. W. Houseknecth, C. A. Kertis, A. T. Iannacchione

Major problems facing the development of coal and gas resources of the Hartshorne Coalbeds include the complex distribution of minable and unminable coal, high methane content and bed pressure, faulting, variations in degree of dip, presence of natural gas fields in associated sandstones, and legal problems, caused by local geologic characteris- tics, in identifying gas origin. This Bureau of Mines study provides pertinent geologic information for long-range planning of subsurface coal and gas production from the Hartshorne Coalbeds. Pittsburg, Coal, Hughes, and Atoka Counties, OK, have approximately 1 billion metric tons (1.1 billion short tons) of Hartshorne coal in place. The methane resource of Hartshorne Coalbeds is estimated at 9.2 billion m3 (325 billion ft3) and varies with overburden and rank, These estimates were compiled from gas well density logs, coal-core data, out- crop measurements, abandoned mine maps, and the literature. The Hartshorne Coalbeds represent a valuable coal and gas resource which at present is contributing nothing to coal and gas production. This report discusses potential problems and serves as a reference for future exploration and development work. Recognition of these potential geologically related problems prior to development of this basin will reduce hazards and allow for an economic recovery of these resources.

Jan 1, 1983

By J. C. Kerkering

The Bureau of Mines used mathematical reliability theory to define, for use in the mining industry, the concepts of risk, safety, reliability, hazard, and mean time between accidents. In this report, the definitions are explained theoretically and illustrated by application to actual underground mine accident data extending over a 9-1/2-year period. The theoretical development proceeds along two parallel analytical paths. For each line of reasoning, the data are presumed to be independent. If they are not, the analysis stops, although there are interesting implications when dependency is demonstrated. The first method uses the elapsed times between accidents as the basic data. These elapsed times are fitted to a negative exponential distribution function using least squares and yielding the function parameter, P1 The P1 is used to form the Poisson distribution function for the data, which is then used to define the safety-related concepts. The second method uses the maximum likelihood estimator to formulate a Poisson distribution function for the data. The function is tested for adequacy by a goodness-of-fit test; if the fit is acceptable, the Poison function is used to define the concepts. Both methods were applied to the data base, yielding nearly identical results.

Jan 1, 1987

By J. H. Jansky, P. W. Jeran, G. L. Hassett, M. C. Irani

This Bureau of Mines report tabulates methane emissions from U.S. bituminous coal mines with daily emission rates of at least 100,000 cfd according to States, counties, and coalbeds. Most of the methane emitted is from mines in the Appalachian States. Total daily emissionin 1975 was 216.3 MMcfd, compared with 227.0 MMcfd in 1971 and 214.5 MMcfd in 1973. Thirty counties in nine States had daily methane emissions of 1 MMcfd or more, These emitted 93 percent of the total methane. The highest emissions were from Monongalia County, W. Va,, which accounted for 18.9 percent of the total. This was followed by Marion County, W. Va., 9.6 percent; Buchanan County, Va., 8.5 percent; Jefferson County, Ala., 6.1 percent; and Washington County, Pa., 5.9 percent. The Pittsburgh coalbed emitted 45.7 percent of the total methane, followed by the Pocahontas No. 3 coalbed with 12.9 percent. The report lists 196 mines, of which 60 had daily methane emissions of 1 MMcfd or more. Included in this compilation are the identification and thickness of the coalbed, methane emission, coal production and ventilation rates, number of drifts, shafts, and slopes used for ventilation purposes, shaft depth, age of mine, and gas-to-coal ratio.

Jan 1, 1975

By John C. Edwards

The Bureau of Mines has developed a time-dependent mathematical model of radiative heating of bulkheads in mines. The model includes both reradiation from the duct (cylindrical) walls and direct radiation from the fire zone. Thermal loss into the wall of the duct and into the bulkhead is included. Both brick and wood bulkheads are considered. It is found that the heating rate of the system scales as the duct length-to-diameter ratio and the flame temperature. In particular, the time required for the irradiated surface of the bulkhead to reach a specified temperature decreases with increasing flame temperature for a fixed length-to-diameter ratio and increases with increasing length-to-diameter ratio for a specified flame temperature. It is also deter-mined that the time, T, for the bulkhead surface temperature to reach a specific value, Tb, for a fixed length-to-diameter ratio less than 4 and for a flame temperature of 1,200 K is approximately linearly dependent on Tb for 500 K < Tb < 700 K, and is nearly exponentially dependent on the length-to-diameter ratio for Tb = 600 and 700 K.

Jan 1, 1979

By H. S. Caldwell

This report describes work by the Bureau of Mines on the vacuum distilla¬tion of some of the more volatile metals such as cadmium, zinc, and magnesium from lead and tin. Evacuation within a distillation apparatus allows rapid diffusion of vapor away from the evaporation surface and prevents reaction of the vapor with residual gases. A reduction of pressure to several tenths of a millimeter makes possible practicable distillation rates, at temperatures for which the partial pressure of the metal vapor exceeds 10-3 atmosphere. The rate and selectivity of distillation depend primarily on the volatility and molal ratios of the alloy metals, and their chemical activity to each other. For very rapid evaporation or low concentration of the more volatile constituent, the rate is determined by the rate of diffusion of the evaporating metal, to the surface of the melt. Cadmium, zinc, magnesium, and tellurium were found to volatilize readily from both lead and tin. Tellurium appears to volatilize as an intermetallic compound rather than the pure metal. Antimony could not be removed from lead at 1,000° C.; the condensate was nearly all lead. Antimony, bismuth, and lead were removed from tin.

Jan 1, 1960